| Round 1 | | Aston Villa | 0 |
| | Half-time: | 0-1 | | Referee: | Salcedo 7½ | | Attendance: | 37,372 | | Possession: | 45%-55% | | Total shots: | 11-14 | | MoM: | Cirigliano |
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| | (4-3-3): Viviano 7, Naughton 7½, Taylor 7, Cirigliano 7½, Collins 7½, Cuéllar 6, Sidwell 6½, Bannan 6½, Delfouneso 6½, Reo-Coker 5½, Aissati 6½ | | Brøndby | 1 | 13 Selçuk |
| | (4-3-3): Sirigu 7, Jantschke 6, Lulic 7½, Raúl García 7, Zapata 7, Corluka 6, Pérez 7, Gervinho 7, Bacca 6½ (77 Ansaldi 6), Selçuk 7, Roberto Firmino 6 | | Atlético Madrid | 3 | 3 Borja, 17 Marcos Alonso, 80 Lanzini | | Half-time: | 2-3 | | Referee: | Cesari 5½ | | Attendance: | 42,980 | | Possession: | 58%-42% | | Total shots: | 16-10 | | MoM: | Iago |
| | 19 Lanzini, 63 Reyes | | (4-3-3): Marinelli 5½, Mario 7, Marcos Alonso 7, Biglia 7½, Rodríguez 7 (55 Ismail 6½), Banega 6½, Salvio 7, Iago 8½, Borja 7, Lanzini 7, Bojan 5½ (54 Reyes 6½) | | Inter | 3 | 25 Zuñiga, 36 Arnautovic, 42 Zuñiga |
| | (4-3-3): Belec 5½, Donati 6½ (55 Mariga 6½), Zuñiga 6½, Maxim 7, Britos 6½, Biava 6, Rômulo 7, Arnautovic 7, Milito 5½, Eto'o 5½, Pandev 6 | | Boca Juniors | 2 | 30 Burdisso, 82 Moralez | | Half-time: | 1-1 | | Referee: | Ancion 7 | | Attendance: | 38,717 | | Possession: | 55%-45% | | Total shots: | 17-9 | | MoM: | Mavuba | | TV: | highlights |
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| | (4-3-3): Kirev 6, Juárez 7½, Monzón 7½, Bruno César 7, Burdisso 7, Muñoz 7½, Routledge 7½, Moralez 7, Funes 6½ (82 Barroso 6), Chavez 6 (82 Barrera 6), Saviola 7 | | AZ | 2 | 34 Tiendalli, 90 Guðmundsson |
| | (4-3-3): Stamatopoulos 6, Husev 6½, Tiendalli 6, Mavuba 8½, Moisander 7, Moreno 7, Heitinga 6½, Esswein 6½, Guðmundsson 5½, Brama 6½, N'Zogbia 5½ | | CSKA | 0 |
| | Half-time: | 0-0 | | Referee: | Bazzoli 5 | | Attendance: | 13,102 | | Possession: | 50%-50% | | Total shots: | 10-19 | | MoM: | Denisov |
| | 17 Nababkin | | (4-3-3): Moyá 8, Nababkin 7, Schennikov 8, Denisov 8, Ignashevich 7½, Pelé 7, Oliseh 8, Dzsudzsák 6½, King 6, Okay 7, Gyasi 5½ | | VfB Stuttgart | 0 |
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| | (4-3-3): Ulreich 8, Hilbert 6½ (47 Walch 7), Boka 7, Aquilani 7½, Osorio 7½, Niedermeier 6½, Kuzmanovic 5½, Gebhart 7, Schieber 6, Hamit 6, Marica 5½ | | Fenerbahçe | 2 | 20 Mehmet, 87 Cech | | Half-time: | 1-0 | | Referee: | Rudy 6½ | | Attendance: | 42,117 | | Possession: | 57%-43% | | Total shots: | 10-3 | | MoM: | Gökhan | | TV: | highlights |
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| | (4-3-3): Tolga 7, Gökhan 8½, Bekir 8, Özer 7½, Egemen 8, Remzi Giray 6, Mehmet 7, Cech 6½, Sow 7½, Semih 6½, Burak 7 | | Independiente | 0 |
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| | (4-3-3): Orión 7, Dijkhuizen 7, Vallés 7 (69 Piatti 6½), Suarez 7 (48 Nuñez 6½), Galeano 7, Vittor 6, Mancuello 6½, Rodríguez 6, Osvaldo 7, Gandín 5½, Gutierrez 6 | | Hajduk Split | 1 | 22 Strinic | | Half-time: | 1-1 | | Referee: | Borriello 6½ | | Attendance: | 34,855 | | Possession: | 59%-41% | | Total shots: | 13-7 | | MoM: | Maloca |
