| Round 1 | | Accrington Stan. | 2 | 22 Sturridge, 71 Ramsey | | Half-time: | 1-0 | | Referee: | Babin 7 | | Attendance: | 30,878 | | Possession: | 60%-40% | | Total shots: | 17-10 | | MoM: | Ramsey |
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| | (4-3-3): Hart 7½, Smalling 8, Rose 6½, Alli 7½, Cahill 6 (56 Ward-Prowse 7), Jagielka 7, Ramsey 8, Musa 7, Sturridge 7½, Barkley 6½, Welbeck 6½ (77 Iheanacho 6) | | Feyenoord | 0 |
| | 8 Van Wolfswinkel, 29 Kazim-Richards | | (4-3-3): Vermeer 7½, Hutchinson 7, Kongolo 5½, Maduro 6½, Van Beek 6, Schenkeveld 6, Kuyt 7½, Vilhena 6½, Castaignos 7, Van Wolfswinkel 6, Kazim-Richards 5½ | | Arsenal | 3 | 11 Reus, 48 Reus, 65p Boyé | | Half-time: | 1-0 | | Referee: | Van Der Pas 6 | | Attendance: | 58,699 | | Possession: | 57%-43% | | Total shots: | 16-8 | | MoM: | Ribéry | | TV: | live |
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| | (4-3-3): Cech 7, Tolisso 6½, Martins-Indi 7½, Marchisio 7, Mertesacker 5½ (57 Pedro 6½), Koscielny 6, Ribéry 8, Koke 8, Boyé 7, Reus 6½, Sánchez 6½ | | Benfica | 1 | 52 Drogba |
| | (4-3-3): Lopes 6, Pereira 6, Eliseu 7, Javi García 7½, Maicon 7, Ayala 6, Ruben Amorim 6, Alex 6½, Drogba 7, Welliton 5½, Cardozo 6 | | Borussia Dortmund | 2 | 7 Lewandowski, 74 Hazard | | Half-time: | 1-1 | | Referee: | Wieser 6½ | | Attendance: | 54,500 | | Possession: | 51%-49% | | Total shots: | 8-9 | | MoM: | Payet | | TV: | highlights |
| | 4 Fekir, 23 Ramires | | (4-3-3): Zieler 7, Höwedes 6 (68 Can 7½), Schmelzer 7, Saúl 7, Giménez 7, Ginter 6½, Ramires 7½, Hazard 6½, Lewandowski 6½, Guarín 7, Fekir 6½ | | Nantes | 1 | 29 Gonalons |
| | (4-3-3): Mandanda 6½, Colin 7, Digne 7½, Payet 8, Kurzawa 6½, Mendy 6, Sissoko 6½, Di María 6, Gomis 6, Gonalons 6½, Gouffran 5 | | Exeter City | 2 | 41 Austin, 90 Blackett | | Half-time: | 1-1 | | Referee: | Craciun 7½ | | Attendance: | 19,777 | | Possession: | 60%-40% | | Total shots: | 16-8 | | MoM: | Barry |
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| | (4-3-3): Foster 6½, Coleman 7, Johnson 6½, Barry 8½, Jones 8, Keane 6 (62 Targett 6), Drinkwater 8, Milner 6½ (66 Blackett 7½), Austin 7, Delph 7, Vardy 7 | | Tottenham Hotspur | 1 | 37 Foor |
| | (4-3-3): Leno 7, Cáceres 6, Ogbonna 7, Shirokov 7½, Álvarez 6, Cole 6½, Foor 7, Nani 6½, Matavz 6, Wickham 5½, Gabbiadini 7 | | FC Basel | 1 | 67p Enes | | Half-time: | 0-1 | | Referee: | Kefalas 6 | | Attendance: | 38,334 | | Possession: | 52%-48% | | Total shots: | 14-12 | | MoM: | Dani Alves |
