| Round 5 | | Barcelona | 2 | 23 Iniesta, 26 Iniesta | | Half-time: | 2-1 | | Referee: | Dinelli 7½ | | Attendance: | 51,422 | | Possession: | 62%-38% | | Total shots: | 12-10 | | MoM: | Maxwell | | TV: | live |
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| | (4-3-3): Bravo 6½, Abate 7, Maxwell 8½, Rakitic 7½, Skrtel 7, Bartra 6½, Dos Santos 8, Iniesta 6 (53 Tiago 8), Gomez 7½, Suárez 6½, Neymar 6½ | | VfB Stuttgart | 2 | 42 Aquilani, 46 Hilbert |
| | (4-3-3): Ulreich 6½, Hilbert 7, Boka 6, Aquilani 7, Niedermeier 6, Osorio 6, Kuzmanovic 6, Thorsby 6, Schieber 6, Hamit 5½, Marica 5½ | | Boulogne | 3 | 17 Jadson, 20 Jadson, 79 Thiago | | Half-time: | 2-1 | | Referee: | Gvardis 7 | | Attendance: | 14,979 | | Possession: | 50%-50% | | Total shots: | 15-10 | | MoM: | Klose |
| | 76 Klose | | (4-3-3): Frey 7, Srna 5½ (54 Mikel 7½), Ibañez 7, Thiago 7, Klose 7½, Kverkvelia 6½, Gökhan 6½, Jadson 7, Álvaro 6½, Muniain 7, Kalou 6½ | | Lorient | 1 | 43 Balmont |
| | (4-3-3): Sorin 7, Baca 6, Morel 7½, Balmont 7½, Puygrenier 7, Mignot 6, Birsa 7½, Pied 6, Hoarau 6½, Mvuemba 5½, Sagbo 6 | | Brøndby | 2 | 26 Lulic, 79 Selçuk | | Half-time: | 1-1 | | Referee: | Larsen 7½ | | Attendance: | 28,915 | | Possession: | 56%-44% | | Total shots: | 14-11 | | MoM: | Marchese |
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| | (4-3-3): Diego López 7, Zapata 6½, Lulic 6½, Raúl García 6, Jantschke 7, Corluka 6, Pérez 7½, Gervinho 6½, Mirallas 7½, Selçuk 6 (80 Adrián 6), Roberto Firmino 6 | | Fiorentina | 1 | 38 Gilardino |
| | (4-3-3): Mirante 7, Konko 6½, Marchese 8, Rômulo 7, Cana 6½, Felipe 7 (59 Camporese 6), Donadel 6½, Braafheid 6, Gilardino 7, Seferovic 6½ (58 Keirrison 5½), Jovetic 6 | | CSKA | 1 | 34 Denisov | | Half-time: | 1-2 | | Referee: | Reijgwart 7½ | | Attendance: | 13,073 | | Possession: | 47%-53% | | Total shots: | 9-10 | | MoM: | Biglia |
| | 7 Washington, 62 Ignashevich | | (4-3-3): Moyá 6, Nababkin 5½, Schennikov 8½, Denisov 7½, Ignashevich 7, Sergio Sánchez 6½, Okay 6½, Dzsudzsák 7, Devic 6½, Oliseh 5½, Washington 5½ | | Atlético Madrid | 2 | 8 Rodríguez, 24 Marcos Alonso | | 13 Rodríguez | | (4-3-3): Marinelli 6½, Mario 7, Marcos Alonso 8½, Biglia 8½, Rodríguez 7½, Marc Muniesa 7½, Salvio 7½, Reyes 8, Borja Bastón 6½, Bojan 6½, Rodrigo 5½ | | Chelsea | 2 | 30og Mathieu, 71 Perisic | | Half-time: | 1-0 | | Referee: | Beschin 6½ | | Attendance: | 55,500 | | Possession: | 47%-53% | | Total shots: | 18-15 | | MoM: | Mathieu |
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| | (4-3-3): Muslera 8, Rafinha 7½, Baines 7, Bender 7½, Mangala 7½, Mustafi 6, Callejón 6 (80 Jonny 6), Perisic 7, Llorente 7, Schürrle 6, Bellarabi 5½ | | Rosenborg | 0 |
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| | (4-3-3): Trapp 7½, Cédric 7, Mathieu 8, Maher 7½, Toprak 6½ (64 Van Dijk 7), Zouma 6, Skjelbred 7, Corona 7, Pizarro 6½, Kovacic 6½, Aboubakar 6 | | Deportivo | 3 | 12 Nouioui, 25 Dominguez, 33 Diamé | | Half-time: | 3-0 | | Referee: | Tanner 7½ | | Attendance: | 34,542 | | Possession: | 52%-48% | | Total shots: | 17-11 | | MoM: | Juan Rodríguez |
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| | (4-3-3): Beto 7½, Javi López 7, Dominguez 7½, Juan Rodríguez 8½, José Castro 6, Colotto 6, Diamé 8, Guardado 7, Adúriz 6½, Juan Domínguez 7½, Nouioui 6 | | SV Werder Bremen | 1 | 48p Dost | | 75 Hunt | | (4-3-3): Gabulov 7, Prödl 7, Abdennour 7½, Samaris 8, Santacroce 6½, Uchida 6, Bargfrede 7, Hunt 6½, Dost 7, Diego Capel 5½, Adebayor 6½ | | Hamburger SV | 1 | 80 Ebert | | Half-time: | 0-0 | | Referee: | Webb 6 | | Attendance: | 38,345 | | Possession: | 55%-45% | | Total shots: | 17-6 | | MoM: | Trochowski |
