| Round 3 | | Bayer Leverkusen | 1 | 15 Rubén Pérez | | Half-time: | 1-2 | | Referee: | Bettin 7 | | Attendance: | 22,322 | | Possession: | 51%-49% | | Total shots: | 9-15 | | MoM: | Cassano | | TV: | highlights |
| | 69 Kakuta | | (4-3-3): Stanek 4, Fritz 7, Schulz 6½, Cambiasso 7, Díaz 6½, Castro 5½, Elano 6½, Kakuta 5½, Kuranyi 6½, Rubén Pérez 6½, Gavranovic 6½ (63 Balitsch 5½) | | Palermo | 5 | 5 Cassano, 8 Insigne, 58 Candreva, 63 Insigne, 87 Cassano |
| | (4-4-2): Consigli 5, Darmian 8, Montolivo 7, Moretti 7½, Bonaventura 7½, Astori 6, Criscito 7½, Cassano 8, Candreva 7½, Inler 6½, Insigne 7 | | Internacional | 2 | 28 Kléber, 84 Walter | | Half-time: | 1-0 | | Referee: | Colic 7½ | | Attendance: | 52,772 | | Possession: | 41%-59% | | Total shots: | 11-9 | | MoM: | Mamaev | | TV: | live |
| | 40 Taison | | (4-3-3): Fernando Henrique 7, Mariano 7, Kléber 8, Fernando 7½, Marcelo 6 (56 Dalton 7½), Hilton 6, Giuliano 7, Wágner 7 (59 Walter 7½), Jô 6½, Fred 6, Taison 6 | | Spartak | 1 | 55 Rondón | | 74 Ozdoev, 90 Makeev | | (4-3-3): Ryzhikov 7, Parshivlyuk 7, Kombarov 8, Mamaev 8, Makeev 7, Berezutsky 7½, Zhirkov 6, Dzagoev 7½, Rondón 7½, Ozdoev 6½, Yakovlev 5½ | | Lorient | 7 | 8 Sagbo, 10 Sagbo, 31 Sagbo, 43 Congré, 45+3 Diarra, 68p Sagbo, 90 Amalfitano | | Half-time: | 5-0 | | Referee: | Reinert 7½ | | Attendance: | 15,708 | | Possession: | 57%-43% | | Total shots: | 21-9 | | MoM: | Amalfitano |
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| | (4-3-3): Sorin 7, Congré 8, Morel 8, Balmont 7½, Marchal 7½, Kanté 7, Amalfitano 8, Diarra 7, Sagbo 7, Jouffre 7½, Birsa 6½ | | SV Werder Bremen | 1 | 59 Fetfatzidis | | 52 Samaris, 74 Smith | | (4-4-2): Parish 6, Prödl 7, Diego Capel 7, Bargfrede 7, Smith 6, Samaris 5½, Oar 6, Hunt 6, Dost 7, Fetfatzidis 7, Wagner 6 | | Sevilla | 2 | 19 Luscombe, 33 Kiko | | Half-time: | 2-1 | | Referee: | Racalbuto 5 | | Attendance: | 40,076 | | Possession: | 51%-49% | | Total shots: | 13-9 | | MoM: | Silvestre |
| | 42 Luscombe, 66 Raul Meireles | | (4-3-3): Navas 6½, Silvestre 7½, Fernando Navarro 7, Raul Meireles 7½, Naldo 7½, Alexis 7, Kiko 7, Luscombe 5, Kiessling 7, Makoun 6, Novillo 6 | | Espanyol | 2 | 5 Ninkovic, 49 Verdú |
| | (4-3-3): Yoel 6½, Coke 7, Pinto 6 (69 Motta 7½), Juanmi 7, Pareja 6½, Roncaglia 7, Corominas 7, Verdú 7, Tamudo 6, Ninkovic 6, Olic 5½ | | Viktoria Plzen | 1 | 66 Rosický | | Half-time: | 0-0 | | Referee: | Van Der Ende 7½ | | Attendance: | 43,764 | | Possession: | 57%-43% | | Total shots: | 16-3 | | MoM: | Rosický |
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| | (4-3-3): Vaclik 7, Gebre Selassie 8, Kadlec 7, Darida 8½, Hübschman 8, Suchý 7½, Kolár 7½, Rosický 8½, Vydra 6½, Sivok 7, Lafata 7 | | Liverpool | 0 |
| | 16 Sřrum, 22 Carroll, 38 Aleksic | | (4-3-3): Pyatov 6½, Vrsaljko 6, Insúa 6½, Badelj 7, Aleksic 6, Nolan 6, Ball 5½, Saric 5½, Carroll 6½, Sřrum 5½, Németh 6 | | Round 4 | | Ajax | 1 | 11 Sneijder | | Half-time: | 1-3 | | Referee: | José Pratas 7 | | Attendance: | 51,577 | | Possession: | 55%-45% | | Total shots: | 17-17 | | MoM: | Rose |
