| Round 5 | | Anderlecht | 3 | 24 Lange, 41 Lange, 51 Lange | | Half-time: | 2-0 | | Referee: | Quartuccio 5 | | Attendance: | 28,976 | | Possession: | 51%-49% | | Total shots: | 14-10 | | MoM: | Palermo | | TV: | highlights |
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| | (4-3-3): Niemi 7, Tula 5½ (52 Neuendorf 6½), Vermaelen 7, Sirieix 7, Dheedene 7, Mansouri 6, Vlcek 7½, Ambrosini 7½, Lange 7, Farías 6½, Luis García 7 (80 Van Der Heyden 6) | | Olympiakos | 1 | 48p Palermo | | 2 Antzas, 32 Torosidis | | (4-3-3): Tochouroglou 6½, Torosidis 5½, Seric 7, Gitas 6, Antzas 7 (48 Mavrogenidis 6½), Kostoulas 6, Giannakopoulos 6½, Djordjevic 7, Palermo 7½, Choutos 5½, Nuńez 6 | | Benfica | 2 | 41 Tonel, 82 Ronaldo | |
| | (4-3-3): Cavallero 7½, Scaloni 8, Sorín 7½, Titov 8, Tonel 8, Fernando Couto 7, Frechaut 6½, Tello 6½, Urzaiz 6½, Wicky 7, Ronaldo 7 | | SV Werder Bremen | 1 | 16 Cani | | 39 Cani | | (4-3-3): Walke 7½, Stalteri 7 (50 Säumel 6), Magnin 7, Manuel Fernandes 7½, Dogan 7, Zivkovic 6, Varela 7½, Cani 6½, Gomez 6½, Amanatidis 6, Klasnic 6 | | Bologna | 1 | 78p Helstad | | Half-time: | 0-0 | | Referee: | Norman 6 | | Attendance: | 40,440 | | Possession: | 51%-49% | | Total shots: | 12-15 | | MoM: | Fukal |
| | 5 Luciano, 15 Faé, 54 Pandev, 80 Helstad | | (4-3-3): Roma 7, Diana 7, Tonetto 7½, Faé 6½, Gamberini 6½, Castellini 6½, Luciano 7, Pandev 7, Helstad 7, Firmani 6½, Lodi 6 | | Borussia Mönchengladbach | 1 | 55 Svensson | | 11 Kahę, 41 Róbson Ponte, 77 Strasser | | (4-3-3): Pröll 7, Fukal 8, Pander 7, De Ascentis 7½, Svensson 7½, Strasser 6½, Róbson Ponte 6½, Misimovic 6½, Kahę 7, Kluge 7, Neuville 5½ | | Club Brugge | 1 | 55 Sonck | | Half-time: | 0-0 | | Referee: | Bettin 5½ | | Attendance: | 18,288 | | Possession: | 47%-53% | | Total shots: | 11-7 | | MoM: | Källström | | TV: | live |
| | 47 Polák, 57 Buffel | | (4-3-3): Postulka 7½, Hoefkens 7, Vandooren 7, Buffel 7, Clement 7, Lembi 5½, Polák 6½, Meert 7½, Sonck 7, Cavens 6, Jorginho 6½ | | Feyenoord | 0 |
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| | (4-3-3): Penneteau 7, Paulo Ferreira 5½, Nesmachnyi 7½, Källström 8, Boulahrouz 6½, Boumsong 6, Castelen 7 (71 Rufete 7), Giménez 7, Milevskyi 6½, Barreto 5½, Rafael Sobis 6 | | Dinamo Zagreb | 1 | 82 Cale | | Half-time: | 0-2 | | Referee: | Racalbuto 5½ | | Attendance: | 25,855 | | Possession: | 51%-49% | | Total shots: | 16-14 | | MoM: | Gardner | | TV: | highlights |
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| | (1-3-3-3): Butina 5½, Sedloski 6½, Cale 7½, Townsley 7½, Kébé 6½, Tokic 7, Mikic 7, Akalé 6½, Giovanni 7, Gondzic 6, Seol 6½ | | Bolton Wanderers | 4 | 9 Downing, 27 Borgetti, 63 Downing, 74 Pischorn |
| | (4-3-3): Green 6, Hunt 7, Gardner 8½, Nolan 7½, Silvestre 7, Pischorn 6½, Benayoun 7½, Downing 6½ (71 Livesey 6), Borgetti 7, Walters 6, Townson 6 | | Mallorca | 1 | 29 Vintra | | Half-time: | 1-0 | | Referee: | Miranda 7½ | | Attendance: | 24,847 | | Possession: | 56%-44% | | Total shots: | 19-16 | | MoM: | Arzu |
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| | (4-3-3): Leo Franco 8, Vintra 7, Capdevila 8, Arzu 8½, Josemi 7, Murat 6½ (54 Di Salvo 6½), Joaquín 7, Vicente 7½, Iachtchouk 7, Gaitán 7, Tchite 6½ | | Celta Vigo | 0 |