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| | (4-3-3): Weidenfeller 6½, Dani Alves 8, Jordi Alba 7½, Rodríguez 7½, Dante 7½, Lichtsteiner 5½, Traoré 6½, Willian 7½, Enes 7, Mkhitaryan 6½, Berardi 6 | | Helsingborg | 1 | 4 Sigurðsson |
| | (4-3-3): De Gea 7½, Wass 7, Rojo 7 (55 Sisto 7½), Nordtveit 6½, Kjær 6½, Vestergaard 6½, Ekdal 7½, Sigurðsson 7½, Agüero 7½, Diego Costa 6, Fischer 5½ | | FC Porto | 1 | 42 Fernandinho | | Half-time: | 1-0 | | Referee: | Bolognino 6½ | | Attendance: | 49,148 | | Possession: | 48%-52% | | Total shots: | 15-15 | | MoM: | Luisão |
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| | (4-3-3): Rui Patrício 8, Bruno Alves 7 (58 Anderson Talisca 7½), Alex Sandro 7, Danny 7½, Luisão 8, Alex 6½, Marcelo 6½ (55 Rolando 6½), Douglas Costa 7½, Falcao 7, Fernandinho 6½, Hulk 6½ | | Valencia | 0 |
| | 8 Paco Alcácer, 67 Rodrigo | | (4-3-3): Reina 8, Javi Manquillo 6½, Vargas 7 (63 Paulinho 7½), André Gomes 7½, San Jose 7, Aderlan 6, Lennon 7½, Perotti 7, Hernández 6½, Paco Alcácer 5½, Rodrigo 6 | | Lazio | 0 |
| | Half-time: | 0-0 | | Referee: | Poyet 7 | | Attendance: | 48,216 | | Possession: | 49%-51% | | Total shots: | 10-12 | | MoM: | Boateng | | TV: | live |
| | 70 Babacar | | (4-3-3): Stekelenburg 6½, Bonera 7, Antonelli 6, Onazi 7, Maurício 6½, Ariaudo 6½, Schelotto 7 (66 Verdi 7), Ilicic 6½, Djordjevic 6, Matri 6, Babacar 7 | | Newcastle United | 2 | 65 Vidal, 70 Vidal |
| | (4-3-3): Handanovic 7, Boateng 8, Alaba 7 (56 De Bruyne 6), Vidal 7, Godín 7½, Hummels 6½, Götze 7, Özil 6½, Mitrovic 6½, Silva 7, Ayoze 6 | | Lille | 3 | 16 Gaitán, 18 Negredo, 80 Lallana | | Half-time: | 2-0 | | Referee: | Korac 7 | | Attendance: | 17,998 | | Possession: | 54%-46% | | Total shots: | 17-7 | | MoM: | Valencia | | TV: | highlights |
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| | (4-3-3): Lloris 7, Jallet 8, Evrà 6½, Lallana 7½, Rosales 7, Rodriguez 7½, Valencia 8, Gaitán 7, Negredo 7, Mavuba 6½, Tallo 6½ | | Ajax | 0 |
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| | (4-3-3): Cillessen 7½, Veltman 6½, Willems 7, De Jong 7, Bruma 7, Vlaar 6, Narsingh 6½ (76 Van Rhijn 6), Sinkgraven 7, Huntelaar 7½, Klaassen 7, Lens 6 | | Liverpool | 2 | 15 Henderson, 40 Vitolo | | Half-time: | 2-0 | | Referee: | Hauge 6½ | | Attendance: | 34,034 | | Possession: | 51%-49% | | Total shots: | 18-12 | | MoM: | Sakho |
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| | (4-3-3): Pyatov 7, Vrsaljko 6 (53 Sørum 7½), Sakho 7½, Badelj 7½, Lovren 6½, Taylor 7 (81 Ings 6), Henderson 6½, Vitolo 7, Carroll 6½, Antonio 5½, Moses 6 | | Newport County | 1 | 78 Ayew |
