| Round 3 | | Baník Ostrava | 3 | 15 Arda, 48 Totti, 50 Di Natale | | Half-time: | 1-0 | | Referee: | Ansuátegui Roca 6½ | | Attendance: | 17,264 | | Possession: | 51%-49% | | Total shots: | 15-9 | | MoM: | Vela |
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| | (4-3-3): Perin 7½, Hubocan 7½, Filipe Luis 7½, Xhaka 7, Varane 6½, N'Koulou 6½, Kouassi 7½, Arda 6, Di Natale 7½, Martínez 5½, Totti 6½ | | Athletic Bilbao | 1 | 88 Vela | | 58 Amorebieta | | (4-3-3): Pigliacelli 6½, Torres 7 (75 Toquero 6), Canella 6, Mario Suárez 7½, Botía 7, Amorebieta 6, Nsue 7, Susaeta 7, Osvaldo 7 (62 Dzalamidze 7), Albrighton 5½, Vela 7½ | | Celtic | 1 | 18 Keane | | Half-time: | 1-0 | | Referee: | Levnikov 6½ | | Attendance: | 33,744 | | Possession: | 51%-49% | | Total shots: | 14-9 | | MoM: | Cissé |
| | 57 Iturbe, 87 Cissé | | (4-3-3): Boruc 6½, José Ángel 6, Izaguirre 7, Defour 6½ (73 Cissé 8), Rogne 7, Ki 6½, Fulton 6, Iturbe 6½, Cissé 6, Brown 6½ (80 Mlapa 6), Keane 7 | | Feyenoord | 2 | 72 Kuyt, 87 Nelom |
| | (4-3-3): Alvarado 6, Hutchinson 6½ (47 Johansson 7½), Nelom 7, Biseswar 7½, Van Beek 7, Maduro 6, Kuyt 7½, De Guzman 7, Castaignos 6, Leerdam 7 (50 Schenkeveld 6½), Kazim-Richards 6½ | | Espanyol | 2 | 57 Coke, 69 Pedersen | | Half-time: | 0-1 | | Referee: | Ancion 6½ | | Attendance: | 30,779 | | Possession: | 46%-54% | | Total shots: | 14-15 | | MoM: | Monreal |
| | 46 Tamudo | | (4-3-3): Álvarez 6, Roncaglia 6 (54 Coke 7½), Leugers 6½, Verdú 7½, Gurpegui 7, Pareja 6, Corominas 6, Pedersen 6½, Tamudo 6½, Juanmi 7, Olic 6½ | | Tottenham Hotspur | 3 | 12 Monreal, 83 Nani, 89 Nani | | 7 Nani, 71 Álvarez | | (4-3-3): Leno 6½, Rami 7½, Monreal 8, Shirokov 7, Ogbonna 6½, Cole 7 (57 Álvarez 6½), Foor 6, Nani 7, Matavz 7, Wickham 5½, Gabbiadini 7 | | Fenerbahçe | 0 |
| | Half-time: | 0-1 | | Referee: | Reha 7 | | Attendance: | 43,162 | | Possession: | 49%-51% | | Total shots: | 12-16 | | MoM: | Oxlade-Chamberlain | | TV: | highlights |
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| | (4-3-3): Tolga 5½, Gökhan 6½, Bekir 7, Özer 7½, Remzi Giray 6½, Serkan 6, Mehmet 7, Selçuk 6½, Sow 7½, Semih 6, Burak 6 | | Ayr United | 3 | 17p Kane, 47 Kane, 59 Oxlade-Chamberlain |
| | (4-3-3): Butland 5½, Clyne 8, Brunt 7½, McCarthy 7, Shawcross 6½, Dier 6½, Davis 7, Oxlade-Chamberlain 8, Kane 7, Wilshere 6, Berahino 6½ | | Internacional | 2 | 10 Kléber, 87 Jô | | Half-time: | 1-0 | | Referee: | Vorjas 5 | | Attendance: | 34,789 | | Possession: | 48%-52% | | Total shots: | 7-10 | | MoM: | Giuliano |
