| Round 3 | | Athletic Bilbao | 2 | 12 Eduardo, 87 Vela | | Half-time: | 1-1 | | Referee: | Knight 7½ | | Attendance: | 30,317 | | Possession: | 46%-54% | | Total shots: | 9-11 | | MoM: | Schelotto | | TV: | highlights |
| | 11 Torres, 46 Jurado, 72 Osvaldo | | (4-3-3): Dhoest 5½, Iraola 6 (77 Rodri 6), Aurtenetxe 6, Mario Suárez 7½, Botía 6, Torres 6, Susaeta 6½, Vela 7, Eduardo 7½, Jurado 6, Osvaldo 7 | | Lazio | 2 | 8 Matri, 56 Antonelli |
| | (4-3-3): Stekelenburg 6, Bonera 6, Antonelli 7, Ilicic 7½, Radu 6½, Ariaudo 6, Schelotto 8, Mertens 6½, Matri 6, Babacar 6, Théréau 7 | | Bayern München | 1 | 77 McEachran | | Half-time: | 0-0 | | Referee: | Sandra 5½ | | Attendance: | 53,405 | | Possession: | 46%-54% | | Total shots: | 16-16 | | MoM: | Essien |
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| | (4-3-3): Andújar 7, Essien 8, Pranjic 7½, Sahin 8, Demichelis 7½, Papastathopoulos 6½, Forlin 6½ (71 Djourou 6½), Marin 6½, Klose 7, Barrios 5½, Aubameyang 7 (71 McEachran 5½) | | Newcastle United | 1 | 60 Vidal |
| | (3-4-1-2): Cech 6½, Godín 7½, Boateng 7, Vidal 7½, Hummels 6½, Alaba 7, Bale 7½, Götze 7½, Cavani 6½, Sánchez 6, Robben 7 | | Exeter City | 0 |
| | Half-time: | 0-2 | | Referee: | Trentalange 7 | | Attendance: | 19,751 | | Possession: | 42%-58% | | Total shots: | 9-12 | | MoM: | Xabi Alonso | | TV: | live |
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| | (3-4-3): Foster 6, Jones 6½, Milner 6½, Barry 7, Terry 6½, Coleman 7, Dyer 6, Johnson 6½, Delph 7, Walcott 6½, Austin 7½ | | Real Madrid | 2 | 22 Messi, 30 Ronaldo |
| | (4-4-2): Neuer 6½, Sergio Ramos 7½, Kompany 7 (76 Pepe 6), Piqué 7½, Chiellini 7, De Rossi 6, Xabi Alonso 8, Silva 8, Ronaldo 7½, Messi 6½, Özil 7 (76 Santi Cazorla 6) | | FC Porto | 2 | 31 Oscar, 52 Luizão | | Half-time: | 1-0 | | Referee: | Piraux 6 | | Attendance: | 50,782 | | Possession: | 54%-46% | | Total shots: | 13-9 | | MoM: | Luizão |
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| | (4-3-3): Rui Patrício 7, Bruno Alves 7½, Alex Sandro 7½, João Moutinho 7½, Luizão 7½, Dedé 7, Marcelo 6½, Oscar 7½, Falcao 7, Danny 6½, Hulk 6½ | | Arsenal | 1 | 58 Pedro |
| | (4-3-3): Buffon 7, Lahm 7, Adriano 7, Fabregas 7, Mascherano 7, Ivanovic 6, Auro 6, Pedro 6½, Boye 6, Marchisio 6, Neymar 6 | | Lille | 2 | 64 Gaitán, 75 Gaitán | | Half-time: | 0-0 | | Referee: | Damgaard 7 | | Attendance: | 18,074 | | Possession: | 51%-49% | | Total shots: | 21-8 | | MoM: | Hélton |
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| | (4-3-3): Lloris 8½, Valencia 8, Evrà 8, Rakitic 7½, Rodriguez 7, Jallet 6½, Rosales 6 (53 Lallana 6½), Gaitán 6½, Negredo 7, Thauvin 6½, Origi 6½ | | São Paulo | 0 |
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| | (4-3-3): Hélton 8½, Maicon 8, Juan 7½, Diego 7½, Lúcio 6½, Rodrigo Caio 6½, Kelvin 6½, Lucas 6½, Willian 7, Ganso 6, Robinho 6½ | | Nantes | 1 | 60 Payet | | Half-time: | 0-0 | | Referee: | Vorjas 6½ | | Attendance: | 37,435 | | Possession: | 52%-48% | | Total shots: | 14-8 | | MoM: | Toulalan | | TV: | live |
