| Round 3 | | Aston Villa | 1 | 17 Heskey | | Half-time: | 1-0 | | Referee: | López Nieto 6 | | Attendance: | 34,273 | | Possession: | 51%-49% | | Total shots: | 8-13 | | MoM: | Naughton | | TV: | live |
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| | (4-3-3): Viviano 7½, Naughton 8, Fryers 6½, Aissati 7½, Collins 7½, Davies 6½, Sidwell 7½, Gabriel Jesus 7, Heskey 6, Cirigliano 6½, Bamford 6 | | FC Schalke 04 | 0 |
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| | (4-3-3): Mielitz 6½, Simpson 6½, Durm 7, Träsch 7, Kelly 6½, Williamson 5½, Farfán 7, Rausch 7, De Jong 7, Barnetta 5½, Elmander 6 | | Bayern München | 2 | 5 Marin, 63 Barrios | | Half-time: | 1-0 | | Referee: | Alves Azevedo 7 | | Attendance: | 42,625 | | Possession: | 46%-54% | | Total shots: | 17-13 | | MoM: | Dijkhuizen | | TV: | highlights |
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| | (4-3-3): Kraft 6, Forlin 7, Pranjic 6½, Ignjovski 6½, Papastathopoulos 7, Djourou 6½, Coman 7, Marin 6½, Barrios 7, Sahin 5½, Anelka 6½ | | Independiente | 1 | 62 Tévez |
| | (4-3-3): Orión 6½, Dijkhuizen 7½, Vallés 7, Fernández 7½, Galeano 6½, Vittor 6½, Fredes 6½, Mancuello 7, Gandín 6½, Gutierrez 5½, Tévez 7 | | Boulogne | 1 | 4 Thiago | | Half-time: | 1-0 | | Referee: | Vassaras 6½ | | Attendance: | 14,950 | | Possession: | 60%-40% | | Total shots: | 17-10 | | MoM: | Gökhan |
| | 6 Kverkvelia | | (4-3-3): Frey 6, Srna 7½, Ibáńez 7, Thiago 6½ (79 Sammir 6), Gamberini 7, Kverkvelia 5½, Gökhan 8, Muniain 7½, Emeghara 7, Mikel 6½, Kalou 7 | | Fiorentina | 2 | 78 Gilardino, 87 Jovetic |
| | (4-3-3): Mirante 6½, Rispoli 6½, Marchese 7 (58 Comotto 7), Rômulo 6½, Cana 6, Felipe 6, Donadel 7, Seferovic 5½, Gilardino 6½, Altidore 6½ (48 Keirrison 5½), Jovetic 6½ | | TSG Hoffenheim | 1 | 28 Sessčgnon | | Half-time: | 1-0 | | Referee: | Trentalange 6 | | Attendance: | 30,020 | | Possession: | 56%-44% | | Total shots: | 8-14 | | MoM: | Gulde |
| | 52 Ba | | (4-3-3): Fährmann 7, Kaderábek 6, Luna 7, Gross 6½ (55 Gulde 8½), Ruíz 7½, Amat 7, Vukcevic 6½, Carlos Eduardo 7½, Ibisevic 6½ (71 Salihovic 6), Ba 5½, Sessčgnon 7 | | Roma | 0 |
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| | (4-3-3): Adler 7, Jonathan 6½, Fazio 6, Çalhanoglu 7½, Evans 6½, Coloccini 7, Schneiderlin 6½, Kagawa 7½, Pazzini 6, Tadic 6, Kruse 6 | | Udinese | 2 | 31 Basta, 69 Théréau | | Half-time: | 1-0 | | Referee: | Dean 8 | | Attendance: | 30,812 | | Possession: | 56%-44% | | Total shots: | 23-8 | | MoM: | Zimling |
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| | (4-3-3): Szczesny 7, Basta 6½, Adnan 7½, Iturra 7½, Danilo 6½, Papadopoulos 7, Isla 6 (55 Jaime 7½), Zimling 8, Zapata 8, Lodi 6½, Théréau 7 (75 Lukovic 7) | | CSKA | 1 | 66 Dzsudzsák |
| | (4-3-3): Barta 6½, Nababkin 6½, Schennikov 7, Denisov 6½, Ignashevich 6, Sergio Sánchez 6, Okay 5½, Dzsudzsák 6½, Devic 7, Borriello 5½, Washington 5½ | | VfB Stuttgart | 1 | 60 Schieber | | Half-time: | 0-0 | | Referee: | Vorjas 6 | | Attendance: | 40,023 | | Possession: | 55%-45% | | Total shots: | 15-12 | | MoM: | Gibbs |
