| Round 1 | | AEK | 1 | 81 Di Natale | | Half-time: | 0-2 | | Referee: | Ceccarini 7½ | | Attendance: | 51,530 | | Possession: | 47%-53% | | Total shots: | 12-14 | | MoM: | Ujfalusi | | TV: | highlights |
| | 45 Alexopoulos | | (4-3-3): Doni 6, Ujfalusi 8, Bridge 7, Katsouranis 7, Albiol 7, Alexopoulos 6½, Wright-Phillips 7, Diarra 6, Drogba 7, Owen 6, Di Natale 7 | | Fiorentina | 2 | 6 Oddo, 12 Cacau |
| | (4-3-3): Lobont 6½, Oddo 7, Kirilov 7, Zanetti 7½, Rodríguez 7, Dainelli 7, Godeas 7½, Van Der Meyde 6, Mista 6, Donadel 6½, Cacau 7 | | Deportivo | 1 | 45+1og Tymoschuk | | Half-time: | 1-0 | | Referee: | Cesari 7½ | | Attendance: | 34,533 | | Possession: | 45%-55% | | Total shots: | 17-12 | | MoM: | Sergio |
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| | (4-3-3): Munúa 6½, Krøldrup 6½ (70 Taborda 7½), Pander 7½, Sergio 7½, Jorge Andrade 7, Konchesky 6½, Gallardo 6, Munitis 7½, Xisco 6½, Montella 6½, Jô 6 | | Shakhtar | 1 | 85 Schulz |
| | (4-3-3): Lastùvka 7, Stoican 6½, Schulz 7½, Matuzalém 7, Chyhrynskyi 7, Rat 7, Krasic 7, Tymoschuk 6½ (86 Caffa 6), Byelik 6½, Duljaj 6, Marica 6 | | Espanyol | 2 | 15 De La Peña, 74 Castro | | Half-time: | 1-0 | | Referee: | Chiesa 5½ | | Attendance: | 54,939 | | Possession: | 51%-49% | | Total shots: | 24-8 | | MoM: | Diarra |
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| | (4-3-3): Kameni 7, Ilsinho 7, David García 7, Diarra 7½, Fukal 6½, Castro 6½, Juanfran 6½, Morales 7, Tamudo 7, De La Peña 7, Luis García 6½ | | Bayern München | 1 | 83 Demichelis |
| | (4-3-3): Corona 7, Salihamidzic 6, Warnock 7½, Karimi 7, Demichelis 6½, Görlitz 6½, Dos Santos 5½, Zé Roberto 6½, Santa Cruz 7, Guerrero 5½, Makaay 6½ | | Hamburger SV | 4 | 6og Davies, 50 Schlaudraff, 67 Yakubu, 70p Yakubu | | Half-time: | 1-1 | | Referee: | Cinciripini 6½ | | Attendance: | 49,491 | | Possession: | 55%-45% | | Total shots: | 23-16 | | MoM: | Farfán |
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| | (4-3-3): Jentzsch 6½, Reveillère 7, Jansen 6½, Kahlenberg 7½, Nelsen 7½, Boulahrouz 7½, Farfán 7½, Trochowski 7, Yakubu 7, Gilardino 6½, Schlaudraff 6½ | | Newcastle United | 1 | 43 Mido | | 62 Bowyer, 82 Dyer | | (4-3-3): Cerný 6, Stalteri 7, Nyatanga 7, Bowyer 7, Hübschman 6½, Davies 6, Dyer 6, Emre 6½, Mido 6½, Luque 5½, Boa Morte 6½ | | Middlesbrough | 1 | 77 Viduka | | Half-time: | 0-2 | | Referee: | Collina 5 | | Attendance: | 35,044 | | Possession: | 47%-53% | | Total shots: | 13-12 | | MoM: | Léo | | TV: | highlights |
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| | (4-3-3): Runje 7, Parnaby 7, Taylor 7½, Boateng 7½, Wheater 7, Janssens 6, Cattermole 6, Downing 7½, Viduka 6, Sebo 5½, Rivaldo 6½ | | Benfica | 2 | 8 Léo, 23 Culina | | 66 Nuno Assis | | (4-3-3): Quim 6½, Ben Haim 7½, Léo 8½, Karagounis 6½, André Bahia 7, Nielsen 7½, Geovanni 7½, Beasley 7 (64 Nuno Assis 6), Smolarek 6½, Culina 6½, Mantorras 6 | | Paris SG | 1 | 42 Luccin | | Half-time: | 1-0 | | Referee: | Dinelli 6½ | | Attendance: | 46,958 | | Possession: | 51%-49% | | Total shots: | 14-10 | | MoM: | José Enrique |
