| Round 3 | | Boca Juniors | 0 |
| | Half-time: | 0-1 | | Referee: | Romaschenko 6½ | | Attendance: | 44,744 | | Possession: | 46%-54% | | Total shots: | 9-18 | | MoM: | Lulic |
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| | (4-3-3): Renan 6, Juárez 7, Monzón 7½, Manuel Fernandes 7½, Burdisso 6½, Muńoz 6, Bruno César 7 (53 Diego Mauricio 7), Moralez 7½, Funes 7 (57 Albín 6½), Barrera 6, Saviola 6 | | Brřndby | 1 | 27 Selçuk |
| | (4-3-3): Sirigu 6½, Jantschke 6½, Lulic 8, Raúl García 6½ (66 Ansaldi 6½), Zapata 6½, Corluka 7, Pérez 7, Gervinho 7, Bacca 6½, Selçuk 7, Roberto Firmino 6½ | | Newport County | 3 | 43 Bertrand, 45+2og Aquilani, 81 Ings | | Half-time: | 2-0 | | Referee: | Vink 7 | | Attendance: | 19,401 | | Possession: | 51%-49% | | Total shots: | 17-10 | | MoM: | Aquilani | | TV: | highlights |
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| | (4-3-3): McGregor 6½, Stones 6½, Bertrand 7½, Cleverley 7½, Tomkins 7, Clark 7, Henderson 6, Ayew 6, Armstrong 5½, Badu 6½, Ings 7 | | VfB Stuttgart | 1 | 50p Schieber | | 66 Boulahrouz | | (4-3-3): Ulreich 6½, Osorio 7½, Boka 7, Aquilani 8, Niedermeier 7½, Boulahrouz 6, Kuzmanovic 6½, Gebhart 6, Schieber 6, Hamit 6, Marica 6 | | West Ham United | 2 | 22 Brozovic, 43 Holmes | | Half-time: | 2-1 | | Referee: | Maisonlahti 6 | | Attendance: | 34,468 | | Possession: | 45%-55% | | Total shots: | 13-14 | | MoM: | Arnautovic |
| | 3 Brozovic, 27 Bent, 59 Brozovic, 74 Holmes | | (4-3-3): Green 5½, Gray 6, Gibbs 6, Gerrard 6 (59 Johnson 7½), Samba 6½, Mancienne 7, Holmes 6, Brozovic 7½, Bent 6, Carroll 7, Sellin 5½ | | Inter | 3 | 13 Milito, 61 Pandev, 79 Arnautovic |
| | (4-3-3): Belec 6½, Donati 6½ (79 Mariga 6), Zuńiga 7½, Maxim 6, Britos 6½, Biava 7, Rômulo 7, Arnautovic 8, Milito 7, Eto'o 7, Pandev 5½ | | Round 4 | | AZ | 0 |
| | Half-time: | 0-3 | | Referee: | Heim 7½ | | Attendance: | 17,077 | | Possession: | 37%-63% | | Total shots: | 7-21 | | MoM: | Tadic |
| | 4 Guđmundsson | | (4-3-3): Stamatopoulos 6, Husev 6, Tiendalli 6, Mavuba 7, Moisander 6, Moreno 6½, Heitinga 5½, Esswein 6½, Guđmundsson 6, Brama 6, N'Zogbia 6 | | Roma | 3 | 27 Tadic, 39 Tadic, 42 Pazzini |
| | (4-3-3): Adler 6½, Jonathan 7, Young 7½, Schneiderlin 8, Fazio 8, Coloccini 6½, Cuadrado 7½, Tadic 8½, Pazzini 7, Calhanoglu 6½, Kruse 6 | | Ayr United | 3 | 9 Kane, 59 Davis, 66 Berahino | | Half-time: | 1-3 | | Referee: | Reijgwart 6 | | Attendance: | 24,095 | | Possession: | 54%-46% | | Total shots: | 16-8 | | MoM: | Fletcher |
| | 35 Kane | | (4-4-2): Butland 6½, Clyne 7, Robertson 7½, Fletcher 8½, Dann 6½, Shawcross 6, Davis 7½, Oxlade-Chamberlain 8, Kane 8, McCarthy 6½, Berahino 7 | | CSKA | 3 | 6 Dzsudzsák, 16 Dzsudzsák, 33 Dzsudzsák | | 69 King, 85 Pelé | | (4-3-3): Moyá 5½, Nababkin 6½, Schennikov 6, Denisov 7½, Ignashevich 6, Pelé 6, Oliseh 7½, Dzsudzsák 6½, King 5½, Okay 6, Gyasi 6 | | Barcelona | 2 | 26 Gomez, 81 Maxwell | | Half-time: | 1-2 | | Referee: | Řvrebř 5½ | | Attendance: | 40,593 | | Possession: | 54%-46% | | Total shots: | 16-8 | | MoM: | Mexčs | | TV: | highlights |
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| | (4-3-3): Müller 5½, Abate 7, Maxwell 8, Tiago 7, Mexčs 8½, Fernández 6½, Jeffren 7, Isaac Cuenca 6½, Gomez 8, Torres 5½, Vílla 6 | | Lyon | 3 | 10 Bedimo, 25 Boussoufa, 73 Belfodil |
| | (4-3-3): Bettinelli 5½, Théophile-Catherine 7, Bedimo 7½, Coquelin 7, Armand 6½, Taiwo 6, Obraniak 7, Boussoufa 7 (55 Sunu 6½), Roux 7, Fatih 6, Belfodil 6 | | Boulogne | 2 | 26 Muniain, 37 Muniain | | Half-time: | 2-0 | | Referee: | Stein 6 | | Attendance: | 14,863 | | Possession: | 52%-48% | | Total shots: | 15-13 | | MoM: | Frey |
| | 3 Jadson, 8 Klose | | (4-3-3): Frey 7½, Galhardo 6, Ibańez 7, Mikel 7½, Gamberini 6½ (85 Kverkvelia 6), Klose 6, Gökhan 6½, Muniain 6 (75 Emeghara 7), Álvaro 6½, Jadson 7, Kalou 6½ | | Fenerbahçe | 0 |
