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| 13 | JUAN's header was well saved by the Villarreal 'keeper. |
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| 16 | The stunned Botafogo 'keeper was all agog as a backpass from LEANDRINHO dropped just wide. |
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| 19 | GOAL!! A quick free-kick allowed PÉREZ to knock the ball to CHECHU who hit a deadly shot into the net. (1-0 Villarreal) |
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| 25 | TRIGUEROS beat JUAN and placed the ball to PÉREZ who fumbled his shot wide. |
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| 26 | A neatly crafted pass from BRUNO, was blasted goalbound by MOI GÓMEZ only for JÉFFERSON to palm clear. |
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| 28 | MUSACCHIO brought the ball away from MÁRIO FERNANDES and flicked a poor shot well wide. |
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| 42 | JÉFFERSON saved a lovely strike from PÉREZ. |
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| 43 | A shot from TRIGUEROS was smothered by the Botafogo 'keeper. |
| |
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| 49 | PÉREZ drilled a looping shot wide from close range. |
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| 51 | A pin-point pass fell to AQUINO and his deadly shot floated narrowly wide. |
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| 53 | GOAL!! A goalmouth scramble culminated with PÉREZ blasting the ball into the net. (2-0 Villarreal) |
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| 56 | MARIO's shot beat the Botafogo 'keeper but rebounded off the Botafogo crossbar. |
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| 58 | PÉREZ rushed an easy chance. |
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| 60 | A shot from MOI GÓMEZ seemed a certain goal but the 'keeper managed to punch the ball clear. |
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| 62 | A mix up in the Botafogo defence enabled MUSACCHIO to hit an effort inches wide. |
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| 64 | A penalty box scramble resulted in PÉREZ driving a low shot wide. |
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| 67 | GOAL!! A quick-witted RONALDINHO pounced on a loose ball just inside the box and made no mistake. (2-1 Villarreal) |
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| 71 | GOAL!! An outswinging corner headed out by PAULINHO was fired into the net by AQUINO. (3-1 Villarreal) |
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| 78 | A fine ball from TRIGUEROS on the left fell to MUSACCHIO who scuffed his shot just wide. |
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| 79 | A shot from MORATA held little difficulty for the Botafogo 'keeper. |
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| 81 | CHECHU hoofed the ball wide from the edge of the box. |
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| 82 | VINÍCIUS ARAÚJO shot over. |
