| Round 3 | | Athletic Bilbao | 0 |
| | Half-time: | 0-2 | | Referee: | Ahmed 6½ | | Attendance: | 46,190 | | Possession: | 37%-63% | | Total shots: | 7-14 | | MoM: | Albelda | | TV: | highlights |
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| | (4-3-3): Pinto 6, Cicinho 7½, Mignot 8, Auriac 7, Scharner 6, Riseth 6½, Konstantinidis 6½, Yeste 6½, Blanco 6, Mista 6, McCarthy 6½ | | Arsenal | 2 | 5 Gilardino, 12og Riseth | | 23 Adriano | | (4-3-3): Ricardo 6½, Maicon 8, Antonio López 6½, Albelda 8½, Juan 7, Abidal 7, Schneider 7, Tymoschuk 7, Gilardino 7½, Adriano 6, Tévez 6½ | | Inter | 0 |
| | Half-time: | 0-1 | | Referee: | Miranda Torres 6½ | | Attendance: | 72,220 | | Possession: | 51%-49% | | Total shots: | 16-5 | | MoM: | Chiellini | | TV: | live |
| | 32 Totti | | (4-3-3): Akinfeev 7, Piqué 6½, Puyol 7, Chiellini 8½, Carragher 8, Pirlo 6½, Totti 7½, Xavi 6½, Drogba 7, Klose 6, Cristiano Ronaldo 7 | | Santos | 1 | 9 Renato | | 4 Deivid | | (4-3-3): McGregor 6½, Cafú 7½, Rool 7, Gilberto Silva 6½ (65 Leonardo 6½), Lugano 7, Domingos 6½, Paulo César 7, Renato 6½, Deivid 6½, Ricardinho 7½, Douglas 6 | | Juventus | 1 | 4 Quaresma | | Half-time: | 1-0 | | Referee: | Joslin 6½ | | Attendance: | 45,913 | | Possession: | 64%-36% | | Total shots: | 7-7 | | MoM: | Touré |
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| | (3-5-2): Van Der Sar 7, Escudé 7, Marquez 6½, Touré 7½, Hargreaves 6½, Xabi Alonso 6½, Shevchenko 6½, Gourcuff 7, Huntelaar 6½, Quaresma 6, Adebayor 5½ | | Chelsea | 0 |
| | 55 Larsson, 89 Walton | | (4-3-3): Coppola 7½, Bates 6, Bouma 6½ (61 Morrison 6), Smith 7, Beto 6½, Davis 6½, Dyer 7 (71 Walton 6), Boukhari 7, Crouch 6½, Shearer 6, Larsson 6 | | Monaco | 0 |
| | Half-time: | 0-1 | | Referee: | Dardenne 6½ | | Attendance: | 52,084 | | Possession: | 51%-49% | | Total shots: | 14-15 | | MoM: | Panucci |
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| | (4-3-3): Landreau 5, Eduardo 7, Garrido 6, Tainio 7½, Van Buyten 7, Berthod 7, Jenas 7½, Dejagah 6½, Recoba 6½, Rommedahl 6, Tuncay 6½ | | Fiorentina | 3 | 25 Esposito, 74 Esposito, 81 Panucci |
| | (4-3-3): Coutinho 5½, Panucci 7½, Favalli 7, Convey 7, Tacchinardi 7, Navarro 6½, Walasiak 6½, Esposito 7½, Donovan 6½, Johnson 6, Rivaldo 7 | | Newcastle United | 1 | 35 Jankulovski | | Half-time: | 1-2 | | Referee: | Wilkie 7 | | Attendance: | 36,807 | | Possession: | 52%-48% | | Total shots: | 13-14 | | MoM: | Robben | | TV: | highlights |
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| | (4-3-3): Given 6, Gallas 7, Jankulovski 7½, Van Bommel 7, Wheater 6, Edmílson 6, Kuijt 7½, Robben 7½, Van Nistelrooy 7½, Defoe 6, Odemwingie 6½ | | Lens | 3 | 15 Rothen, 42 Thomert, 71 Coulibaly | | 53 Rothen | | (4-4-2): Dida 6½, Gilberto 6, Beye 6½, Micoud 7½, Diagne-Faye 6, Coulibaly 6½, Luís Fabiano 7 (66 Eduardo 6), Thomert 6½, Appiah 5½, Rothen 6½, Giuly 7 (66 Dacourt 6) | | PSV | 1 | 72 Cocu | | Half-time: | 0-2 | | Referee: | Gómez 6½ | | Attendance: | 26,845 | | Possession: | 45%-55% | | Total shots: | 6-21 | | MoM: | Ferdinand |