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| | (4-3-3): Karnezis 7½, Rincón 8, Aogo 7½, Trochowski 8, Piris 7½, Mathijsen 6½, Ebert 7½, Elia 7, Guerrero 7, Demel 7, Petric 6½ | | Independiente | 0 |
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| | (4-3-3): Orión 7, Matheu 6½, Vallés 6½, Acevedo 7, Vittor 7, Fredes 6, Fernández 7, Mancuello 7 (81 Busse 6), Osvaldo 7, Gandín 6½, Suarez 5½ | | Hansa Rostock | 1 | 32 Gündogan | | Half-time: | 1-0 | | Referee: | Dowd 6½ | | Attendance: | 28,927 | | Possession: | 51%-49% | | Total shots: | 15-4 | | MoM: | Forster |
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| | (4-3-3): Howard 7, Piszczek 7½, Johnson 7, Gündogan 6½, Geromel 6½, Reinartz 6½, Gentner 7½, Goretzka 7½, Dzeko 6½, Benteke 6½, Martins 6 | | West Ham United | 0 |
| | 65 Brozovic, 76 Gibbs | | (4-3-3): Forster 8, Gray 6½, Gibbs 6, Gerrard 7½, Sané 7, Samba 6, Holmes 6½, Johnson 6½, Bent 6½, Brozovic 6½ (73 Cresswell 6), Sellin 5½ | | Lyon | 2 | 23 Lacazette, 66 Boussoufa | | Half-time: | 1-1 | | Referee: | Ancion 7 | | Attendance: | 27,619 | | Possession: | 55%-45% | | Total shots: | 17-8 | | MoM: | Lacazette |
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| | (4-3-3): Bettinelli 6½, Théophile-Catherine 6½, Bedimo 7½, Obraniak 7½, Armand 7½, Coulibaly 6½, Boussoufa 7½, Lacazette 7½, Roux 7½, Fatih 6½, Belfodil 6½ | | Aston Villa | 3 | 18 Aissati, 58p Heskey, 73p Heskey |
| | (4-3-3): Viviano 6, Naughton 7½, Warnock 7½, Bannan 7, Collins 6½, Davies 6, Reo-Coker 7 (63 Fryers 6), Aissati 6½, Heskey 7, Salifou 6, Bamford 5½ | | Roma | 2 | 2 Kruse, 26 Kruse | | Half-time: | 2-0 | | Referee: | Vink 7 | | Attendance: | 50,700 | | Possession: | 55%-45% | | Total shots: | 16-9 | | MoM: | Young | | TV: | highlights |
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| | (4-3-3): Adler 7½, Fazio 6½, Young 9, Schneiderlin 8, Evans 7, Coloccini 6, Tadic 7½, Çalhanoglu 7½, Pazzini 7, Gago 7½, Kruse 7 | | Bayer Leverkusen | 0 |
| | 29 Kuranyi | | (4-3-3): Giefer 7½, Fritz 7 (68 Cañete 7), Friedrich 6, Castro 6½, Servet 6½, Cambiasso 6½, Elano 7, Kakuta 6½, Kuranyi 7½, Rubén Pérez 6, Zárate 5½ | | TSG Hoffenheim | 0 |
| | Half-time: | 0-0 | | Referee: | Fenton 6½ | | Attendance: | 28,911 | | Possession: | 51%-49% | | Total shots: | 13-9 | | MoM: | Didac | | TV: | highlights |
| | 46 Sessègnon, 61 Ibisevic, 62 Maicosuel, 75 Ibisevic | | (4-3-3): Fährmann 7½, Lustig 6½, Didac 8, Gross 7½, Mangane 8, Amat 6½, Vukcevic 7½, Carlos Eduardo 7½, Ibisevic 6½, Maicosuel 5½, Sessègnon 6 | | Udinese | 0 |
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| | (4-3-3): Szczesny 8, Basta 6½, Hanley 6½, Isla 6½ (72 Diarra 6), Papadopoulos 6½, Léo 6½, Lodi 6½, Zimling 6½, Alex Geijo 6½, D'Agostino 6, Jaime 5½ | | Round 3 | | Hansa Rostock | 1 | 21 Johnson | | Half-time: | 1-0 | | Referee: | Rennie 7½ | | Attendance: | 28,926 | | Possession: | 51%-49% | | Total shots: | 13-7 | | MoM: | Johnson |
| | 83 Gentner | | (4-3-3): Howard 7, Piszczek 7, Johnson 8, Gündogan 7½, Geromel 6½, Reinartz 6, Gentner 6½, Goretzka 7½, Dzeko 6½, Benteke 6½, Martins 6½ | | Aston Villa | 0 |
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| | (4-3-3): Viviano 8, Naughton 7, Warnock 7, Bannan 7½, Collins 7½, Davies 6, Reo-Coker 7, Aissati 7, Heskey 6½, Salifou 6½, Bamford 6½ (58 Harewood 6) |
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