| | 18 Ismaël | | (4-3-3): Létizi 8, Mendy 7½, Distin 7½, Luccin 7½, Ismaël 6½ (56 Grax 7½), Armand 6½, Didot 6½, Meghni 5½, Luyindula 6, Dia 5½, Frau 5½ | | Independiente | 0 |
| | 7 Sanogo, 84 Culio | | (4-3-3): Víctor Valdés 7, Rodríguez 7½, José Enrique 8, Carlos Martins 6½, Paletta 7, Abraham 6, Ramón 6, Cardozo 7½, Sanogo 7, Culio 6, Carlos Alberto 5½ | | Real Betis | 0 |
| | Half-time: | 0-2 | | Referee: | Fucci 5½ | | Attendance: | 49,877 | | Possession: | 52%-48% | | Total shots: | 17-10 | | MoM: | Chica | | TV: | live |
| | 37 Yeste, 68 Rosina | | (4-3-3): Armando 6, Chica 8, Antonio López 7, Petit 7, Alex 7½, Jarque 6½, Raúl García 7 (54 Marc Torrejón 7), Elano 7, Carew 6½, Rosina 6, Yeste 6 | | Feyenoord | 2 | 24 Greene, 45+4 Buckley | | 65 Ergün, 90+1 Buckley | | (4-3-3): Mondragón 6½, Greene 7½, Ergün 7, Dessena 6½, Luizão 6½, Tomas 6½, Vincken 7, Buckley 6½, Derbyshire 6, Van Der Gun 6½, Amoah 6½ | | Spartak | 2 | 23 Titov, 34 Vidic | | Half-time: | 2-1 | | Referee: | Gnedojs 7 | | Attendance: | 53,194 | | Possession: | 51%-49% | | Total shots: | 25-12 | | MoM: | Shishkin | | TV: | highlights |
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| | (4-3-3): Adler 6½, Shishkin 8, Marquez 7, Diego 7, Vidic 7½, Evseev 6, Kuijt 7½, Bilyaletdinov 7, Sahar 6½, Titov 7½, D'Alessandro 7 | | Manchester City | 2 | 5 Plasil, 79 Plasil | | 6 Makélélé | | (4-4-2): Van Der Sar 6, Ayala 6½, De Cler 6, Juanito 7, Makélélé 7, Dunne 7, Joaquín 7, Rozehnal 5½, Crespo 7, Crouch 6½, Plasil 6 | | Udinese | 0 |
| | Half-time: | 0-0 | | Referee: | Vejlgaard 7 | | Attendance: | 41,751 | | Possession: | 54%-46% | | Total shots: | 15-4 | | MoM: | Diarra |
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| | (4-3-3): Ivankov 7, Sagnol 7, Bedoya 7, O'Shea 7, Sala 6½, Cantaluppi 6, Zenoni 6½, Djordjevic 7, Bonazzoli 6, Pedretti 6½, Ronaldo 6 | | Aston Villa | 0 |
| | 6 Lescott, 16 Bouma, 23 Diarra | | (4-3-3): Howard 7½, Hughes 6, Lescott 7, Diarra 7½, Bouma 6, Ridgewell 7 (56 Obodo 7), McCann 6, Richardson 6½, Figueroa 6½, Ballack 7 (51 Makoun 6½), McFadden 6½ | | Valencia | 1 | 35 Regueiro | | Half-time: | 1-0 | | Referee: | Pellegrino 7 | | Attendance: | 47,235 | | Possession: | 41%-59% | | Total shots: | 10-13 | | MoM: | Pelizzoli |
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| | (4-4-2): Viera 7½, Curro Torres 6½, Fábio Aurélio 7, Mathijsen 7, Hofland 6½, Rothen 7, Regueiro 6½, Daniel Carvalho 7, Menez 7, Rufete 7, Schaars 6½ | | Roma | 0 |
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| | (4-3-3): Pelizzoli 8, Panucci 7½, Tonetto 7, Afellay 7½, Bovo 7½, Felipe 6½, Sidwell 7, Mauri 7, Lucarelli 6½, Dabo 6½, Chevantón 6 | | Villarreal | 1 | 90+1 Xisco Nadal | | Half-time: | 0-2 | | Referee: | Racalbuto 7 | | Attendance: | 22,890 | | Possession: | 44%-56% | | Total shots: | 14-17 | | MoM: | Nélson |
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| | (4-3-3): Timmer 6½, Labaka 6½, Arruabarrena 7, Arzo 7, Josico 7, Peña 5½, Font 7½, Santi 6½, Xisco Nadal 6½, Giménez 5½, Forlán 5½ | | PSV | 2 | 6 Koller, 35 Alex |