| | 79 Tobiasen | | (4-3-3): Timmer 5½, Tobiasen 6, Thatcher 6½ (63 Cohen 6), Torrado 7, Addo 6½, Janssen 6, Maldonado 7, Cocu 7, Smolarek 6½, Lurling 6, Chevantón 6 | | Liverpool | 2 | 35 Ronaldinho, 41 Rooney |
| | (3-4-3): Cech 7½, Ferdinand 8, Vidic 6½, Pepe 7, Cambiasso 7, Fabregas 7½, Messi 6½, Robinho 7½, Rooney 7 (79 Ronaldo 7), Kaká 7, Ronaldinho 7 | | Paris SG | 3 | 17 Fernando Torres, 55 Fernando Torres, 81 Fernando Torres | | Half-time: | 1-0 | | Referee: | Mogosanu 7 | | Attendance: | 48,689 | | Possession: | 51%-49% | | Total shots: | 17-9 | | MoM: | Essien | | TV: | highlights |
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| | (4-4-2): Amelia 7, Daniel 7½, Milito 7, Essien 7½, Squillaci 6½, Marchena 7, Navas 7, Silva 7, Eto'o 7½, Fernando Torres 6½, Ribéry 7 | | São Paulo | 0 |
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| | (4-3-3): Gomes 7, André Bahia 5½, Arruabarrena 6½, Júlio Baptista 7, Cris 6½, Wescley 6½, Dalmat 6, Bruggink 6½, Kléber 6, Valerón 7 (69 Elmer 6), Nihat 7 | | Roma | 2 | 13 Iniesta, 33 Diarra | | Half-time: | 2-0 | | Referee: | Merk 5 | | Attendance: | 61,662 | | Possession: | 57%-43% | | Total shots: | 18-7 | | MoM: | Diarra | | TV: | live |
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| | (4-3-3): Buffon 7½, Sergio Ramos 7½, Evrà 7, Sneijder 7, Zaccardo 7½, Pablo 6, Schweinsteiger 7, Iniesta 7½, Benzema 6½, Diarra 8, Ibrahimovic 7½ | | VfB Stuttgart | 0 |
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| | (4-3-3): Quim 7, Jerez 6, Schulz 6½, Fahrenhorst 7½, Madlung 6½, Cimen 6, Dindane 6½, Ivanschitz 6, Inzaghi 6, Freier 5, Cacau 6½ | | Round 4 | | Arsenal | 3 | 4 Gilardino, 19p Gilardino, 21 Gilardino | | Half-time: | 3-1 | | Referee: | Vad 7½ | | Attendance: | 67,014 | | Possession: | 51%-49% | | Total shots: | 13-9 | | MoM: | Dedé |
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| | (4-3-3): Ricardo 6½, Maicon 7, Abidal 5½ (80 Dedé 8½), Albelda 6½, Juan 6½ (82 Ayala 6), Samuel 6½, Schneider 6½, Tymoschuk 6½, Gilardino 7, Adriano 6, Tévez 8 | | Sampdoria | 2 | 45 Bonazzoli, 90+2 Contini | | 36 Dalla Bona | | (4-3-3): Castellazzi 5, Oddo 7½, Maldini 7, Volpi 6½, Contini 7½, Pavan 6, Galletti 6½, Zauli 5½, Bonazzoli 6, Dalla Bona 6, Borriello 6½ | | Barcelona | 1 | 90 Hleb | | Half-time: | 0-0 | | Referee: | Grabher 6 | | Attendance: | 72,563 | | Possession: | 44%-56% | | Total shots: | 9-12 | | MoM: | Silva |
| | 68 Chivu | | (3-4-3): Reina 7½, Metzelder 7½, Cannavaro 7, Chivu 7, Del Piero 6, De Rossi 6½, Hleb 7, Seedorf 7½, Keane 6, Raúl 7½, Henry 7 | | Paris SG | 0 |
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| | (4-4-2): Amelia 7, Daniel 7½, Milito 6½, Essien 7, Squillaci 7 (90+1 Van Der Vaart 6), Marchena 7½, Navas 6½, Silva 8, Eto'o 6, Fernando Torres 6½, Ribéry 6 | | Chelsea | 1 | 29 Crouch | | Half-time: | 1-1 | | Referee: | Wieser 6½ | | Attendance: | 41,425 | | Possession: | 42%-58% | | Total shots: | 14-13 | | MoM: | Chiellini |
| | 32 Davis | | (4-3-3): Coppola 5½, Bates 6, Bouma 7, Smith 7½, Beto 6½, Davis 6½, Dyer 6½, Boukhari 6, Crouch 6, Shearer 6, Larsson 6½ | | Inter | 2 | 24 Cristiano Ronaldo, 84 Klose |
