| Round 3 | | Anderlecht | 3 | 75 Ambrosini, 78 Lange, 88 Ambrosini | | Half-time: | 0-0 | | Referee: | Goethals 6 | | Attendance: | 29,035 | | Possession: | 51%-49% | | Total shots: | 17-9 | | MoM: | Vermaelen | | TV: | highlights |
| | 13 Farías | | (4-3-3): Niemi 7, Tula 7, Vermaelen 8½, Sirieix 7½, Dheedene 7, Van Der Heyden 6½, Vlcek 6½, Ambrosini 7, Lange 7½, Farías 5½, Luis García 7½ | | SV Werder Bremen | 1 | 56 Banovic |
| | (4-3-3): Walke 6½, Stalteri 7½, Magnin 6½, Manuel Fernandes 6½, Friedrich 6½, Dogan 6, Varela 6½, Cani 6½, Gomez 6½, Banovic 6½, Klasnic 6½ | | Benfica | 0 |
| | Half-time: | 0-1 | | Referee: | Amendolia 5½ | | Attendance: | 35,106 | | Possession: | 46%-54% | | Total shots: | 10-17 | | MoM: | Taylor | | TV: | highlights |
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| | (4-3-3): Cavallero 5½, Caneira 8, Sorín 8, Petre 7, Tonel 7, Fernando Couto 7, Scaloni 7, Tello 7 (54 Bruno Basto 6½), Urzaiz 6, Wicky 6, Cafú 6 | | West Ham United | 3 | 30 Kepa, 61 Daugaard, 90+1 Galásek |
| | (4-3-3): Ramé 6½, Taylor 8, Maxwell 6 (84 Kluivert 6), King 7½, Jarque 7, Ooijer 6, Galásek 8, Ambrose 7½, Kepa 6½, Daugaard 7, Youla 6 | | Bologna | 1 | 45og Licata | | Half-time: | 1-1 | | Referee: | Arena 7 | | Attendance: | 40,452 | | Possession: | 51%-49% | | Total shots: | 14-12 | | MoM: | Faé | | TV: | live |
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| | (4-3-3): Roma 6½, Diana 7, Tonetto 6½ (86 Marcinho 8), Faé 8, Gamberini 7½, Castellini 6½, Luciano 6½, Pandev 7½, Amoruso 6½ (86 Dal Canto 6), Firmani 6½, Lodi 6 | | Bolton Wanderers | 2 | 3 Downing, 86 Warnock |
| | (4-3-3): Green 6, Hunt 6½, Warnock 6½, Licata 7, Silvestre 6, Cahill 6, Benayoun 6, Downing 7½, Borgetti 7 (86 Livesey 6), Walters 6, Townson 5½ | | Dinamo Zagreb | 0 |
| | Half-time: | 0-1 | | Referee: | Rayer 5½ | | Attendance: | 31,102 | | Possession: | 50%-50% | | Total shots: | 17-13 | | MoM: | Guti |
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| | (1-3-3-3): Vasilj 6½, Sedloski 7, Cale 7, Townsley 6½, Kébé 7, Tokic 7, Mikic 6½, Seol 7, Giovanni 7, Gondzic 6, Akalé 7 | | Celta Vigo | 1 | 35 Hasan | | 60 Tamudo | | (4-3-3): Almunia 6½, Neville 6½, Marcos 6½, Guti 7½, Murillo 6½, Contra 6½, Víctor 6½, Dani 6, Morientes 6, Tamudo 6, Hasan 6½ | | Mallorca | 1 | 57 Vicente | | Half-time: | 0-1 | | Referee: | Bolognino 7 | | Attendance: | 24,925 | | Possession: | 57%-43% | | Total shots: | 13-8 | | MoM: | Méndez | | TV: | highlights |
| | 65 Amaya | | (4-3-3): Leo Franco 6½, Vintra 7½, Capdevila 6½, Arzu 7, Josemi 7, Amaya 7, Joaquín 7½, Vicente 8, Iachtchouk 7, Serrano 5½, Tchite 7 | | Boca Juniors | 1 | 41 López |
| | (4-3-3): Hélton 7, Salihamidzic 7, Léo 7½, Ravenhill 6, Quiroga 7, Méndez 8, Ponzio 7, Romeo 6½, Cruz 6½, Delgado 5½, López 6½ | | Round 4 | | Ajax | 1 | 25 Makaay | | Half-time: | 1-1 | | Referee: | Borriello 6 | | Attendance: | 51,424 | | Possession: | 53%-47% | | Total shots: | 12-17 | | MoM: | Vermaelen |
