| Round 5 | | Aston Villa | 1 | 13 Bannan | | Half-time: | 1-0 | | Referee: | Vorjas 5 | | Attendance: | 38,417 | | Possession: | 54%-46% | | Total shots: | 21-7 | | MoM: | Aissati | | TV: | highlights |
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| | (4-3-3): Viviano 7½, Naughton 7½, Fryers 8, Aissati 8½, Collins 8, Davies 6, Sidwell 6½, Gabriel Jesus 7, Heskey 5½, Bannan 6½, Bamford 6½ | | West Ham United | 0 |
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| | (4-3-3): Wiedwald 7, Gray 5½, Gibbs 6½, Brozovic 7, Samba 7, Sané 5½, Holmes 6, Richardson 7, Bent 7, Mancienne 6½, Sellin 6 | | Athletic Bilbao | 1 | 6 Susaeta | | Half-time: | 1-0 | | Referee: | Marriner 6½ | | Attendance: | 39,745 | | Possession: | 57%-43% | | Total shots: | 12-7 | | MoM: | Verratti |
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| | (4-3-3): Pigliacelli 7½, Torres 7, Canella 8, Parejo 7½, Botía 6½, Amorebieta 6, Nsue 7, Susaeta 7, Eduardo 7, Mario Suárez 6, Vela 7 | | Paris SG | 0 |
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| | (4-3-3): Trapp 7½, Marquinhos 6, Trémoulinas 7½, Verratti 8, Thiago Silva 7, Stambouli 6½, Traoré 6½, Gakpé 7, Cavenaghi 6½, Sané 6½, Cavani 6½ | | Bayer Leverkusen | 0 |
| | Half-time: | 0-1 | | Referee: | Gumienny 7½ | | Attendance: | 22,399 | | Possession: | 47%-53% | | Total shots: | 8-6 | | MoM: | Castro |
| | 79 Gavranovic | | (4-3-3): Giefer 6½, Sakai 5½, Kakuta 6½, Castro 7½, Díaz 7, Servet 6½, Fritz 7, Zárate 7, Kuranyi 7 (56 Cańete 7), Cambiasso 6, Gavranovic 5½ | | CSKA | 1 | 37 Borriello |
| | (4-3-3): Moyá 7, Nababkin 6, Schennikov 7, Denisov 6½, Ignashevich 7, Sergio Sánchez 7 (50 Oliseh 6½), Pelé 6, Dzsudzsák 7½, Borriello 7, Devic 6½, Washington 6½ | | Bayern München | 2 | 7 Barrios, 58 Barrios | | Half-time: | 1-1 | | Referee: | Dowd 7 | | Attendance: | 55,554 | | Possession: | 49%-51% | | Total shots: | 16-13 | | MoM: | Rispoli |
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| | (4-3-3): Kraft 7, Forlin 7, Pranjic 7½, Ignjovski 7, Papastathopoulos 7, Djourou 6½, Coman 7, Marin 7, Barrios 6½, Sahin 7, Anelka 5½ | | Fiorentina | 1 | 41 Gilardino |
| | (4-3-3): Mirante 7, Rispoli 8, Marchese 7 (58 Comotto 7½), Rômulo 7½, Cana 7½, Felipe 7, Donadel 6½, Seferovic 6, Gilardino 7, Altidore 6½ (58 Keirrison 6), Jovetic 6½ | | Boulogne | 1 | 80 Muniain | | Half-time: | 0-0 | | Referee: | Sandra 6 | | Attendance: | 14,963 | | Possession: | 48%-52% | | Total shots: | 15-13 | | MoM: | Guilherme | | TV: | live |
| | 82 Gamberini | | (4-3-3): Frey 7½, Srna 7, Ibáńez 8, Thiago 8, Gamberini 6, Kverkvelia 6, Gökhan 6½, Muniain 6½, Álvaro 6½, Diarra 6½, Kalou 6 | | Deportivo | 0 |
