| Round 5 | | AEK | 0 |
| | Half-time: | 0-0 | | Referee: | Clattenburg 7½ | | Attendance: | 33,363 | | Possession: | 55%-45% | | Total shots: | 15-10 | | MoM: | Ozan |
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| | (4-3-3): Ersin 7½, Wass 7½, Kurzawa 7½, Taylor 7 (60 Mitroglou 7½), Ozan 7½, Vitão 6, Aaronson 7, Cengiz 7, Paulinho 7½, Wendel 7½, Rashica 5½ | | Zenit | 0 |
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| | (4-3-3): Kerzhakov 6½, Karavaev 7, Krugovoy 6, Barrios 7, Robert Renan 6½, Alip 6, Kuzyaev 6½, Mak 7 (69 Musaev 6½), Dzyuba 6½, Ozdoev 6, Cassierra 6½ | | Arsenal | 2 | 39 Mkhitaryan, 76 Fábio Vieira | | Half-time: | 1-0 | | Referee: | Walton 7 | | Attendance: | 38,342 | | Possession: | 57%-43% | | Total shots: | 14-11 | | MoM: | Xhaka | | TV: | live |
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| | (4-3-3): Turner 6½, Azpilicueta 7½, Marcos Alonso 6½, Xhaka 8, Pablo 7, Chambers 6, Fábio Vieira 7, Mkhitaryan 7, Mayoral 7½, Broja 6, Balogun 6½ | | VfL Wolfsburg | 1 | 57 Steffen | | 49 Mbabu, 60 Gerhardt | | (4-3-3): Bushchan 7½, Mbabu 6½, Paulo Otávio 7½, Arnold 6½, Lacroix 7, Bruma 5½, Guilavogui 6½, Steffen 7 (58 Philipp 6½), Moraes 6½, Gerhardt 6, Marmoush 6½ | | Athletic Bilbao | 0 |
| | Half-time: | 0-0 | | Referee: | Sandra 8 | | Attendance: | 39,665 | | Possession: | 52%-48% | | Total shots: | 11-14 | | MoM: | Max |
| | 19 De Marcos | | (4-3-3): Iago 7½, De Marcos 6½, Max 8, Vesga 7½, Planas 7½, Raúl 7, Unai López 7, Muniain 7, Guruzeta 6½, Al-Musrati 6½, Sabin 6 | | Parma | 0 |
| | 63 Origi | | (4-3-3): Meret 7½, Milenkovic 7, Spinazzola 7½, Gigot 7½, Diop 6½, Del Prato 5½, Candreva 7, Pereiro 7½, Mitrovic 6½, Origi 5½, Siligardi 6½ (61 Odriozola 6) | | Atlético Madrid | 3 | 16 Dani García, 68 Doherty, 84 Borja Garcés | | Half-time: | 1-1 | | Referee: | Marriner 5½ | | Attendance: | 39,365 | | Possession: | 44%-56% | | Total shots: | 15-22 | | MoM: | Marçal |
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| | (4-3-3): Adán 7, Doherty 7, Marçal 8, Dani García 7, Copete 6½, Tomkins 6, Aleix Vidal 6, Iago 6½, Borja Garcés 6, Merquelanz 6, Sergio Camello 5½ (57 Montero 6) | | Sampdoria | 2 | 29 Jankto, 61 Quagliarella |
| | (4-3-3): Parera 7, Bereszynski 7, Augello 7½, Adrien Silva 7, Ferrari 7, Murillo 6½ (85 Defrel 6), Léris 7, Jankto 7½, Quagliarella 7, Bonazzoli 6, Caprari 6 | | B.Mönchengladbach | 2 | 10 N'Goumou, 80 Kainz | | Half-time: | 1-0 | | Referee: | Atkinson 7½ | | Attendance: | 45,567 | | Possession: | 59%-41% | | Total shots: | 12-15 | | MoM: | Klaassen |
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| | (4-3-3): Gikiewicz 7, Scally 7, Augustinsson 7½, Klaassen 8, Itakura 7, Friedrich 7, Hofmann 7½, Kainz 8, Stindl 6½, Eggestein 6 (85 Rode 6), N'Goumou 7 | | Hertha BSC Berlin | 1 | 56 Darida |
| | (4-3-3): Jarstein 7, Weigandt 6½, Bernat 7, Darida 7, Stark 6½, Brooks 6½, Serdar 6, Tolga 6, Haller 6½, Selke 6, Duda 6 | | Espanyol | 1 | 3 Marc Roca | | Half-time: | 1-0 | | Referee: | Colic 5 | | Attendance: | 28,520 | | Possession: | 55%-45% | | Total shots: | 16-10 | | MoM: | Marc Roca |
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| | (4-3-3): Oier 6½, Miguelón 6½, Berchiche 7, Marc Roca 7½, David López 7, Cabrera 7½, Vargas 6, Adri Embarba 7, Calleri 6½ (71 Mariano 6), Melendo 6½, Javi Puado 7 | | Roma | 1 | 51 Okaka |
| | (4-3-3): Olsen 6½, Zeki 6½, Zalewski 6, Portu 6½, Smalling 7 (76 Tahirovic 6), Marchizza 6½, Pussetto 6½, Sánchez 7, Okaka 6½, Solbakken 5½, Shomuradov 7 | | Lille | 3 | 2 Weah, 15 André, 41p Weah | | Half-time: | 3-0 | | Referee: | Simcic 5 | | Attendance: | 18,055 | | Possession: | 53%-47% | | Total shots: | 17-8 | | MoM: | Reinildo | | TV: | highlights |
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| | (4-3-3): Chevalier 7½, Sabaly 7, Reinildo 8, André 8, José Fonte 6½, Alexsandro 5½ (75 Hwang 6), Bamba 7½, Cabella 7½, Weah 7½, Xeka 6, Kamano 6 | | Celtic | 0 |
