| Round 5 | | Accrington Stan. | 0 |
| | Half-time: | 0-0 | | Referee: | Morán 7½ | | Attendance: | 30,953 | | Possession: | 47%-53% | | Total shots: | 16-9 | | MoM: | Stones | | TV: | live |
| | 17 Jagielka | | (4-3-3): Hart 7½, Smalling 7, Rose 7½, Alli 7 (47 Ward-Prowse 7½), Stones 8, Jagielka 6½, Ramsey 7½, Sterling 7½, Iheanacho 5½, Barkley 6, Musa 5½ | | Valencia | 1 | 62 Perotti | | 19 Paco Alcácer | | (4-3-3): Reina 7½, Javi Manquillo 6, Vargas 7½, André Gomes 7 (74 Paulinho 7), San Jose 6½, Aderlan 6½, Lennon 7, Perotti 7½, Paco Alcácer 6½, Hernández 5½, Santi Mina 5½ | | Arsenal | 2 | 30 Koke, 53 Nacho Monreal | |
| | (4-3-3): Buffon 7, Tolisso 7, Nacho Monreal 8½, Reus 7, Mertesacker 6 (77 Debuchy 6), Koscielny 6½, Marchisio 6½, Koke 7½, Boyé 6½, Coquelin 6½, Pedro 6 | | São Paulo | 1 | 40 Willian |
| | (4-3-3): Hélton 6½, Maicon 6½, Wendell 7, Casemiro 6½, Juan 7, Rodrigo Caio 6½, Kelvin 6, Michel Bastos 6½, Willian 7, Diego 6½, Robinho 5½ | | Borussia Dortmund | 1 | 26 Hazard | | Half-time: | 1-0 | | Referee: | Halsey 7 | | Attendance: | 54,432 | | Possession: | 54%-46% | | Total shots: | 11-11 | | MoM: | Höwedes | | TV: | live |
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| | (4-3-3): Zieler 6½, Höwedes 8, Schmelzer 7½, Saúl 7½, Giménez 7½, Ginter 7½, Ramires 6½, Hazard 7, Lewandowski 7, Can 7, Podolski 7½ | | Helsingborg | 1 | 53 Kjær |
| | (4-3-3): De Gea 6½, Wass 6½, Rojo 7 (83 Henriksen 6), Nordtveit 6½, Kjær 7, Vestergaard 6, Ekdal 7, Sigurðsson 6½, Agüero 6, Diego Costa 6, Fischer 6 (53 Braithwaite 6) | | Exeter City | 2 | 7 Drinkwater, 50 Milner | | Half-time: | 1-2 | | Referee: | Kakos 7½ | | Attendance: | 19,631 | | Possession: | 48%-52% | | Total shots: | 21-11 | | MoM: | Drinkwater |
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| | (4-3-3): Foster 6, Jenkinson 7½, Johnson 7, Delph 8, Terry 7, Keane 6, Drinkwater 8, Milner 6½, Austin 7, Barry 7, Vardy 7½ | | Benfica | 2 | 34p Drogba, 42 Drogba |
| | (4-3-3): Lopes 6, Pereira 7, Eliseu 6½, André Almeida 7, Ricardo Carvalho 7, Ayala 6, Javi García 7 (68 Gourcuff 6½), Alex 6, Drogba 7½, Alan 7, Cardozo 6 | | FC Basel | 0 |
| | Half-time: | 0-0 | | Referee: | Cardona 6½ | | Attendance: | 38,368 | | Possession: | 43%-57% | | Total shots: | 8-8 | | MoM: | Willems |
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| | (4-3-3): Weidenfeller 7, Dani Alves 7½, Bernat 6½, Rodríguez 8, Dante 6½, Juanfran 6, Florenzi 6½, Isco 6½, Enes 7, Draxler 5½, Berardi 6½ | | Ajax | 1 | 58 Van Amersfoort |
| | (4-3-3): Cillessen 7, Veltman 7, Willems 8½, Sneijder 7½, Bruma 7, Vlaar 6, Narsingh 8, Lens 6½, Huntelaar 6½, Milik 6½, Van Amersfoort 5½ | | FC Porto | 2 | 3 Falcao, 20 Douglas Costa | | Half-time: | 2-2 | | Referee: | Dinelli 7½ | | Attendance: | 50,820 | | Possession: | 57%-43% | | Total shots: | 13-8 | | MoM: | Danny |
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| | (4-3-3): Rui Patrício 6½, Bruno Alves 7½, Alex Sandro 7½, Danny 8, Luisão 7½, Alex 6½, Marcelo 7, Douglas Costa 6 (55 Bruma 7), Falcao 7, Fernandinho 6½, Hulk 7 | | Newcastle United | 2 | 15 Mitrovic, 33 Müller |
| | (4-3-3): Courtois 6, Boateng 6½, Alaba 6, Vidal 6½, Godín 6, Hummels 6½, De Bruyne 7½, Özil 6½, Mitrovic 6, Silva 6½, Müller 6 | | Lazio | 1 | 73 Ilicic | | Half-time: | 0-0 | | Referee: | Circhetta 8 | | Attendance: | 36,431 | | Possession: | 51%-49% | | Total shots: | 13-15 | | MoM: | Antonelli | | TV: | highlights |