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| | (4-3-3): Wapenaar 6, Torres 7½, Van Bronckhorst 6½, Van Der Gun 7½, Lacruz 7, Valgaeren 6, Norris 7, Sávio 7, Arizmendi 7, Wéldon 6½, Makaay 6½ | | Anderlecht | 3 | 2og Norris, 63 Ambrosini, 72 Vermaelen | | 59 Somers | | (4-3-3): Niemi 6, Tula 6½, Vermaelen 8, Sirieix 7, Dheedene 7, Van Der Heyden 6½, Vlcek 7½, Ambrosini 7, Lange 7, Somers 6, Luis García 5½ | | Auxerre | 2 | 9 Legear, 63 Ibagaza | | Half-time: | 1-0 | | Referee: | Braschi 7 | | Attendance: | 40,401 | | Possession: | 55%-45% | | Total shots: | 15-13 | | MoM: | Ibagaza |
| | 79 Song | | (4-3-3): Butelle 7, Lichtsteiner 7, Song 7, Ibagaza 8, Dellas 6½, Medjani 6, Smertin 7½, Kapo 7½, Luyindula 6½, Berson 7, Legear 7 | | Sporting | 1 | 73 Bernardi | | 29 Matteo, 37 Mantorras, 49 Hélder Postiga | | (4-3-3): Ten Rouwelaar 7, Alessandro 7, Matteo 7½, Verón 7½, Bernardi 6½, Parker 5½, Arteta 6½, Óscar Pérez 6, Nuno Gomes 6, Hélder Postiga 6½, Mantorras 6 | | Borussia Mönchengladbach | 2 | 16 Misimovic, 24 Róbson Ponte | | Half-time: | 2-1 | | Referee: | Cardona 6 | | Attendance: | 46,116 | | Possession: | 53%-47% | | Total shots: | 13-6 | | MoM: | De Ascentis |
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| | (4-3-3): Pröll 7, Fukal 5, Pander 7½, De Ascentis 8, Svensson 7, Strasser 7, Róbson Ponte 7½, Misimovic 7, Kahê 7, Kluge 6½, Neuville 6½ | | Mallorca | 1 | 37 Vicente | | 50 Amaya | | (4-3-3): Leo Franco 7, Vintra 6½, Capdevila 6½, Gaitán 6, Josemi 7, Amaya 6, Joaquín 7 (68 Arzu 7½), Vicente 7½, Iachtchouk 7½, Serrano 5½, Tchite 6 | | Boca Juniors | 0 |
| | Half-time: | 0-0 | | Referee: | Ceccarini 6 | | Attendance: | 44,330 | | Possession: | 38%-62% | | Total shots: | 12-11 | | MoM: | Salihamidzic |
| | 4 Romeo, 55 Ponzio | | (4-3-3): Hélton 6½, Salihamidzic 8, Léo 7, Ravenhill 7, Quiroga 6, Méndez 7, Ponzio 6, Romeo 6, Cruz 7½, Delgado 5½, López 6 | | Middlesbrough | 0 |
| | 70 Mulgrew | | (4-3-3): Schwarzer 7½, Brown 8, Higginbotham 6½, Jônatas 7½, Marcelo Mattos 7½, Mulgrew 6½, Bratu 6½, Park 7, Bellucci 7, Pecchia 6½, Giménez 6 | | Bolton Wanderers | 2 | 67 Downing, 73 Downing | | Half-time: | 0-0 | | Referee: | Cesari 7 | | Attendance: | 27,717 | | Possession: | 47%-53% | | Total shots: | 14-17 | | MoM: | Downing |
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| | (4-3-3): Green 8, Hunt 7, Warnock 6½, Licata 7, Silvestre 7½, Cahill 7, Benayoun 7, Downing 8, Borgetti 5½, Walters 6, Townson 5½ | | Benfica | 0 |
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| | (4-3-3): Cavallero 7½, Caneira 7½, Sorín 7, Petre 7, Tonel 7½, Fernando Couto 7, Scaloni 7, Tello 7½, Urzaiz 6, Wicky 6, Cafú 5½ | | Celta Vigo | 0 |
| | Half-time: | 0-1 | | Referee: | Zunic 6 | | Attendance: | 32,625 | | Possession: | 48%-52% | | Total shots: | 22-18 | | MoM: | Rodríguez |
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| | (4-3-3): Almunia 6, Neville 6½, Marcos 6½, Guti 7½, Murillo 6½, Contra 6, Víctor 8, Adem 5½, Morientes 7, Tamudo 6½, Hasan 6½ | | Milan | 2 | 38 Kuranyi, 82 Cannavaro | | 21 Emre, 29 Materazzi, 45+1 Del Horno | | (4-3-3): Howard 6½, Rodríguez 8½, Del Horno 8, Kovac 8, Materazzi 7½, Woodgate 6½, Izmailov 8½, Emre 7 (66 Cannavaro 6), Kuranyi 7, Pandiani 6½, Kezman 6½ | | Feyenoord | 2 | 7 Giménez, 43 Boumsong | | Half-time: | 2-0 | | Referee: | Stafoggia 5 | | Attendance: | 47,142 | | Possession: | 57%-43% | | Total shots: | 17-5 | | MoM: | Källström |
