| Round 3 | | Baník Ostrava | 1 | 87 Totti | | Half-time: | 0-0 | | Referee: | Webb 6 | | Attendance: | 17,347 | | Possession: | 56%-44% | | Total shots: | 10-5 | | MoM: | Carrasso |
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| | (4-3-3): Perin 7½, Hubocan 7, Filipe Luis 6½, Xhaka 8, Medel 6½ (47 Nastasic 7), Schär 6½, Traoré 6½, Yarmolenko 7, Giroud 7½, Arnold 7, Totti 6½ | | Dynamo | 0 |
| | 34 Khacheridi, 40 Harmash, 60 Kravets | | (4-3-3): Carrasso 8, Vida 6, Nesmachnyi 6½, Blanco 7½, Mykhalyk 6, Khacheridi 6, Bystrov 6½, Pienaar 6½, Milevskyi 7, Harmash 6, Kravets 6 | | Barcelona | 1 | 9 Feghouli | | Half-time: | 1-0 | | Referee: | Almeida Marcal 7 | | Attendance: | 53,654 | | Possession: | 56%-44% | | Total shots: | 14-6 | | MoM: | Rakitic | | TV: | highlights |
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| | (4-3-3): Ter Stegen 7½, Sergi Roberto 7½, Maxwell 7, Busquets 7, Bartra 6½, Fernández 6½, Feghouli 7½, Iniesta 6½ (50 Torres 6), Suárez 7½, Rakitic 8, Neymar 7 | | Ayr United | 0 |
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| | (4-3-3): Butland 7½, Clyne 7, Brunt 7 (69 Westwood 6), McCarthy 6½, Dann 6½, Shawcross 6, Wilshere 7, Oxlade-Chamberlain 7, Kane 7, Fletcher 6½, Long 7 (62 Townsend 5½) | | Chelsea | 2 | 8 Pellé, 57 Pellé | | Half-time: | 1-0 | | Referee: | Kazlauskas 6½ | | Attendance: | 55,408 | | Possession: | 48%-52% | | Total shots: | 11-14 | | MoM: | Muslera | | TV: | live |
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| | (4-3-3): Muslera 8, Rüdiger 6½, Baines 6 (76 Khedira 6), Matic 7, Mustafi 7½, Touré 6½, Callejón 7½, Schürrle 6½, Pellé 7, Kramer 7 (82 Perisic 6), Bellarabi 6½ | | Milan | 0 |
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| | (4-3-3): Oblak 8, Aurier 7½, Kolasinac 6½, Cabaye 7, Javi Martínez 6½, Laporte 7, Volland 7, El Shaarawy 7, Mandzukic 6½, Bacca 6½, Niang 6 | | Espanyol | 0 |
| | Half-time: | 0-1 | | Referee: | Brito Arceo 8 | | Attendance: | 34,647 | | Possession: | 55%-45% | | Total shots: | 10-13 | | MoM: | Prudnikov |
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| | (4-3-3): Lux 7, Roncaglia 7½, Pinto 7 (62 Chica 7½), Javi Márquez 6½, Motta 6, Coke 6½, Olic 5½, Pedersen 7, Tamudo 6, Verdú 7½, Juanmi 7 | | Spartak | 1 | 29 Ozdoev | | 21 Makeev | | (4-3-3): Ryzhikov 7, Mário Fernandes 7, Kombarov 7, Dzagoev 7½, Makeev 5½, Berezutsky 6, Bazhenov 7½, Mamaev 7, Prudnikov 7½, Ozdoev 7½, Arshavin 5½ | | Manchester City | 3 | 17 Rodríguez, 31 Soldado, 56 Ambrose | | Half-time: | 2-1 | | Referee: | Cinciripini 6 | | Attendance: | 47,345 | | Possession: | 42%-58% | | Total shots: | 11-11 | | MoM: | Giovani |
