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| 1 | FOMIN beat BEBÉ and fired the ball to LUIZ ADRIANO who toe-poked his shot wide. |
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| 3 | A fine run was ended by a good save by the advancing KHUDZHAMOV. |
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| 5 | A cross from STROBL left HLEB in lots of space but he fluffed his shot. |
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| 6 | The Villarreal 'keeper parried a lovely shot from LUIZ ADRIANO. |
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| 8 | DAWSON booked by the referee for a clinical challenge. |
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| 18 | The Villarreal 'keeper saved a beautiful shot from KOBIN. |
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| 21 | GOAL!! After being forced wide FORLÁN was able to hammer the ball in from the tightest of angles. (1-0 Villarreal) |
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| 24 | The Shakhtar 'keeper dived to his left to stop a fierce shot from Villarreal's CAPDEVILA. |
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| 28 | ILSINHO rifled an easy chance past the lefthand post. |
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| 36 | A strike from FORLÁN held little difficulty for the Shakhtar 'keeper. |
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| 37 | A corner was collected by FORLÁN who forced the ball wide. |
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| 39 | KHUDZHAMOV was able to claw away a tame header from GUÐJOHNSEN. |
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| 45+1 | HLEB's shot was well saved by the Shakhtar 'keeper. |
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| 47 | GOAL!! A long ball from JUAN had the Shakhtar defence back-pedalling and HLEB made the most of the opportunity with a lovely goal. (2-0 Villarreal) |
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| 49 | A twenty yard shot from LUIZ ADRIANO caused the Villarreal 'keeper little difficulty. |
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| 51 | JUAN booked for a high tackle. |
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| 52 | DERDIYOK was put clear by BEBÉ and he beat the 'keeper but drilled his shot inches wide. |
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| 60 | A free-kick from HLEB raced over the bar. |
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| 65 | KHUDZHAMOV managed to block a powerful effort. |
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| 77 | A clever pass from KRAVCHENKO, was flicked goalbound by SHEVCHUK only for the 'keeper to palm clear. |
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| 81 | FORLÁN booted the ball wide from the edge of the box. |
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| 90+1 | LUIZ ADRIANO ran onto a wonderful ball from FERNANDINHO but toe-poked his effort wide of the goal. |