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| | (4-3-3): Ulreich 7½, Hilbert 7, Boka 8½, Aquilani 7½, Osorio 6½, Hamit 6, Kuzmanovic 6½, Thorsby 7½, Schieber 7½, Lanig 6, Marica 6 | | West Ham United | 0 |
| | 63 Carroll, 90+2 Carroll | | (4-3-3): Wiedwald 8, Gray 7, Gibbs 8½, Brozovic 7½, Samba 7½, Sané 6, Holmes 6½, Carroll 7, Bent 7, Mancienne 6, Sellin 6 | | Round 4 | | Bursaspor | 2 | 32 Çinaz, 85 Bakambu | | Half-time: | 1-1 | | Referee: | Řvrebř 7½ | | Attendance: | 25,591 | | Possession: | 44%-56% | | Total shots: | 11-10 | | MoM: | Beck | | TV: | highlights |
| | 50 Necid | | (4-3-3): Fehmi Mert 5½, Beck 8, Emre 6½, Jorquera 6½, Mehmet 6, Spahic 6½, Josué 7, Volkan 6½, Bakambu 7, Çinaz 6, Necid 7 | | Udinese | 2 | 35 Théréau, 80 Lodi |
| | (4-3-3): Szczesny 6, Basta 7, Adnan 7½, Iturra 6½, Danilo 6½, Papadopoulos 6, Isla 6½ (81 Jaime 6), Zimling 7, Zapata 7, Lodi 6½, Théréau 7 (81 Lukovic 6) | | CSKA | 1 | 53 Dzsudzsák | | Half-time: | 0-2 | | Referee: | Uilenberg 7½ | | Attendance: | 13,153 | | Possession: | 46%-54% | | Total shots: | 9-7 | | MoM: | Ignjovski |
| | 1 Nababkin | | (4-3-3): Barta 6½, Nababkin 7½, Schennikov 6½, Denisov 6½, Ignashevich 7, Sergio Sánchez 6, Okay 6, Dzsudzsák 7½, Devic 6½, Borriello 6, Washington 6 | | Bayern München | 2 | 32 Sahin, 45+1 Sahin |
| | (4-3-3): Kraft 7, Forlin 5, Pranjic 7½, Ignjovski 8, Papastathopoulos 7, Djourou 6½, Coman 6½, Marin 7½, Barrios 6½, Sahin 6½, Anelka 6½ | | Deportivo | 5 | 12 Adúriz, 29 Adúriz, 38 Guardado, 69p Adúriz, 84 Juan Rodríguez | | Half-time: | 3-0 | | Referee: | Brignoccoli 6½ | | Attendance: | 34,544 | | Possession: | 55%-45% | | Total shots: | 16-15 | | MoM: | Guilherme |
| | 8 Colotto | | (4-3-3): Guilherme 8, Javi López 4½ (74 José Castro 8), Jaume 6½ (84 Antonio Tomás 6), Juan Rodríguez 8, Dominguez 7½, Colotto 6, Diamé 7½, Guardado 7, Adúriz 7, Juan Domínguez 7, Sabin 6½ | | CS Constantine | 0 |
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| | (4-3-3): Samassa 7, M'Bengue 5, Ghoulam 6½, Brahimi 7, Benatia 7, Kouyaté 6, Belhanda 6½ (50 Taďder 8), Khazri 7 (82 M'Bia 6), Bony 7½, Bolasie 5½, Choupo Moting 6 | | FC Schalke 04 | 2 | 69 Elmander, 90 Barnetta | | Half-time: | 0-1 | | Referee: | Vink 6 | | Attendance: | 35,790 | | Possession: | 54%-46% | | Total shots: | 8-10 | | MoM: | Simpson |
| | 33 Simpson, 90+1 Rausch | | (4-3-3): Mielitz 5½, Simpson 8½, Durm 7½, Träsch 8, Kelly 6½, Williamson 6½, Farfán 7½, Barnetta 7, De Jong 7, Rausch 6½, Elmander 6½ | | Athletic Bilbao | 2 | 6 Vela, 62 Eduardo | | 7 Eduardo, 57 Mario Suárez | | (4-3-3): Pigliacelli 5½, Iraola 7 (49 Traoré 6), Canella 6½, Parejo 7½, Botía 7, Duffy 7 (48 Rodri 6½), Nsue 7, Osvaldo 6, Eduardo 7, Mario Suárez 5½, Vela 5½ | | Fiorentina | 1 | 60 Gilardino | | Half-time: | 0-0 | | Referee: | Beschin 6½ | | Attendance: | 36,860 | | Possession: | 37%-63% | | Total shots: | 7-16 | | MoM: | Mathieu |
