| Round 3 | | Accrington Stan. | 1 | 35 Rose | | Half-time: | 1-0 | | Referee: | Bola 8 | | Attendance: | 30,861 | | Possession: | 56%-44% | | Total shots: | 17-3 | | MoM: | Rose | | TV: | highlights |
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| | (4-3-3): Hart 7½, Smalling 6½, Rose 8, Cahill 8, Jagielka 7½, Barkley 7, Musa 6½ (81 Walker 6), Allen 6½, Sturridge 7, Ramsey 7½, Sterling 7½ | | Lille | 0 |
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| | (4-3-3): Lloris 7, Jallet 8, Rodriguez 7, Lallana 7, David Luiz 8, Evrà 6½, Valencia 6½, Gaitán 6½, Negredo 7 (72 Guirassy 6), Mavuba 6½, Tallo 5½ | | Benfica | 1 | 78 Drogba | | Half-time: | 0-1 | | Referee: | Uilenberg 5½ | | Attendance: | 37,440 | | Possession: | 48%-52% | | Total shots: | 9-8 | | MoM: | Pereira |
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| | (4-3-3): Lopes 6½, Pereira 7½, Eliseu 7, Gourcuff 7½, Maicon 7, Ricardo Carvalho 6½, Ruben Amorim 6½, César Peixoto 6½ (70 Bosingwa 6), Drogba 7½, Cleiton Xavier 6½, Cardozo 6½ | | Valencia | 1 | 32 Lennon | | 1 André Gomes | | (4-3-3): Reina 7, Arbeloa 6½, Vargas 7, Javi Fuego 7 (49 Paulinho 7½), San Jose 6½, Aderlan 6½, Lennon 7 (64 Perotti 7½), Rafinha 6, Hernández 7, André Gomes 6½, Santi Mina 5½ | | Borussia Dortmund | 0 |
| | Half-time: | 0-0 | | Referee: | Wieser 8 | | Attendance: | 60,832 | | Possession: | 51%-49% | | Total shots: | 12-21 | | MoM: | Piqué |
| | 4 Ginter, 6 Can | | (4-3-3): Akinfeev 6½, Höwedes 7, Schmelzer 6½, Guarín 7½, Ginter 6, Can 6, Ramires 7½, Hazard 6½, Lewandowski 7, Grosskreutz 6, Lavezzi 6 | | Real Madrid | 1 | 51 Messi |
| | (4-1-3-2): Neuer 7, Sergio Ramos 8, Piqué 8, Mascherano 7½, Chiellini 7½, De Rossi 6, Silva 7 (76 Özil 6), Modric 6½ (76 Santi Cazorla 7), Ronaldo 6½, Messi 7, Fabregas 7 | | Cruz Azul | 0 |
| | Half-time: | 0-2 | | Referee: | D'Urso 7 | | Attendance: | 32,850 | | Possession: | 41%-59% | | Total shots: | 8-13 | | MoM: | Kombarov | | TV: | highlights |
| | 69 Ochs | | (4-3-3): Iraizoz 5½, De Marcos 6½, Pereira 7, Hamsík 7½, Huiqui 7 (84 João Pereira 6), Samuel 6, Fellaini 6½, Suso 7½, Ishige 6, Torrado 7 (47 Jiránek 6), Ochs 6 | | Spartak | 4 | 11 Dzagoev, 23 Dzagoev, 66 Kombarov, 82 Kombarov | | 49 Mário Fernandes | | (4-3-3): Ryzhikov 5, Mário Fernandes 7½, Kombarov 8½, Mamaev 7½, Makeev 6½, Berezutsky 7, Bazhenov 7 (59 Prudnikov 7½), Dzagoev 7½, Rondón 7, Ozdoev 7½, Arshavin 5½ | | Dynamo | 1 | 54 Harmash | | Half-time: | 0-2 | | Referee: | Hill 7½ | | Attendance: | 52,080 | | Possession: | 37%-63% | | Total shots: | 10-19 | | MoM: | Wass | | TV: | live |