| | 5 Wágner, 27 Walter, 69 Marcelo | | (4-3-3): Fernando Henrique 6½, Danilo 6 (63 Júlio Baptista 7), Kléber 7½, João Pedro 7½, Marcelo 6½, André Bahia 6, Giuliano 8, Wágner 7, Jô 6½, Walter 5½, Taison 6½ | | Palmeiras | 0 |
| | 30 Ronaldinho, 58 Diego Souza | | (4-3-3): Júlio César 7½, Henrique 7½, Alex Telles 7, Lucas 7½, Danilo 7, Rafael Toloi 6, Márcio Araújo 6½, Marquinhos 7½, Ewerthon 7, Diego Souza 6, Ronaldinho 5½ | | Newport County | 3 | 2 Clark, 31 Stones, 87 Bertrand | | Half-time: | 2-1 | | Referee: | Bazzoli 7½ | | Attendance: | 19,447 | | Possession: | 59%-41% | | Total shots: | 20-7 | | MoM: | Rodriguez | | TV: | live |
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| | (4-3-3): McGregor 6½, Stones 7½, Bertrand 7½, Alli 7½, Tomkins 7½, Clark 7½, Cleverley 7, Ayew 7, Rhodes 7, Livermore 6, Rodriguez 7½ | | Liverpool | 2 | 10 Origi, 59 Henderson |
| | (4-3-3): Pyatov 5½, Vrsaljko 7 (47 Valencic 6), Sakho 7, Badelj 7½, Lovren 7 (88 Németh 6), Taylor 6, Henderson 6½, Vitolo 6½, Carroll 5½, Ings 6, Origi 6½ | | Sevilla | 3 | 3 Kiessling, 14 Kiessling, 51 Aleix Vidal | | Half-time: | 2-0 | | Referee: | Queudrue 7 | | Attendance: | 35,644 | | Possession: | 59%-41% | | Total shots: | 19-5 | | MoM: | Aleix Vidal | | TV: | highlights |
| | 20 Silvestre, 48 Fernando Navarro, 87 Piatti | | (4-3-3): Navas 6½, Aleix Vidal 8, Fernando Navarro 7½, Raul Meireles 7½, Silvestre 7, Alexis 7, Kiko 6½, Piatti 7½, Kiessling 7, Makoun 6½, Giovinco 6½ | | Manchester United | 1 | 69 Berbatov |
| | (4-3-3): Kuszczak 7, Rafael 6, Davies 7, Schweinsteiger 7, O'Shea 6½ (58 Anderson 6), McNair 6, Giovani 7, Obertan 6½, Berbatov 6½, Huddlestone 6½, Martial 5½ | | Round 4 | | Athletic Bilbao | 1 | 38 Susaeta | | Half-time: | 1-1 | | Referee: | Knight 7½ | | Attendance: | 28,496 | | Possession: | 49%-51% | | Total shots: | 8-13 | | MoM: | Izaguirre |
| | 7 Aurtenetxe, 22 Botía, 44 Mario Suárez, 47 Albrighton, 86 Susaeta | | (4-3-3): Pigliacelli 6½, Torres 6½, Canella 7½, Mario Suárez 6½, Botía 6½, Aurtenetxe 6, Nsue 6, Susaeta 7, Osvaldo 7, Albrighton 6, Vela 6 | | Celtic | 2 | 31 Iturbe, 53 Cissé | | 18 Cissé | | (4-3-3): Boruc 6½, Konchesky 6½, Izaguirre 8, Defour 7, Rogne 7, Ki 7, Fulton 6½, Iturbe 7, Cissé 6½, Brown 6½ (53 Barton 6), Keane 6½ | | Ayr United | 3 | 38 Kane, 67 Long, 69 Wilshere | | Half-time: | 1-1 | | Referee: | Collina 6½ | | Attendance: | 34,171 | | Possession: | 55%-45% | | Total shots: | 16-9 | | MoM: | McCarthy | | TV: | highlights |
