| Round 3 | | Bayer Leverkusen | 2 | 16 Schwegler, 22 Kiessling | | Half-time: | 2-1 | | Referee: | Angelov 5 | | Attendance: | 22,479 | | Possession: | 51%-49% | | Total shots: | 16-10 | | MoM: | Barnetta | | TV: | live |
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| | (4-3-3): Bossio 6½, Castro 7½, Gresko 7½, Rolfes 7½, Haggui 7, Sinkiewicz 6½, Frings 6½, Barnetta 8, Kiessling 7, Schwegler 6, Bulykin 5½ | | Trabzonspor | 2 | 41 Necati, 90+3 Necati |
| | (4-3-3): Fevzi 6½, Ali Eren 6½, Fábio Aurélio 7½, Barton 7½, Ufuk 7, Gustavo Nery Sá 6½, Ayhan 6, Alex 7, Necati 6½, Loskov 6, Ereros 5½ | | Lazio | 5 | 3 Paro, 42 Felipe, 54 Luizăo, 63 Paro, 88p Bellamy | | Half-time: | 2-0 | | Referee: | Sars 6½ | | Attendance: | 41,385 | | Possession: | 52%-48% | | Total shots: | 17-14 | | MoM: | Paro |
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| | (4-3-3): Mondragón 6½, Leonardo Moura 4½ (71 Bayly 7), Grosso 7½, Zanetti 7, Luizăo 7½, Vranjes 7 (76 Lustenberger 6), Almirón 7½, Felipe 6, Bellamy 7½, Paro 7½, Frei 6½ | | FK Austria | 2 | 69 Linz, 77 Linz | | 58 Linz | | (4-3-3): Didulica 6, Dospel 7, Troyanski 5½, Blanchard 6, Antonsson 6½, Kiesenebner 6, Sionko 6, Janocko 7, Linz 7, Vachousek 6, Rushfeldt 6½ | | Panathinaikos | 0 |
| | Half-time: | 0-1 | | Referee: | Sundell 6½ | | Attendance: | 43,005 | | Possession: | 46%-54% | | Total shots: | 12-14 | | MoM: | Iarley |
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| | (4-3-3): Nikopolidis 6½, Serrizuela 7, Van Boxel 5, Iarley 7½, Goumas 7, Karagounis 6, Belluschi 7, Basinas 6, Llorente 7, Volkan 6½, Radzinski 5½ | | Kaiserslautern | 2 | 40 Kruska, 85 Yelen | | 78 Pimenov | | (1-3-3-3): Lehmann 6½, Owomoyela 7, Müller 7, Kruska 6½ (60 Stark 7), Baránek 6, Ümit 7, Kovac 7½, Pimenov 7, Floro Flores 6½, Yelen 7, Yakin 7 | | Real Betis | 2 | 33p Robert, 54 Gutiérrez | | Half-time: | 1-0 | | Referee: | Meese 7½ | | Attendance: | 34,642 | | Possession: | 51%-49% | | Total shots: | 11-9 | | MoM: | Krznar | | TV: | highlights |
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| | (4-3-3): Prats 7, Kvarme 7, Pasqual 7, Karhan 7½, Marc Torrejón 7½, Lequi 7, Husev 7½, Gutiérrez 6 (58 Krznar 7½), Robert 7½, Nenę 6, Salva 5½ | | Napoli | 1 | 52 Sosa |
| | (4-3-3): Cudicini 7, Manfredini 6½, Bertotto 7, Locatelli 7, Stendardo 7, Zamboni 6½, Fábio Simplício 7, Bisgaard 6½, Sosa 5½, Liverani 5½, Warley 5½ | | Valencia | 4 | 13 Doni, 27 Gekas, 53 Gekas, 83 Morrison | | Half-time: | 2-0 | | Referee: | Piraux 7½ | | Attendance: | 31,508 | | Possession: | 50%-50% | | Total shots: | 15-12 | | MoM: | José Enrique |
| | 5 Doni, 51 Zanchi | | (4-3-3): Palop 7½, Faubert 6, Scardina 7½, Fernando 7, Oleguer 7, Yahia 6½, Gerardo 6½, Doni 5 (74 Morrison 6), Gekas 7, Batista 5½, Zanchi 5½ | | Deportivo | 0 |
