Round 1 | Accrington Stan. | 1 | 43 Smalling | Half-time: | 1-0 | Referee: | Norman 6 | Attendance: | 30,858 | Possession: | 46%-54% | Total shots: | 15-14 | MoM: | Can | TV: | highlights |
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| (4-3-3): Hart 7, Smalling 7½, Rose 7½, Barkley 7½, Cahill 7, Stones 7, Ramsey 7½, Sterling 7½, Sturridge 6, Allen 6½, Musa 7 | Liverpool | 0 |
| 46 Henderson, 77 Origi, 83 Badelj, 90+3 Vrsaljko | (4-3-3): Pyatov 7, Vrsaljko 6½, Sakho 6½, Badelj 7½, Lovren 6½, Wimmer 6, Henderson 7, Vitolo 6½, Sørum 6½ (70 Insúa 6), Can 7½, Origi 6 | Anderlecht | 0 |
| Half-time: | 0-1 | Referee: | Dowd 7½ | Attendance: | 27,920 | Possession: | 51%-49% | Total shots: | 10-9 | MoM: | Cabaye | TV: | highlights |
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| (4-3-3): Mignolet 5½, Gillet 7½, Deschacht 7, Dembélé 7, Chedjou 7½, Ramis 6½, Marecek 7½, Mollo 7, Lukaku 7, Kerzhakov 6, Jonas 6½ | Milan | 2 | 7 El Shaarawy, 64p Mandzukic |
| (4-3-3): Rajkovic 7, Aurier 7½, Kolasinac 7½, Cabaye 8, Javi Martínez 7, Laporte 6, Volland 6½, El Shaarawy 6½, Mandzukic 7, Bacca 6, Niang 6½ | Arsenal | 1 | 76 Boyé | Half-time: | 0-1 | Referee: | Bazzoli 5 | Attendance: | 56,458 | Possession: | 51%-49% | Total shots: | 8-10 | MoM: | Chiellini |
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| (4-3-3): Buffon 6½, Bellerín 6, Nacho Monreal 8, Koke 7½, Koscielny 6½ (63 Iwobi 7), Mertesacker 6½, Marchisio 6½, Sánchez 7½, Boyé 7, Reus 6½, Campbell 5½ | Real Madrid | 1 | 5 Ibrahimovic |
| (4-3-3): Neuer 7, Lahm 6½, Chiellini 8, Kroos 8, Sergio Ramos 7½, Piqué 6½ (77 Mascherano 6), Modric 6½, Bale 6½, Ibrahimovic 7½, Pepe 6½, Robben 5½ | Barcelona | 0 |
| Half-time: | 0-2 | Referee: | Beschin 6½ | Attendance: | 58,663 | Possession: | 52%-48% | Total shots: | 21-13 | MoM: | Maxwell |
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| (4-3-3): Ter Stegen 6½, Abate 7½, Maxwell 8, Busquets 7½, Bartra 8, Fernández 7 (62 Fontás 6), Dos Santos 6½, Iniesta 6, Suárez 7½, Neymar 5½, Messi 5½ | Exeter City | 2 | 20 Vardy, 45 Barry |
| (4-3-3): Foster 6½, Coleman 6½, Milner 6½, Barry 7, Terry 7, Keane 6, Drinkwater 7, Redmond 6½, Vardy 6½ (74 Austin 6), Lampard 6½, Walcott 7 | Borussia Dortmund | 1 | 9 Lewandowski | Half-time: | 1-0 | Referee: | Bettin 7 | Attendance: | 54,025 | Possession: | 48%-52% | Total shots: | 6-9 | MoM: | Akinfeev | TV: | highlights |
| 61 Schürrle, 64 Höwedes | (4-3-3): Akinfeev 7½, Höwedes 7½, Schmelzer 6½ (58 Berezutsky 7), Saúl 6½, Ginter 6½, Giménez 6½, Ramires 6, Hazard 7, Lewandowski 7 (85 Bernard 6), Fekir 6, Schürrle 6½ | Ayr United | 0 |
| 5 Shawcross, 66 Townsend, 70 McCarthy | (4-3-3): Gordon 7½, Clyne 7, Brunt 6½, Fletcher 7, Shawcross 7, Dann 6½, Davis 7, Townsend 6½, Fletcher 6½, McCarthy 6, Long 5½ | Chelsea | 2 | 38 Pedro, 73 Khedira | Half-time: | 1-0 | Referee: | Cesari 7½ | Attendance: | 55,444 | Possession: | 53%-47% | Total shots: | 18-11 | MoM: | Rafinha | TV: | live |