| | 90+1 Ariaudo | | (4-3-3): Stekelenburg 7½, Bonera 7½, Antonelli 7½, Onazi 6, Maurício 7, Ariaudo 6, Schelotto 7½, Ilicic 6½, Djordjevic 7½, Matri 5½, Babacar 6 | | Feyenoord | 0 |
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| | (4-3-3): Vermeer 7, Hutchinson 7, Kongolo 6½, Leerdam 7, Van Beek 6½, Maduro 6, Kuyt 7 (66 Schenkeveld 6½), Vilhena 6½, Castaignos 6½, De Guzman 6½, Kazim-Richards 6 | | Lille | 1 | 28 Gaitán | | Half-time: | 1-0 | | Referee: | Fröhlich 7½ | | Attendance: | 18,079 | | Possession: | 48%-52% | | Total shots: | 11-7 | | MoM: | Gaitán |
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| | (4-3-3): Lloris 7½, Jallet 7, Evrà 7, Lallana 7, Rosales 6½, Rodriguez 7, Valencia 7½, Gaitán 7½, Negredo 7, Mavuba 5½, Tallo 6½ | | Nantes | 0 |
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| | (4-3-3): Mandanda 7, Colin 6, Digne 7½, Guilavogui 7, Gonalons 6½, Kurzawa 7, Toulalan 7 (68 Mendy 6), Di María 7, Gomis 6½, Payet 6½, Benzia 5½ | | Liverpool | 2 | 28 Vitolo, 80 Sakho | | Half-time: | 1-0 | | Referee: | Alves Azevedo 5½ | | Attendance: | 39,046 | | Possession: | 57%-43% | | Total shots: | 18-8 | | MoM: | Sakho | | TV: | highlights |
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| | (4-3-3): Pyatov 7, Vrsaljko 7, Sakho 8½, Badelj 7½, Lovren 7½, Taylor 7, Henderson 7½, Vitolo 6 (63 Aleksic 7½), Carroll 7, Ings 6, Moses 6 | | Anderlecht | 1 | 63 Lukaku |
| | (4-3-3): Mignolet 7, Gillet 6½, Pocognoli 8, Dembélé 7½, Chedjou 6½, Ramis 6½, Marecek 6½, Ilicevic 6½, Lukaku 7, Kerzhakov 6, Mollo 5½ | | Palermo | 2 | 3 Insigne, 45+2 Insigne | | Half-time: | 2-0 | | Referee: | Levnikov 7 | | Attendance: | 38,937 | | Possession: | 57%-43% | | Total shots: | 13-11 | | MoM: | McGregor | | TV: | highlights |
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| | (4-3-3): Sommer 7, Zappacosta 7, Romagnoli 7½, Motta 7½, Astori 8, Rugani 7½, Candreva 7½, Insigne 8, Destro 7, Parolo 7, Éder 6½ | | Newport County | 0 |
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| | (4-3-3): McGregor 8, Tomkins 6½, Bertrand 7 (66 Acheampong 8), Cleverley 7½, Dummett 6½, Clark 6, Livermore 6½, Ayew 7, Rhodes 5½, Phillips 5½, Rodriguez 6 | | Real Madrid | 3 | 6 Ronaldo, 48 Ronaldo, 86 Ronaldo | | Half-time: | 1-0 | | Referee: | Jesenicnik 6½ | | Attendance: | 71,074 | | Possession: | 51%-49% | | Total shots: | 12-6 | | MoM: | Chiellini |
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| | (4-3-3): Neuer 7½, Lahm 8, Chiellini 8, Kroos 8, Piqué 5½ (84 Bonucci 6), Sergio Ramos 7½, Modric 6½, Ronaldo 7½, Ibrahimovic 7, Bale 7½, Vílla 6½ | | Tottenham Hotspur | 0 |
| | 67 Nani | | (4-3-3): Leno 8, Cáceres 7½, Ogbonna 7½, Shirokov 7, Rami 6½, Álvarez 6½, Foor 6½, Nani 7, Matavz 5½, Benitez 5½, Wickham 6 | | Round 3 | | Liverpool | 4 | 34 Carroll, 38 Moses, 58 Vitolo, 63 Badelj | | Half-time: | 2-0 | | Referee: | Pyanikh 5½ | | Attendance: | 40,841 | | Possession: | 55%-45% | | Total shots: | 22-10 | | MoM: | Lovren |
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| | (4-3-3): Pyatov 7, Vrsaljko 7, Sakho 8, Badelj 7½, Lovren 8, Taylor 5½, Henderson 7½, Vitolo 7½, Carroll 7, Ings 5½, Moses 6 | | Tottenham Hotspur | 1 | 75 Ogbonna | | 45+1 Matavz | | (4-3-3): Leno 6½, Cáceres 7, Ogbonna 8, Shirokov 7, Rami 7, Álvarez 6, Foor 7, Nani 7, Matavz 7, Fierro 5½, Wickham 5½ |
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