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| | (4-3-3): Mandanda 6½, Debuchy 7, Kurzawa 7½, Valbuena 6½, Koscielny 7, Digne 6½, Sissoko 7½, Payet 7½, Gomis 6½, Toulalan 7½, Lacazette 6 | | Cruz Azul | 1 | 57 Jelavic | | 49 Huiqui | | (4-3-3): Iraizoz 7½, De Marcos 6½, Pereira 6 (74 Castro 6), Hamsík 7½, Huiqui 6½, Samuel 6½, João Pereira 6½, Giménez 6, Paco Alcácer 6½, Torrado 6, Jelavic 6 | | Round 4 | | Arsenal | 1 | 9p Boye | | Half-time: | 1-0 | | Referee: | Kefalas 6½ | | Attendance: | 59,822 | | Possession: | 57%-43% | | Total shots: | 19-4 | | MoM: | Lahm |
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| | (4-3-3): Buffon 7½, Lahm 8½, Adriano 7½, Fabregas 7, Mascherano 6, Ivanovic 7½, Auro 6½, Di María 7½, Boye 7, Suárez 6, Neymar 7½ | | Valencia | 0 |
| | 12 Paulinho, 51 Knockaert, 57 Javi Manquillo | | (4-3-3): Reina 7, Arbeloa 7, Perotti 6½, Rafinha 6½, San Jose 6½, Van Der Vaart 6, Lennon 7, Pastore 6½, Javi Manquillo 6, Knockaert 5½, Paulinho 6½ | | Benfica | 1 | 49 Cleiton Xavier | | Half-time: | 0-1 | | Referee: | Hauge 7 | | Attendance: | 45,835 | | Possession: | 44%-56% | | Total shots: | 16-20 | | MoM: | Lloris |
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| | (4-3-3): Eduardo 6½, Pereira 7, Eliseu 7, Javi García 7½, Ricardo Carvalho 7, Maicon 6½, Gourcuff 6, Cleiton Xavier 6½, Drogba 6½ (47 Rafa 7), Cardozo 5½, Alex 5½ | | Lille | 1 | 19 Negredo |
| | (4-3-3): Lloris 8, Valencia 6½, Evrà 7½, Rakitic 7½, Rodriguez 7, Jallet 5½, Rosales 7 (53 Lallana 7½), Gaitán 8, Negredo 7½, Thauvin 6½, Origi 6½ | | Borussia Dortmund | 2 | 17 Schmelzer, 87 Lewandowski | | Half-time: | 1-1 | | Referee: | Almeida Marcal 5 | | Attendance: | 57,113 | | Possession: | 44%-56% | | Total shots: | 9-9 | | MoM: | De Sciglio | | TV: | highlights |
| | 11 Höwedes, 45 Ramires | | (4-3-3): Akinfeev 6, Höwedes 6, Schmelzer 8, Schweinsteiger 7, Mertesacker 7, Subotic 6½, Ramires 6½, Iniesta 6 (82 Guarín 6), Lewandowski 7, Bender 7, Lavezzi 5½ | | Baník Ostrava | 2 | 10 Giroud, 81og Mertesacker |
| | (4-3-3): Courtois 6, Hubocan 8½, De Sciglio 9, Touré 7, Barzagli 6½, Varane 7 (82 Medel 6), Kouassi 6½, Arda 7½, Giroud 7, Busquets 6, Totti 7 | | Cruz Azul | 2 | 36 Fellaini, 38 Paco Alcácer | | Half-time: | 2-1 | | Referee: | Constantin 5½ | | Attendance: | 35,769 | | Possession: | 49%-51% | | Total shots: | 12-17 | | MoM: | Hamsík | | TV: | highlights |
| | 8 Giménez, 41 Hamsík, 67 Jelavic | | (4-3-3): Iraizoz 5½, De Marcos 7, Pereira 6½, Hamsík 7½, Huiqui 6½, Samuel 6½, João Pereira 7, Giménez 6, Paco Alcácer 6½, Fellaini 7, Jelavic 6 (84 Brown 6) | | Anderlecht | 2 | 18 Kerzhakov, 57 Legear |