| | 78 Ambrose | | (4-3-3): Kapino 6½, Sagna 7, Vertonghen 6, Touré 7, Blind 7, Mangala 6, Song 7½, Rodríguez 6, Soldado 6½, Ambrose 6½, Vucinic 6 | | Manchester United | 2 | 18 Berbatov, 66 Depay |
| | (4-3-3): Kuszczak 7, Rafael 7½, Santon 6½, Schweinsteiger 7, O'Shea 6½, McNair 6½, Giovani 8, Depay 7½, Berbatov 6½, Herrera 6½, Rooney 6 | | Palmeiras | 1 | 41 Ronaldinho | | Half-time: | 1-2 | | Referee: | José Pratas 6½ | | Attendance: | 28,485 | | Possession: | 49%-51% | | Total shots: | 12-12 | | MoM: | Reveillère | | TV: | highlights |
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| | (4-3-3): Gomes 5½, Henrique 6½, Alex Telles 7, Diego Souza 6½, Lucas 6½, Rafael Toloi 6½, Márcio Araújo 6½, Marquinhos 6½, Robert 6½, Ewerthon 6, Ronaldinho 6½ | | Marseille | 3 | 11 Benzema, 44 Ben Arfa, 80 Benzema |
| | (4-3-3): Riou 6½, Reveillère 7½, Kolodziejczak 7½, Pjanic 7½, Alex Silva 7, Lamela 6½, González 7½, Ben Arfa 7 (61 Brandão 7), Benzema 7½, Kaboré 6½, Menez 6 | | Viktoria Plzen | 2 | 45 Gebre Selassie, 86 Vydra | | Half-time: | 1-0 | | Referee: | Beeby 7 | | Attendance: | 30,640 | | Possession: | 60%-40% | | Total shots: | 12-8 | | MoM: | Darida |
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| | (4-3-3): Vaclik 7½, Gebre Selassie 6½, Kadlec 8, Darida 8, Hübschman 6 (71 Plasil 8), Suchý 8, Prikryl 6½, Krejcí 7½, Vydra 7½, Sivok 7, Lafata 6½ | | River Plate | 1 | 90+2 López |
| | (4-3-3): Caballero 7, Mercado 7½, Basanta 7½, Buonanotte 6½, Cabral 6½, López 6, Affranchino 6, Amrabat 6½, López 6, Castillejos 5½, Víctor 5½ | | Round 4 | | Ayr United | 0 |
| | Half-time: | 0-1 | | Referee: | Dondarini 6½ | | Attendance: | 34,010 | | Possession: | 60%-40% | | Total shots: | 17-8 | | MoM: | Wilshere |
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| | (4-3-3): Butland 6½, Clyne 7½, Brunt 7 (69 Westwood 6½), McCarthy 7½, Dann 7, Shawcross 6½, Wilshere 8½, Oxlade-Chamberlain 7, Kane 7½, Fletcher 6½, Long 7 (62 Townsend 8) | | Sevilla | 1 | 9 Kiessling | | 1 Kiko, 45 Renato | | (4-3-3): Navas 7, Silvestre 6½, Alexis 6, Raul Meireles 7½, Squillaci 6, Renato 5½, Aleix Vidal 7½, Luscombe 5, Kiessling 7, Kiko 5½, Giovinco 6 | | Brøndby | 2 | 14 Gervinho, 53 Mirallas | | Half-time: | 1-1 | | Referee: | Arena 5½ | | Attendance: | 28,846 | | Possession: | 57%-43% | | Total shots: | 20-8 | | MoM: | Boilesen | | TV: | highlights |
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| | (4-3-3): Sirigu 7, Jantschke 7½, Lulic 7½, Raúl García 7 (73 Ansaldi 6), Zapata 7, Corluka 6½, Pérez 6 (61 Boilesen 7½), Mirallas 7½, Adrián 7, Selçuk 6, Gervinho 7 | | Espanyol | 2 | 5 Pedersen, 60 Javi Márquez |