| | 57 Colotto | | (4-3-3): Guilherme 8, Javi López 7½, Jaume 6½, Juan Rodríguez 7, Dominguez 6½, Colotto 6½, Diamé 7 (62 José Castro 6½), Guardado 7, Adúriz 7½, Juan Domínguez 6, Sabin 5½ | | CS Constantine | 3 | 2 Bony, 28 Khazri, 79 Khazri | | Half-time: | 2-2 | | Referee: | Dean 5½ | | Attendance: | 38,213 | | Possession: | 45%-55% | | Total shots: | 16-16 | | MoM: | Simpson |
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| | (4-3-3): Samassa 6½, M'Bengue 6½, Ghoulam 6½, Brahimi 6½, Benatia 7, Kouyaté 5½ (55 M'Bia 6), Belhanda 7½, Khazri 7, Bony 6½, Bolasie 6, Choupo Moting 6 | | FC Schalke 04 | 2 | 5 Durm, 41 De Jong |
| | (4-3-3): Mielitz 5½, Simpson 7½, Durm 5½, Träsch 7½, Kelly 6½, Williamson 6, Farfán 6½, Barnetta 7, De Jong 7, Rausch 6, Elmander 6 | | Celtic | 0 |
| | Half-time: | 0-0 | | Referee: | Almeida Marcal 6 | | Attendance: | 36,401 | | Possession: | 44%-56% | | Total shots: | 14-10 | | MoM: | Harnik |
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| | (4-3-3): Boruc 7½, José Ángel 6½, Izaguirre 7, Defour 7½, Sviatchenko 8, Rogne 6½, Fulton 6, Iturbe 6½, Cissé 7½, Brown 6½, Cissé 6½ | | Hamburger SV | 0 |
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| | (4-3-3): Karnezis 7½, Rincón 6½, Fuchs 7½, Aogo 8, Piris 6, Rozehnal 6, Harnik 8, Elia 7, Guerrero 6½, Jansen 6, Petric 6 | | Rosenborg | 1 | 75 Batshuayi | | Half-time: | 0-0 | | Referee: | Krondl 6½ | | Attendance: | 21,052 | | Possession: | 53%-47% | | Total shots: | 8-12 | | MoM: | Tadic | | TV: | highlights |
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| | (4-3-3): Vicente Guaita 6½, Cédric 7, Mathieu 7, Kovacic 7½, Zouma 6, Toprak 6½, Skjelbred 6½, Corona 7, Batshuayi 7, Gueye 6½ (62 Unai López 6½), Aboubakar 6½ | | Roma | 1 | 78 Kagawa |
| | (4-3-3): Adler 7½, Jonathan 6½, Fazio 6½, Schneiderlin 7½, Evans 7, Jřrgensen 6½, Tadic 7½, Kagawa 6½, Pazzini 6, Çalhanoglu 5½, Kruse 6 | | TSG Hoffenheim | 0 |
| | Half-time: | 0-0 | | Referee: | Brito Arceo 6½ | | Attendance: | 30,099 | | Possession: | 46%-54% | | Total shots: | 17-13 | | MoM: | Sessčgnon |
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| | (4-3-3): Fährmann 6, Kaderábek 7½, Luna 6, Gross 6½, Ruíz 7½, Lustig 6, Vukcevic 7, Carlos Eduardo 6, Ibisevic 6½, Obasi 6, Sessčgnon 8 | | Independiente | 1 | 51 Mancuello |
| | (4-3-3): Orión 6½, Dijkhuizen 6½ (71 Acevedo 7), Vallés 6, Fernández 8, Galeano 7, Vittor 7, Fredes 7½, Mancuello 6, Gandín 7, Gutierrez 6½, Tévez 6½ | | Udinese | 2 | 13 Danilo, 56 Zapata | | Half-time: | 1-0 | | Referee: | Racalbuto 7 | | Attendance: | 30,854 | | Possession: | 49%-51% | | Total shots: | 16-8 | | MoM: | Adnan |