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| | (4-3-3): Butland 7, Clyne 7½, Brunt 5½ (68 Anya 7), McCarthy 8, Dier 7, Shawcross 7, Davis 7½, Oxlade-Chamberlain 7, Kane 7, Wilshere 7, Long 6½ | | Internacional | 1 | 17 Taison | | 54 João Pedro | | (4-3-3): Fernando Henrique 7, Danilo 6½, Kléber 6, João Pedro 6½, Marcelo 6, André Bahia 6, Giuliano 7, Wágner 6, Walter 7, Jô 6, Taison 5½ | | Bayern München | 0 |
| | Half-time: | 0-1 | | Referee: | Pyanikh 5½ | | Attendance: | 44,392 | | Possession: | 58%-42% | | Total shots: | 12-14 | | MoM: | Ignjovski |
| | 51 Marin, 71 Forlin, 90 Marin | | (4-3-3): Kraft 7, Essien 6, Pranjic 7, Ignjovski 8, Papastathopoulos 7½, Djourou 7, Sahin 6½, Marin 7, Barrios 7, Forlin 6½, Aubameyang 7 | | Newport County | 1 | 25 Ayew |
| | (4-3-3): McGregor 7½, Stones 7, Bertrand 8, Alli 7½, Tomkins 7, Clark 6½, Cleverley 6½ (63 Dummett 6), Ayew 6½, Rhodes 6, Phillips 5½, Rodriguez 6 | | Feyenoord | 3 | 21 Kuyt, 78 De Guzman, 84 De Guzman | | Half-time: | 1-1 | | Referee: | Bettin 7½ | | Attendance: | 38,274 | | Possession: | 60%-40% | | Total shots: | 13-5 | | MoM: | Kuyt |
| | 19 Kuyt | | (4-3-3): Alvarado 7, Hutchinson 8, Nelom 6½, Biseswar 8, Van Beek 7, Maduro 7, Kuyt 8½, De Guzman 7, Castaignos 7½, Leerdam 6½, Kazim-Richards 7½ | | River Plate | 1 | 42 Buonanotte | | 12 Víctor, 34 Cabral, 54 Affranchino | | (4-3-3): Marchesín 7, Cicinho 6, Basanta 6, Prediger 6½, Cabral 6½, López 6, Affranchino 6, Buonanotte 6½ (78 Mercado 6), López 6, Castillejos 5½, Víctor 6 | | Liverpool | 2 | 9 Henderson, 20 Origi | | Half-time: | 2-1 | | Referee: | Sung 7½ | | Attendance: | 41,235 | | Possession: | 50%-50% | | Total shots: | 18-12 | | MoM: | Henderson |
| | 89 Badelj | | (4-3-3): Pyatov 6½, Vrsaljko 7, Sakho 7, Badelj 7, Lovren 6½, Taylor 6½, Henderson 8, Vitolo 6, Carroll 7, Ings 6, Origi 6 | | Baník Ostrava | 1 | 23 Di Natale |
| | (4-3-3): Perin 6, Hubocan 5½, Filipe Luis 7, Xhaka 6, Varane 6½, N'Koulou 6, Kouassi 5½, Arda 6, Di Natale 7, Martínez 6, Totti 7 | | Manchester City | 1 | 81og Raul Meireles | | Half-time: | 0-3 | | Referee: | Piller 6 | | Attendance: | 47,392 | | Possession: | 49%-51% | | Total shots: | 15-11 | | MoM: | Touré |
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| | (4-3-3): Kapino 5, Sagna 6½, Vertonghen 7, Touré 7½, Demichelis 7, Song 7, Navas 7½, Herrmann 7, Soldado 6½, Källström 6, Vucinic 6 | | Sevilla | 4 | 1 Kiessling, 10 Piatti, 41 Alexis, 83 Kiessling | | 30 Giovinco | | (4-3-3): Navas 5½, Silvestre 7, Fernando Navarro 6½, Raul Meireles 7, Alexis 7, Squillaci 6½, Aleix Vidal 6½, Piatti 6½ (66 O'Donnell 6½), Kiessling 7, Makoun 6½, Giovinco 6 | | Manchester United | 1 | 2 Berbatov | | Half-time: | 1-2 | | Referee: | Korac 6 | | Attendance: | 43,270 | | Possession: | 53%-47% | | Total shots: | 20-13 | | MoM: | Plasil |
