| Round 5 | | Baník Ostrava | 3 | 7 Arda, 12 Arda, 52 Giroud | | Half-time: | 2-0 | | Referee: | Uilenberg 5½ | | Attendance: | 17,226 | | Possession: | 52%-48% | | Total shots: | 13-8 | | MoM: | Filipe Luis | | TV: | highlights |
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| | (4-3-3): Perin 7½, Hubocan 6½, Filipe Luis 8, Xhaka 5½ (75 Konoplyanka 7½), Varane 7, Medel 5½, Kouassi 7½, Arda 7½, Giroud 7, Arnold 6½, Totti 7 | | Manchester United | 0 |
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| | (4-3-3): Kuszczak 7½, Rafael 7, Davies 7, Schweinsteiger 6½, O'Shea 6½ (58 Anderson 7), McNair 6½, Giovani 7, Obertan 6½, Berbatov 5½, Huddlestone 6½, Martial 6½ | | Celtic | 2 | 30 Keane, 32 Brown | | Half-time: | 2-1 | | Referee: | Almeida Marcal 7 | | Attendance: | 31,308 | | Possession: | 50%-50% | | Total shots: | 11-16 | | MoM: | Defour |
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| | (4-3-3): Boruc 7, Konchesky 6, Izaguirre 7, Defour 7½, Rogne 6½, Ki 6, Fulton 6½, Iturbe 7, Cissé 6½, Brown 6 (47 Barton 7), Keane 6 | | Tottenham Hotspur | 1 | 26 Nani |
| | (4-3-3): Leno 7, Rami 7, Monreal 7, Shirokov 7, Ogbonna 7, Cole 6½, Foor 6, Nani 7½, Matavz 6½, Wickham 6½, Gabbiadini 5½ | | Espanyol | 1 | 33 Pedersen | | Half-time: | 1-0 | | Referee: | Constantin 6 | | Attendance: | 26,538 | | Possession: | 46%-54% | | Total shots: | 10-7 | | MoM: | Pareja |
| | 30 Juanmi | | (4-3-3): Álvarez 7, Roncaglia 7, Pinto 6½, Gurpegui 7, Pareja 7½, Hangeland 6, Corominas 7, Pedersen 7, Tamudo 6, Verdú 7, Juanmi 6½ | | Athletic Bilbao | 0 |
| | 50 Susaeta, 77 Mario Suárez | | (4-3-3): Pigliacelli 7, Torres 7, Canella 7, Mario Suárez 6½, Botía 7, Aurtenetxe 6½, Nsue 6, Susaeta 7, Osvaldo 6½, Albrighton 5½, Vela 7 | | FC Schalke 04 | 1 | 70 De Jong | | Half-time: | 0-1 | | Referee: | Levnikov 6 | | Attendance: | 38,407 | | Possession: | 45%-55% | | Total shots: | 18-14 | | MoM: | Badelj |
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| | (4-3-3): Mielitz 6, Träsch 6½ (68 Avevor 7½), Durm 7, Costa 6½, Salcido 6½, Kelly 7, Farfán 6½, Barnetta 6½, De Jong 6½, Crouch 6, Elmander 6½ | | Liverpool | 2 | 19 Vitolo, 47 Origi |
| | (4-3-3): Pyatov 6½, Vrsaljko 7, Sakho 8, Badelj 8, Lovren 7½, Taylor 6½, Henderson 6½, Vitolo 7½, Carroll 7, Ings 6, Origi 6½ | | Fenerbahçe | 3 | 29 Selçuk, 57 Sow, 65 Gökhan | | Half-time: | 1-0 | | Referee: | Michel 6 | | Attendance: | 35,829 | | Possession: | 44%-56% | | Total shots: | 11-20 | | MoM: | Vertonghen | | TV: | highlights |
| | 71 Semih | | (4-3-3): Tolga 6½, Gökhan 8, Bekir 8, Özer 7, Remzi Giray 7, Serkan 6, Mehmet 6½, Selçuk 6½, Sow 6½, Semih 6, Burak 6 | | Manchester City | 1 | 72 Herrmann | | 90+3 Demichelis | | (4-3-3): Kapino 7, Sagna 7, Vertonghen 8, Touré 6½, Demichelis 7½, Song 5½, Navas 6½, Herrmann 7½, Soldado 7½, Källström 7, Vucinic 6½ | | Internacional | 0 |
| | Half-time: | 0-0 | | Referee: | Norman 7½ | | Attendance: | 38,178 | | Possession: | 51%-49% | | Total shots: | 9-6 | | MoM: | Marcelo |
| | 11 Marcelo, 45+3 Jô | | (4-3-3): Fernando Henrique 7½, Danilo 7 (56 Sandro 7½), Kléber 7, João Pedro 7, Marcelo 8, André Bahia 7, Giuliano 8, Wágner 7, Walter 7, Jô 6, Taison 6½ | | Feyenoord | 0 |
| | 55 Maduro, 65 Kuyt, 82 Biseswar | | (4-3-3): Alvarado 7, Hutchinson 7½, Nelom 8, Biseswar 7, Van Beek 7½, Maduro 6½, Kuyt 7, De Guzman 7½, Castaignos 7½, Leerdam 6½, Kazim-Richards 6 | | Milan | 1 | 22 Joaquín | | Half-time: | 1-0 | | Referee: | Karlsson 7 | | Attendance: | 54,103 | | Possession: | 55%-45% | | Total shots: | 16-10 | | MoM: | Andújar |