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| (4-3-3): Sergio Asenjo 7, Rafinha 8, Baines 6, Khedira 7½, Koulibaly 7, Mustafi 6½, Callejón 6½, Pedro 7½, Llorente 7, Nasri 6½, Bellarabi 5½ | FC Basel | 1 | 82 Matuidi |
| (4-3-3): Weidenfeller 7½, Dani Alves 8, Jordi Alba 8, Denis 8, Dante 7, Juanfran 6½, Traoré 7½, Matuidi 7, Enes 6½, Mkhitaryan 6½, Keita 5½ | FC Porto | 2 | 36 Danny, 72 Hulk | Half-time: | 1-1 | Referee: | Cinciripini 5½ | Attendance: | 49,260 | Possession: | 43%-57% | Total shots: | 18-12 | MoM: | Miranda |
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| (4-3-3): Rui Patrício 6, Wallace 7, Alex Sandro 6 (76 Ricardo Esgaio 6), Philippe Coutinho 6½, Miranda 7½, Luisão 6, Marcelo 6, Douglas Costa 6, Falcao 7, Danny 6½, Hulk 6½ | Ajax | 2 | 10 Sneijder, 60 Huntelaar |
| (4-3-3): Cillessen 6, Veltman 7, Willems 6½, Klaassen 7, Bruma 6, De Vrij 6, Promes 7½, Kishna 7, Huntelaar 7 (69 Narsingh 7), Sneijder 7, Milik 6 | Lazio | 1 | 90 Mertens | Half-time: | 0-0 | Referee: | Sarvan 5½ | Attendance: | 52,012 | Possession: | 57%-43% | Total shots: | 14-8 | MoM: | Mertens |
| 27 Babacar | (4-3-3): Berisha 8, Schelotto 7, Radu 6½, Ilicic 6½ (54 Antonelli 7½), Maurício 7½, Bonera 6½, Onazi 7 (67 Ariaudo 7), Mertens 8, Defoe 7, Matri 6½, Babacar 6 | Lille | 0 |
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| (4-3-3): Lloris 7½, Jallet 7½, Evrà 7, Lallana 7½, Rosales 6½, Rodriguez 7, Valencia 6½, Gaitán 7, Negredo 6½, Mavuba 6½, Tallo 5½ | Newcastle United | 2 | 14 Vidal, 70 Götze | Half-time: | 1-0 | Referee: | Ziller 7½ | Attendance: | 52,214 | Possession: | 58%-42% | Total shots: | 18-8 | MoM: | De Bruyne | TV: | live |
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| (4-3-3): Courtois 7, Boateng 7, Alaba 7½, Vidal 7½, Godín 7, Hummels 6½, De Bruyne 7½, Silva 7, Higuaín 6½, Götze 6½, Müller 7½ | Nantes | 1 | 49 Valbuena |
| (4-3-3): Ruffier 6, Colin 6½, Digne 6½, Payet 6½, Mendy 6½, Kurzawa 6½, Sissoko 6½ (85 Toulalan 6), Di María 6½, Gomis 6, Valbuena 6, Benzia 5½ | Palermo | 2 | 41 Vázquez, 75 Drmic | Half-time: | 1-0 | Referee: | Vorjas 7 | Attendance: | 38,853 | Possession: | 57%-43% | Total shots: | 14-4 | MoM: | Montolivo |
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| (4-3-3): Sommer 7½, Zappacosta 7½, Romagnoli 7, Montolivo 8½, Criscito 7, Astori 7, Candreva 7½, Bonaventura 6 (47 Drmic 7), Destro 7, Parolo 6, Vázquez 7½ | Helsingborg | 0 |
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| (4-3-3): De Gea 7, Azpilicueta 8, Rojo 7, Christensen 6½, Kjær 7, Vestergaard 6, Ekdal 6½, Eriksen 6, Diego Costa 6½, Wass 6½, King 6 | Valencia | 0 |
| Half-time: | 0-0 | Referee: | Blankenstein 7½ | Attendance: | 48,343 | Possession: | 51%-49% | Total shots: | 15-19 | MoM: | Kelvin |
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| (4-3-3): Reina 6½, Arbeloa 7, Vargas 6½, André Gomes 7½, San Jose 7, Aderlan 7, Lennon 7½, Perotti 6½, Paco Alcácer 7 (88 Javi Fuego 6), Hernández 5½, Santi Mina 6 | São Paulo | 1 | 87 Willian |