| | (4-3-3): Loncaric 7, Nélson 8, Dedé 7, Albelda 6½, Ooijer 6½ (47 Lucius 8), Ânderson 6½, González 7, Alex 6½, Koller 6½, Davies 7, Ewerthon 5½ | | Round 2 | | Aston Villa | 2 | 4 Richardson, 37 Mascherano | | Half-time: | 2-0 | | Referee: | Rodomonti 7 | | Attendance: | 42,496 | | Possession: | 57%-43% | | Total shots: | 15-8 | | MoM: | Runje |
| | 34 McCann, 52 Ballack, 56 Bouma, 63 Lescott | | (4-3-3): Howard 7½, Hughes 7½, Bouma 6 (75 De La Cruz 6), Mascherano 7½, Lescott 7, Ridgewell 6½, McCann 7½, Richardson 7½, Smith 6, Ballack 7, McFadden 6 | | Middlesbrough | 0 |
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| | (4-3-3): Runje 8, Parnaby 7, Taylor 6½, Boateng 7, Wheater 6½, Janssens 6½, Cattermole 6, Downing 6½, Viduka 7, Sebo 5½, Rivaldo 6 | | Bayern München | 1 | 25og Katsouranis | | Half-time: | 1-1 | | Referee: | Rosica 6 | | Attendance: | 48,146 | | Possession: | 51%-49% | | Total shots: | 18-17 | | MoM: | Bridge |
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| | (4-3-3): Corona 6, Salihamidzic 7, Warnock 6½, Karimi 7½, Demichelis 6½, Görlitz 6½, Dos Santos 6½, Zé Roberto 7, Santa Cruz 7, Guerrero 6, Makaay 6 | | AEK | 3 | 42 Drogba, 65 Drogba, 76 Drogba | | 44 Owen | | (4-3-3): Doni 7, Ujfalusi 6½, Bridge 8, Katsouranis 8, Albiol 7½, Alexopoulos 6, Wright-Phillips 6½, Diarra 6½ (76 Gekas 6), Drogba 7, Owen 5½, Di Natale 6 | | Benfica | 0 |
| | Half-time: | 0-0 | | Referee: | Trentalange 5½ | | Attendance: | 49,514 | | Possession: | 54%-46% | | Total shots: | 16-10 | | MoM: | Jansen |
| | 20 Karagounis, 80 André Bahia | | (4-3-3): Quim 7, Ben Haim 7 (50 Addo 6½), Léo 7½, Karagounis 7, André Bahia 7½, Nielsen 6½, Geovanni 6½, Beasley 7½, Smolarek 6½, Culina 6½, Mantorras 6 | | Hamburger SV | 0 |
| | 32 Gilardino, 33 Farfán, 34 Kahlenberg, 41 Reveillère, 82 Trochowski | | (4-3-3): Jentzsch 7, Reveillère 6½, Jansen 8½, Kahlenberg 7, Nelsen 7, Boulahrouz 6½, Farfán 7, Trochowski 6½, Yakubu 6, Gilardino 5½, Schlaudraff 5½ | | Feyenoord | 1 | 69 Amoah | | Half-time: | 0-1 | | Referee: | Benkö 5½ | | Attendance: | 49,089 | | Possession: | 49%-51% | | Total shots: | 10-16 | | MoM: | Greene |
| | 34 Buckley | | (4-3-3): Mondragón 7, Greene 8, Ergün 6, Dessena 7½, Luizão 7, Paauwe 6½ (66 Van Der Gun 7), Vincken 7, Buckley 6½, Amoah 6½, Derbyshire 6, Kalou 6 | | Paris SG | 1 | 11 Frau |
| | (4-3-3): Létizi 7, Mendy 7½, Distin 6, Luccin 7½, Ismaël 7 (56 Grax 7½), Armand 6½, Didot 7½, Meghni 6, Luyindula 6½, Dia 6, Frau 6½ | | Fiorentina | 2 | 27 Mista, 55 Cacau | | Half-time: | 1-2 | | Referee: | Blareau 7½ | | Attendance: | 47,089 | | Possession: | 52%-48% | | Total shots: | 10-16 | | MoM: | Zanetti |
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| | (4-3-3): Lobont 6½, Oddo 7½, Kirilov 7, Zanetti 8, Rodríguez 7, Dainelli 7, Godeas 7½, Van Der Meyde 7, Mista 6½, Donadel 6, Cacau 7 | | Villarreal | 2 | 12 Santi, 39og Dainelli |
| | (4-3-3): Timmer 7, Labaka 6½, Arruabarrena 7½, Arzo 7, Josico 6½, Peña 6½, Font 6½, Santi 7, Xisco Nadal 6½, Giménez 5½, Forlán 7 | | Independiente | 2 | 1 Sanogo, 31 Sanogo | | Half-time: | 2-0 | | Referee: | Sars 7½ | | Attendance: | 47,070 | | Possession: | 42%-58% | | Total shots: | 11-13 | | MoM: | Shishkin |