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| | (4-3-3): Tolga 7, Gökhan 6½, Bekir 7, Özer 7, Egemen 6½, Remzi Giray 6, Mehmet 7, Cech 7, Sow 7 (61 Serdar 7), Semih 6, Burak 6½ | | Brřndby | 1 | 17 Gervinho | | Half-time: | 1-0 | | Referee: | Onufer 6½ | | Attendance: | 28,937 | | Possession: | 45%-55% | | Total shots: | 12-14 | | MoM: | Salvio | | TV: | live |
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| | (4-3-3): Sirigu 7½, Jantschke 7, Lulic 7½, Raúl García 6½ (66 Ansaldi 6), Zapata 6½, Corluka 6½, Pérez 7, Gervinho 6½, Bacca 6½, Selçuk 6, Roberto Firmino 6 | | Atlético Madrid | 0 |
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| | (4-3-3): Marinelli 7½, Mario 7½, Marcos Alonso 6½, Biglia 7½, Rodríguez 6½, Marc Muniesa 6½ (51 Jesús 6½), Salvio 8, Iago 7, Borja 7, Banega 7 (67 Schaars 6), Bojan 6½ | | Fiorentina | 2 | 26 Konko, 41p Gilardino | | Half-time: | 2-1 | | Referee: | Medina Cantalejo 6½ | | Attendance: | 34,722 | | Possession: | 46%-54% | | Total shots: | 9-9 | | MoM: | Gobbi |
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| | (4-3-3): Mirante 7, De Silvestri 6½, Gobbi 8, Rômulo 7, Cana 7, Felipe 6½, Konko 6½, Marchionni 5½, Gilardino 6, Donadel 7, Ljajic 6½ | | Aston Villa | 2 | 34 Bannan, 83 Aissati |
| | (4-3-3): Viviano 6½, Naughton 7, Taylor 8, Cirigliano 6½, Collins 7, Cuéllar 5½, Sidwell 7, Bannan 6½, Delfouneso 6½, Reo-Coker 6½, Aissati 6½ | | Hamburger SV | 1 | 64 Petric | | Half-time: | 0-2 | | Referee: | Díaz Vega 7 | | Attendance: | 46,020 | | Possession: | 56%-44% | | Total shots: | 12-10 | | MoM: | Harnik |
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| | (4-3-3): Karnezis 6½, Boenisch 7, Aogo 6½, Rincón 7, Mathijsen 6½, Piris 7, Harnik 7½, Jansen 6, Guerrero 7, Pavlyuchenko 5½, Petric 7 | | Milan | 2 | 35 Mandzukic, 45+1 Mandzukic |
| | (4-3-3): Ospina 6½, Aurier 6½, Kolarov 6 (85 Quintero 6), Cabaye 6½, Javi Martínez 7, Dória 5½, Joaquín 6½, Depay 5½, Mandzukic 6½, Ander 6½, Volland 6½ | | Independiente | 2 | 47 Gutierrez, 61 Osvaldo | | Half-time: | 0-0 | | Referee: | Grabher 7 | | Attendance: | 35,119 | | Possession: | 46%-54% | | Total shots: | 18-11 | | MoM: | Rodríguez |
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| | (4-3-3): Orión 7½, Dijkhuizen 8, Vallés 7, Rodríguez 8½, Galeano 7½, Vittor 6½, Fredes 6, Mancuello 8, Osvaldo 7, Gandín 6, Gutierrez 6½ | | West Ham United | 1 | 88og Vittor | | 17 Carroll, 57 Bent | | (4-3-3): Green 7, Gray 7½, Gibbs 6, Gerrard 7½, Samba 6, Mancienne 6, Holmes 7, Brozovic 7, Bent 6½, Carroll 7 (47 Brown 6), Sellin 5½ | | Inter | 3 | 6 Milito, 14 Donati, 82 Arnautovic | | Half-time: | 2-0 | | Referee: | Nielsen 6½ | | Attendance: | 43,499 | | Possession: | 45%-55% | | Total shots: | 17-13 | | MoM: | Britos |
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| | (4-3-3): Belec 7, Donati 5½ (55 Mariga 6½), Zuńiga 7, Maxim 6½, Britos 8, Biava 6, Rômulo 7, Arnautovic 7, Milito 7, Eto'o 6½, Pandev 6 | | Hajduk Split | 0 |
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| | (4-3-3): Tomic 7½, Oremus 6, Jozinovic 7 (73 Cernat 6), Vrdoljak 7½, Maloca 7, Buljat 6½, Rubil 7, Ibricic 7, Lakic 6, Cop 6, Sharbini 7 | | Udinese | 1 | 38 Basta | | Half-time: | 1-1 | | Referee: | Webb 6½ | | Attendance: | 30,829 | | Possession: | 38%-62% | | Total shots: | 9-13 | | MoM: | Stones |
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| | (4-3-3): Szczesny 7, Basta 7, Papadopoulos 7½, Isla 7, Léo 7½, Diarra 7, Lodi 6, Zimling 6, Alex Geijo 6, D'Agostino 6½, Jaime 5 | | Newport County | 2 | 10 Ayew, 54 Cleverley |
| | (4-3-3): McGregor 7, Stones 8, Bertrand 7½, Badu 7½, Tomkins 7, Clark 7 (79 Phillips 6), Henderson 7½, Ayew 8, Woodrow 6½, Cleverley 7½, Ings 6½ |
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