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| | (4-3-3): Szczesny 7½, Basta 7, Adnan 7½, Iturra 7, Danilo 6½, Papadopoulos 6½, Isla 6 (55 Jaime 6½), Zimling 6½, Zapata 6, Lodi 6, Théréau 7 (75 Lukovic 7) | | Rubin | 0 |
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| | (4-3-3): Rebrov 7½, Kuzmin 6½, Kaleshin 5½, Gökdeniz 7, César Navas 7, Jordi 6, Ryazantsev 6½, Kasaev 6½, Movsisyan 7, Dyadyun 5½, Ari 6 | | VfB Stuttgart | 1 | 58 Lanig | | Half-time: | 0-1 | | Referee: | Beschin 6½ | | Attendance: | 44,181 | | Possession: | 44%-56% | | Total shots: | 15-9 | | MoM: | Mehmet |
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| | (4-3-3): Ulreich 6½, Hilbert 6½, Boka 8, Aquilani 7½, Osorio 7, Hamit 6½, Kuzmanovic 6½ (85 Veigneau 6), Thorsby 6½, Schieber 6, Lanig 6, Marica 6 | | Bursaspor | 2 | 17 Tosic, 61 Bakambu |
| | (4-3-3): Harun 6½, Beck 8, Emre 7½, Jorquera 7, Mehmet 8, Spahic 7, Josué 7, Tosic 7, Bakambu 6, Necid 6½, Volkan 6½ | | Round 3 | | Celtic | 0 |
| | Half-time: | 0-1 | | Referee: | Cinciripini 6 | | Attendance: | 33,595 | | Possession: | 45%-55% | | Total shots: | 11-16 | | MoM: | Diamé |
| | 38 Defour | | (4-3-3): Boruc 6, Izaguirre 7, José Ángel 8, Defour 7, Sviatchenko 7½, Rogne 5½, Fulton 7, Iturbe 6½, Cissé 7 (50 Oliver 7), Ki 6½, Cissé 6 (78 McGeady 6) | | Deportivo | 2 | 14 Jaume, 65 Guardado |
| | (4-3-3): Guilherme 7, Javi López 6 (74 José Castro 6), Jaume 7 (84 Antonio Tomás 6), Juan Rodríguez 7, Dominguez 7, Colotto 6½, Diamé 8, Guardado 6½, Adúriz 6½, Juan Domínguez 6, Sabin 6 | | Round 4 | | Independiente | 2 | 9 Fernández, 51 Fernández | | Half-time: | 1-1 | | Referee: | Jol 6½ | | Attendance: | 32,728 | | Possession: | 55%-45% | | Total shots: | 14-8 | | MoM: | Fernández |
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| | (4-3-3): Orión 7, Dijkhuizen 6 (71 Acevedo 7), Vallés 6, Fernández 8½, Galeano 7, Vittor 6½, Fredes 7, Mancuello 7, Gandín 6½, Gutierrez 6, Tévez 6½ | | VfB Stuttgart | 1 | 6 Kuzmanovic |
| | (4-3-3): Ulreich 6½, Hilbert 7, Boka 6½, Aquilani 6½, Osorio 7½, Hamit 6, Kuzmanovic 7 (85 Veigneau 6), Thorsby 6½, Schieber 7, Lanig 6, Marica 6 | | West Ham United | 4 | 6 Carroll, 64 Gibbs, 77 Gibbs, 87 Holmes | | Half-time: | 1-2 | | Referee: | Arena 5½ | | Attendance: | 32,593 | | Possession: | 53%-47% | | Total shots: | 16-14 | | MoM: | Gibbs |
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| | (4-3-3): Wiedwald 6½, Gray 7, Gibbs 8½, Brozovic 7½, Samba 7, Sané 5 (56 Cole 7), Holmes 6, Carroll 7, Bent 6½, Richardson 5½, Sellin 5½ | | Boulogne | 3 | 2 Muniain, 42 Gamberini, 46 Álvaro | | 37 Muniain, 48 Kalou | | (4-3-3): Frey 5½, Srna 6½ (73 Galhardo 6), Ibáńez 7, Thiago 7, Gamberini 7½, Kverkvelia 7½, Gökhan 6, Muniain 7½, Álvaro 6½, Jadson 6½, Kalou 5½ |
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