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| | (4-3-3): Krul 6, Van Der Wiel 7½, Willems 7, De Jong 7½, De Vrij 7, Van Rhijn 6½, Promes 7, Lens 6½, Huntelaar 6, Sneijder 6½, Narsingh 5½ | | Accrington Stan. | 3 | 33 Jagielka, 37 Musa, 42 Welbeck |
| | (4-3-3): Hart 6, Smalling 7, Rose 8, Cahill 6½, Jagielka 7, Ramsey 6, Musa 7½, Allen 7, Sturridge 6, Barkley 6½ (81 Williams 6), Welbeck 7 | | Celtic | 1 | 14 Cissé | | Half-time: | 1-0 | | Referee: | Salcedo 7½ | | Attendance: | 43,734 | | Possession: | 49%-51% | | Total shots: | 16-13 | | MoM: | Cahill | | TV: | highlights |
| | 7 Cissé | | (4-3-3): Boruc 8, José Ángel 6, Izaguirre 8, Cahill 8½, Rogne 6½, Brown 6, Oliver 6, McGeady 7½, Cissé 6½, Cissé 6½ (62 Templeton 6), Keane 6½ | | Tottenham Hotspur | 0 |
| | 33 Torres, 45 Wickham, 90 Shirokov | | (4-3-3): Leno 7, Cáceres 7, Cole 7, Shirokov 7½, Rami 7, Álvarez 6, Wickham 7, Nani 7, Torres 6½, Fierro 5½, Gabbiadini 6 | | Feyenoord | 2 | 42 De Guzman, 89 Castaignos | | Half-time: | 1-2 | | Referee: | Wieser 7½ | | Attendance: | 36,310 | | Possession: | 56%-44% | | Total shots: | 15-11 | | MoM: | Kuyt |
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| | (4-3-3): Verhoeven 6, Hutchinson 7½, Nelom 6, Leerdam 7, Pieters 7½, Dingsdag 6, Kuyt 7½, De Guzman 7½, Castaignos 7½, Van Wolfswinkel 6, Schaken 5½ | | Manchester United | 2 | 23 Anderson, 37 Berbatov |
| | (4-3-3): Kuszczak 6, Rafael 6, Santon 6½, Carrick 6 (90 Shelvey 6), Matip 7 (89 Wilson 6), O'Shea 6½, Giovani 6½, King 6, Berbatov 7, Anderson 6½, Diouf 6 | | Liverpool | 2 | 24 Carroll, 42 Németh | | Half-time: | 2-0 | | Referee: | Penicka 7 | | Attendance: | 28,070 | | Possession: | 49%-51% | | Total shots: | 12-9 | | MoM: | Fritz | | TV: | highlights |
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| | (4-3-3): Pyatov 7, Vrsaljko 7, Insúa 7, Badelj 7½, Aleksic 5½, Nolan 6½, Ball 6, Saric 6, Carroll 7, Sřrum 6, Németh 7 | | Bayer Leverkusen | 0 |
| | 1 Rubén Pérez, 79 Fritz | | (4-3-3): Stanek 7, Fritz 8, Schulz 6½, Cambiasso 7, Díaz 8, Castro 6, Elano 7½, Kakuta 6, Kuranyi 7, Rubén Pérez 6½, Gavranovic 6½ (63 Balitsch 5½) | | Marseille | 3 | 3 Kolodziejczak, 6 Tabanou, 39 Menez | | Half-time: | 3-0 | | Referee: | Brito Arceo 7 | | Attendance: | 45,295 | | Possession: | 56%-44% | | Total shots: | 14-12 | | MoM: | Lamela |
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| | (4-3-3): Riou 7, Richarlyson 6½, Tabanou 7½, Lamela 7½, Kolodziejczak 6½, Kaboré 6, Pjanic 5½ (65 Jarvis 7½), Menez 7½, Abriel 7, Ben Arfa 7½, Benzema 7 | | Lorient | 0 |
| | 73 Diarra | | (4-3-3): Sorin 7, Congré 7, Morel 6½, Balmont 6½, Marchal 6½, Kanté 6, Amalfitano 7, Diarra 6, Sagbo 6½, Mvuemba 6½, Birsa 6 | | Napoli | 1 | 26 Gignac | | Half-time: | 1-2 | | Referee: | Waddel 6 | | Attendance: | 42,929 | | Possession: | 51%-49% | | Total shots: | 13-13 | | MoM: | Keita |
