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| 3 | GUARDADO was put clear by JAVI LÓPEZ and he raced past the Villarreal 'keeper but struck his shot just beyond the far post. |
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| 9 | ADÚRIZ scuffed a simple chance. |
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| 10 | ADÚRIZ worked the ball to GUARDADO, RIKI collected his cross and kicked the ball within easy reach of ANDERSEN. |
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| 12 | GUARDADO's shot was well held by ANDERSEN. |
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| 13 | GOAL!! A one-handed save from the Villarreal 'keeper enabled GUARDADO to glance the ball into the empty net. (1-0 Deportivo) |
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| 14 | A cross from CAMPAÑA left DERDIYOK in plenty of space but he scuffed his shot. |
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| 15 | ADÚRIZ nodded the ball wide from just inside the area. |
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| 29 | A looping effort from CAPDEVILA was stopped by BETO. |
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| 30 | RIKI headed inches wide. |
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| 34 | A delightful save prevented GUARDADO from scoring an exceptional goal. |
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| 37 | A clever cross from FORLÁN, was tapped goalbound by DERDIYOK only for the Deportivo 'keeper to claw away. |
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| 44 | A mix up in the Villarreal defence enabled ADÚRIZ to blast an effort inches over. |
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| 45 | CAIO brought the ball round DOMINGUEZ and poked a weak shot well wide. |
| |
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| 48 | A fine ball from DOMINGUEZ on the left was collected by GUARDADO who scuffed his shot over. |
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| 49 | A fine piece of skill was ended by a good save by the oncoming BETO. |
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| 51 | An inswinging corner was fired into the arms of the 'keeper by DOMINGUEZ. |
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| 53 | A corner found ADÚRIZ who fired the ball just wide. |
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| 60 | JUAN RODRÍGUEZ beat two Villarreal players and thundered a great chance wide. |
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| 66 | A twenty-five yard drive from DERDIYOK caused BETO no problem. |
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| 70 | DIAMÉ beat EBOUÉ and flicked the ball to GUARDADO who blasted his shot wide. |
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| 72 | The referee yellow cards JUAN RODRÍGUEZ for a clinical tackle. |
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| 87 | A shot from HLEB was smothered by the Deportivo 'keeper. |