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| | (4-3-3): Carrasso 5½, Vida 6½, Nesmachnyi 7½, Granero 7, Tymoschuk 7, Mykhalyk 6, Bystrov 6, Harmash 6½, Milevskyi 6½, Kravets 5½, Zozulya 5½ | | Helsingborg | 3 | 12 Agüero, 19 Agüero, 84 Sigurðsson |
| | (4-3-3): De Gea 6, Wass 8½, Azpilicueta 7½, Kjær 7½, Rojo 7, Wernbloom 7½, Braithwaite 7½, Henriksen 7, Diego Costa 6½, Sigurðsson 6, Agüero 6½ | | Lazio | 2 | 12 Matri, 70 Schelotto | | Half-time: | 1-0 | | Referee: | Rodomonti 7 | | Attendance: | 57,997 | | Possession: | 49%-51% | | Total shots: | 11-15 | | MoM: | Antonelli | | TV: | live |
| | 37 Matri | | (4-3-3): Stekelenburg 7½, Bonera 7, Antonelli 8, Onazi 7, Radu 7½, Maurício 6, Schelotto 6, Ilicic 7, Matri 6 (68 Ariaudo 7), Defoe 6, Théréau 6½ | | Nantes | 0 |
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| | (4-3-3): Mandanda 7½, Colin 7½, Digne 8, Valbuena 8, Xavi 6½, Kurzawa 7, Sissoko 6½, Griezmann 6½, Gomis 6½, Gonalons 7, Lacazette 6 | | Newcastle United | 3 | 41 Müller, 47 Bale, 84 Bale | | Half-time: | 1-0 | | Referee: | Strampe 6 | | Attendance: | 51,320 | | Possession: | 52%-48% | | Total shots: | 16-15 | | MoM: | Cillessen |
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| | (4-3-3): Courtois 7, Boateng 7, Alaba 7½, Vidal 7, Thiago Silva 6½, Godín 6, Götze 6½, Bale 7, Mitrovic 6, Cavani 6, Müller 7½ | | Ajax | 0 |
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| | (4-3-3): Cillessen 8, Janmaat 7, Kongolo 6½, Sneijder 7½, Bruma 6, De Vrij 6½, Promes 6½, Lens 7 (62 Narsingh 7½), Huntelaar 6½, Klaassen 6, Van Amersfoort 5½ | | Palermo | 2 | 55 Shaqiri, 59 Parolo | | Half-time: | 0-1 | | Referee: | Constantin 7½ | | Attendance: | 38,989 | | Possession: | 47%-53% | | Total shots: | 7-15 | | MoM: | Darmian | | TV: | highlights |
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| | (4-3-3): Benaglio 6½, Calabresi 6½, Darmian 8, Jorginho 7, Romagnoli 6½, Rugani 7, Candreva 7½, Shaqiri 6½, Cerri 6, Parolo 6½, Éder 6½ | | São Paulo | 1 | 1 Maicon |
| | (4-3-3): Hélton 6, Maicon 7, Wendell 8, Ganso 7, Juan 8, Lúcio 6, Kelvin 6, Lucas Moura 7, Willian 7 (56 Michel Bastos 6), Renato Augusto 6½, Robinho 6½ | | Round 4 | | Anderlecht | 3 | 76 Chedjou, 85 Deschacht, 90+3p Lukaku | | Half-time: | 0-0 | | Referee: | McCluskey 6½ | | Attendance: | 27,976 | | Possession: | 57%-43% | | Total shots: | 18-12 | | MoM: | Dembélé |
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| | (4-3-3): Mignolet 7½, Gillet 7, Deschacht 8, Dembélé 8, Chedjou 8, Chyhrynskyi 6, Marecek 6, Mollo 7, Lukaku 7, Faty 7, Kerzhakov 6 | | Cruz Azul | 0 |
| | 4 Torrado, 56 Torrado | | (4-3-3): Iraizoz 8, De Marcos 8, Pereira 7½, Hamsík 7, Riedewald 6½, Huiqui 6, Fellaini 6, Suso 6, Jelavic 6, Torrado 6½, Ochs 5½ | | Arsenal | 1 | 26 Koke | |