| (4-3-3): Hélton 7, Maicon 7½, Juan 6½, Casemiro 7, Rodrigo Caio 6, Wendell 6½, Kelvin 7½, Lucas Moura 6½, Willian 6½, Michel Bastos 6, Robinho 5½ | Round 2 | Ajax | 2 | 12 Kishna, 63 Huntelaar | Half-time: | 1-1 | Referee: | Van Vliet 6½ | Attendance: | 50,415 | Possession: | 51%-49% | Total shots: | 4-11 | MoM: | Höwedes |
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| (4-3-3): Cillessen 7, Veltman 7½, Willems 7½, Klaassen 7, Bruma 7, De Vrij 6, Promes 7½, Kishna 6, Huntelaar 6 (69 Narsingh 6½), Sneijder 7, Milik 6½ | Borussia Dortmund | 1 | 40 Höwedes | 45+2 Hazard, 51 Saúl | (4-3-3): Akinfeev 7, Höwedes 7½, Schmelzer 7½, Saúl 7½, Giménez 6½, Ginter 6½, Ramires 7, Hazard 6½, Lewandowski 6, Schürrle 5, Fekir 6½ | Ayr United | 2 | 43 Townsend, 82 Brunt | Half-time: | 1-0 | Referee: | Detruche 6½ | Attendance: | 34,007 | Possession: | 52%-48% | Total shots: | 21-8 | MoM: | Arbeloa |
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| (4-3-3): Gordon 7½, Clyne 7½, Brunt 6½, Fletcher 7, Dann 7, Shawcross 6, Davis 7½, Townsend 6½, Fletcher 7, McCarthy 6½, Long 6 | Valencia | 0 |
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| (4-3-3): Reina 7, Arbeloa 8, Vargas 6, André Gomes 6½, San Jose 7, Aderlan 5½, Lennon 7½, Perotti 6½, Paco Alcácer 7 (47 Javi Fuego 7½), Hernández 6, Santi Mina 6 | Exeter City | 1 | 52 Vardy | Half-time: | 0-1 | Referee: | Vassaras 7½ | Attendance: | 19,709 | Possession: | 44%-56% | Total shots: | 18-9 | MoM: | Drinkwater |
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| (4-3-3): Foster 6½, Coleman 6½, Milner 7½, Barry 7½, Terry 7½, Keane 6½, Drinkwater 8, Redmond 6, Vardy 6, Lampard 7, Walcott 6½ (52 Johnson 6) | Chelsea | 1 | 45 Callejón |
| (4-3-3): Sergio Asenjo 7, Rüdiger 7½, Baines 7½, Matic 7, Koulibaly 7, Mustafi 6½, Callejón 7, Pedro 6½, Llorente 7½, Kramer 6½, Bellarabi 6 | FC Basel | 2 | 62 Keita, 88 Matuidi | Half-time: | 0-0 | Referee: | Rosetti 5 | Attendance: | 38,363 | Possession: | 42%-58% | Total shots: | 8-17 | MoM: | Jordi Alba |
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| (4-3-3): Weidenfeller 7, Dani Alves 7½, Jordi Alba 8, Denis 7½, Dante 7, Juanfran 6, Traoré 6½, Matuidi 6, Enes 6 (69 Rabiot 7), Mkhitaryan 6½, Keita 5½ | Barcelona | 0 |
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| (4-3-3): Ter Stegen 7½, Abate 7½, Maxwell 7½, Busquets 8, Bartra 7, Fernández 7 (62 Fontás 7), Dos Santos 6½, Iniesta 6, Suárez 7, Neymar 6, Messi 6 | Helsingborg | 2 | 27p Diego Costa, 53 Diego Costa | Half-time: | 1-0 | Referee: | Rodomonti 8 | Attendance: | 40,694 | Possession: | 44%-56% | Total shots: | 12-12 | MoM: | Azpilicueta |
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| (4-3-3): De Gea 6½, Azpilicueta 7½, Rojo 6½, Christensen 7, Kjær 7, Vestergaard 6½, Ekdal 7, Eriksen 7½, Diego Costa 7½, Wass 6½, King 6 | Accrington Stan. | 1 | 58 Sterling | 27 Smalling | (4-3-3): Hart 7½, Stones 7½, Rose 7½, Allen 7½, Cahill 6, Smalling 6½, Ramsey 7, Sterling 6½, Sturridge 7, Barkley 6½, Musa 6 | Lille | 1 | 61 Negredo | |
