| Round 5 | | Accrington Stan. | 0 |
| | Half-time: | 0-0 | | Referee: | Kefalas 7 | | Attendance: | 30,913 | | Possession: | 54%-46% | | Total shots: | 17-16 | | MoM: | Smalling | | TV: | live |
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| | (4-3-3): Hart 8, Smalling 8½, Rose 7½, Cahill 7, Jagielka 7, Barkley 6½, Musa 6½, Allen 7, Sturridge 7, Ramsey 6½, Sterling 7 | | Anderlecht | 0 |
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| | (4-3-3): Mignolet 6½, Gillet 6½, Deschacht 6, Dembélé 8, Chedjou 7½, Ramis 6, Marecek 7, Ilicevic 6, Lukaku 7, Wuytens 6½, Jonas 7½ | | Benfica | 2 | 19 Cleiton Xavier, 26 Drogba | | Half-time: | 2-0 | | Referee: | Styles 6½ | | Attendance: | 36,093 | | Possession: | 49%-51% | | Total shots: | 11-13 | | MoM: | Maicon |
| | 5 Gourcuff | | (4-3-3): Lopes 7, Pereira 6½, Eliseu 8½, Gourcuff 7, Maicon 8½, Ricardo Carvalho 7, Ruben Amorim 7½, César Peixoto 6, Drogba 7½, Cleiton Xavier 6½, Cardozo 7½ | | Flamengo | 1 | 90 Siqueira | | 34 Babel, 59 Babel | | (4-3-3): Muriel 6½, Danilo Silva 7, Siqueira 6, Willians 6½, David 6½, Xandão 6, Belluschi 6½, Babel 6, Lima 7, Vágner Love 6, Nixon 6½ | | Borussia Dortmund | 4 | 21 Lewandowski, 28 Lavezzi, 63 Hazard, 66 Lewandowski | | Half-time: | 2-1 | | Referee: | Dean 6½ | | Attendance: | 55,821 | | Possession: | 53%-47% | | Total shots: | 16-16 | | MoM: | Sneijder |
| | 49 Guarín | | (4-3-3): Akinfeev 6½, Höwedes 7½, Schmelzer 5 (81 Subotic 6), Guarín 7, Ginter 7, Can 5½, Ramires 7½, Hazard 7, Lewandowski 7½, Grosskreutz 6, Lavezzi 6 | | Ajax | 2 | 34 Sneijder, 79 Huntelaar |
| | (4-3-3): Cillessen 7, Janmaat 6½, Kongolo 6, Sneijder 8, Bruma 7, De Vrij 6½, Promes 6, Lens 7 (62 Narsingh 6), Huntelaar 7, Klaassen 6½, Van Amersfoort 5½ | | Cruz Azul | 1 | 67 Hamsík | | Half-time: | 0-2 | | Referee: | Grabher 8 | | Attendance: | 35,793 | | Possession: | 42%-58% | | Total shots: | 15-14 | | MoM: | Sergio Ramos |
| | 33 Jelavic | | (4-3-3): Iraizoz 5½, De Marcos 7½, Pereira 7, Hamsík 7, Riedewald 6, Huiqui 6, Fellaini 7, Giménez 6½, Jelavic 7, Castro 6½, Suso 6 | | Real Madrid | 3 | 13 Piqué, 24 Messi, 47 Ronaldo |
| | (4-1-3-2): Neuer 5½, Sergio Ramos 8, Piqué 7½, Mascherano 7, Chiellini 7½, De Rossi 6½, Kroos 7 (76 Özil 6), Modric 7 (76 Silva 7), Ronaldo 6½, Messi 7, Fabregas 6½ | | Dynamo | 0 |
| | Half-time: | 0-2 | | Referee: | Cesari 8 | | Attendance: | 41,253 | | Possession: | 44%-56% | | Total shots: | 14-16 | | MoM: | Mário Fernandes | | TV: | highlights |
| | 18 Zozulya, 33 Harmash, 77 Zozulya | | (4-3-3): Carrasso 4½, Vida 6, Nesmachnyi 7½, Granero 7, Tymoschuk 7½, Mykhalyk 6, Bystrov 7½, Harmash 6½, Milevskyi 6, Kravets 5½, Zozulya 6 | | Spartak | 5 | 16 Ozdoev, 31 Rondón, 60 Arshavin, 75 Dzagoev, 80 Kombarov |
