| Round 3 | | Brřndby | 2 | 3 Lulic, 31 Gervinho | | Half-time: | 2-0 | | Referee: | Papapanagiotou 7 | | Attendance: | 28,921 | | Possession: | 51%-49% | | Total shots: | 11-8 | | MoM: | Prödl | | TV: | highlights |
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| | (4-3-3): Diego López 7, Zapata 7½, Lulic 6½, Raúl García 7½, Jantschke 6, Corluka 6, Pérez 7½, Gervinho 7½, Mirallas 6½, Selçuk 6 (73 Adrián 7½), Roberto Firmino 5½ | | SV Werder Bremen | 0 |
| | 7 Santacroce | | (4-3-3): Gabulov 7, Prödl 8, Abdennour 8, Samaris 7, Santacroce 5½, Uchida 6, Bargfrede 6½, Hunt 7, Dost 6½, Diego Capel 6, Adebayor 6½ | | CSKA | 2 | 6 Washington, 81 Ignashevich | | Half-time: | 1-1 | | Referee: | Cesari 7 | | Attendance: | 13,143 | | Possession: | 57%-43% | | Total shots: | 25-10 | | MoM: | Denisov | | TV: | highlights |
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| | (4-3-3): Moyá 7½, Nababkin 8, Schennikov 7½, Denisov 8½, Ignashevich 7½, Stranzl 8, Okay 6, Dzsudzsák 8, Devic 7½, Borriello 6, Washington 6 | | West Ham United | 1 | 37 Johnson |
| | (4-3-3): Forster 7½, Gray 6½, Cresswell 7½, Gerrard 7, Sané 7 (80 Mancienne 6), Samba 6, Holmes 6½, Johnson 7, Bent 6, Brozovic 6, Sellin 6 | | Deportivo | 1 | 14p Adúriz | | Half-time: | 1-0 | | Referee: | Boggi 6 | | Attendance: | 34,475 | | Possession: | 60%-40% | | Total shots: | 10-8 | | MoM: | Vallés | | TV: | live |
| | 42 Javi López | | (4-3-3): Guilherme 7, Javi López 8, Jaume 7, Juan Rodríguez 7½, Dominguez 7, Colotto 7, Pablo Álvarez 8, Guardado 7½, Adúriz 7½, Juan Domínguez 7, Nouioui 5½ | | Independiente | 1 | 51 Matheu |
| | (4-3-3): Orión 7, Matheu 6, Vallés 8, Acevedo 6, Vittor 6½, Fredes 6, Fernández 5½, Mancuello 6½, Osvaldo 6½, Gandín 5½, Suarez 6 | | Round 4 | | Aston Villa | 0 |
| | Half-time: | 0-0 | | Referee: | Atkinson 5½ | | Attendance: | 25,442 | | Possession: | 45%-55% | | Total shots: | 8-13 | | MoM: | Warnock |
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| | (4-3-3): Viviano 7, Naughton 7½, Warnock 7½, Bannan 7, Collins 7½, Davies 6½, Reo-Coker 6½, Aissati 7, Heskey 7, Salifou 6½, Bamford 5½ | | TSG Hoffenheim | 0 |
| | 1 Mangane, 66 Gross, 90+1 Vukcevic | | (4-3-3): Fährmann 7, Lustig 6, Didac 6½, Gross 6½, Mangane 6½, Amat 6½, Vukcevic 6½, Carlos Eduardo 7, Ibisevic 7, Maicosuel 6½, Sessčgnon 6 | | Atlético Madrid | 1 | 12 Lanzini | | Half-time: | 1-3 | | Referee: | Styles 6½ | | Attendance: | 40,236 | | Possession: | 49%-51% | | Total shots: | 16-12 | | MoM: | Skrtel |
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| | (4-3-3): Hamon 4½, Mario 7½, Marcos Alonso 6½, Biglia 7, Rodríguez 7, Marc Muniesa 6½, Bojan 7, Lanzini 7, Borja Bastón 6½, Schaars 6, Rodrigo 6 | | Barcelona | 4 | 13 Gomez, 21 Gomez, 41 Iniesta, 68 Maxwell |