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| | (4-3-3): Kuszczak 6, Rafael 7½, Davies 7½, Schweinsteiger 7, O'Shea 6½ (58 Anderson 7½), McNair 6, Giovani 6½, Obertan 7, Berbatov 7, Huddlestone 6½, Martial 6½ | | Viktoria Plzen | 2 | 15 Gebre Selassie, 21 Gebre Selassie |
| | (4-3-3): Vaclik 6½, Gebre Selassie 6½, Kadlec 6½ (69 Procházka 6), Plasil 8, Hübschman 7½, Suchý 7½, Prikryl 6½, Hlousek 6, Vydra 6½, Sivok 6, Lafata 6 | | Marseille | 3 | 12 Brandão, 29 Ben Arfa, 67 Benzema | | Half-time: | 2-1 | | Referee: | Sarvan 7 | | Attendance: | 43,784 | | Possession: | 54%-46% | | Total shots: | 12-8 | | MoM: | Reveillère |
| | 11 Pjanic, 23 Benzema, 27 Menez, 36 Lamela, 68 Ben Arfa | | (4-3-3): Riou 6½, Reveillère 7½, Kolodziejczak 7½, Menez 7, Alex Silva 6½, Tabanou 7, Pjanic 5½ (70 González 6), Lamela 7, Brandão 6½, Ben Arfa 6½, Benzema 7 | | FC Schalke 04 | 1 | 33 Salcido |
| | (4-3-3): Mielitz 6½, Träsch 7 (68 Avevor 6½), Durm 6½, Costa 6, Salcido 7½, Kelly 6½, Farfán 7, Barnetta 7½, De Jong 6½, Crouch 5½, Elmander 5½ | | Napoli | 3 | 6 Zuñiga, 38 Quagliarella, 55 El Kaoutari | | Half-time: | 2-1 | | Referee: | Dondarini 7 | | Attendance: | 51,394 | | Possession: | 42%-58% | | Total shots: | 9-11 | | MoM: | Depay |
| | 72 Gastaldello | | (4-3-3): De Sanctis 6½, Maggio 6½, El Kaoutari 7, Ledesma 7½, Gastaldello 7 (83 Zaccardo 6), Cannavaro 5½ (81 Mesto 6), Mokotjo 6, Zuñiga 7½, Gignac 6½, Necip 6, Quagliarella 7 | | Milan | 1 | 40 Mandzukic |
| | (4-3-3): Ospina 6, Jedvaj 7½, Kolarov 8, Cabaye 6½, Ranocchia 7, Laporte 6, Joaquín 6½ (49 Ander 6), Depay 8½, Mandzukic 7½, Bacca 6, Volland 6 | | Palmeiras | 2 | 10 Márcio Araújo, 54 Alex Telles | | Half-time: | 1-0 | | Referee: | Hansson 6½ | | Attendance: | 28,563 | | Possession: | 46%-54% | | Total shots: | 12-10 | | MoM: | Corominas |
| | 7 Diego Souza, 58 Marquinhos, 77 Marquinhos | | (4-3-3): Júlio César 6½, Henrique 7½, Alex Telles 6½, Lucas 7½, Danilo 7½, Rafael Toloi 6½, Diego Souza 6½, Marquinhos 7, Ewerthon 6½, Márcio Araújo 6 (84 Edinho 6), Ronaldinho 6½ | | Espanyol | 1 | 87 Javi Márquez |
| | (4-3-3): Álvarez 7, Roncaglia 7½, Leugers 6½, Juanmi 7, Gurpegui 7½, Pareja 6½, Corominas 8, Pedersen 6, Tamudo 6½ (58 Verdú 6), Javi Márquez 6½, Olic 6 |
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