| | (4-3-3): Lux 6½, Roncaglia 7½, Pinto 7, Javi Márquez 7, Olic 6½, Coke 6, McKenna 6, Pedersen 6, Tamudo 6½, Verdú 6, Juanmi 6 | | Cruz Azul | 2 | 19 Torrado, 58 Torrado | | Half-time: | 1-0 | | Referee: | Karlsson 8 | | Attendance: | 35,707 | | Possession: | 50%-50% | | Total shots: | 10-18 | | MoM: | Riedewald |
| | 51 Castro | | (4-3-3): Iraizoz 8, De Marcos 7½, Riedewald 8, Hamsík 7½, Huiqui 6½, Castro 5½, Fellaini 7, Suso 7, Jelavic 7½, Torrado 7, Giménez 6½ | | Internacional | 0 |
| | 9 Danilo | | (4-3-3): Alisson 8, Danilo 7, Kléber 7, Fernando 7, Hilton 6½, Marcelo 6½, Giuliano 7½, Wágner 6½, Walter 7, João Pedro 6, Taison 5½ | | Dynamo | 2 | 26 Kravets, 65 Kravets | | Half-time: | 1-1 | | Referee: | Rosetti 6 | | Attendance: | 42,358 | | Possession: | 55%-45% | | Total shots: | 16-14 | | MoM: | Nesmachnyi |
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| | (4-3-3): Carrasso 7, Vida 7, Nesmachnyi 8, Blanco 7½, Mykhalyk 7, Khacheridi 6, Bystrov 8, Pienaar 7½, Milevskyi 7, Harmash 6½, Kravets 6½ | | Napoli | 1 | 19 Ledesma | | 2 Zaccardo, 82 Quagliarella | | (4-3-3): De Sanctis 6, Maggio 6½, El Kaoutari 7, Keita 7½, Gastaldello 6½, Zaccardo 6½, Cigarini 6½, Gargano 5½, Quagliarella 6½, Ledesma 7 (81 Mokotjo 6), Campagnaro 5½ | | Fenerbahçe | 3 | 2 Sow, 25p Sow, 33 Sow | |
| | (4-3-3): Tolga 6½, Gökhan 7½, Bekir 7, Özer 8, Egemen 6½, Remzi Giray 7, Mehmet 6½, Cech 6½, Sow 7, Semih 5½, Burak 7½ | | Hansa Rostock | 1 | 5 Dzeko |
| | (4-3-3): Hitz 6, Piszczek 7, Johnson 6½, Hasebe 7, Geromel 6½, Rever 6, Gentner 6, Goretzka 6½, Dzeko 7½, Benteke 6½, Martins 5½ | | Flamengo | 1 | 9 Luiz Adriano | | Half-time: | 1-1 | | Referee: | Wiley 7½ | | Attendance: | 41,240 | | Possession: | 54%-46% | | Total shots: | 13-10 | | MoM: | Luiz Adriano |
| | 78 Willians | | (4-3-3): Bolat 6½, Danilo Silva 7½, Adriano 6½, Willians 7½, David 6½ (60 Siqueira 7), Xandão 6½, Belluschi 7, Everton 7, Luiz Adriano 8, Lima 6, Wellington Nem 5½ | | Viktoria Plzen | 2 | 18 Prikryl, 82 Krejcí |
| | (4-3-3): Vaclik 7½, Gebre Selassie 7½, Kadlec 7½, Darida 8, Hübschman 6, Suchý 6½, Prikryl 6½ (82 Rosický 6), Krejcí 6½, Vydra 6, Sivok 6½, Lafata 6 | | River Plate | 1 | 43 Víctor | | Half-time: | 1-2 | | Referee: | Korac 7½ | | Attendance: | 33,874 | | Possession: | 51%-49% | | Total shots: | 14-16 | | MoM: | Buonanotte |
| | 12 Cabral | | (4-3-3): Caballero 6, Mercado 7½, Basanta 7½, Buonanotte 8, Cabral 6½, López 6½, Affranchino 6½, Amrabat 6½, López 7, Johansen 7, Víctor 6 | | Chelsea | 3 | 15 Baines, 41 Baines, 86 Matic |
| | (4-3-3): Muslera 6, Rafinha 7½, Baines 6½, Matic 8, Rüdiger 7½, Mustafi 6, Callejón 7, Schürrle 6½, Pellé 6½, Khedira 7 (68 Rémy 6½), Bellarabi 6 |
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