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| | (4-3-3): Mirante 7, Rispoli 7½, Marchese 7 (58 Comotto 7½), Rômulo 6½, Cana 6½, Felipe 6, Donadel 6, Seferovic 5½, Gilardino 6½, Altidore 6½ (49 Keirrison 6), Jovetic 6 | | Rosenborg | 1 | 48 Cédric |
| | (4-3-3): Vicente Guaita 7, Cédric 6½, Mathieu 8½, Kovacic 7½, Zouma 7½, Toprak 7, Skjelbred 8, Corona 7½, Batshuayi 7, Gueye 7 (62 Unai López 6½), Aboubakar 6½ | | Hamburger SV | 2 | 10 Rincón, 17 Guerrero | | Half-time: | 2-0 | | Referee: | Penicka 8 | | Attendance: | 43,331 | | Possession: | 61%-39% | | Total shots: | 11-4 | | MoM: | Guerrero |
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| | (4-3-3): Karnezis 6½, Rincón 6 (72 Boenisch 6), Fuchs 8, Aogo 8, Piris 8, Rozehnal 6, Harnik 7½, Elia 7, Guerrero 8, Jansen 5½, Petric 6½ | | Bayer Leverkusen | 1 | 75 Zárate | | 42 Zárate, 51 Kakuta | | (4-3-3): Giefer 6½, Fritz 7, Friedrich 6, Castro 7½, Díaz 6½, Cambiasso 6, Elano 6½, Zárate 6½, Kuranyi 6½, Kakuta 5½, Gavranovic 6 | | Paris SG | 3 | 20 Cavani, 40 Cavani, 66 Cavani | | Half-time: | 2-0 | | Referee: | Bettin 6½ | | Attendance: | 44,392 | | Possession: | 58%-42% | | Total shots: | 20-8 | | MoM: | Thiago Silva |
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| | (4-3-3): Trapp 7½, Marquinhos 7½, Trémoulinas 8, Verratti 8, Thiago Silva 8, Stambouli 6½, Traoré 6, Gakpé 8, Cavenaghi 5½ (73 Kimpembe 6), Sané 6½, Cavani 7½ | | TSG Hoffenheim | 0 |
| | 50 Sessčgnon | | (4-3-3): Fährmann 7½, Kaderábek 6, Luna 6½, Gross 6½, Ruíz 6½, Amat 5½, Vukcevic 6½, Carlos Eduardo 6½, Ibisevic 5½, Ba 6, Sessčgnon 6 | | Roma | 0 |
| | Half-time: | 0-0 | | Referee: | Styles 6 | | Attendance: | 45,627 | | Possession: | 52%-48% | | Total shots: | 17-9 | | MoM: | Adler |
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| | (4-3-3): Adler 8, Jonathan 6½, Fazio 7, Schneiderlin 7, Evans 6½, Jřrgensen 6½, Tadic 7½, Kagawa 7, Pazzini 7, Çalhanoglu 7, Kruse 7½ | | Celtic | 0 |
| | 42 Cissé, 45+4 Cissé | | (4-3-3): Boruc 7½, José Ángel 6½, Izaguirre 7½, Defour 6½, Sviatchenko 6, Rogne 6, Fulton 6½ (70 McGeady 6), Iturbe 6½, Cissé 7, Ki 7, Cissé 6 | | Rubin | 1 | 17 Ari | | Half-time: | 1-0 | | Referee: | Sedlacek 7 | | Attendance: | 24,874 | | Possession: | 59%-41% | | Total shots: | 11-10 | | MoM: | Movsisyan |
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| | (4-3-3): Rebrov 7½, Kuzmin 6½, Kaleshin 7½, Gökdeniz 7, César Navas 7½, Jordi 6, Ryazantsev 6, Kasaev 6½, Movsisyan 7½, Dyadyun 6, Ari 7 | | Aston Villa | 0 |
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| | (4-3-3): Viviano 7, Naughton 7½, Fryers 6½, Aissati 6½, Collins 6½, Davies 6½, Sidwell 6½, Gabriel Jesus 6, Heskey 6½, Bannan 6½, Bamford 5½ |
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