| Round 1 | | Baník Ostrava | 2 | 4 Arda, 47 Totti | | Half-time: | 1-0 | | Referee: | Ziober 6 | | Attendance: | 17,365 | | Possession: | 46%-54% | | Total shots: | 9-11 | | MoM: | Lamela |
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| | (4-3-3): Perin 6, Hubocan 7, Filipe Luis 6½, Xhaka 7, Varane 6½, N'Koulou 6, Kouassi 6, Arda 6½, Martínez 7, Arnold 6 (52 Busch 6), Totti 7 | | Marseille | 2 | 56 Brandăo, 73 Lamela |
| | (4-3-3): Riou 6½, Reveillčre 7, Kolodziejczak 7½, Menez 7½, Alex Silva 6½, Tabanou 7, Pjanic 7, Lamela 7½, Brandăo 6½, Kaboré 6½, Benzema 7 | | Celtic | 0 |
| | Half-time: | 0-0 | | Referee: | Vorjas 5½ | | Attendance: | 35,550 | | Possession: | 54%-46% | | Total shots: | 15-5 | | MoM: | Rogne |
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| | (4-3-3): Boruc 7, José Ángel 6½, Izaguirre 7½, Defour 7½, Rogne 8½, Ki 7 (65 Cissé 6½), Oliver 6½, McGeady 7½, Cissé 7, Cahill 6½, Keane 7 | | Palmeiras | 0 |
| | 22 Marquinhos, 24 Ronaldinho, 50 Pierre, 52 Robert, 85 Henrique | | (4-3-3): Júlio César 7½, Henrique 6½, Alex Telles 8, Lucas 6½, Danilo 8, Armero 6½, Diego Souza 6½, Marquinhos 6, Robert 6, Pierre 6½, Ronaldinho 6 | | Espanyol | 1 | 48 Gurpegui | | Half-time: | 0-1 | | Referee: | Rudy 6½ | | Attendance: | 35,287 | | Possession: | 40%-60% | | Total shots: | 15-10 | | MoM: | Gurpegui | | TV: | highlights |
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| | (4-3-3): Álvarez 6½, Roncaglia 6½, Leugers 7, Raúl Baena 6, Gurpegui 8, Pareja 6½, Corominas 6, Pedersen 6, Tamudo 7, Juanmi 6, Olic 6½ | | Feyenoord | 1 | 33 Castaignos | | 57 Maduro | | (4-3-3): Alvarado 7, Hutchinson 7, Nelom 7½, Leerdam 7, Van Beek 7, Maduro 6½, Kuyt 7, Van La Parra 7, Castaignos 6, Van Wolfswinkel 6, Kazim-Richards 7½ | | FC Schalke 04 | 1 | 18 Barnetta | | Half-time: | 1-1 | | Referee: | Damgaard 7 | | Attendance: | 39,047 | | Possession: | 42%-58% | | Total shots: | 11-14 | | MoM: | Mielitz | | TV: | highlights |
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| | (4-3-3): Mielitz 7½, Träsch 6½, Durm 7, Costa 7½, Salcido 7, Kelly 6, Farfán 6½, Barnetta 6, De Jong 6, Crouch 6½, Elmander 6½ | | Manchester City | 1 | 32 Vucinic | | 26 Touré | | (4-3-3): Kapino 7, Sagna 7, Vertonghen 7½, Touré 7½, Demichelis 7, Song 6, Navas 7, Herrmann 7, Soldado 7, Källström 7, Vucinic 7 | | Fenerbahçe | 2 | 1 Mehmet, 9 Burak | | Half-time: | 2-0 | | Referee: | Borriello 7 | | Attendance: | 41,437 | | Possession: | 37%-63% | | Total shots: | 10-11 | | MoM: | Rafael |