| | (4-3-3): Mignolet 6½, Maggio 6½, Deschacht 7 (53 Taylor 7), Dembélé 6½, Chedjou 6, Juhász 6½, Legear 7, Ilicevic 6½ (49 Pocognoli 6½), Lukaku 7, Rolfes 6, Kerzhakov 7 | | Dynamo | 1 | 49 Harmash | | Half-time: | 0-0 | | Referee: | Alfassi 6 | | Attendance: | 42,344 | | Possession: | 44%-56% | | Total shots: | 11-21 | | MoM: | Wendt |
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| | (4-3-3): Carrasso 7, Vida 6½, Khacheridi 6½, Vukojevic 7, Mykhalyk 6, Diakhaté 5½, Bystrov 7½, Pienaar 6, Milevskyi 6½, Harmash 6½, Zozulya 5½ | | Helsingborg | 1 | 46 Diego Costa |
| | (4-3-3): Nyland 7½, Azpilicueta 7½, Wendt 8, Kjær 7, Rojo 7½, Wernbloom 6½, Schøne 7½, Henriksen 6, Diego Costa 7½, Eriksen 7½, Agüero 7 | | FC Basel | 0 |
| | Half-time: | 0-0 | | Referee: | Hansson 7½ | | Attendance: | 38,443 | | Possession: | 45%-55% | | Total shots: | 13-15 | | MoM: | Hulk |
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| | (4-3-3): Diego 6½, Dani Alves 7, Jordi Alba 7 (50 Isco 6), Pirlo 6, Dante 6½, Juanfran 6½, Florenzi 6, Rodríguez 6½, Ibrahimovic 6½ (51 Enes 7), Matuidi 7, Berardi 5½ | | FC Porto | 1 | 80 Falcao |
| | (4-3-3): Rui Patrício 7, Bruno Alves 7, Alex Sandro 6½, João Moutinho 7, Luizão 7, Dedé 7 (80 Ricardo Esgaio 6), Marcelo 6½, Oscar 7, Falcao 7, Danny 6½, Hulk 7½ | | Flamengo | 1 | 81 Willians | | Half-time: | 0-3 | | Referee: | Nazareno 7½ | | Attendance: | 46,767 | | Possession: | 32%-68% | | Total shots: | 3-23 | | MoM: | Koscielny |
| | 3 Lima, 63 Willians | | (4-3-3): Muriel 4½, Danilo Silva 6, Siqueira 6½, Willians 6½, Xandão 5½, David 6, Wellington Nem 6½, Marlos 5½, Lima 6, Babel 6, Nixon 6 | | Nantes | 4 | 13 Kurzawa, 22 Payet, 42 Kurzawa, 66 Kurzawa |
| | (4-3-3): Mandanda 5½, Debuchy 7, Kurzawa 7½, Valbuena 8½, Koscielny 8½, Digne 7½, Sissoko 7½, Payet 7½, Gomis 7½, Toulalan 6, Lacazette 7 | | Newcastle United | 2 | 28 Götze, 54 Götze | | Half-time: | 1-1 | | Referee: | Rudy 6½ | | Attendance: | 52,218 | | Possession: | 53%-47% | | Total shots: | 15-13 | | MoM: | Vidal |
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| | (3-4-1-2): Cech 7, Godín 6½, Boateng 7½, Vidal 8, Hummels 7½, Alaba 7½, Bale 7½, Götze 7½, Cavani 7½, Sánchez 7, Robben 7 | | Exeter City | 1 | 18 Dyer |
| | (3-4-3): Foster 7, Jones 6, Milner 7, Barry 7, Terry 6½, Coleman 6½, Dyer 6½, Johnson 7, Delph 6½, Walcott 6, Austin 6½ | | São Paulo | 2 | 51p Willian, 58 Lucas | | Half-time: | 0-0 | | Referee: | Gumienny 6 | | Attendance: | 35,126 | | Possession: | 51%-49% | | Total shots: | 19-10 | | MoM: | Diego |
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| | (4-3-3): Hélton 7½, Maicon 8, Juan 8, Diego 8½, Rodrigo Caio 7, Lúcio 7, Kelvin 6½, Lucas 8, Willian 6½, Renato Augusto 7, Robinho 6 | | Palmeiras | 0 |
| | 12 Lucas, 70 Ronaldinho, 89 Marquinhos, 90 Júlio César | | (4-3-3): Júlio César 7, Henrique 7½, Armero 6½, Lucas 6½, Danilo 7 (49 Ewerthon 6), Rafael Toloi 5½, Edinho 5, Marquinhos 6, Robert 7, Márcio Araújo 6, Ronaldinho 5½ |
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