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| | (4-3-3): Tomic 6½, Oremus 7½, Strinic 8, Vrdoljak 8, Maloca 8, Buljat 8, Rubil 7½, Ibricic 8, Lakic 6½, Cop 6, Sharbini 7 | | Udinese | 2 | 45+1 Zimling, 85 Zimling |
| | (4-3-3): Szczesny 7, Basta 7½, Papadopoulos 6½, Isla 7, Léo 7, Diarra 6, Lodi 5½, Zimling 7, Alex Geijo 6, D'Agostino 6½ (85 Wright-Phillips 6), Jaime 5½ | | Lyon | 1 | 30 Coquelin | | Half-time: | 1-3 | | Referee: | Arena 5½ | | Attendance: | 40,351 | | Possession: | 40%-60% | | Total shots: | 7-11 | | MoM: | Shawcross |
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| | (4-3-3): Bettinelli 5½, Théophile-Catherine 7, Bedimo 7½, Coquelin 7½, Armand 6, Tiéné 6½, Obraniak 6½, Boussoufa 6½, Roux 6½, Marveaux 6, Belfodil 6½ (53 Faure 6) | | Ayr United | 3 | 23 Kane, 33 Davis, 45+1 Berahino |
| | (4-4-2): Butland 6½, Clyne 7½, Robertson 6½, Fletcher 7½, Dann 7½, Shawcross 8, Davis 7½, Oxlade-Chamberlain 7½, Kane 7½, McCarthy 6½, Berahino 6½ | | Milan | 3 | 23 Mandzukic, 40 Mandzukic, 44 Mandzukic | | Half-time: | 3-1 | | Referee: | Waddel 5 | | Attendance: | 54,302 | | Possession: | 55%-45% | | Total shots: | 14-15 | | MoM: | Tomecak |
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| | (4-3-3): Ospina 6, Aurier 7, Kolarov 7½, Cabaye 7, Javi Martínez 6½, Dória 7, Joaquín 7, Depay 6½, Mandzukic 7½, Ander 7, Volland 6 | | Boulogne | 3 | 32 Thiago, 75 Mikel, 82 Emeghara | | 27 Klose | | (4-3-3): Frey 5½, Tomecak 7½, Ibañez 6½, Mikel 6½ (84 Sammir 6), Gamberini 6, Klose 6, Gökhan 7, Muniain 6½, Álvaro 6½, Thiago 6½, Emeghara 6 | | Newport County | 1 | 35 Dummett | | Half-time: | 1-0 | | Referee: | López Nieto 7½ | | Attendance: | 19,508 | | Possession: | 55%-45% | | Total shots: | 9-8 | | MoM: | Rhodes | | TV: | live |
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| | (4-3-3): McGregor 7, Stones 7, Clark 7, Cleverley 6½, Tomkins 7, Dummett 7, Henderson 6½ (66 Cresswell 7½), Ayew 7, Rhodes 7½, Badu 7, Ings 6½ | | Fiorentina | 0 |
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| | (4-3-3): Mirante 7½, De Silvestri 7½, Gobbi 6½, Rômulo 7, Cana 7, Felipe 6, Konko 6, Donadel 6½, Gilardino 6½, Marchionni 6½, Ljajic 6½ | | Roma | 2 | 53 Tadic, 55 Pazzini | | Half-time: | 0-1 | | Referee: | Karlsson 7 | | Attendance: | 45,177 | | Possession: | 46%-54% | | Total shots: | 12-13 | | MoM: | Boenisch |
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| | (4-3-3): Adler 6, Jonathan 7½, Young 7, Schneiderlin 7, Fazio 6½, Coloccini 7, Cuadrado 7, Tadic 8, Pazzini 7, Calhanoglu 5½, Kruse 6½ | | Hamburger SV | 2 | 8 Guerrero, 77 Pavlyuchenko |
| | (4-3-3): Karnezis 6, Boenisch 8, Aogo 6½, Rincón 7, Mathijsen 6, Piris 7, Harnik 6½, Jansen 7½, Guerrero 7, Pavlyuchenko 6½, Petric 6 | | West Ham United | 4 | 8 Cole, 16 Bent, 22 Brozovic, 87 Sellin | | Half-time: | 3-1 | | Referee: | Vorjas 6½ | | Attendance: | 34,477 | | Possession: | 52%-48% | | Total shots: | 12-15 | | MoM: | Gibbs |
| | 62 Mancienne | | (4-3-3): Green 5½, Gray 7, Gibbs 8, Gerrard 7½, Samba 7½, Mancienne 5½, Holmes 6½, Brozovic 7, Bent 7½, Cole 6, Sellin 5½ | | Barcelona | 2 | 15 Abate, 89p Gomez |