| | 37 Semih | | (4-3-3): Tolga 7, Gökhan 7, Bekir 6½, Özer 7½, Remzi Giray 6½, Serkan 5½, Mehmet 6, Selçuk 5½, Sow 7, Semih 6, Burak 6½ | | Manchester United | 1 | 47 Berbatov |
| | (4-3-3): Kuszczak 7, Rafael 8½, Davies 7, Schweinsteiger 7½, O'Shea 6½ (58 Anderson 7½), McNair 7½, Giovani 8½, Obertan 7½, Berbatov 7½, Huddlestone 6½, Martial 6 | | Internacional | 2 | 59 Júlio Baptista, 66 Fred | | Half-time: | 0-2 | | Referee: | Fallmann 7 | | Attendance: | 42,936 | | Possession: | 53%-47% | | Total shots: | 18-15 | | MoM: | Ignjovski |
| | 19 Júlio Baptista | | (4-3-3): Fernando Henrique 5½, Danilo 6, Kléber 7, Júlio Baptista 7½, Marcelo 6, André Bahia 7, Giuliano 7, Wágner 7, Fred 7, Jô 6½, Taison 6 (53 Mariano 6½) | | Bayern München | 3 | 20 Barrios, 33 Klose, 49 Klose | | 54 Djourou, 78 Aubameyang | | (4-3-3): Kraft 6½, Essien 6½, Pranjic 6½ (56 Palacios 6½), Ignjovski 7½, Papastathopoulos 7½, Djourou 6½, Forlin 5½, Marin 6½, Klose 6½, Barrios 5½, Aubameyang 5½ | | Milan | 4 | 8 Depay, 27 Ranocchia, 29 Joaquín, 53 Volland | | Half-time: | 3-1 | | Referee: | Rodomonti 6 | | Attendance: | 49,253 | | Possession: | 51%-49% | | Total shots: | 16-8 | | MoM: | Cabaye |
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| | (4-3-3): Ospina 7, Jedvaj 7½, Kolarov 6½, Cabaye 8, Ranocchia 7½, Laporte 6½, Joaquín 7½, Depay 6½, Mandzukic 6½, Bacca 6, Volland 7 | | Athletic Bilbao | 1 | 33 Mario Suárez | | 20 Susaeta, 26 Vela | | (4-3-3): Pigliacelli 6½, Iraola 6, Aurtenetxe 6, Parejo 7½, Botía 7½, Torres 6, Susaeta 7 (82 Canella 7½), Vela 6½ (67 Nsue 6), Eduardo 6½, Mario Suárez 7½, Osvaldo 6 | | Newport County | 3 | 59 Rodriguez, 81 Rhodes, 88 Badu | | Half-time: | 0-1 | | Referee: | Sh'habri 7 | | Attendance: | 19,465 | | Possession: | 49%-51% | | Total shots: | 15-14 | | MoM: | Cleverley |
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| | (4-3-3): McGregor 7, Stones 6½, Bertrand 6, Cleverley 8, Tomkins 7½, Clark 5½ (73 Baker 6), Alli 6½, Ayew 7, Rhodes 6½, Badu 6½, Rodriguez 5½ | | Tottenham Hotspur | 1 | 39 Monreal | | 47 Benitez | | (4-3-3): Alnwick 7, Rami 6, Monreal 6½, Shirokov 6½, Ogbonna 6½, Cole 7, Foor 6½, Nani 6, Matavz 5½, Benitez 5½, Wickham 6 | | River Plate | 2 | 28 Amrabat, 32 Basanta | | Half-time: | 2-1 | | Referee: | Clattenburg 7 | | Attendance: | 40,991 | | Possession: | 46%-54% | | Total shots: | 8-19 | | MoM: | López | | TV: | highlights |
| | 52 Mouche, 57 Johansen, 58 Johansen, 71 Mouche | | (4-3-3): Marchesín 5½, Mercado 6½, Basanta 7, Buonanotte 7, Cabral 6½, López 6½, Formica 6½, Amrabat 7½, López 7½, Johansen 5½, Mouche 6 | | Liverpool | 3 | 25 Vitolo, 72 Carroll, 83 Vitolo |