| | (4-3-3): McGregor 7½, Tomkins 7½, Bertrand 6½ (66 Acheampong 6½), Cleverley 7, Dummett 7, Clark 5½, Livermore 6, Ayew 6, Rhodes 7, Phillips 6, Rodriguez 6 | | Palermo | 3 | 22p Destro, 71 Bernardeschi, 84 Bernardeschi | | Half-time: | 1-1 | | Referee: | Waddel 7 | | Attendance: | 38,862 | | Possession: | 51%-49% | | Total shots: | 15-12 | | MoM: | Criscito | | TV: | highlights |
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| | (4-3-3): Benaglio 6½, Zappacosta 6½, Criscito 8, Jorginho 7½, Astori 7, Rugani 7, Bentivegna 6, Bernardeschi 7½, Destro 6½, Montolivo 5½ (54 Vázquez 6½), Éder 5½ | | São Paulo | 1 | 10 Lucas Moura |
| | (4-3-3): Hélton 7, Maicon 7½, Wendell 7, Casemiro 7, Juan 7, Rodrigo Caio 6, Kelvin 6½, Lucas Moura 7 (55 Diego 6½), Willian 6½, Renato Augusto 6½, Robinho 6½ | | Real Madrid | 2 | 25 Ronaldo, 51 Ronaldo | | Half-time: | 1-0 | | Referee: | Severino 7 | | Attendance: | 63,636 | | Possession: | 59%-41% | | Total shots: | 15-6 | | MoM: | Bale |
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| | (4-3-3): Neuer 7, Sergio Ramos 8, Chiellini 8, Lahm 7½, Piqué 6 (56 Bale 8), Mascherano 6, Modric 7½, Ronaldo 7½, Ibrahimovic 7, Kroos 6½, Vílla 6½ | | Anderlecht | 0 |
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| | (4-3-3): Mignolet 7½, Gillet 7, Deschacht 6½, Dembélé 6, Chedjou 7, Ramis 6, Marecek 6½ (53 Godoy 6), Ilicevic 6, Lukaku 7, Mollo 5½, Jonas 5½ | | Round 2 | | Ajax | 1 | 37 Kishna | | Half-time: | 1-0 | | Referee: | Karlsson 6½ | | Attendance: | 51,499 | | Possession: | 42%-58% | | Total shots: | 10-13 | | MoM: | Kroos |
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| | (4-3-3): Cillessen 7½, Veltman 7, Willems 7½, De Jong 7½, Bruma 7, Vlaar 6½, Narsingh 6½, Kishna 6½, Huntelaar 6½, Klaassen 6½, Lens 5½ | | Real Madrid | 0 |
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| | (4-3-3): Neuer 8, Lahm 7, Chiellini 7½, Kroos 8½, Piqué 7½, Sergio Ramos 6, Modric 7, Ronaldo 8, Ibrahimovic 6½, Bale 6½, Vílla 6½ | | Anderlecht | 2 | 2 Lukaku, 8 Lukaku | | Half-time: | 2-3 | | Referee: | Detruche 6½ | | Attendance: | 27,900 | | Possession: | 44%-56% | | Total shots: | 9-11 | | MoM: | Bonera |
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| | (4-3-3): Mignolet 5½, Gillet 6, Deschacht 6, Dembélé 6½, Chedjou 7½, Ramis 5½, Marecek 6 (53 Godoy 6½), Ilicevic 7, Lukaku 7, Mollo 5½, Jonas 6½ | | Lazio | 3 | 21 Ilicic, 28 Schelotto, 34 Schelotto | | 70 Djordjevic, 86 Ariaudo | | (4-3-3): Stekelenburg 5½, Bonera 7½, Antonelli 6½, Onazi 6½, Maurício 6½, Ariaudo 6, Schelotto 7½, Ilicic 6½, Djordjevic 6, Matri 6, Babacar 6½ | | Benfica | 0 |