| | 40 El Kaoutari | | (4-3-3): Sepe 6, Campagnaro 7 (77 Necip 6), El Kaoutari 6½, Keita 7½, Cannavaro 7½, Gastaldello 6½, Cigarini 6½, Gargano 6½, Gignac 6½ (76 Zaccardo 6), Mokotjo 7½, Quagliarella 7 | | Internacional | 3 | 9 Wágner, 43 Wágner, 65 Jô |
| | (4-3-3): Fernando Henrique 6½, Mariano 6½ (58 Joăo Pedro 8), Kléber 7, Fernando 6½, Marcelo 6, Hilton 6½, Giuliano 7 (81 Walter 6), Wágner 7, Jô 7, Fred 6, Taison 6½ | | Palermo | 4 | 10 Inler, 30 Cassano, 54 Candreva, 77 Insigne | | Half-time: | 2-0 | | Referee: | Uilenberg 7½ | | Attendance: | 38,808 | | Possession: | 55%-45% | | Total shots: | 13-8 | | MoM: | Cassano |
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| | (4-4-2): Consigli 7, Darmian 7½, Montolivo 7½, Moretti 6½, Bonaventura 7½, Astori 6, Criscito 7, Cassano 8, Candreva 8, Inler 7, Insigne 7 | | Manchester City | 0 |
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| | (4-3-3): Arrizabalaga 6½, Sagna 7, Vertonghen 6½, Källström 6½, Vidic 6, Badstuber 6½, Rodríguez 7 (85 McAllister 6), Herrmann 6, Soldado 7½, Ocampos 6, Vucinic 6½ | | SV Werder Bremen | 0 |
| | Half-time: | 0-3 | | Referee: | Steinberg 6½ | | Attendance: | 31,169 | | Possession: | 46%-54% | | Total shots: | 7-16 | | MoM: | Barnetta |
| | 87 Wagner | | (4-4-2): Parish 4½, Prödl 6½, Diego Capel 6, Bargfrede 7½, Smith 6, Samaris 6, Oar 6, Hunt 7, Dost 7, Fetfatzidis 7, Wagner 6 | | FC Schalke 04 | 5 | 12 Barnetta, 20 Elmander, 44 De Jong, 65 Barnetta, 77 Barnetta | | 70 Kelly, 86 Avevor | | (4-3-3): Mielitz 5½, Kelly 7½, Durm 7½, Träsch 6½, Salcido 6½, Avevor 6½, Kroos 7½, Barnetta 8, De Jong 7½, Crouch 6, Elmander 7 | | Spartak | 5 | 21 Ozdoev, 35 Dzagoev, 38 Berezutsky, 58 Mamaev, 82 Dzagoev | | Half-time: | 3-0 | | Referee: | Larsen 7½ | | Attendance: | 39,669 | | Possession: | 47%-53% | | Total shots: | 19-16 | | MoM: | Raul Meireles |
| | 6 Makeev | | (4-3-3): Ryzhikov 6½, Parshivlyuk 7½, Kombarov 7, Mamaev 6½, Makeev 7, Berezutsky 6½, Zhirkov 6½, Dzagoev 7, Rondón 6, Ozdoev 7½, Yakovlev 6½ | | Sevilla | 0 |
| | 1 Kiko, 28 Renato, 29 Renato | | (4-3-3): Navas 7½, Silvestre 7½, Fernando Navarro 7½, Raul Meireles 8, Naldo 7, Alexis 6½, Navas 6½, Luscombe 5½, Kiessling 6½, Renato 6, Kiko 6½ | | TSG Hoffenheim | 0 |
| | Half-time: | 0-1 | | Referee: | Vítor Pereira 6½ | | Attendance: | 30,141 | | Possession: | 42%-58% | | Total shots: | 11-14 | | MoM: | López |
| | 19 Zuculini, 73 Ba, 74 Ibisevic | | (4-3-3): Fährmann 6½, Ebondo 6½, Raitala 7, Maicosuel 7½, Ruíz 6½, Mangane 6, Zuculini 6, Salihovic 6, Ba 7 (83 Amat 6), Ibisevic 6, Sessčgnon 5½ | | River Plate | 2 | 25 López, 65 López | | 44 Orban, 59 Johansen, 66 Mouche | | (4-3-3): Marchesín 7, López 8½, Basanta 8, Johansen 7, Cabral 7½, Orban 7, Affranchino 7½, Amrabat 6½, López 7, Mouche 5½, Víctor 6½ |
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