| | (4-3-3): Pyatov 6½, Vrsaljko 7, Sakho 7½, Badelj 7, Lovren 6½, Insúa 7½, Henderson 7 (58 Keane 6), Vitolo 6½, Carroll 7, Moses 6, Origi 6 | | Sevilla | 0 |
| | Half-time: | 0-0 | | Referee: | Stanisteanu 7 | | Attendance: | 38,311 | | Possession: | 55%-45% | | Total shots: | 12-6 | | MoM: | Piatti | | TV: | live |
| | 59 Silvestre | | (4-3-3): Navas 7, Aleix Vidal 7½, Fernando Navarro 6, Makoun 7½, Naldo 6½, Silvestre 6, Kiko 6½, Piatti 8, Kiessling 7, Novillo 5½, Giovinco 6½ | | Napoli | 1 | 54 Gignac |
| | (4-3-3): De Sanctis 7, Maggio 6½, El Kaoutari 7, Cigarini 7, Cannavaro 7½, Gastaldello 7, Gargano 6½, Ledesma 6½, Gignac 7, Mokotjo 6½, Quagliarella 6 | | Viktoria Plzen | 2 | 15 Darida, 46 Darida | | Half-time: | 1-1 | | Referee: | Wiley 6 | | Attendance: | 40,140 | | Possession: | 45%-55% | | Total shots: | 14-13 | | MoM: | Brunt |
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| | (4-3-3): Vaclik 7, Gebre Selassie 7, Hlousek 7½, Plasil 7, Hübschman 7, Suchý 6½, Kolár 6, Jirácek 6 (78 Procházka 6), Vydra 6½, Darida 6, Lafata 6½ | | Ayr United | 1 | 19 McCarthy | | 31 Dann | | (4-3-3): Guzan 7½, Clyne 7, Brunt 8, Wilshere 6½, Shawcross 7, Dann 6, McCarthy 7, Oxlade-Chamberlain 7, Kane 7½, Fletcher 6, Berahino 5½ | | Round 2 | | Athletic Bilbao | 0 |
| | Half-time: | 0-4 | | Referee: | Craciun 8 | | Attendance: | 35,598 | | Possession: | 44%-56% | | Total shots: | 12-19 | | MoM: | Bertrand |
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| | (4-3-3): Pigliacelli 4, Iraola 7, Aurtenetxe 6½, Parejo 6½, Botía 7, Torres 5½, Susaeta 6 (82 Canella 6), Vela 7 (67 Nsue 6), Eduardo 6½, Mario Suárez 6, Osvaldo 5½ | | Newport County | 5 | 2 Rodriguez, 15 Ayew, 21 Rodriguez, 43 Rhodes, 67 Rhodes |
| | (4-3-3): McGregor 5½, Stones 6½ (85 Baker 6), Bertrand 8, Cleverley 6, Tomkins 7½, Clark 6, Alli 7, Ayew 8, Rhodes 7½, Badu 6, Rodriguez 7½ | | Ayr United | 0 |
| | Half-time: | 0-2 | | Referee: | Collina 7½ | | Attendance: | 34,113 | | Possession: | 55%-45% | | Total shots: | 12-9 | | MoM: | Wilshere |
| | 18 Fletcher | | (4-3-3): Guzan 6½, Clyne 7½, Brunt 7½, Wilshere 8½, Shawcross 8, Dann 6, McCarthy 6, Oxlade-Chamberlain 7½, Kane 7½, Fletcher 6, Berahino 6½ | | Milan | 2 | 7 Mandzukic, 14 Mandzukic |
| | (4-3-3): Ospina 7, Jedvaj 7½, Kolarov 6½, Cabaye 7, Ranocchia 7½, Laporte 6½, Joaquín 6½, Depay 7½, Mandzukic 7, Bacca 5½, Volland 6 | | Bayern München | 1 | 36 Marin | | Half-time: | 1-3 | | Referee: | Michel 6 | | Attendance: | 45,981 | | Possession: | 47%-53% | | Total shots: | 11-17 | | MoM: | Farfán |