| | Half-time: | 0-0 | | Referee: | Sarvan 7½ | | Attendance: | 41,638 | | Possession: | 47%-53% | | Total shots: | 9-12 | | MoM: | Badelj |
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| | (4-3-3): Lopes 7½, Pereira 6½, Eliseu 7, Javi García 7, Maicon 7, Ayala 6½, Ruben Amorim 6½, Alex 6½, Drogba 7 (59 Alan 7½), Welliton 5½, Cardozo 6½ | | Liverpool | 0 |
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| | (4-3-3): Pyatov 7½, Vrsaljko 6½, Sakho 7½, Badelj 7½, Lovren 6½, Taylor 6½, Henderson 7½, Vitolo 7 (61 Aleksic 7), Carroll 6½, Ings 6, Moses 6½ | | Feyenoord | 0 |
| | Half-time: | 0-2 | | Referee: | Wiley 7 | | Attendance: | 42,258 | | Possession: | 46%-54% | | Total shots: | 17-18 | | MoM: | Marchisio |
| | 8 Castaignos, 17 Hutchinson | | (4-3-3): Vermeer 6, Hutchinson 5, Kongolo 6½, Maduro 7½, Van Beek 6½, Schenkeveld 6½, Kuyt 6½, Vilhena 6½, Castaignos 7, Van Wolfswinkel 6, Kazim-Richards 6 | | Arsenal | 3 | 15 Reus, 32 Martins-Indi, 78 Koke |
| | (4-3-3): Cech 6, Tolisso 8, Martins-Indi 7, Marchisio 8, Mertesacker 7 (57 Pedro 7), Koscielny 6½, Ribéry 7, Koke 7, Boyé 6, Reus 7, Sánchez 6½ | | Helsingborg | 3 | 43 Kjær, 50 Diego Costa, 70 Agüero | | Half-time: | 1-0 | | Referee: | Rosetti 7 | | Attendance: | 40,682 | | Possession: | 44%-56% | | Total shots: | 13-12 | | MoM: | Austin |
| | 89 Sigurðsson | | (4-3-3): De Gea 7, Wass 6½, Rojo 5½ (55 Sisto 8), Nordtveit 6½, Kjær 7½, Vestergaard 6½, Ekdal 7, Sigurðsson 6½, Agüero 7, Diego Costa 5½, Fischer 5½ | | Exeter City | 1 | 47 Milner |
| | (4-3-3): Foster 6½, Coleman 6½, Johnson 6½, Barry 8, Jones 7½, Keane 6½, Drinkwater 7, Milner 6½, Austin 8½, Delph 6, Vardy 7½ | | Nantes | 1 | 58 Di María | | Half-time: | 0-1 | | Referee: | Heynemann 6½ | | Attendance: | 37,436 | | Possession: | 51%-49% | | Total shots: | 9-14 | | MoM: | Digne |
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| | (4-3-3): Mandanda 6½, Colin 6, Digne 7½, Payet 7, Mendy 6½, Kurzawa 7, Sissoko 6, Di María 7, Gomis 7, Gonalons 6½, Gouffran 6 | | FC Porto | 1 | 4 Hulk |
| | (4-3-3): Rui Patrício 7, Bruno Alves 7 (58 Anderson Talisca 6½), Alex Sandro 7½, Danny 7½, Luisão 6½, Alex 6, Marcelo 6½ (55 Rolando 7), Douglas Costa 7½, Falcao 6½, Fernandinho 6, Hulk 6½ | | Newcastle United | 2 | 69 Özil, 73 Özil | | Half-time: | 0-1 | | Referee: | Levnikov 7 | | Attendance: | 52,211 | | Possession: | 53%-47% | | Total shots: | 22-16 | | MoM: | Boateng |
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| | (4-3-3): Handanovic 6½, Boateng 7½, Alaba 6 (69 De Bruyne 6½), Vidal 7, Godín 7, Hummels 6½, Götze 7, Özil 6½, Mitrovic 6, Silva 7, Ayoze 6 | | Palermo | 1 | 6 Éder |