| | (4-3-3): Müller 6, Abate 7, Maxwell 7½, Tiago 7½, Mexès 6½, Fernández 7, Jeffren 6½, Isaac Cuenca 6½, Gomez 7, Torres 5, Vílla 6 | | Round 2 | | AZ | 0 |
| | Half-time: | 0-2 | | Referee: | Nielsen 6½ | | Attendance: | 17,170 | | Possession: | 42%-58% | | Total shots: | 3-17 | | MoM: | Banega |
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| | (4-3-3): Stamatopoulos 6, Husev 6½, Tiendalli 7½, Mavuba 6½, Moisander 6, Moreno 6, Heitinga 5½, Esswein 7, Guðmundsson 6, Brama 5½, N'Zogbia 6½ | | Atlético Madrid | 2 | 27 Iago, 40 Banega | | 65 Banega | | (4-3-3): Marinelli 6, Mario 8, Marcos Alonso 7½, Biglia 7, Rodríguez 7, Marc Muniesa 7, Salvio 7 (69 Jesús 7), Iago 7½, Borja 7½, Banega 8, Bojan 7 | | Ayr United | 2 | 22 Robertson, 37 Berahino | | Half-time: | 2-0 | | Referee: | Fraise 5 | | Attendance: | 24,097 | | Possession: | 49%-51% | | Total shots: | 17-8 | | MoM: | Robertson |
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| | (4-4-2): Butland 7½, Clyne 7, Robertson 8, Fletcher 7, Dann 7½, Shawcross 6½, Davis 7, Oxlade-Chamberlain 7, Kane 6½, McCarthy 7, Berahino 7½ | | Aston Villa | 0 |
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| | (4-3-3): Viviano 7½, Naughton 6½, Taylor 7, Cirigliano 7½, Collins 7, Cuéllar 6½, Sidwell 7, Bannan 5½, Delfouneso 6½, Reo-Coker 6, Aissati 6½ | | Barcelona | 1 | 36og Cleverley | | Half-time: | 1-3 | | Referee: | Korac 7 | | Attendance: | 47,033 | | Possession: | 39%-61% | | Total shots: | 8-17 | | MoM: | Stones |
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| | (4-3-3): Müller 4½, Abate 7, Maxwell 7, Tiago 7, Mexès 7, Fernández 5½, Jeffren 6½, Isaac Cuenca 6, Gomez 6½, Torres 6½, Vílla 6 | | Newport County | 3 | 19 Henderson, 25 Ayew, 31 Ayew |
| | (4-3-3): McGregor 6, Stones 7½, Clark 6½, Cleverley 7½, Tomkins 7, Dummett 6½, Henderson 7 (66 Cresswell 6½), Ayew 7½, Rhodes 6½, Badu 6½, Ings 6½ | | Boulogne | 1 | 16 Mikel | | Half-time: | 1-1 | | Referee: | Wiley 7½ | | Attendance: | 14,873 | | Possession: | 50%-50% | | Total shots: | 15-14 | | MoM: | Denisov |
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| | (4-3-3): Frey 7, Tomecak 7, Ibañez 7½, Mikel 6½ (84 Sammir 6), Gamberini 6½, Klose 6, Gökhan 6, Muniain 7, Álvaro 7, Thiago 6½, Emeghara 6½ | | CSKA | 1 | 3 Dzsudzsák | | 42 Okay, 80 Nababkin | | (4-3-3): Moyá 7, Nababkin 7, Schennikov 7, Denisov 8, Ignashevich 6½, Pelé 6, Oliseh 6, Dzsudzsák 7½, King 5½, Okay 6, Gyasi 6 | | Brøndby | 2 | 66 Roberto Firmino, 85 Pérez | | Half-time: | 0-0 | | Referee: | Sedlacek 8 | | Attendance: | 28,902 | | Possession: | 55%-45% | | Total shots: | 20-12 | | MoM: | Richardson |
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| | (4-3-3): Sirigu 7½, Jantschke 6½, Lulic 8, Raúl García 6 (85 Ansaldi 6), Zapata 7½, Corluka 6½, Pérez 7½, Gervinho 7, Bacca 7½, Selçuk 6½, Roberto Firmino 7 | | West Ham United | 1 | 52 Bent | | 39 Brozovic | | (4-3-3): Green 6½, Gray 6, Gibbs 7 (50 Richardson 8), Gerrard 7, Samba 6½, Mancienne 6, Holmes 6½, Brozovic 6, Bent 6½, Carroll 7 (47 Brown 6½), Sellin 6 | | Fiorentina | 1 | 68 Gilardino | | Half-time: | 0-0 | | Referee: | Clattenburg 7½ | | Attendance: | 39,477 | | Possession: | 44%-56% | | Total shots: | 12-8 | | MoM: | Gobbi |