| | (4-3-3): Bravo 6, Fernández 7, Maxwell 7, Busquets 7, Skrtel 7½, Bartra 6, Feghouli 7½, Iniesta 7½, Gomez 7, Suárez 6, Neymar 6½ | | Bayer Leverkusen | 1 | 50 Kuranyi | | Half-time: | 0-0 | | Referee: | Sedlacek 7 | | Attendance: | 22,405 | | Possession: | 55%-45% | | Total shots: | 8-11 | | MoM: | Kakuta |
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| | (4-3-3): Giefer 7, Fritz 7½, Servet 7, Castro 7, Díaz 7, Friedrich 6½, Elano 6½, Kakuta 7½, Kuranyi 6½ (71 Kaplan 7), Cambiasso 7, Zárate 5½ | | CSKA | 1 | 72 Dzsudzsák |
| | (4-3-3): Moyá 6, Nababkin 7, Schennikov 7, Denisov 7½, Ignashevich 7½, Stranzl 6, Okay 6, Dzsudzsák 7 (85 Gyasi 6), Devic 7, Borriello 5½, Washington 6½ | | Fiorentina | 3 | 3 Jovetic, 34p Gilardino, 59 Altidore | | Half-time: | 2-0 | | Referee: | Řvrebř 6 | | Attendance: | 35,707 | | Possession: | 45%-55% | | Total shots: | 9-9 | | MoM: | Srna |
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| | (4-3-3): Mirante 7½, Konko 7½, Marchese 5½ (53 Altidore 7), Rômulo 7½, Cana 7, Felipe 6, Donadel 6½, Braafheid 6½, Gilardino 7, Seferovic 6, Jovetic 6½ | | Boulogne | 0 |
| | 34 Gamberini | | (4-3-3): Rakovsky 7, Srna 8, Ibańez 6½, Thiago 6½, Gamberini 7, Klose 6½, Gökhan 6, Muniain 6, Álvaro 6½, Pajot 7, Kalou 7 | | Independiente | 0 |
| | Half-time: | 0-1 | | Referee: | Bedin 7½ | | Attendance: | 50,841 | | Possession: | 49%-51% | | Total shots: | 13-15 | | MoM: | Howard |
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| | (4-3-3): Orión 7, Matheu 6½, Vallés 5½, Acevedo 7, Vittor 7, Fredes 6, Fernández 6½, Mancuello 7 (57 Busse 7), Osvaldo 6½, Gandín 6½, Suarez 6 | | Hansa Rostock | 1 | 29 Dzeko | | 43 Gentner | | (4-3-3): Howard 7½, Piszczek 7, Johnson 7, Gündogan 7½, Geromel 6½, Reinartz 6½, Gentner 6½, Goretzka 7, Dzeko 7½, Benteke 6, Martins 5½ | | Lorient | 2 | 53 Sagbo, 56p Hoarau | | Half-time: | 0-1 | | Referee: | Hauge 7½ | | Attendance: | 15,822 | | Possession: | 47%-53% | | Total shots: | 12-10 | | MoM: | Balmont |
| | 47 Baca | | (4-3-3): Sorin 6, Baca 7, Morel 7, Balmont 8, Puygrenier 6½, Mignot 6½, Birsa 8, Pied 7, Hoarau 6½, Mvuemba 6, Sagbo 6½ | | Hamburger SV | 3 | 35 Petric, 54 Guerrero, 79 Elia |
| | (4-3-3): Karnezis 6, Rincón 6½, Aogo 6, Trochowski 6½, Piris 7, Mathijsen 6½, Ebert 7, Elia 7, Guerrero 6½, Demel 7, Petric 6½ | | Rosenborg | 3 | 3 Skjelbred, 6 Kovacic, 73 Corona | | Half-time: | 2-0 | | Referee: | Krondl 7 | | Attendance: | 20,989 | | Possession: | 56%-44% | | Total shots: | 14-8 | | MoM: | Corona |
