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| Round 1 (22) Athletic Bilbao - Lokomotiv Atlético-MG - Marseille Boca Juniors - Shakhtar Celta Vigo - Ajax FC Porto - Wolves Leicester City - Independiente Lyon - Anderlecht Real Madrid - Monaco Torino - Everton Valencia - Milan West Ham United - Borussia Dortmund | Round 2 (23) Ajax - Real Madrid Anderlecht - Valencia Borussia Dortmund - FC Porto Everton - West Ham United Independiente - Atlético-MG Lokomotiv - Celta Vigo Marseille - Torino Milan - Lyon Monaco - Athletic Bilbao Shakhtar - Leicester City Wolves - Boca Juniors |
| Round 3 (24) Athletic Bilbao - Shakhtar Atlético-MG - Ajax Boca Juniors - Borussia Dortmund Celta Vigo - Milan FC Porto - Everton Leicester City - Wolves Lyon - Monaco Real Madrid - Marseille Torino - Lokomotiv Valencia - Independiente West Ham United - Anderlecht | Round 4 (25) Ajax - Valencia Anderlecht - Real Madrid Borussia Dortmund - Atlético-MG Everton - Leicester City Independiente - Lyon Lokomotiv - Boca Juniors Marseille - Athletic Bilbao Milan - FC Porto Monaco - Celta Vigo Shakhtar - West Ham United Wolves - Torino |
| Round 5 (26) Athletic Bilbao - Wolves Atlético-MG - Shakhtar Boca Juniors - Anderlecht Celta Vigo - Everton FC Porto - Ajax Leicester City - Borussia Dortmund Lyon - Marseille Real Madrid - Independiente Torino - Milan Valencia - Lokomotiv West Ham United - Monaco | Round 6 (27) Athletic Bilbao - Leicester City Boca Juniors - FC Porto Borussia Dortmund - Shakhtar Celta Vigo - Lyon Independiente - Ajax Marseille - Lokomotiv Monaco - Anderlecht Torino - Atlético-MG Valencia - Real Madrid West Ham United - Milan Wolves - Everton |
| Round 7 (28) Ajax - West Ham United Anderlecht - Marseille Atlético-MG - Boca Juniors Everton - Borussia Dortmund FC Porto - Athletic Bilbao Leicester City - Torino Lokomotiv - Independiente Lyon - Valencia Milan - Monaco Real Madrid - Celta Vigo Shakhtar - Wolves | Round 8 (29) Ajax - Lokomotiv Anderlecht - Milan Atlético-MG - Athletic Bilbao Borussia Dortmund - Wolves Everton - Real Madrid Independiente - Marseille Lyon - Leicester City Monaco - Shakhtar Torino - Boca Juniors Valencia - Celta Vigo West Ham United - FC Porto |
| Round 9 (30) Athletic Bilbao - Torino Boca Juniors - West Ham United Celta Vigo - Independiente FC Porto - Valencia Leicester City - Atlético-MG Lokomotiv - Anderlecht Marseille - Ajax Milan - Borussia Dortmund Real Madrid - Lyon Shakhtar - Everton Wolves - Monaco | Round 10 (31) Ajax - Everton Anderlecht - Wolves Celta Vigo - Athletic Bilbao Independiente - West Ham United Lokomotiv - Shakhtar Lyon - Boca Juniors Marseille - FC Porto Milan - Leicester City Monaco - Borussia Dortmund Real Madrid - Torino Valencia - Atlético-MG |
| Round 11 (32) Athletic Bilbao - Real Madrid Atlético-MG - Milan Boca Juniors - Ajax Borussia Dortmund - Valencia Everton - Anderlecht FC Porto - Independiente Leicester City - Celta Vigo Shakhtar - Marseille Torino - Monaco West Ham United - Lyon Wolves - Lokomotiv | Round 12 (33) Athletic Bilbao - Valencia Atlético-MG - Anderlecht Boca Juniors - Milan Borussia Dortmund - Lyon Everton - Lokomotiv FC Porto - Monaco Leicester City - Real Madrid Shakhtar - Independiente Torino - Celta Vigo West Ham United - Marseille Wolves - Ajax |
| Round 13 (34) Ajax - Shakhtar Anderlecht - Athletic Bilbao Celta Vigo - Boca Juniors Independiente - Wolves Lokomotiv - FC Porto Lyon - Torino Marseille - Borussia Dortmund Milan - Everton Monaco - Atlético-MG Real Madrid - West Ham United Valencia - Leicester City | Round 14 (35) Athletic Bilbao - Ajax Atlético-MG - Real Madrid Boca Juniors - Marseille Borussia Dortmund - Lokomotiv Everton - Independiente FC Porto - Celta Vigo Leicester City - Monaco Shakhtar - Lyon Torino - Anderlecht West Ham United - Valencia Wolves - Milan |
| Round 15 (36) Ajax - Borussia Dortmund Anderlecht - Leicester City Celta Vigo - Atlético-MG Independiente - Boca Juniors Lokomotiv - West Ham United Lyon - Athletic Bilbao Marseille - Wolves Milan - Shakhtar Monaco - Everton Real Madrid - FC Porto Valencia - Torino | Round 16 (37) Athletic Bilbao - Milan Atlético-MG - Lyon Boca Juniors - Monaco Borussia Dortmund - Independiente Everton - Marseille FC Porto - Anderlecht Leicester City - Lokomotiv Shakhtar - Real Madrid Torino - Ajax West Ham United - Celta Vigo Wolves - Valencia |
| Round 17 (38) Athletic Bilbao - Borussia Dortmund Atlético-MG - Lokomotiv Boca Juniors - Everton Celta Vigo - Anderlecht FC Porto - Shakhtar Leicester City - Marseille Lyon - Ajax Real Madrid - Milan Torino - Independiente Valencia - Monaco West Ham United - Wolves | Round 18 (39) Anderlecht - Borussia Dortmund Athletic Bilbao - West Ham United Atlético-MG - Everton Celta Vigo - Wolves Leicester City - Ajax Lyon - FC Porto Milan - Independiente Monaco - Marseille Real Madrid - Lokomotiv Torino - Shakhtar Valencia - Boca Juniors |
| Round 19 (40) Ajax - Monaco Boca Juniors - Real Madrid Borussia Dortmund - Celta Vigo Everton - Valencia FC Porto - Leicester City Independiente - Athletic Bilbao Lokomotiv - Lyon Marseille - Milan Shakhtar - Anderlecht West Ham United - Torino Wolves - Atlético-MG | Round 20 (41) Anderlecht - Independiente Athletic Bilbao - Boca Juniors Atlético-MG - FC Porto Celta Vigo - Marseille Leicester City - West Ham United Lyon - Everton Milan - Ajax Monaco - Lokomotiv Real Madrid - Wolves Torino - Borussia Dortmund Valencia - Shakhtar |
| Round 21 (42) Ajax - Anderlecht Boca Juniors - Leicester City Borussia Dortmund - Real Madrid Everton - Athletic Bilbao FC Porto - Torino Independiente - Monaco Lokomotiv - Milan Marseille - Valencia Shakhtar - Celta Vigo West Ham United - Atlético-MG Wolves - Lyon | |
| League rounds 22-42 (in brackets) are the respective return ties of rounds 1-21 above, i.e. round 42 is Anderlecht - Ajax, Athletic Bilbao - Everton etc. | |