| | (4-3-3): Benaglio 6½, Zappacosta 6, Criscito 6½ (62 Vázquez 6½), Jorginho 7, Astori 6½, Rugani 6, Bentivegna 6, Bernardeschi 6, Destro 7, Montolivo 6, Éder 7 | | Newport County | 0 |
| | Half-time: | 0-1 | | Referee: | Damgaard 6 | | Attendance: | 19,335 | | Possession: | 48%-52% | | Total shots: | 10-13 | | MoM: | Cahill |
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| | (4-3-3): McGregor 6½, Tomkins 7, Bertrand 7 (66 Acheampong 7), Cleverley 6½, Dummett 7, Clark 7, Livermore 6, Ayew 6½, Rhodes 6½, Phillips 5½, Rodriguez 7 | | Accrington Stan. | 2 | 10 Musa, 79 Sterling |
| | (4-3-3): Hart 6½, Smalling 7, Rose 7, Alli 6½, Cahill 8, Stones 5½, Ramsey 6½ (77 Ward-Prowse 7½), Sterling 7, Sturridge 7 (78 Allen 6), Barkley 7, Musa 6½ | | São Paulo | 2 | 13 Kelvin, 86 Renato Augusto | | Half-time: | 1-1 | | Referee: | Larsen 6½ | | Attendance: | 46,664 | | Possession: | 51%-49% | | Total shots: | 8-11 | | MoM: | Schmelzer |
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| | (4-3-3): Hélton 6, Maicon 7½, Wendell 7½, Casemiro 8, Juan 7, Rodrigo Caio 7, Kelvin 6, Lucas Moura 6 (55 Diego 7), Willian 6½, Renato Augusto 6½, Robinho 6½ (86 Henrique 6) | | Borussia Dortmund | 2 | 35 Giménez, 68 Schmelzer | | 50 Fekir | | (4-3-3): Zieler 6, Höwedes 6½, Schmelzer 8, Saúl 6, Giménez 7, Ginter 7 (86 Contento 6), Ramires 7, Hazard 6½ (58 Hofmann 7), Lewandowski 6½, Bender 6, Fekir 5½ | | Tottenham Hotspur | 1 | 37 Nani | | Half-time: | 1-1 | | Referee: | Colic 6½ | | Attendance: | 36,067 | | Possession: | 46%-54% | | Total shots: | 19-12 | | MoM: | Ogbonna |
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| | (4-3-3): Leno 7, Cáceres 7, Ogbonna 9, Shirokov 7, Álvarez 7, Cole 7, Foor 7½, Nani 7, Matavz 6½, Wickham 5½, Gabbiadini 6½ | | FC Basel | 1 | 45+2 Willian |
| | (4-3-3): Weidenfeller 7, Dani Alves 7, Jordi Alba 6½, Rodríguez 7, Dante 7, Lichtsteiner 7, Traoré 7, Willian 7, Enes 6½, Mkhitaryan 6½, Berardi 5½ | | Valencia | 1 | 5 André Gomes | | Half-time: | 1-0 | | Referee: | Dondarini 6 | | Attendance: | 47,117 | | Possession: | 51%-49% | | Total shots: | 10-7 | | MoM: | Valencia |
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| | (4-3-3): Reina 7½, Javi Manquillo 6½, Vargas 7, André Gomes 6½ (74 Paulinho 7½), San Jose 7, Aderlan 7, Lennon 6½, Perotti 7, Paco Alcácer 7½, Hernández 6, Santi Mina 6 | | Lille | 0 |
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| | (4-3-3): Lloris 7½, Jallet 6½, Evrà 7, Lallana 7, Rosales 6, Rodriguez 6½, Valencia 8, Gaitán 7½, Negredo 6, Mavuba 6, Tallo 5½ |
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