| | (4-3-3): Ryzhikov 4½, Mário Fernandes 8, Kombarov 8, Mamaev 8, Makeev 7, Berezutsky 6½, Bazhenov 7, Dzagoev 7½, Rondón 8, Ozdoev 6½, Arshavin 6 | | Exeter City | 2 | 17 Milner, 87 Walcott | | Half-time: | 1-0 | | Referee: | Franceschini 5 | | Attendance: | 19,790 | | Possession: | 48%-52% | | Total shots: | 14-12 | | MoM: | Shelvey | | TV: | highlights |
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| | (4-3-3): Foster 7½, Coleman 6½, Johnson 7½, Shelvey 8, Terry 7, Jones 7, Drinkwater 6, Milner 7½, Austin 6 (60 Caulker 7), Delph 7, Walcott 5½ | | Lille | 1 | 70 Gaitán |
| | (4-3-3): Lloris 7, Jallet 7½, Rodriguez 7½, Lallana 7½, David Luiz 6½, Evrà 7, Valencia 7, Gaitán 7, Negredo 7 (88 Guirassy 6), Mavuba 7, Tallo 6 | | FC Basel | 3 | 9p Ibrahimovic, 78 Dani Alves, 90 Isco | | Half-time: | 1-1 | | Referee: | Trentalange 8 | | Attendance: | 38,337 | | Possession: | 51%-49% | | Total shots: | 17-18 | | MoM: | Juan | | TV: | highlights |
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| | (4-3-3): Diego 7, Dani Alves 8, Jordi Alba 7, Pirlo 7, Dante 7½, Lichtsteiner 6, Florenzi 7½, Isco 7, Ibrahimovic 8, Rodríguez 6½, Berardi 6 | | São Paulo | 1 | 39 Robinho |
| | (4-3-3): Hélton 7½, Maicon 6, Juan 8½, Renato Augusto 6½, Rodrigo Caio 6½, Wendell 6, Kelvin 7, Lucas Moura 7 (79 Roger Carvalho 6), Willian 7, Ganso 6, Robinho 6½ | | FC Porto | 1 | 90+1p Falcao | | Half-time: | 0-0 | | Referee: | Foy 8 | | Attendance: | 47,631 | | Possession: | 51%-49% | | Total shots: | 13-14 | | MoM: | Rui Patrício |
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| | (4-3-3): Rui Patrício 8, Bruno Alves 7, Coentrão 7, João Moutinho 7, Miranda 7½, Luisão 6, Marcelo 7, Danny 6½ (78 Fábio Sturgeon 6), Falcao 7, Oscar 6, Hulk 6½ (52 Fernandinho 6½) | | Valencia | 0 |
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| | (4-3-3): Reina 6½, Arbeloa 6, Vargas 6, Javi Fuego 7½, San Jose 7, Aderlan 6, Lennon 7, Rafinha 7, Hernández 6, André Gomes 6, Santi Mina 6½ | | Lazio | 1 | 82 Ilicic | | Half-time: | 0-0 | | Referee: | Vorjas 7½ | | Attendance: | 57,765 | | Possession: | 54%-46% | | Total shots: | 20-14 | | MoM: | Rojo | | TV: | live |
| | 20 Defoe | | (4-3-3): Stekelenburg 7½, Bonera 7½, Antonelli 6½, Onazi 6½ (70 Ariaudo 7½), Radu 7, Maurício 6, Schelotto 6½, Ilicic 6½, Matri 6½, Defoe 6, Théréau 5 | | Helsingborg | 1 | 70 Eriksen | | 72 Sigurðsson | | (4-3-3): De Gea 7, Wass 7, Azpilicueta 6½, Kjær 7½, Rojo 7½, Wernbloom 6½, Eriksen 6, Henriksen 6, Diego Costa 7, Sigurðsson 5½, Agüero 7 | | Newcastle United | 3 | 2 Mitrovic, 23 Müller, 40 Bale | | Half-time: | 3-1 | | Referee: | Damgaard 5½ | | Attendance: | 52,347 | | Possession: | 48%-52% | | Total shots: | 7-9 | | MoM: | Ribéry |
