| Round 3 | | Arsenal | 2 | 41 Koke, 90 Debuchy | | Half-time: | 1-0 | | Referee: | Leyden 8 | | Attendance: | 59,839 | | Possession: | 57%-43% | | Total shots: | 16-5 | | MoM: | Marchisio |
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| | (4-3-3): Buffon 7, Tolisso 7, Nacho Monreal 8, Marchisio 8, Mertesacker 7, Koscielny 6½, Ribéry 7½, Koke 7, Boyé 6 (61 Debuchy 6½), Reus 7, Pedro 5½ | | Nantes | 1 | 67 Gomis |
| | (4-3-3): Mandanda 7, Colin 6, Digne 7½, Guilavogui 7, Gonalons 6½, Kurzawa 6½, Toulalan 6, Di María 6½, Gomis 7, Payet 6, Benzia 6½ (68 Alessandrini 6) | | Exeter City | 1 | 60 Austin | | Half-time: | 0-2 | | Referee: | Aksenov 7 | | Attendance: | 19,786 | | Possession: | 53%-47% | | Total shots: | 21-12 | | MoM: | Drinkwater |
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| | (4-3-3): Foster 6½, Trippier 6½, Johnson 7, Delph 7½, Terry 7, Jones 7, Drinkwater 8, Milner 7, Austin 7½, Barry 6½, Vardy 6½ | | Valencia | 2 | 15 Javi Manquillo, 41 Paco Alcácer |
| | (4-3-3): Reina 6, Javi Manquillo 6½, Vargas 7, André Gomes 7 (74 Paulinho 6), San Jose 7, Aderlan 6½, Lennon 6½, Perotti 6½, Paco Alcácer 6½, Hernández 6, Santi Mina 6 | | FC Basel | 2 | 8 Draxler, 20 Enes | | Half-time: | 2-0 | | Referee: | Fisk 7½ | | Attendance: | 38,384 | | Possession: | 47%-53% | | Total shots: | 18-12 | | MoM: | Weidenfeller | | TV: | highlights |
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| | (4-3-3): Weidenfeller 8, Dani Alves 7, Bernat 8, Matuidi 7½, Dante 6½, Lichtsteiner 6, Florenzi 6½, Isco 7, Enes 6½, Draxler 7, Berardi 5½ | | Feyenoord | 0 |
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| | (4-3-3): Vermeer 6½, Hutchinson 7, Kongolo 7, Maduro 7½, Van Beek 6½, Schenkeveld 6½, Kuyt 6½, Vilhena 7½, Castaignos 6½, Van Wolfswinkel 5½, Kazim-Richards 7 | | FC Porto | 3 | 18 Danny, 39 Fernandinho, 86 Falcao | |
| | (4-3-3): Rui Patrício 7, Bruno Alves 6½ (58 Anderson Talisca 8½), Alex Sandro 7, Danny 7½, Luisão 8, Alex 6½, Marcelo 5½ (55 Rolando 8), Douglas Costa 7, Falcao 8, Fernandinho 7, Hulk 7 | | São Paulo | 1 | 29 Renato Augusto |
| | (4-3-3): Hélton 6½, Maicon 6, Wendell 7½, Casemiro 7, Juan 6½, Rodrigo Caio 6½, Kelvin 6½, Renato Augusto 6½, Willian 6, Michel Bastos 6, Robinho 6½ | | Lazio | 0 |
| | Half-time: | 0-1 | | Referee: | Kurisawa 7 | | Attendance: | 45,330 | | Possession: | 49%-51% | | Total shots: | 10-13 | | MoM: | Antonelli | | TV: | live |
| | 54 Schelotto | | (4-3-3): Stekelenburg 7, Bonera 8, Antonelli 8½, Onazi 8, Maurício 7, Ariaudo 7, Schelotto 7 (63 Verdi 7), Ilicic 6½, Djordjevic 7, Matri 6½, Babacar 6 | | Helsingborg | 1 | 7 Agüero | | 1 Diego Costa | | (4-3-3): De Gea 7, Wass 8, Rojo 6½ (55 Sisto 6½), Nordtveit 7, Kjær 6½, Vestergaard 6½, Ekdal 7, Sigurðsson 6½, Agüero 7, Diego Costa 5½, Fischer 5½ | | Palermo | 1 | 56p Destro | | Half-time: | 0-2 | | Referee: | Dinelli 8 | | Attendance: | 38,965 | | Possession: | 51%-49% | | Total shots: | 26-8 | | MoM: | Insigne |