| | (4-3-3): Akinfeev 6, Piqué 7½, Puyol 7, Chiellini 8, Carragher 7½, Pirlo 6, Totti 7, Xavi 6½, Drogba 7, Klose 7, Cristiano Ronaldo 6½ | | Everton | 1 | 21 Pavón | | Half-time: | 1-0 | | Referee: | Barry 6½ | | Attendance: | 42,142 | | Possession: | 60%-40% | | Total shots: | 18-9 | | MoM: | Edman |
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| | (4-3-3): Simonsen 7½, Ferdinand 7½, Edman 8, Butt 7½, Pavón 7½, O'Brien 6½ (46 Ljungberg 6), Osman 7, Giggs 6, Maccarone 7, Montenegro 7, Helguson 6½ | | Athletic Bilbao | 1 | 71 Blanco | | 15 Blanco | | (4-3-3): Pinto 7½, Cicinho 7, Mignot 7, Auriac 6, Scharner 6½ (71 Alaña 6), Riseth 6½, Konstantinidis 6½, Yeste 5½, Blanco 7, Mista 6, McCarthy 5½ | | Lens | 1 | 69 Luís Fabiano | | Half-time: | 0-1 | | Referee: | Cleivaldo 6 | | Attendance: | 41,567 | | Possession: | 49%-51% | | Total shots: | 9-11 | | MoM: | Gilberto |
| | 17 Giuly | | (4-4-2): Dida 7, Gilberto 8½, Beye 8, Micoud 7, Diagne-Faye 7, Coulibaly 7, Luís Fabiano 6, Simão 6½ (66 Guilherme 6½), Appiah 6, Rothen 7, Giuly 6½ | | Real Madrid | 1 | 38 Pires |
| | (4-3-3): Stekelenburg 7, Johnson 6½, Kaladze 7½, Baraja 7, Givet 7½, Armand 7½, Bentley 7, Pires 7½, Aílton Almeida 6½, Renato 6½, Etxeberria 5½ | | Santos | 2 | 37 Deivid, 80 Deivid | | Half-time: | 1-0 | | Referee: | Tolga 6½ | | Attendance: | 28,018 | | Possession: | 55%-45% | | Total shots: | 14-9 | | MoM: | Cafú |
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| | (4-3-3): McGregor 6½, Cafú 8, Rool 6 (66 Derlei 6), Gilberto Silva 8, Lugano 7½, Domingos 6, Paulo César 7½, Renato 7, Deivid 7½, Ricardinho 7, Douglas 5½ | | Monaco | 1 | 65 Recoba |
| | (4-3-3): Landreau 7½, Eduardo 7, Garrido 7½, Tainio 7, Van Buyten 6½, Berthod 6½, Jenas 6, Dejagah 6½ (70 Owusu-Abeyie 6½), Recoba 6½, Rommedahl 5½, Tuncay 6 | | Sevilla | 0 |
| | Half-time: | 0-1 | | Referee: | Sedlacek 5½ | | Attendance: | 36,216 | | Possession: | 53%-47% | | Total shots: | 13-11 | | MoM: | Seitaridis |
| | 1 Casquero, 4 Aitor Ocio, 15 Seitaridis, 41 Martí | | (4-3-3): Ricardo 7, Seitaridis 8½, Helguera 6½, Casquero 7½, Aitor Ocio 7 (57 Edgar 6), Javi Navarro 6½, Rivera 6½, Ezquerro 6½, Riki 7½, Martí 7½, Kovacevic 7½ | | Cruzeiro | 1 | 43 Ibson |
| | (4-3-3): Rogério 7, Rogério 7½, Kléber 7½, Pedretti 7, Thiago 6½, André Luís 6½, Gavilán 7, Maciel 6½, Washington 6, Ibson 7, Phillips 6½ | | VfB Stuttgart | 2 | 2 Inzaghi, 89 Leko | | Half-time: | 1-0 | | Referee: | Ancion 7 | | Attendance: | 42,412 | | Possession: | 49%-51% | | Total shots: | 16-14 | | MoM: | Cohen |
| | 48 Ivanschitz | | (4-3-3): Quim 7, Jerez 7, Schulz 7½, Fahrenhorst 7½, Madlung 7, Cimen 7 (77 Niemeyer 6), Dindane 7½, Ivanschitz 6½, Inzaghi 6 (64 Leko 7), Freier 5½, Cacau 6 | | PSV | 1 | 64 Smolarek | | 69 Torrado | | (4-3-3): Timmer 7½, Tobiasen 7, Thatcher 6½ (63 Cohen 7½), Torrado 7, Addo 7, Janssen 6½, Maldonado 7, Cocu 6½, Smolarek 7, Lurling 6, Chevantón 6 |
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