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| | (4-3-3): Ospina 6½, Jedvaj 7, Kolarov 7, Cabaye 7, Ranocchia 7½, Laporte 7, Joaquín 7½, Depay 7, Mandzukic 5½, Bacca 7, Volland 7 | | Bayern München | 0 |
| | 68 Ignjovski | | (4-3-3): Andújar 7½, Essien 7½, Pranjic 7½, Sahin 7½, Papastathopoulos 6, Djourou 6, Forlin 6½, McEachran 6½, Barrios 6, Ignjovski 6, Aubameyang 6½ | | Newport County | 1 | 56 Rhodes | | Half-time: | 0-0 | | Referee: | Sarvan 6 | | Attendance: | 19,428 | | Possession: | 47%-53% | | Total shots: | 13-20 | | MoM: | Stones | | TV: | live |
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| | (4-3-3): McGregor 6, Stones 8, Bertrand 6, Alli 7, Tomkins 6½, Clark 6½, Cleverley 6½ (63 Dummett 7), Ayew 6, Rhodes 6½, Phillips 5½, Rodriguez 6 | | Ayr United | 1 | 76 Kane | | 30 Shawcross | | (4-3-3): Butland 6½, Clyne 6½, Brunt 7, McCarthy 7, Dier 6½, Shawcross 7, Davis 7½, Oxlade-Chamberlain 7½, Kane 7, Wilshere 6½, Long 5½ | | River Plate | 0 |
| | Half-time: | 0-1 | | Referee: | Pyanikh 7½ | | Attendance: | 37,391 | | Possession: | 49%-51% | | Total shots: | 12-13 | | MoM: | El Kaoutari | | TV: | highlights |
| | 51 Cabral, 68 López, 69 Mercado | | (4-3-3): Marchesín 6, Cicinho 6½, Basanta 7, Prediger 7, Cabral 6, López 6½, Affranchino 7, Buonanotte 7 (55 Mercado 7½), López 7½, Castillejos 6, Víctor 6 | | Napoli | 2 | 8 Quagliarella, 46 Gignac | | 2 Gastaldello, 7 Cigarini | | (4-3-3): De Sanctis 6, Maggio 6½, El Kaoutari 8, Ledesma 7½, Gastaldello 7½, Cannavaro 6½ (77 Necip 6½), Cigarini 6, Gargano 7, Gignac 6½, Mokotjo 7, Quagliarella 6 | | Sevilla | 3 | 21 Piatti, 39 Kiessling, 51 Fernando Navarro | | Half-time: | 2-0 | | Referee: | Vassaras 7½ | | Attendance: | 43,653 | | Possession: | 51%-49% | | Total shots: | 17-14 | | MoM: | Raul Meireles |
| | 81 O'Donnell | | (4-3-3): Navas 7, Silvestre 6½, Fernando Navarro 6½, Raul Meireles 8, Alexis 7, Squillaci 6, Aleix Vidal 7, Piatti 5½ (66 O'Donnell 7), Kiessling 7½, Makoun 6½, Giovinco 6 | | Marseille | 1 | 58 Brandão | | 24 Brandão, 71 Ben Arfa | | (4-3-3): Riou 7, Reveillère 6½, Kolodziejczak 7½, Menez 7, Alex Silva 7 (50 Rodwell 6½), Tabanou 6½, Pjanic 7½, Lamela 6½, Brandão 6, Ben Arfa 5½, Benzema 7 (52 González 6) | | Viktoria Plzen | 0 |
| | Half-time: | 0-1 | | Referee: | Colic 5 | | Attendance: | 40,965 | | Possession: | 52%-48% | | Total shots: | 16-15 | | MoM: | Kadlec |
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| | (4-3-3): Vaclik 6½, Gebre Selassie 7, Kadlec 8, Plasil 7½, Hübschman 6½, Suchý 6½, Prikryl 6½, Hlousek 7, Vydra 7, Sivok 6½, Lafata 7 | | Palmeiras | 2 | 3 Lucas, 86 Lucas | | 2 Danilo, 58 Lucas | | (4-3-3): Júlio César 7, Henrique 7, Alex Telles 7, Lucas 7, Danilo 7, Rafael Toloi 6, Diego Souza 6, Pierre 5½, Robert 6½ (48 Ewerthon 6), Márcio Araújo 6, Ronaldinho 7 | | Round 3 | | Milan | 0 |
| | Half-time: | 0-0 | | Referee: | Krondl 6½ | | Attendance: | 54,151 | | Possession: | 55%-45% | | Total shots: | 7-14 | | MoM: | Kapino |
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| | (4-3-3): Ospina 7, Jedvaj 7½, Kolarov 7, Cabaye 7½, Ranocchia 7, Laporte 6½, Joaquín 7, Depay 7½, Mandzukic 7½, Bacca 6, Volland 7 | | Manchester City | 0 |
| | 58 Song | | (4-3-3): Kapino 8, Sagna 7, Vertonghen 6, Touré 7, Demichelis 7½, Song 6, Navas 6½, Herrmann 6½, Soldado 6½, Källström 5½, Vucinic 7 |
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