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| Round 1 (22) AEK - Fiorentina Deportivo - Shakhtar Espanyol - Bayern München Hamburger SV - Newcastle United Middlesbrough - Benfica Paris SG - Independiente Real Betis - Feyenoord Spartak - Manchester City Udinese - Aston Villa Valencia - Roma Villarreal - PSV | Round 2 (23) Aston Villa - Middlesbrough Bayern München - AEK Benfica - Hamburger SV Feyenoord - Paris SG Fiorentina - Villarreal Independiente - Spartak Manchester City - Espanyol Newcastle United - Udinese PSV - Real Betis Roma - Deportivo Shakhtar - Valencia |
| Round 3 (24) AEK - Manchester City Deportivo - Aston Villa Espanyol - Independiente Hamburger SV - Roma Middlesbrough - Bayern München Paris SG - Shakhtar Real Betis - Benfica Spartak - Feyenoord Udinese - PSV Valencia - Fiorentina Villarreal - Newcastle United | Round 4 (25) Aston Villa - Hamburger SV Bayern München - Paris SG Benfica - Espanyol Feyenoord - AEK Fiorentina - Deportivo Independiente - Villarreal Manchester City - Real Betis Newcastle United - Valencia PSV - Middlesbrough Roma - Spartak Shakhtar - Udinese |
| Round 5 (26) AEK - Independiente Deportivo - PSV Espanyol - Shakhtar Hamburger SV - Feyenoord Middlesbrough - Manchester City Paris SG - Aston Villa Real Betis - Roma Spartak - Newcastle United Udinese - Fiorentina Valencia - Benfica Villarreal - Bayern München | Round 6 (27) Aston Villa - Shakhtar Espanyol - Spartak Fiorentina - Newcastle United Hamburger SV - Deportivo Independiente - Bayern München Manchester City - Feyenoord Middlesbrough - AEK PSV - Benfica Paris SG - Roma Real Betis - Villarreal Valencia - Udinese |
| Round 7 (28) AEK - Real Betis Bayern München - Manchester City Benfica - Fiorentina Deportivo - Valencia Feyenoord - Independiente Newcastle United - Paris SG Roma - Aston Villa Shakhtar - PSV Spartak - Middlesbrough Udinese - Hamburger SV Villarreal - Espanyol | Round 8 (29) Aston Villa - Bayern München Deportivo - AEK Feyenoord - Udinese Fiorentina - PSV Independiente - Manchester City Newcastle United - Benfica Paris SG - Spartak Real Betis - Espanyol Shakhtar - Roma Valencia - Hamburger SV Villarreal - Middlesbrough |
| Round 9 (30) AEK - Villarreal Bayern München - Feyenoord Benfica - Shakhtar Espanyol - Paris SG Hamburger SV - Fiorentina Manchester City - Aston Villa Middlesbrough - Real Betis PSV - Newcastle United Roma - Independiente Spartak - Valencia Udinese - Deportivo | Round 10 (31) Aston Villa - Independiente Benfica - Bayern München Deportivo - Espanyol Fiorentina - Paris SG Hamburger SV - Middlesbrough Newcastle United - Feyenoord PSV - Spartak Roma - AEK Shakhtar - Manchester City Udinese - Real Betis Valencia - Villarreal |
| Round 11 (32) AEK - Hamburger SV Bayern München - PSV Espanyol - Newcastle United Feyenoord - Shakhtar Independiente - Valencia Manchester City - Benfica Middlesbrough - Udinese Paris SG - Deportivo Real Betis - Aston Villa Spartak - Fiorentina Villarreal - Roma | Round 12 (33) AEK - Udinese Bayern München - Fiorentina Espanyol - Roma Feyenoord - Benfica Independiente - Deportivo Manchester City - Newcastle United Middlesbrough - Valencia Paris SG - PSV Real Betis - Hamburger SV Spartak - Aston Villa Villarreal - Shakhtar |
| Round 13 (34) Aston Villa - Villarreal Benfica - Spartak Deportivo - Real Betis Fiorentina - Manchester City Hamburger SV - Espanyol Newcastle United - Bayern München PSV - Independiente Roma - Feyenoord Shakhtar - Middlesbrough Udinese - Paris SG Valencia - AEK | Round 14 (35) AEK - Aston Villa Bayern München - Deportivo Espanyol - PSV Feyenoord - Fiorentina Independiente - Benfica Manchester City - Roma Middlesbrough - Newcastle United Paris SG - Valencia Real Betis - Shakhtar Spartak - Hamburger SV Villarreal - Udinese |
| Round 15 (36) Aston Villa - Feyenoord Benfica - Paris SG Deportivo - Middlesbrough Fiorentina - Espanyol Hamburger SV - Villarreal Newcastle United - Independiente PSV - Manchester City Roma - Bayern München Shakhtar - AEK Udinese - Spartak Valencia - Real Betis | Round 16 (37) AEK - Benfica Bayern München - Udinese Espanyol - Aston Villa Feyenoord - PSV Independiente - Fiorentina Manchester City - Valencia Middlesbrough - Roma Paris SG - Hamburger SV Real Betis - Newcastle United Spartak - Shakhtar Villarreal - Deportivo |
| Round 17 (38) AEK - PSV Deportivo - Newcastle United Espanyol - Feyenoord Hamburger SV - Shakhtar Middlesbrough - Independiente Paris SG - Manchester City Real Betis - Fiorentina Spartak - Bayern München Udinese - Roma Valencia - Aston Villa Villarreal - Benfica | Round 18 (39) AEK - Newcastle United Aston Villa - PSV Deportivo - Spartak Hamburger SV - Manchester City Middlesbrough - Paris SG Real Betis - Bayern München Roma - Fiorentina Shakhtar - Independiente Udinese - Benfica Valencia - Espanyol Villarreal - Feyenoord |
| Round 19 (40) Bayern München - Shakhtar Benfica - Deportivo Espanyol - Udinese Feyenoord - Valencia Fiorentina - Middlesbrough Independiente - Hamburger SV Manchester City - Villarreal Newcastle United - Aston Villa PSV - Roma Paris SG - Real Betis Spartak - AEK | Round 20 (41) AEK - Paris SG Aston Villa - Benfica Deportivo - Feyenoord Hamburger SV - PSV Middlesbrough - Espanyol Real Betis - Independiente Roma - Newcastle United Shakhtar - Fiorentina Udinese - Manchester City Valencia - Bayern München Villarreal - Spartak |
| Round 21 (42) Bayern München - Hamburger SV Benfica - Roma Espanyol - AEK Feyenoord - Middlesbrough Fiorentina - Aston Villa Independiente - Udinese Manchester City - Deportivo Newcastle United - Shakhtar PSV - Valencia Paris SG - Villarreal Spartak - Real Betis | |
| League rounds 22-42 (in brackets) are the respective return ties of rounds 1-21 above, i.e. round 42 is AEK - Espanyol, Aston Villa - Fiorentina etc. | |