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| | (4-3-3): Kraft 6, Essien 7, Pranjic 7½, Ignjovski 7½, Papastathopoulos 7, Djourou 6, Sahin 6, Marin 7, Klose 7½, Barrios 6½, Aubameyang 6½ | | FC Schalke 04 | 3 | 2 Barnetta, 11 Durm, 38 Elmander | | 50 Kelly | | (4-3-3): Mielitz 6, Träsch 7, Durm 7½, Costa 7, Salcido 7, Kelly 6, Farfán 8, Barnetta 7½, De Jong 6½, Crouch 5½, Elmander 6½ | | Feyenoord | 2 | 29 Kuyt, 79 Castaignos | | Half-time: | 1-0 | | Referee: | Korac 5½ | | Attendance: | 39,318 | | Possession: | 43%-57% | | Total shots: | 6-12 | | MoM: | Gökhan |
| | 18 Kazim-Richards | | (4-3-3): Alvarado 7, Hutchinson 6½, Nelom 7, Biseswar 7, Van Beek 7½, Maduro 6, Kuyt 7½, De Guzman 7, Castaignos 7, Leerdam 5½, Kazim-Richards 6 | | Fenerbahçe | 0 |
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| | (4-3-3): Tolga 7, Gökhan 8, Bekir 6½, Özer 7½, Remzi Giray 6, Serkan 6, Mehmet 6½, Selçuk 6½, Sow 7½, Semih 6, Burak 6 | | Liverpool | 1 | 23 Carroll | | Half-time: | 1-0 | | Referee: | Rennie 6 | | Attendance: | 40,127 | | Possession: | 47%-53% | | Total shots: | 12-13 | | MoM: | Álvarez |
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| | (4-3-3): Pyatov 7, Vrsaljko 7, Sakho 6½, Badelj 6½, Lovren 7½, Insúa 7, Henderson 6, Vitolo 7, Carroll 7½, Moses 5½, Origi 7 | | Espanyol | 0 |
| | 13 Corominas | | (4-3-3): Álvarez 8, Roncaglia 7, Leugers 6½, Gurpegui 7½, Pareja 6½, Hangeland 6½, Corominas 6½, Pedersen 7, Tamudo 6, Raúl Baena 6, Olic 6½ | | Manchester City | 1 | 49 Soldado | | Half-time: | 0-0 | | Referee: | Hansson 7 | | Attendance: | 43,212 | | Possession: | 57%-43% | | Total shots: | 16-5 | | MoM: | Sagna |
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| | (4-3-3): Kapino 6½, Sagna 8½, Vertonghen 8, Touré 7, Demichelis 7½, Song 6, Navas 7½, Herrmann 7½, Soldado 7, Källström 7½, Vucinic 6 | | Viktoria Plzen | 1 | 54 Lafata |
| | (4-3-3): Vaclik 6, Gebre Selassie 6½, Kadlec 7, Plasil 7, Hübschman 6½, Suchý 6, Kolár 6½ (66 Hlousek 7), Jirácek 6½, Vydra 5½, Sivok 6, Lafata 6 | | Manchester United | 2 | 8 Berbatov, 33 Obertan | | Half-time: | 2-1 | | Referee: | Larsen 6 | | Attendance: | 40,665 | | Possession: | 59%-41% | | Total shots: | 14-6 | | MoM: | Obertan |
