| Round 5 | | Ajax | 1 | 32 Davies | | Half-time: | 1-2 | | Referee: | Agustín 8 | | Attendance: | 42,221 | | Possession: | 53%-47% | | Total shots: | 18-11 | | MoM: | Bernardo Silva |
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| | (4-3-3): Rui Patrício 6½, Dumfries 7, Hakimi 7½, Fernández 7, De Ligt 5½, Pau Torres 6½, Bernardo Silva 8, Davies 7½, Kane 7, Havertz 6½, Jota 5½ | | Aston Villa | 2 | 33 Abraham, 38 Abraham | | 67 Ramsey, 70 Ramsey, 86 McKennie, 87 Højbjerg | | (4-3-3): Pope 6½, McKennie 6½, Mæhle 7½, Højbjerg 7, Tomori 6, Konsa 7 (70 Fábio Silva 6), Kjær 6½, Doku 6½ (53 Justin 6½), Abraham 7, Ramsey 6, David 6½ | | Bayern München | 1 | 80 Gvardiol | | Half-time: | 0-0 | | Referee: | Rennie 7 | | Attendance: | 48,346 | | Possession: | 51%-49% | | Total shots: | 17-16 | | MoM: | Gnabry | | TV: | highlights |
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| | (4-3-3): Casteels 7½, Henrichs 7, Gvardiol 7½, Laimer 7, Acerbi 7, Koopmeiners 6½, Cuadrado 6½, Gnabry 7½, Vlahovic 6½ (80 Günter 6), Gallagher 5½, Jutglà 6½ (46 Nico Williams 6) | | Barcelona | 1 | 50 Grealish | | 23 Stones, 45 Diaby, 45+2 Rodri, 63 Diaby, 69 Gerard | | (4-5-1): Simón 7, Di Lorenzo 7½, Hernández 7, Rodri 7½, Stones 7, Saliba 7, Grealish 7 (61 Gavi 7½), Bellingham 6½, Gerard 6½, Kovacic 7 (71 Mario Hermoso 6), Diaby 6½ | | Boca Juniors | 2 | 32 Martínez, 45+1 Díaz | | Half-time: | 2-0 | | Referee: | D'Urso 6 | | Attendance: | 58,183 | | Possession: | 55%-45% | | Total shots: | 21-10 | | MoM: | Martínez | | TV: | live |
| | 53 Martínez | | (4-2-2-2): Martínez 8, Emerson 7½, Acuña 7½, De Paul 8, Araújo 8, Martínez 6½, Valverde 7½, Raphinha 6 (66 Mac Allister 8), Álvarez 7½, Martínez 7, Díaz 6½ | | Napoli | 0 |
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| | (4-3-3): Benítez 7½, Zanoli 7, Mário Rui 6½, Oriol Romeu 7 (65 Maksimovic 7), Llorente 6½, Friedl 6, Callejón 6, Politano 5½, Vitinha 6, Gonçalo Guedes 5½, Pedrinho 6½ | | Chelsea | 2 | 18og Hummels, 49 Pléa | | Half-time: | 1-2 | | Referee: | Magnussen 7½ | | Attendance: | 34,188 | | Possession: | 42%-58% | | Total shots: | 12-19 | | MoM: | Amiri |
| | 5 Vertonghen, 9 Hateboer, 33 Götze, 82 Götze | | (4-3-3): Bergström 4½, Chalobah 6½, Vertonghen 6, Antony 7½, Humphreys 6½, Hateboer 6½, Horta 6 (65 Weghorst 7), Gil 5½, Jiménez 6, Götze 6, Pléa 6½ | | FC Schalke 04 | 5 | 29 Ziyech, 32 Hummels, 64 Wolf, 84 Samardzic, 90+1 Gosens |
| | (4-3-3): Neuer 5, Kehrer 7, Gosens 7, Amiri 8, Hummels 7½, Klostermann 6, Wolf 7, Ziyech 7, Woltemade 6½, Samardzic 6, Musiala 7½ | | FC Basel | 0 |
| | Half-time: | 0-1 | | Referee: | Wieser 5 | | Attendance: | 30,433 | | Possession: | 43%-57% | | Total shots: | 10-11 | | MoM: | Isak |