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| | (4-3-3): Sommer 5½, Zappacosta 6, Romagnoli 7½, Jorginho 7½, Astori 7½, Rugani 6½, Candreva 7, Insigne 8, Destro 7½, Parolo 6½, Éder 6½ | | Anderlecht | 2 | 11 Ilicevic, 32 Dembélé |
| | (4-3-3): Mignolet 6½, Gillet 6, Pocognoli 7, Dembélé 7, Chedjou 6½, Ramis 5½, Marecek 6½, Ilicevic 7, Lukaku 6½, Kerzhakov 5½, Mollo 6 | | Real Madrid | 2 | 5 Bale, 14 Ronaldo | | Half-time: | 2-0 | | Referee: | Georgiev 7½ | | Attendance: | 66,648 | | Possession: | 61%-39% | | Total shots: | 26-7 | | MoM: | Lahm |
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| | (4-3-3): Neuer 7½, Lahm 8, Chiellini 7, Kroos 7½, Piqué 6 (84 Bonucci 6), Sergio Ramos 6½, Modric 7, Ronaldo 7, Ibrahimovic 7½, Bale 7½, Vílla 7½ | | Benfica | 0 |
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| | (4-3-3): Lopes 7½, Pereira 7, Eliseu 6½, Javi García 6½, Ricardo Carvalho 7, Ayala 6½, Ruben Amorim 6, Alex 6, Drogba 7, André Almeida 6, Cardozo 6½ | | Round 4 | | Ajax | 0 |
| | Half-time: | 0-0 | | Referee: | Ziober 5½ | | Attendance: | 51,602 | | Possession: | 44%-56% | | Total shots: | 9-12 | | MoM: | Koscielny | | TV: | highlights |
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| | (4-3-3): Cillessen 6½, Veltman 7½, Willems 7½, Sneijder 7, Bruma 7, Vlaar 6½, Narsingh 7, Lens 7, Huntelaar 6½, Milik 6, Van Amersfoort 7 (64 Van Aken 6) | | Arsenal | 2 | 51 Boyé, 81p Boyé |
| | (4-3-3): Buffon 7, Tolisso 7, Nacho Monreal 7½, Marchisio 7½, Koscielny 7½, Mertesacker 6, Ribéry 6½, Koke 7 (79 Denayer 6), Boyé 6, Reus 6½, Pedro 6½ | | Benfica | 0 |
| | Half-time: | 0-0 | | Referee: | Constantin 7 | | Attendance: | 40,510 | | Possession: | 42%-58% | | Total shots: | 13-18 | | MoM: | Zieler |
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| | (4-3-3): Lopes 7½, Pereira 6½, Eliseu 6, Javi García 7½, Ricardo Carvalho 6½, Ayala 6, Ruben Amorim 7, Alex 6, Drogba 7, André Almeida 5½, Cardozo 7 | | Borussia Dortmund | 0 |
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| | (4-3-3): Zieler 7½, Höwedes 6½, Schmelzer 6½, Saúl 7½, Giménez 7½, Ginter 6½, Ramires 7, Hazard 7, Lewandowski 7½, Can 6½, Podolski 6 | | Feyenoord | 0 |
| | Half-time: | 0-0 | | Referee: | Craciun 6½ | | Attendance: | 29,010 | | Possession: | 48%-52% | | Total shots: | 9-13 | | MoM: | Maduro |
| | 65 Kuyt | | (4-3-3): Vermeer 7½, Hutchinson 7½, Kongolo 7, Maduro 8, Van Beek 7, Schenkeveld 6, Kuyt 6½, Vilhena 7, Castaignos 7½, Van Wolfswinkel 6½, Kazim-Richards 7 (56 Johansson 6) | | Liverpool | 0 |