| | 63 Carlos Alberto | | (4-3-3): Víctor Valdés 7½, Rodríguez 6½, José Enrique 7, Carlos Martins 6½, Paletta 6, Abraham 6½, Ramón 5½, Cardozo 7, Sanogo 7, Culio 6, Carlos Alberto 6½ | | Spartak | 0 |
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| | (4-3-3): Adler 7, Shishkin 8, D'Alessandro 6½, Marquez 6½, Vidic 7½, Evseev 6, Kuijt 8, Bilyaletdinov 6½, Sahar 7, Diego 7½, Pavlenko 5½ | | Manchester City | 1 | 21p Crespo | | | 35 Ayala, 87 Van Der Sar | | (4-4-2): Van Der Sar 5½, Ayala 7, De Cler 7½, Juanito 6½, Makélélé 7½, Dunne 7, Joaquín 7½, Rosický 7, Crespo 7, Crouch 6½, Plasil 6½ | | Espanyol | 3 | 13 Castro, 44 De La Peña, 74 David García |
| | (4-3-3): Kameni 5½, Ilsinho 7, David García 8, Diarra 6, Fukal 6½, Castro 6½, Juanfran 7, Morales 6½, Tamudo 7, De La Peña 6, Luis García 6½ | | Newcastle United | 2 | 10 Emre, 58 Dyer | | Half-time: | 1-1 | | Referee: | Piraux 5 | | Attendance: | 43,428 | | Possession: | 42%-58% | | Total shots: | 12-14 | | MoM: | Sagnol |
| | 28 Hübschman, 76 Boa Morte, 77 Dyer | | (4-3-3): Cerný 6½, Stalteri 6½, Nyatanga 6, Bowyer 7, Hübschman 7, Davies 6 (74 Pattison 5½), Dyer 7, Emre 6, Mido 6, Luque 5½, Boa Morte 6 | | Udinese | 1 | 14 Djordjevic |
| | (4-3-3): Ivankov 7, Sagnol 8½, Bedoya 7½, O'Shea 8, Sala 7½, Cantaluppi 7, Zenoni 7, Djordjevic 6½, Bonazzoli 7, Pedretti 6½, Ronaldo 6½ (59 Maresca 7½) | | PSV | 2 | 49 Nélson, 56p Koller | | Half-time: | 0-3 | | Referee: | Sandra 6 | | Attendance: | 35,095 | | Possession: | 53%-47% | | Total shots: | 12-9 | | MoM: | Dedé |
| | 42 Ewerthon | | (4-3-3): Loncaric 4½, Nélson 6½, Dedé 8, Albelda 7, Ooijer 7, Ânderson 7, González 6½, Alex 7, Koller 6½, Davies 6½, Ewerthon 6 | | Real Betis | 4 | 3 Elano, 23 Alex, 27 Carew, 87 Yeste | | 6 Petit, 31 Carew, 39 Jarque, 77 Yeste | | (4-3-3): Doblas 5, Chica 6½, Antonio López 7, Petit 6½, Alex 7, Jarque 6½, Raúl García 6, Elano 6½, Carew 6, Rosina 5½, Yeste 6½ | | Roma | 2 | 38 Panucci, 55 Mauri | |
| | (4-3-3): Pelizzoli 6½, Panucci 6½, Tonetto 7½, Afellay 7½, Bovo 7, Felipe 6½, Sidwell 6½ (82 Volpato 7), Mauri 7½, Lucarelli 7½, Dabo 6 (65 Motta 6), Chevantón 6 | | Deportivo | 1 | 88 Xisco |
| | (4-3-3): Munúa 7, Krøldrup 7, Pander 7, Sergio 7½, Jorge Andrade 7, Konchesky 6, Gallardo 6½, Munitis 7, Xisco 6½, Montella 6½, Jô 6 | | Shakhtar | 1 | 64 Duljaj | | Half-time: | 0-0 | | Referee: | Bogdanov 5½ | | Attendance: | 40,448 | | Possession: | 53%-47% | | Total shots: | 13-8 | | MoM: | Mathijsen |
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| | (4-3-3): Lastùvka 7, Stoican 6½, Schulz 7½, Matuzalém 7½, Chyhrynskyi 6½, Rat 7, Krasic 7½, Tymoschuk 6½ (53 Caffa 7½), Byelik 6½, Duljaj 6½, Marica 5½ | | Valencia | 0 |
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| | (4-4-2): Viera 7½, Curro Torres 7, Fábio Aurélio 7, Mathijsen 8½, Hofland 7½, Rothen 6½, Regueiro 7, Daniel Carvalho 6½, Menez 7, Rufete 6½, Schaars 7 |
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