| | (4-3-3): Vesic 5, Lahm 7, Martins-Indi 7½, Marchisio 7, Koscielny 8, Denayer 6½, Ribéry 6½, Koke 6½, Boyé 5½, Reus 6½, Rooney 7½ | | Accrington Stan. | 3 | 6 Musa, 28 Sturridge, 75 Sterling |
| | (4-3-3): Hart 6½, Smalling 7½, Rose 6½, Cahill 7, Jagielka 6½, Barkley 6, Musa 6½ (81 Walker 6), Allen 7, Sturridge 6½, Ramsey 6½, Sterling 6½ | | Flamengo | 0 |
| | Half-time: | 0-1 | | Referee: | Onufer 5½ | | Attendance: | 37,517 | | Possession: | 45%-55% | | Total shots: | 5-19 | | MoM: | Alaba |
| | 90+1 Everton | | (4-3-3): Muriel 5½, Danilo Silva 6, Fabrício 6½, Willians 7½, David 7 (52 Welinton 7½), Xandão 6, Belluschi 7, Babel 6½, Vágner Love 7, Everton 6, Emerson 5½ | | Newcastle United | 2 | 19 Müller, 52 Müller |
| | (4-3-3): Cech 7, Boateng 6, Alaba 8, Vidal 7, Thiago Silva 6½, Godín 7½, Sánchez 6½, Bale 6½, Mitrovic 7, Götze 6½, Müller 7½ | | Helsingborg | 2 | 3 Agüero, 45+3og Terry | | Half-time: | 2-0 | | Referee: | Damgaard 6½ | | Attendance: | 40,768 | | Possession: | 55%-45% | | Total shots: | 13-10 | | MoM: | De Gea |
| | 7 Agüero | | (4-3-3): De Gea 8, Wass 6½, Azpilicueta 7, Kjær 7, Rojo 7, Wernbloom 6½, Braithwaite 6½, Henriksen 7½, Diego Costa 7, Sigurðsson 7, Agüero 7 | | Exeter City | 0 |
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| | (4-3-3): Foster 7, Coleman 7, Johnson 6½, Shelvey 7, Terry 6½ (74 Redmond 6), Jones 6, Drinkwater 7, Milner 7½, Austin 6½, Delph 5½, Walcott 6 | | Nantes | 1 | 7 Griezmann | | Half-time: | 1-0 | | Referee: | Michel 6½ | | Attendance: | 37,351 | | Possession: | 55%-45% | | Total shots: | 14-14 | | MoM: | Mandanda |
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| | (4-3-3): Mandanda 8½, Colin 7, Digne 7½, Valbuena 7½, Xavi 6½, Kurzawa 6½ (79 Payet 6), Sissoko 7, Griezmann 6½, Gomis 7½, Gonalons 7, Lacazette 6 | | FC Basel | 0 |
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| | (4-3-3): Weidenfeller 7, Dani Alves 7, Jordi Alba 6 (79 Willian 6), Matuidi 7½, Dante 7½, Bernat 6, Florenzi 6½, Rodríguez 6½, Ibrahimovic 7, Isco 6½, Berardi 5½ | | São Paulo | 0 |
| | Half-time: | 0-2 | | Referee: | Antonov 6½ | | Attendance: | 36,711 | | Possession: | 51%-49% | | Total shots: | 5-13 | | MoM: | Casemiro |
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| | (4-3-3): Hélton 5½, Maicon 7, Juan 6, Casemiro 8, Lúcio 7, Rodrigo Caio 5½, Kelvin 6½, Lucas Moura 7½, Willian 6½, Renato Augusto 6½, Robinho 7½ | | FC Porto | 2 | 18 Coentrão, 33 João Moutinho |
| | (4-3-3): Rui Patrício 6½, Bruno Alves 6½, Coentrão 7, João Moutinho 7, Miranda 6½, Luisão 6½ (56 Fernandinho 7½), Marcelo 7, Danny 6½, Falcao 6, Oscar 6, Hulk 6 |
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