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| | (4-3-3): Trapp 7, Cédric 6, Mathieu 6½, Maher 6½, Toprak 7, Zouma 7, Skjelbred 5½ (83 Van Dijk 6), Corona 8, Pizarro 6½, Kovacic 7, Aboubakar 6 | | Lyon | 0 |
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| | (4-3-3): Bettinelli 7½, Théophile-Catherine 7, Bedimo 7½, Obraniak 7, Armand 6, Gassama 6, Fatih 6½ (80 Tiéné 6), Boussoufa 7½, Roux 6½, Tafer 5½, Sunu 5½ | | SV Werder Bremen | 1 | 72 Hunt | | Half-time: | 0-1 | | Referee: | Jol 6 | | Attendance: | 42,335 | | Possession: | 45%-55% | | Total shots: | 12-19 | | MoM: | Schneiderlin |
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| | (4-3-3): Gabulov 7, Prödl 7, Abdennour 8, Samaris 8, Santacroce 6, Uchida 6, Bargfrede 6½, Hunt 6½, Dost 8, Diego Capel 5½, Adebayor 6½ | | Roma | 1 | 13 Pazzini |
| | (4-3-3): Adler 7, Fazio 7½, Young 8, Schneiderlin 8½, Evans 8, Coloccini 6½, Tadic 6½, Çalhanoglu 7½, Pazzini 7, Gago 6½, Kruse 7½ | | Udinese | 1 | 68 Alex Geijo | | Half-time: | 0-1 | | Referee: | Vieira 8 | | Attendance: | 30,790 | | Possession: | 50%-50% | | Total shots: | 7-15 | | MoM: | Basta |
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| | (4-3-3): Szczesny 6½, Basta 8, Lukovic 7, Lodi 7½, Papadopoulos 7½, Léo 7, Isla 6½, Zimling 7, Alex Geijo 6, D'Agostino 6½, Jaime 5½ | | Deportivo | 2 | 27 Adúriz, 90 Adúriz | | 21 Adúriz | | (4-3-3): Guilherme 6, Javi López 7½, Jaume 7, Juan Rodríguez 7, Dominguez 7, Colotto 7 (53 José Castro 7), Pablo Álvarez 6½, Guardado 7½, Adúriz 7, Juan Domínguez 7, Nouioui 5½ | | VfB Stuttgart | 2 | 19 Hamit, 38p Schieber | | Half-time: | 2-1 | | Referee: | Gumienny 5½ | | Attendance: | 46,153 | | Possession: | 45%-55% | | Total shots: | 11-19 | | MoM: | Baines |
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| | (4-3-3): Ulreich 6, Hilbert 6½, Boka 7½, Aquilani 6½, Niedermeier 6 (85 Lanig 6), Osorio 7, Kuzmanovic 6½, Thorsby 7, Schieber 6, Hamit 6, Marica 5½ | | Chelsea | 1 | 22 Bellarabi |
| | (4-3-3): Muslera 7, Rafinha 6½, Baines 8, Bender 7½, Mangala 6½, Mustafi 6½, Callejón 7½, Perisic 7½, Llorente 7½, Schürrle 5½, Bellarabi 6 | | West Ham United | 1 | 7 Bent | | Half-time: | 1-0 | | Referee: | Foy 8 | | Attendance: | 31,399 | | Possession: | 44%-56% | | Total shots: | 11-14 | | MoM: | Zapata |
| | 64 Gerrard | | (4-3-3): Forster 7, Gray 6, Cresswell 6, Gerrard 7, Sané 6½, Samba 7, Holmes 5½, Johnson 7, Bent 6, Brozovic 6½, Sellin 6 | | Brřndby | 0 |
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| | (4-3-3): Diego López 7, Zapata 8, Lulic 6½, Raúl García 6½ (77 Adrián 6), Jantschke 7, Corluka 7, Pérez 7, Gervinho 7½, Mirallas 6, Selçuk 6½, Roberto Firmino 7 |
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