| | 88 Xisco | | (4-3-3): Katergiannakis 7, Iraola 8, José Enrique 8, Giannichedda 7½, Ricardo Rocha 6½, Fiore 6, Marney 6½ (55 Parfonov 5½), Xisco 6, Sanogo 6½, Motta 7, Valdo 6½ | | Round 4 | | Deportivo | 1 | 15 Xisco | | | 17 Xisco | | (4-3-3): Katergiannakis 6½, Iraola 7, José Enrique 7½, Fiore 7, Ricardo Rocha 8, Parfonov 6½, Marney 6½ (51 Canobbio 7), Xisco 6½, Sanogo 7½, Valdo 5½, Giannichedda 6½ | | Atlético Madrid | 1 | 11 Rossato | | 19 Fábio Júnior | | (4-3-3): Tońo 6, Diogo 7, Dorado 7, Javi García 6½, Gaspar 7, Maínz 6, Varela 7½, Rossato 6, Fábio Júnior 7, Caggiano 6, Edú 6 | | FC Schalke 04 | 2 | 39 Simunic, 80 Charisteas | | Half-time: | 1-0 | | Referee: | Bogdanov 6 | | Attendance: | 47,450 | | Possession: | 39%-61% | | Total shots: | 10-17 | | MoM: | Pichot |
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| | (4-3-3): Schober 7½, Fritz 7, Simunic 6½, Lincoln 7, Van Kerckhoven 7, Alex 5½, Gentner 7, Hajnal 6, Charisteas 6, Lokvenc 6, Halil 5½ | | Metz | 0 |
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| | (4-3-3): Levitskyi 6½, Pichot 8, Wendell 7½, Proment 6½ (62 Jager 6), Rozehnal 7, Grichting 6, Bastien 7, Keita 7½, Jestrovic 7, Aliadičre 6½, Baros 7 | | Flamengo | 2 | 59 Marcelinho, 64 Fathi | | Half-time: | 0-1 | | Referee: | Momirov 6 | | Attendance: | 39,821 | | Possession: | 50%-50% | | Total shots: | 12-8 | | MoM: | Neru |
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| | (4-3-3): Vermeer 6½, Belletti 7, Fathi 6½, Edu 7½, Ânderson Polga 6, Cadú 6½, Watson 6½, Marcelinho 7, Braaten 7½, Júnior 6, Adúriz 5½ | | Racing Santander | 1 | 22 Neru | | 8 Moratón, 16 Itandje | | (4-3-3): Itandje 6½, Pinillos 7½, Neru 8, Felipe Melo 7½, Rubén 6, Moratón 6½, Balboa 6½, Iriney 7, Zigic 6½, Colsa 6½, Rubén 6 | | Galatasaray | 1 | 75 Semih | | Half-time: | 0-0 | | Referee: | Christensen 7½ | | Attendance: | 39,917 | | Possession: | 43%-57% | | Total shots: | 11-15 | | MoM: | Kiessling |
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| | (4-3-3): Berti 6, Alvarez 7, Ergün 6½, Mladenov 7½, Randrup 6½, Emrah 6, Okan 7, Gökdeniz 6½, Semih 6½, Delporte 5½, Niyazi Serhat 7 | | Bayer Leverkusen | 2 | 56 Kiessling, 73 Rolfes |
| | (4-3-3): Bossio 6, Castro 6½, Gresko 7½, Rolfes 7, Haggui 7½, Sinkiewicz 6½, Frings 7, Barnetta 7, Kiessling 7½, Schwegler 6½, Bulykin 6 | | Gręmio | 1 | 76 Roberto Carlos | | Half-time: | 0-0 | | Referee: | Damgaard 6½ | | Attendance: | 41,662 | | Possession: | 55%-45% | | Total shots: | 14-16 | | MoM: | Lachambre | | TV: | highlights |
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| | (4-3-3): Ochoa 8, Bosingwa 8, Roberto Carlos 6, Raul Meireles 8, Miguel Veloso 8, Ivanovic 7½, Giovani 7½, Sánchez 7½, Hladkyi 6½, Marcos Assunçao 6½, Piatti 6 | | Roda JC | 0 |
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| | (4-3-3): Jevric 7, Sonkaya 7, Lachambre 8½, Sergio 7, Stefanovic 7, Vicelich 5, Van Mieghem 6½, Meeuwis 7, Torma 6, Van Dessel 6, Cristiano 6½ | | Kaiserslautern | 1 | 53 Kovac | | Half-time: | 0-2 | | Referee: | Batta 6½ | | Attendance: | 41,918 | | Possession: | 41%-59% | | Total shots: | 11-15 | | MoM: | Husev |