| | 33 Fink, 90+2 Millar | | (4-3-3): Omlin 6, Xhaka 6½, Rodriguez 7, Alan 7½, Kouyaté 6½, Cömert 6½, Araujo 6, Millar 6, Fink 6, Frei 6½, Seferovic 6 | | Real Madrid | 2 | 8 Isak, 58 Di María | | 81 Rafael Toloi | | (3-5-2): Handanovic 7, Rafael Toloi 7½, Christensen 7½, Modric 7, Tah 7½, Can 7½, Danilo 7, Ødegaard 7½, Isak 7½, Di María 7½, Forsberg 6½ | | FC Porto | 2 | 19 Willian, 65 Stephen Eustáquio | | Half-time: | 1-0 | | Referee: | Brignoccoli 6 | | Attendance: | 40,085 | | Possession: | 47%-53% | | Total shots: | 12-17 | | MoM: | Maguire |
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| | (4-3-3): Remiro 7½, Manafá 7, Sanusi 6½, Pepe 7, Danilo 6½, Mbemba 6½, Nanu 6½, Pepê 7, Willian 6½, Stephen Eustáquio 6, Galeno 7 | | Manchester City | 0 |
| | 3 Guehi, 90+1 Højlund | | (4-3-3): Pickford 8, Alexander-Arnold 6½, Robertson 6, Rice 7½, Maguire 8½, Guehi 6, Maddison 6, Sterling 7, Højlund 7, Henderson 7 (66 Gordon 6), Mané 6½ | | Feyenoord | 3 | 1 Benzema, 43 Aké, 62 De Jong | | Half-time: | 2-0 | | Referee: | Cinciripini 7 | | Attendance: | 43,960 | | Possession: | 51%-49% | | Total shots: | 14-9 | | MoM: | Aké | | TV: | highlights |
| | 66 Rashford, 80 Benzema | | (4-3-3): Ter Stegen 8, Trippier 6½, Aké 8, Bruno Fernandes 7, Laporte 7½, Fabinho 6, Musah 7, Rashford 7, Benzema 7, De Jong 5½, Malen 6 | | Flamengo | 0 |
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| | (4-3-3): Matheus 7½, Matheuzinho 7, Marusic 7, Gerson 6½, David Luiz 7, Rodrigo Caio 6½, Thiago Maia 6½, Vitinho 6½, Pedro 7, João Gomes 6½, Yuri Alberto 6 | | Liverpool | 0 |
| | Half-time: | 0-0 | | Referee: | Meese 5 | | Attendance: | 49,454 | | Possession: | 45%-55% | | Total shots: | 8-12 | | MoM: | Marc Cucurella |
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| | (3-5-2): Trapp 7½, Koundé 7, Bastoni 7, Marquinhos 6½, Ginter 6½, Zielinski 6, Locatelli 6½, Çalhanoglu 6, Dzeko 6½, Correa 6½, Alex Sandro 7 | | Paris SG | 1 | 52 Otavio |
| | (4-3-3): Ramsdale 7, White 7½, Marc Cucurella 8, Cristante 7, Mancini 7½, Lukeba 6½, Tonali 7 (67 Sancho 6½), Otavio 7½, De Ketelaere 6, Caqueret 6, Neymar 7 (74 Zubimendi 6½) | | Manchester United | 1 | 48 Barrenetxea | | Half-time: | 0-0 | | Referee: | Fröhlich 7 | | Attendance: | 53,842 | | Possession: | 47%-53% | | Total shots: | 9-9 | | MoM: | Alex Telles | | TV: | highlights |
| | 72 Dendoncker, 85 Florenzi | | (4-3-3): Mendy 6½, Walker 6, Romagnoli 6½ (50 Alex Telles 7½), Koke 6½, Dendoncker 6½, Diomandé 7, Florenzi 6½, Barrenetxea 6½, Insigne 6½, Mikel Merino 6½, Dybala 7 | | Lyon | 1 | 52p Vinícius Júnior | | 6 Skriniar | | (4-4-2): Alisson 7, James 6½, João Cancelo 7, Tchouaméni 7, Skriniar 7, Rüdiger 6½, Brandt 7, Sané 7½, Griezmann 7 (76 Osimhen 6), Müller 7, Vinícius Júnior 7 | | Marseille | 0 |