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| | (4-3-3): Penneteau 7½, Boulahrouz 7½, Nesmachnyi 8, Källström 8½, Boumsong 7, Kruiswijk 7, Castelen 6½, Giménez 8, Cissé 6½, Tomasson 6 (74 Rafael Sobis 7), Farnerud 6½ | | Dinamo Zagreb | 0 |
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| | (1-3-3-3): Butina 8, Sedloski 7, Cale 6½, Townsley 6, Kébé 6, Tokic 7½, Mikic 6½, Akalé 6½, Giovanni 6½, Gondzic 5½, Seol 5½ | | Hertha BSC Berlin | 0 |
| | Half-time: | 0-1 | | Referee: | Pellegrino 5½ | | Attendance: | 38,269 | | Possession: | 55%-45% | | Total shots: | 16-15 | | MoM: | O'Shea |
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| | (4-3-3): Moreira 6, O'Shea 8½, Queudrue 6, Flamini 7, Huth 7, Callsen-Bracker 6½, Balitsch 7, López 7 (75 Tiffert 6), Hanke 7½, Makélélé 7 (79 Lell 6), Vorobyei 6 | | Club Brugge | 2 | 43 Sonck, 79 Brogno | | 6 Meert, 14 Sonck, 47 Buffel, 54 Jorginho | | (4-3-3): Postulka 6½, Hoefkens 7½, Vandooren 7, Jorginho 7, Clement 7, Lembi 7, Polák 7, Meert 6, Sonck 6½, Buffel 7, Brogno 5½ | | Olympiakos | 0 |
| | Half-time: | 0-3 | | Referee: | Quartuccio 7 | | Attendance: | 33,875 | | Possession: | 45%-55% | | Total shots: | 13-13 | | MoM: | Faé |
| | 8 Kostoulas, 58 Djordjevic | | (4-3-3): Tochouroglou 5½, Torosidis 7, Seric 6, Gitas 7, Antzas 7 (48 Mavrogenidis 7), Kostoulas 6½, Giannakopoulos 6½, Djordjevic 6½, Palermo 7½, Choutos 5½, Nuñez 6 | | Bologna | 3 | 10og Antzas, 31 Pandev, 42 Pandev | | 71 Pandev | | (4-3-3): Roma 5½, Diana 8, Tonetto 8, Faé 8, Gamberini 7, Castellini 7, Luciano 6½, Pandev 7½, Amoruso 7½, Marcinho 5½, Lodi 6½ | | SV Werder Bremen | 2 | 17 Stalteri, 31 Klasnic | | Half-time: | 2-0 | | Referee: | Benkö 7½ | | Attendance: | 35,139 | | Possession: | 49%-51% | | Total shots: | 14-10 | | MoM: | Poulsen |
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| | (4-3-3): Walke 7, Stalteri 7, Magnin 7, Manuel Fernandes 7, Friedrich 7, Dogan 6½, Varela 6½, Cani 7½, Gomez 7½, Daun 6, Klasnic 6 | | Rosenborg | 0 |
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| | (4-3-3): Sørensen 7, Krøldrup 6½, Cagara 7, Poulsen 7½, Laursen 7½, Hangeland 6, Nilsson 6, Jørgensen 7, Carew 5½, Elmander 6½, Pedersen 6 | | West Ham United | 0 |
| | Half-time: | 0-0 | | Referee: | Blareau 6½ | | Attendance: | 25,970 | | Possession: | 51%-49% | | Total shots: | 19-9 | | MoM: | James |
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| | (4-3-3): Ramé 7½, Taylor 7 (72 Rodriguez 7), Maxwell 7½, King 6½, Jarque 7, Ooijer 6, Galásek 7, Ambrose 6½, Kepa 7½, Daugaard 7 (65 Kluivert 7), Youla 6½ | | Manchester United | 0 |
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| | (4-3-3): James 8, Neville 7½, Michel Salgado 6½, De Jong 6, Bassong 6½, Ernst 6, Anita 6½, Petrov 7, Pizarro 7½, Cavenaghi 6, Johnson 6 |
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