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| | (4-3-3): Mirante 7, De Silvestri 7½, Gobbi 8, Rômulo 7½, Cana 7, Felipe 6½, Konko 7, Marchionni 6½, Gilardino 7, Donadel 6, Ljajic 7½ | | Fenerbahçe | 0 |
| | 7 Sow | | (4-3-3): Tolga 7, Gökhan 7½, Bekir 6½, Özer 7½, Egemen 6½, Remzi Giray 7, Mehmet 7½, Cech 7, Sow 7 (68 Serdar 7), Semih 6, Burak 6 | | Hamburger SV | 2 | 3p Guerrero, 41 Jansen | | Half-time: | 2-0 | | Referee: | Díaz Vega 7½ | | Attendance: | 36,041 | | Possession: | 54%-46% | | Total shots: | 10-9 | | MoM: | Piris |
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| | (4-3-3): Karnezis 6, Boenisch 6½, Aogo 7, Rincón 6½, Mathijsen 7½, Piris 7½, Harnik 6, Jansen 7, Guerrero 6½, Pavlyuchenko 5½, Petric 6 | | Boca Juniors | 2 | 49 Chavez, 73 Routledge |
| | (4-3-3): Kirev 6½, Juárez 7, Monzón 7, Bruno César 6½, Burdisso 6½, Muñoz 6, Routledge 6½, Moralez 7, Funes 6, Chavez 6, Saviola 6 | | Independiente | 1 | 23 Osvaldo | | Half-time: | 1-1 | | Referee: | Onufer 6 | | Attendance: | 33,703 | | Possession: | 53%-47% | | Total shots: | 12-11 | | MoM: | Vallés |
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| | (4-3-3): Orión 7, Dijkhuizen 6½, Vallés 8, Suarez 7, Galeano 7, Vittor 7½, Mancuello 6, Rodríguez 7, Osvaldo 7½, Gandín 6½ (58 Nuñez 6), Gutierrez 6 | | Hajduk Split | 1 | 13 Lakic |
| | (4-3-3): Tomic 7, Oremus 7, Strinic 7½, Vrdoljak 6½, Maloca 7, Buljat 6, Rubil 7½, Ibricic 7, Lakic 7, Cop 6, Sharbini 6½ | | Inter | 2 | 45+1 Arnautovic, 81 Zuñiga | | Half-time: | 1-2 | | Referee: | Mayer 6½ | | Attendance: | 40,911 | | Possession: | 40%-60% | | Total shots: | 12-9 | | MoM: | Pazzini |
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| | (4-3-3): Belec 6, Donati 6½, Zuñiga 7, Maxim 7, Britos 7, Biava 6, Rômulo 6½, Arnautovic 6, Milito 6, Eto'o 5½, Pandev 6½ | | Roma | 2 | 4 Tadic, 30 Pazzini |
| | (4-3-3): Adler 6, Jonathan 7, Young 6½, Schneiderlin 7½, Fazio 6½, Coloccini 6½, Cuadrado 7, Tadic 7, Pazzini 7½, Calhanoglu 6½, Kruse 7 | | Udinese | 1 | 1 Alex Geijo | | Half-time: | 1-0 | | Referee: | Vad 5½ | | Attendance: | 30,790 | | Possession: | 37%-63% | | Total shots: | 4-23 | | MoM: | Boussoufa |
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| | (4-3-3): Szczesny 7, Basta 6½, Papadopoulos 6, Isla 6½, Léo 6½, Diarra 6, Lodi 6½, Zimling 7, Alex Geijo 6, D'Agostino 6½ (75 Wright-Phillips 6), Jaime 5½ | | Lyon | 0 |
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| | (4-3-3): Bettinelli 7, Théophile-Catherine 8, Bedimo 7½, Coquelin 8, Armand 6, Taiwo 7 (70 Sunu 6½), Obraniak 7½, Boussoufa 8½, Roux 6½, Fatih 8, Belfodil 6 | | VfB Stuttgart | 0 |
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| | (4-3-3): Ulreich 6½, Osorio 7, Boka 7½, Aquilani 8, Niedermeier 7½, Boulahrouz 5½, Kuzmanovic 6, Gebhart 6, Schieber 6½, Hamit 6, Marica 6 | | Milan | 1 | 14og Boka |
| | (4-3-3): Ospina 7, Aurier 7½, Kolarov 6 (85 Quintero 6), Cabaye 7, Javi Martínez 7, Dória 6, Joaquín 8, Depay 7, Mandzukic 7, Ander 6, Volland 6½ |
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