| (4-3-3): Lloris 7, Jallet 6½, Evrà 7, Lallana 6½, Rosales 7, Rodriguez 6½, Valencia 7½, Gaitán 6½, Negredo 6, Mavuba 6½, Tallo 5½ | FC Porto | 1 | 65 Falcao |
| (4-3-3): Rui Patrício 7, Wallace 7½, Alex Sandro 6 (76 Ricardo Esgaio 7½), Philippe Coutinho 8½, Miranda 8, Luisão 6½, Marcelo 8, Douglas Costa 7½, Falcao 6½, Danny 6½, Hulk 6 | Liverpool | 1 | 89 Sørum | | 82 Wimmer | (4-3-3): Pyatov 6, Vrsaljko 7, Sakho 7, Badelj 6½, Lovren 6, Wimmer 6½, Henderson 8, Vitolo 6½, Sørum 6½, Can 6½ (61 Aleksic 6½), Origi 6 | Newcastle United | 2 | 15p Higuaín, 60 Silva |
| (4-3-3): Courtois 6½, Boateng 7½, Alaba 8, Vidal 6½, Godín 6½, Hummels 6½, De Bruyne 6½, Silva 7½, Higuaín 7½, Wijnaldum 6, Müller 7 | Milan | 1 | 14 Volland | Half-time: | 1-0 | Referee: | Arena 5½ | Attendance: | 52,021 | Possession: | 46%-54% | Total shots: | 12-21 | MoM: | Koscielny |
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| (4-3-3): Rajkovic 6½, Aurier 6, Kolasinac 6, Cabaye 7, Javi Martínez 6½ (81 Dória 6), Laporte 6½, Volland 6, El Shaarawy 6½, Mandzukic 7½, Bacca 6, Niang 6½ | Arsenal | 1 | 55 Sánchez |
| (4-3-3): Buffon 7, Bellerín 7, Nacho Monreal 7, Koke 7, Koscielny 8, Martins-Indi 7, Reus 7½, Sánchez 7, Boyé 7½, Coquelin 6½, Campbell 6½ | Nantes | 2 | 37 Di María, 45 Valbuena | Half-time: | 2-0 | Referee: | Tanner 6 | Attendance: | 37,376 | Possession: | 48%-52% | Total shots: | 16-21 | MoM: | Candreva |
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| (4-3-3): Ruffier 7, Colin 6½, Digne 6½, Payet 7, Mendy 6½, Kurzawa 6½, Sissoko 7, Di María 6, Gomis 6½, Valbuena 6½, Benzia 6½ | Palermo | 1 | 80 Candreva |
| (4-3-3): Sommer 7, Zappacosta 7, Romagnoli 6½, Montolivo 7, Criscito 6½, Astori 6, Candreva 7½, Bonaventura 7½, Destro 6, Parolo 6½, Vázquez 6 | Real Madrid | 3 | 14 Ibrahimovic, 16 Ibrahimovic, 35 Ibrahimovic | Half-time: | 3-0 | Referee: | Jol 5 | Attendance: | 63,544 | Possession: | 49%-51% | Total shots: | 18-11 | MoM: | Chiellini |
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| (4-3-3): Neuer 6½, Sergio Ramos 7½, Chiellini 7½, Lahm 7½, Piqué 5½ (76 Pepe 6), Bonucci 6, Kroos 7, Bale 6½, Ibrahimovic 7½, Modric 6½, Robben 5½ | Lazio | 1 | 84 Mertens |
| (4-3-3): Berisha 6½, Schelotto 7½, Radu 7, Ilicic 6½, Maurício 7, Bonera 6½, Onazi 7, Mertens 6½, Defoe 6, Matri 6½, Babacar 6 | São Paulo | 1 | 5 Maicon | Half-time: | 1-1 | Referee: | Vink 7 | Attendance: | 41,701 | Possession: | 56%-44% | Total shots: | 19-6 | MoM: | Dembélé |
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| (4-3-3): Hélton 7, Maicon 7½, Juan 8, Casemiro 8, Rodrigo Caio 7½, Wendell 8, Kelvin 6½, Lucas Moura 7½, Willian 7, Michel Bastos 7, Robinho 6½ | Anderlecht | 1 | 28 Lukaku |
| (4-3-3): Mignolet 7, Gillet 7½, Deschacht 6½, Dembélé 8, Chedjou 7½, Ramis 6, Marecek 6½, Mollo 6½, Lukaku 6½, Kerzhakov 5½, Jonas 6 |
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