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| | (4-3-3): Kuszczak 6½, Rafael 7, Davies 8, Schweinsteiger 8½, O'Shea 7, McNair 6 (50 Carrick 6½), Giovani 7½, Obertan 8½, Berbatov 7, Huddlestone 7, Martial 5½ | | River Plate | 1 | 5 López | | 13 Amrabat, 38 Amrabat | | (4-3-3): Marchesín 6½, Mercado 6½, Basanta 6½, Buonanotte 6½, Cabral 6½, López 6, Formica 6, Amrabat 6, López 7, Johansen 6½, Mouche 5½ | | Marseille | 1 | 9 Ben Arfa | | Half-time: | 1-1 | | Referee: | Mitrovic 8½ | | Attendance: | 45,604 | | Possession: | 56%-44% | | Total shots: | 13-6 | | MoM: | Menez |
| | 62 Tabanou | | (4-3-3): Riou 7, Reveillčre 7, Kolodziejczak 7½, Menez 8, Alex Silva 7½, Tabanou 7, Pjanic 7½, Lamela 7, Brandăo 6½, Ben Arfa 6, Benzema 6½ | | Celtic | 1 | 33 Cahill |
| | (4-3-3): Boruc 7, José Ángel 5½, Izaguirre 8, Defour 6, Rogne 7, Ki 7 (65 Cissé 6½), Oliver 6, McGeady 6½, Cissé 6½, Cahill 6½, Keane 6½ | | Napoli | 1 | 8 Gargano | | Half-time: | 1-0 | | Referee: | Beeby 5½ | | Attendance: | 46,240 | | Possession: | 42%-58% | | Total shots: | 8-10 | | MoM: | El Kaoutari |
| | 11 Gargano, 49 Cigarini, 66 Gargano | | (4-3-3): De Sanctis 7, Maggio 6½ (68 Zaccardo 7), El Kaoutari 8½, Gargano 7, Gastaldello 7, Cannavaro 6½, Cigarini 5½, Necip 6½, Gignac 7, Ledesma 6, Quagliarella 7 | | Internacional | 1 | 70 Júlio Baptista | | 23 Marcelo | | (4-3-3): Fernando Henrique 7½, Danilo 8, Kléber 7½, Júlio Baptista 7, Marcelo 7, André Bahia 6, Giuliano 7, Wágner 7, Fred 6½ (83 Wellington Silva 6), Walter 6, Taison 7 | | Palmeiras | 3 | 21 Alex Telles, 48 Ronaldinho, 80 Ronaldinho | | Half-time: | 1-0 | | Referee: | Matuet 6½ | | Attendance: | 28,597 | | Possession: | 45%-55% | | Total shots: | 12-7 | | MoM: | Varane |
| | 90 Pierre | | (4-3-3): Júlio César 7, Henrique 7, Alex Telles 7½, Lucas 7, Danilo 7, Rafael Toloi 5½ (81 Armero 6½), Diego Souza 7, Marquinhos 6½, Robert 6, Pierre 7, Ronaldinho 7 | | Baník Ostrava | 0 |
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| | (4-3-3): Perin 7, Hubocan 7½, Filipe Luis 7½, Xhaka 7, Varane 7½, N'Koulou 6½, Kouassi 6, Arda 7, Di Natale 7, Martínez 6½, Totti 6 | | Tottenham Hotspur | 1 | 18 Nani | | Half-time: | 1-2 | | Referee: | Van Der Ende 6 | | Attendance: | 36,069 | | Possession: | 50%-50% | | Total shots: | 17-11 | | MoM: | Shirokov |
| | 32 Matavz | | (4-3-3): Alnwick 5½, Rami 6½, Monreal 8, Shirokov 8½, Ogbonna 6, Cole 7½, Foor 6½, Nani 7½, Matavz 6½, Wickham 6, Gabbiadini 6½ (77 Fierro 6) | | Sevilla | 3 | 2 Kiessling, 20 Kiessling, 82 Piatti | | 11 Piatti, 29 Kiessling, 67 Novillo, 68 Naldo | | (4-3-3): Navas 6½, Aleix Vidal 7½, Fernando Navarro 8, Makoun 6½, Naldo 7½, Silvestre 7, Kiko 6½, Piatti 7, Kiessling 6½, Novillo 6, Giovinco 5½ |
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