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| | (4-3-3): Almunia 8, Neville 7½, Fernando 8, Guti 7, Hasan 6½, Contra 6½, Víctor 6½, Adem 5½, Morientes 7½, Tamudo 6½, Dani 5½ | | Manchester United | 1 | 64 Neville | | Half-time: | 0-2 | | Referee: | Michel 7½ | | Attendance: | 47,862 | | Possession: | 41%-59% | | Total shots: | 14-11 | | MoM: | Neville |
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| | (4-3-3): James 6½, Neville 7½, Michel Salgado 6½, De Jong 7, Bassong 6, Ernst 6, Anita 6, Petrov 6½, Pizarro 6½, Cavenaghi 5½, Johnson 6½ | | Auxerre | 2 | 18 Luyindula, 45+1 Kapo |
| | (4-3-3): Butelle 6½, Lichtsteiner 6, Song 7½, Ibagaza 6½, Dellas 6½, Medjani 6½, Smertin 6½, Kapo 7½, Luyindula 7, Berson 6½, Legear 6½ | | Middlesbrough | 0 |
| | Half-time: | 0-2 | | Referee: | Pinto Correia 6½ | | Attendance: | 34,834 | | Possession: | 51%-49% | | Total shots: | 15-18 | | MoM: | Bratu |
| | 78 Schwarzer | | (4-3-3): Schwarzer 5, Brown 7, Higginbotham 6½, Jônatas 6½, Marcelo Mattos 6½, Mulgrew 6, Bratu 8½, Park 7, Bellucci 7½, Pecchia 6½, Giménez 5½ | | West Ham United | 5 | 2 Galásek, 29 Jarque, 49 Ambrose, 63 Maxwell, 83p Kepa | | 44 Daugaard | | (4-3-3): Ramé 5½, Taylor 7½, Maxwell 6 (84 Kluivert 6), King 7½, Jarque 7, Ooijer 6½, Galásek 6½, Ambrose 6½, Kepa 7, Daugaard 6½, Youla 6½ | | Milan | 2 | 16 Emre, 63p Kuranyi | | Half-time: | 1-1 | | Referee: | Grabher 5 | | Attendance: | 48,216 | | Possession: | 54%-46% | | Total shots: | 11-15 | | MoM: | Rodríguez |
| | 85 Hofland | | (4-3-3): Howard 6½, Rodríguez 8½, Del Horno 7½, Kovac 8, Materazzi 7½, Hofland 6½, Izmailov 6 (59 Cannavaro 7), Emre 6½, Kuranyi 7, Pandiani 6, Kezman 6½ | | Ajax | 1 | 21 Makaay | | 3 Valgaeren, 31 Arizmendi, 62 Wapenaar | | (4-3-3): Wapenaar 6½, Lacruz 7½, Van Bronckhorst 7, Knopper 7, Torres 6½, Valgaeren 5½, Norris 6½, Sávio 6½, Arizmendi 6½, Wéldon 6½ (69 Yakubu 6), Makaay 7 | | Rosenborg | 0 |
| | Half-time: | 0-1 | | Referee: | Braamhaar 6½ | | Attendance: | 39,888 | | Possession: | 45%-55% | | Total shots: | 16-15 | | MoM: | Pizarro |
| | 47 Poulsen | | (4-3-3): Sřrensen 6½, Krřldrup 6½, Cagara 6½, Poulsen 7, Laursen 7, Hangeland 6½, Nilsson 6½, Jřrgensen 7, Carew 7, Elmander 6½, Pedersen 6 | | Boca Juniors | 1 | 44 Pizarro | | 50 Romeo, 66 Delgado, 87 Cruz | | (4-3-3): Hélton 7½, Salihamidzic 7, Léo 7½, Pizarro 7½, Quiroga 7, Méndez 6½, Ponzio 6½, Romeo 6, Cruz 6½, Delgado 6, López 6½ | | Sporting | 0 |
| | Half-time: | 0-1 | | Referee: | Willard 7 | | Attendance: | 39,388 | | Possession: | 50%-50% | | Total shots: | 12-21 | | MoM: | Verón | | TV: | highlights |
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| | (4-3-3): Karcemarskas 6, Alessandro 7, Heinze 7, Verón 8, Matteo 6½, Parker 6, Arteta 7½, Óscar Pérez 6½, Nuno Gomes 6½, Bernardi 6, Beattie 7 | | Hertha BSC Berlin | 2 | 15 Hanke, 47 Sergio | | 70 Trochowski | | (4-3-3): Moreira 6, O'Shea 7, Queudrue 6½ (74 Ziegler 6), Makélélé 7, Kuffour 6½, Lell 6, Balitsch 7½, Trochowski 6½, Hanke 7½, Sergio 7, Vorobyei 7½ |
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