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| | (1-3-3-3): Lehmann 6½, Owomoyela 6½, Müller 6½, Kruska 7, Baránek 6½, Ümit 6½, Kovac 7½, Pimenov 7½, Floro Flores 6½, Yelen 6½, Yakin 6½ (56 Reuter 6) | | Real Betis | 2 | 10 Karhan, 38 Gutiérrez |
| | (4-3-3): Prats 7, Kvarme 8, Pasqual 7½, Karhan 8, Marc Torrejón 7½, Lequi 7, Husev 8, Gutiérrez 6½ (58 Krznar 7), Robert 7, Nenę 6, Salva 5½ | | Lokomotiv | 1 | 37p Sychev | | Half-time: | 1-0 | | Referee: | Leduc 6 | | Attendance: | 29,984 | | Possession: | 62%-38% | | Total shots: | 26-8 | | MoM: | Jiránek |
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| | (4-3-3): Gabulov 6½, Jiránek 8, Spahic 7½, Kalynychenko 7, Sennikov 6½, Had 6, Bystrov 8, Bilyaletdinov 7½, Sychev 7, Kingston 6½, O'Connor 6 | | Blackburn Rovers | 1 | 46 Roberts | | 30 Derbyshire | | (4-3-3): Friedel 7, Emerton 7½, Taylor 6½, Savage 6, Samba 7, Nelsen 6½, Reid 7½, Peter 6, Roberts 6½, Mokoena 6, Derbyshire 5½ | | Lyon | 1 | 71 Giménez | | Half-time: | 0-0 | | Referee: | Suker 7 | | Attendance: | 34,673 | | Possession: | 48%-52% | | Total shots: | 13-17 | | MoM: | Cana |
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| | (4-3-3): Vercoutre 7, Clerc 7, Cesar 7½, Cana 8, Méité 6, Modesto 6, Oruma 6½, Faty 6½ (86 Keogh 6), Piquionne 7½, Maoulida 6½, Giménez 6½ | | Bordeaux | 2 | 85 Bugnet, 87 Álvarez |
| | (4-4-2): Richert 6, Fanni 7½, Cufré 7½, Batllčs 6½, Planus 7 (88 Jay 6), Maietta 6½, Black 7, Ledesma 6½, Bugnet 6½, Lachor 6, Álvarez 6 | | Napoli | 1 | 80 Warley | | Half-time: | 0-1 | | Referee: | Gallagher 7 | | Attendance: | 34,503 | | Possession: | 50%-50% | | Total shots: | 13-13 | | MoM: | Faubert |
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| | (4-3-3): Cudicini 7, Manfredini 7½, Bertotto 7½, Locatelli 6½, Stendardo 6½, Zamboni 6, Fábio Simplício 7, Bisgaard 7, Sosa 7, Liverani 5½, Warley 6 | | Valencia | 1 | 22 Gekas | | 41 Gekas | | (4-3-3): Palop 7½, Faubert 8, Scardina 7½, Leca 7, Oleguer 6½, Yahia 6½, Gerardo 7½, Doni 8, Gekas 7, Batista 6½, Weston 5½ | | Trabzonspor | 3 | 70 Alex, 74 Alex, 84 Ayhan | | Half-time: | 0-0 | | Referee: | Puentes Leira 6½ | | Attendance: | 29,905 | | Possession: | 52%-48% | | Total shots: | 20-10 | | MoM: | Necati |
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| | (4-3-3): Fevzi 6½, Ali Eren 7½, Fábio Aurélio 7½, Barton 7, Ufuk 7½, Gustavo Nery Sá 6½, Ayhan 7½, Alex 5½ (85 Yasin 6), Necati 7½, Loskov 6½, Ereros 5½ | | Lazio | 2 | 56 Felipe, 71 Bellamy |
| | (4-3-3): Mondragón 6½, Leonardo Moura 7 (72 Bayly 6), Grosso 7, Zanetti 7½, Luizăo 6½, Vranjes 5½, Almirón 7, Felipe 7, Bellamy 7½, Paro 6½, Frei 6 |
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