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| | (4-3-3): Pyatov 7, Vrsaljko 7½, Sakho 7, Badelj 7, Lovren 7½, Taylor 6, Henderson 7½, Vitolo 6½ (61 Aleksic 6), Carroll 7, Ings 6, Moses 6 | | Helsingborg | 3 | 6 Agüero, 16 Agüero, 69 Fischer | | Half-time: | 2-0 | | Referee: | Forsell 7 | | Attendance: | 40,755 | | Possession: | 42%-58% | | Total shots: | 11-13 | | MoM: | Sisto | | TV: | live |
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| | (4-3-3): De Gea 7, Wass 6, Rojo 5½ (55 Sisto 8), Nordtveit 7, Kjær 6, Vestergaard 6½, Ekdal 6½, Sigurðsson 7½, Agüero 7½, Diego Costa 6, Fischer 5½ | | Accrington Stan. | 1 | 53 Musa |
| | (4-3-3): Hart 7½, Walker 8, Rose 8, Alli 8, Smalling 7½, Williams 6½, Ramsey 7½, Sterling 7, Sturridge 7, Allen 6½ (79 Rashford 6), Musa 6½ | | Newcastle United | 1 | 67p Higuaín | | Half-time: | 0-1 | | Referee: | Marriner 6 | | Attendance: | 52,217 | | Possession: | 44%-56% | | Total shots: | 13-13 | | MoM: | Lallana |
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| | (4-3-3): Courtois 6½, Boateng 6½, Alaba 7, Vidal 7, Godín 6½, Hummels 6½, De Bruyne 7, Özil 6½, Higuaín 7, Silva 7, Müller 6½ | | Lille | 1 | 14p Negredo |
| | (4-3-3): Lloris 6, Jallet 7½, Evrà 7, Lallana 8, Rosales 6, Rodriguez 7½, Valencia 7½, Gaitán 7, Negredo 7, Mavuba 6½, Tallo 5½ | | Newport County | 2 | 12 Ayew, 57 Ayew | | Half-time: | 1-1 | | Referee: | Breno 7½ | | Attendance: | 19,380 | | Possession: | 52%-48% | | Total shots: | 10-14 | | MoM: | Bertrand |
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| | (4-3-3): McGregor 7, Tomkins 7, Bertrand 8½, Cleverley 7½, Dummett 6½, Clark 6 (47 Acheampong 7), Livermore 6½, Ayew 7½, Rhodes 7, Phillips 5½, Rodriguez 6 | | Exeter City | 1 | 9 Milner |
| | (4-3-3): Foster 7½, Jenkinson 6½, Johnson 8, Delph 7½, Terry 7, Keane 6½, Drinkwater 6, Milner 7½, Austin 7, Barry 6, Vardy 5½ | | Tottenham Hotspur | 1 | 86 Matavz | | Half-time: | 0-1 | | Referee: | Van Hulten 6 | | Attendance: | 36,045 | | Possession: | 39%-61% | | Total shots: | 8-18 | | MoM: | Ogbonna |
| | 63 Shirokov | | (4-3-3): Leno 5½, Cáceres 6½, Ogbonna 8, Shirokov 6½ (65 Torres 7), Álvarez 6½, Crescenzi 6½, Foor 6½, Nani 6, Matavz 6½, Benitez 5½, Wickham 7 | | Palermo | 3 | 22 Candreva, 69og Crescenzi, 81p Destro |
| | (4-3-3): Sommer 6, Zappacosta 7½, Romagnoli 6, Motta 7½, Astori 7½, Rugani 6½, Candreva 8, Insigne 7½, Destro 7½, Parolo 7, Éder 6½ | | Valencia | 1 | 14 Perotti | | Half-time: | 1-0 | | Referee: | Circhetta 7 | | Attendance: | 56,257 | | Possession: | 55%-45% | | Total shots: | 22-7 | | MoM: | Aderlan |
| | 62 San Jose | | (4-3-3): Reina 7½, Javi Manquillo 7½, Vargas 7, André Gomes 6½ (74 Paulinho 7½), San Jose 7, Aderlan 8, Lennon 6½, Perotti 7½, Paco Alcácer 7½, Hernández 6½, Santi Mina 7 | | FC Basel | 0 |
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| | (4-3-3): Weidenfeller 7, Dani Alves 6½, Bernat 7, Matuidi 7½, Dante 6½, Juanfran 6, Florenzi 7, Isco 6½, Enes 6, Rodríguez 6½, Berardi 5½ |
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