| | Half-time: | 0-0 | | Referee: | Morales 7½ | | Attendance: | 59,933 | | Possession: | 47%-53% | | Total shots: | 17-12 | | MoM: | Rúben Dias | | TV: | live |
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| | (3-4-3): Maignan 7, Kimpembe 6½, Akanji 7, Fofana 6½, Disasi 7, Bennacer 7½, Pavard 6½, Thuram 7, Kolo-Muani 7, Nkunku 6, Dembélé 6½ | | Borussia Dortmund | 1 | 71 Kimmich |
| | (3-4-3): Courtois 7, Rúben Dias 7½, Hernández 6½, Kimmich 7, Varane 6½, Kroos 6½, Messi 7½, Lewandowski 7, Haaland 7, Mbappé 6½, Alaba 6½ | | Sporting Braga | 3 | 8 Saka, 12 Saka, 83 Saka | | Half-time: | 2-0 | | Referee: | Schramm 9½ | | Attendance: | 71,015 | | Possession: | 49%-51% | | Total shots: | 13-10 | | MoM: | Le Normand |
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| | (3-4-1-2): Diogo Costa 7, Le Normand 7½, Zinchenko 7½, Pellegrini 7, Romero 6½, Bruno Guimarães 7, Rodrygo 7½, Barella 7½, Gonçalo Ramos 7½, Saka 7½, Rafael Leão 7½ | | Deportivo | 0 |
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| | (4-3-3): Szczesny 7½, Baku 6½, Mitchell 7, Jorginho 7, Bonucci 6, Kana 6, Torres 6½, Saúl 5½, Roberto Firmino 6½, Rakitic 6, Mikel 5½ | | Round 3 | | Boca Juniors | 3 | 27 Díaz, 43 Díaz, 66 Mac Allister | | Half-time: | 2-0 | | Referee: | Krondl 5 | | Attendance: | 62,500 | | Possession: | 55%-45% | | Total shots: | 15-9 | | MoM: | Araújo |
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| | (4-2-2-2): Martínez 7½, Emerson 7, Acuña 6½, De Paul 7, Araújo 8, Martínez 7, Valverde 6½, Raphinha 5½ (66 Mac Allister 7), Álvarez 7½, Martínez 7½, Díaz 6½ | | Aston Villa | 0 |
| | 17 Kjær, 32 Abraham | | (4-3-3): Pope 7½, McKennie 7½, Mæhle 6, Højbjerg 7, Tomori 7, Konsa 6, Kjær 7 (55 Fábio Silva 6½), Doku 6, Abraham 7, Ramsey 7, David 6 | | Round 4 | | Napoli | 2 | 60 Politano, 78 Vitinha | | Half-time: | 0-2 | | Referee: | Craciun 5½ | | Attendance: | 50,839 | | Possession: | 47%-53% | | Total shots: | 11-13 | | MoM: | Friedl |
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| | (4-3-3): Benítez 6½, Zanoli 6 (72 Sensi 7), Mário Rui 6, Oriol Romeu 7, Friedl 7½, Llorente 6½, Callejón 6, Politano 6½, Vitinha 7, Verdi 6½, Pedrinho 7 | | Liverpool | 2 | 4 Alex Sandro, 23 Bastoni | | 47 Zielinski, 77 Bastoni, 89 Correa | | (3-5-2): Trapp 7, Koundé 7, Bastoni 7, Marquinhos 7½, Ginter 7, Zielinski 7½, Locatelli 6½, Çalhanoglu 6, Dzeko 7, Correa 6½, Alex Sandro 7½ |
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