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| | (4-3-3): Buffon 7, Ralston 7, Simunovic 7, Christie 7, Kjær 7, Jones 6½, Abada 6½, Hatate 7, Ajeti 6½, McGregor 6, Maeda 6 | | Sporting | 0 |
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| | (4-3-3): Rui Silva 7½, Dani Alves 6½, Silva 6½, Daniel Bragança 7, Coates 7, Tomás Araújo 6, Pizzi 7, Nani 6½, Beto 7, Higuaín 5½, Marega 6½ | | Corinthians | 0 |
| | 43 Cássio | | (4-3-3): Cássio 7, Fagner 6, Carlos Augusto 7, Du Queiroz 7½, Pedro Henrique 6, Méndez 6, Giuliano 7½, Gustavo Mantuan 7½, Janssen 6½, Paulinho 7, Boselli 6½ | | São Paulo | 3 | 16og Lees-Melou, 46 De Jong, 69p De Jong | | Half-time: | 1-0 | | Referee: | Levnikov 5½ | | Attendance: | 39,470 | | Possession: | 48%-52% | | Total shots: | 15-12 | | MoM: | De Jong | | TV: | highlights |
| | 32 McTominay | | (4-3-3): Jandrei 6, Tomiyasu 7, Angeliño 6½, McTominay 7½, Diego Carlos 7½, Matviyenko 7, Helinho 7, Marlos 6, De Jong 7½, Adams 6, Kakuta 6 | | Auxerre | 2 | 59 Dennis, 83 Renato Sanches |
| | (4-3-3): Sergio Asenjo 6, Arcus 7, Maouassa 7, Renato Sanches 6½, Kumbulla 7, Onguéné 6, Lees-Melou 7, Ejuke 6½, Dennis 6, Igor Gomes 6½, Evanilson 7 | | VfB Stuttgart | 1 | 70 Choupo-Moting | | Half-time: | 0-1 | | Referee: | Pinto Correia 7 | | Attendance: | 48,421 | | Possession: | 42%-58% | | Total shots: | 10-13 | | MoM: | Scalvini |
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| | (4-3-3): Zieler 6, Insúa 6, Ito 7½, Endo 7½, Kempf 6½, Mangala 6, Führich 6, Arnautovic 6½, Guirassy 6½, Karazor 7, Choupo-Moting 6½ | | Dundee United | 2 | 34 Berardi, 62 Berardi |
| | (4-3-3): Barkas 6½, Dodô 6½, Mykolenko 7½, Baumgartner 6½, Scalvini 8, Szalai 6, Brekalo 6½, Berardi 7 (73 Uduokhai 7), Smith 6, Diop 7, Adeyemi 7½ | | Villarreal | 0 |
| | Half-time: | 0-0 | | Referee: | Robert 6 | | Attendance: | 22,806 | | Possession: | 56%-44% | | Total shots: | 21-9 | | MoM: | Álex Baena |
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| | (4-3-3): Jörgensen 7, Jorge Cuenca 6½, Moreno 7, Joan Jordán 8, Vivian 7, Trigueros 6½, Moi Gómez 7, Álex Baena 8, Jackson 7, Coquelin 7, Sansone 7 | | Grêmio | 0 |
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| | (4-3-3): Gabriel Chapecó 7½, Galhardo 7½, Reinaldo 6 (83 Róger 6), Fernando 7, Gustavo Henrique 7, Bruno Alves 5½, Villasanti 7, Messias 7, Felipe Vizeu 6½, Juninho Capixaba 5½, Ferreira 6 | | Round 3 | | B.Mönchengladbach | 2 | 30 Hofmann, 52 Stindl | | | 15 N'Goumou | | (4-3-3): Gikiewicz 7, Scally 7½, Augustinsson 9, Klaassen 8, Itakura 7½, Friedrich 6½, Hofmann 7½, Kainz 8, Stindl 7½, Eggestein 6 (85 Rode 6), N'Goumou 6 | | Roma | 1 | 6 Sánchez |
| | (4-3-3): Olsen 7, Zeki 6½, Zalewski 7 (76 Keramitsis 6), Portu 6 (56 Tahirovic 6½), Smalling 7, Marchizza 7, Pussetto 6½, Sánchez 7, Okaka 6½, Solbakken 6, Shomuradov 6 | | Round 4 | | Celtic | 2 | 21 Ajeti, 29 Abada | | Half-time: | 2-0 | | Referee: | Trentalange 7 | | Attendance: | 37,389 | | Possession: | 45%-55% | | Total shots: | 13-10 | | MoM: | Kjær |
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| | (4-3-3): Buffon 7, Ralston 6½, Simunovic 6½, McGregor 6, Kjær 7½, Jones 5, Abada 7½, Jota 7, Ajeti 7, Christie 6½, Furuhashi 6½ | | AEK | 0 |
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| | (4-3-3): Ersin 7, Wass 7, Kurzawa 6, Wendel 7½, Ozan 7, Vitão 5½, Aaronson 7½, Cengiz 6½, Paulinho 7, Camara 6, Rashica 6½ | | Hertha BSC Berlin | 0 |
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| | (4-3-3): Jarstein 6, Weigandt 6½, Bernat 6, Darida 6½, Stark 6½, Brooks 6, Serdar 6, Tolga 5½, Haller 6½, Selke 6½, Duda 6 | | Sporting | 2 | 22 Marega, 71 Beto |
| | (4-3-3): Rui Silva 6, Dani Alves 8, Silva 6, Daniel Bragança 7½, Coates 7, Tomás Araújo 7, Pizzi 7½, Nani 6½, Beto 7½, Higuaín 5½, Marega 7 |
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