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| | (4-3-3): Courtois 7, Boateng 7½, Alaba 7½, Vidal 5½ (55 Matip 8), Thiago Silva 7, Godín 7 (56 Boëtius 7), Götze 6½, Bale 7, Mitrovic 7, Cavani 5½, Müller 6½ | | Arsenal | 1 | 20 Rooney |
| | (4-3-3): Vesic 7, Lahm 7, Martins-Indi 7½, Marchisio 7, Koscielny 6½, Denayer 7, Ribéry 8, Koke 7, Boyé 6½, Reus 6½, Rooney 6 | | Palermo | 1 | 52 Shaqiri | | Half-time: | 0-0 | | Referee: | Nielsen 7½ | | Attendance: | 38,934 | | Possession: | 55%-45% | | Total shots: | 17-14 | | MoM: | Digne |
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| | (4-3-3): Benaglio 6½, Calabresi 7, Darmian 7, Jorginho 7, Romagnoli 7, Rugani 6, Candreva 7½, Shaqiri 7½, Cerri 6½, Parolo 6½, Éder 7 | | Nantes | 1 | 68 Griezmann |
| | (4-3-3): Mandanda 7, Colin 6½, Digne 7½, Valbuena 7½, Kurzawa 6½, Mendy 7, Sissoko 6½, Griezmann 6½, Gomis 7½, Xavi 6½ (65 Jean 7), Benzia 6 | | Round 4 | | Spartak | 2 | 34 Dzagoev, 49 Mamaev | | Half-time: | 1-0 | | Referee: | Rudy 5½ | | Attendance: | 46,217 | | Possession: | 58%-42% | | Total shots: | 23-7 | | MoM: | Mamaev |
| | 61 Ozdoev | | (4-3-3): Ryzhikov 7, Mário Fernandes 8, Kombarov 7, Dzagoev 8, Makeev 7½, Berezutsky 6½, Bazhenov 7½, Mamaev 8, Rondón 8, Ozdoev 6, Arshavin 6 | | Borussia Dortmund | 1 | 52 Hazard | | 19 Ramires, 71 Lavezzi | | (4-3-3): Akinfeev 7, Höwedes 7, Schmelzer 6½, Guarín 7½, Ginter 6, Can 5½, Ramires 6½, Hazard 7, Lewandowski 7, Grosskreutz 6, Lavezzi 6 | | Round 3 | | FC Basel | 2 | 34 Jordi Alba, 81 Ibrahimovic | | Half-time: | 1-0 | | Referee: | Strampe 8 | | Attendance: | 38,386 | | Possession: | 57%-43% | | Total shots: | 19-10 | | MoM: | Dani Alves |
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| | (4-3-3): Diego 7½, Dani Alves 8½, Jordi Alba 7, Pirlo 8, Dante 7½, Matuidi 7, Florenzi 7½, Rodríguez 6 (79 Isco 6), Ibrahimovic 7½, Mkhitaryan 6½, Berardi 6 | | Anderlecht | 0 |
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| | (4-3-3): Mignolet 7½, Gillet 6, Deschacht 6½, Dembélé 6½, Chedjou 6½, Ramis 6, Marecek 6½, Ilicevic 5½, Lukaku 6½, Mollo 6, Jonas 5½ | | Round 4 | | Lille | 1 | 2p Negredo | | Half-time: | 1-0 | | Referee: | Hauge 6 | | Attendance: | 17,940 | | Possession: | 50%-50% | | Total shots: | 10-10 | | MoM: | Rodriguez |
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| | (4-3-3): Lloris 7½, Jallet 7, Rodriguez 8, Lallana 7½, David Luiz 7½, Evrà 7, Valencia 6½, Gaitán 8, Negredo 7, Mavuba 7, Tallo 6½ | | Palermo | 0 |
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| | (4-3-3): Benaglio 8, Calabresi 7, Darmian 8, Jorginho 7, Romagnoli 6½, Rugani 5½, Candreva 6½, Shaqiri 7½, Cerri 6, Parolo 6½, Éder 5½ |
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