| Round 3 | | Accrington Stan. | 3 | 9 Allen, 15 Sterling, 24 Musa | | Half-time: | 3-0 | | Referee: | Sedlacek 6½ | | Attendance: | 30,922 | | Possession: | 58%-42% | | Total shots: | 14-8 | | MoM: | Cahill |
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| | (4-3-3): Hart 7½, Smalling 7, Rose 6, Allen 8, Cahill 8, Williams 6½, Ramsey 7, Sterling 7, Iheanacho 6½, Barkley 7½, Musa 7 | | Ayr United | 1 | 62 McCarthy | | 4 McCarthy, 29 Brunt | | (4-3-3): Gordon 6½, Clyne 7, Brunt 7, Fletcher 5½, Dann 7½, Shawcross 5½, Davis 7, Townsend 6, Fletcher 6, McCarthy 6, Long 6 | | Borussia Dortmund | 4 | 8 Lewandowski, 71 Saúl, 79 Schmelzer, 90+1 Schmelzer | | Half-time: | 1-1 | | Referee: | Arena 5½ | | Attendance: | 49,672 | | Possession: | 52%-48% | | Total shots: | 17-11 | | MoM: | Ramires | | TV: | live |
| | 19 Giménez, 22 Höwedes, 78 Hazard, 85 Schmelzer | | (4-3-3): Akinfeev 7, Höwedes 5 (79 Bernard 6), Schmelzer 6½, Saúl 8, Giménez 6½, Ginter 6½, Ramires 8, Hazard 7½, Lewandowski 7, Schürrle 6, Fekir 6 | | Helsingborg | 2 | 26 Eriksen, 67 King |
| | (4-3-3): De Gea 6½, Azpilicueta 6½, Rojo 7½, Wass 7½, Kjær 7, Vestergaard 6½, Ekdal 6½ (68 Braithwaite 7), Eriksen 6½, Diego Costa 7½, Sigurðsson 6, King 6 | | Chelsea | 2 | 25 Pedro, 33 Callejón | | Half-time: | 2-1 | | Referee: | Bettin 8 | | Attendance: | 55,421 | | Possession: | 53%-47% | | Total shots: | 10-12 | | MoM: | Sakho |
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| | (4-3-3): Sergio Asenjo 6½, Rüdiger 8, Baines 7½, Matic 7½, Koulibaly 6½, Mustafi 6, Callejón 7½, Pedro 7½, Llorente 7, Kramer 6, Bellarabi 6 | | Liverpool | 2 | 20 Badelj, 58 Sakho |
| | (4-3-3): Pyatov 6½, Vrsaljko 6½, Sakho 8, Badelj 7, Lovren 6½, Wimmer 6½, Henderson 6½, Vitolo 7½, Sørum 6½, Can 6½, Origi 6½ (58 Insúa 6) | | FC Porto | 1 | 23 Douglas Costa | | Half-time: | 1-2 | | Referee: | Bolognino 7 | | Attendance: | 50,785 | | Possession: | 42%-58% | | Total shots: | 7-16 | | MoM: | Lahm | | TV: | highlights |
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| | (4-3-3): Rui Patrício 6½, Wallace 5½, Alex Sandro 7, Philippe Coutinho 8, Miranda 6½, Luisão 6, Marcelo 6, Douglas Costa 6½, Falcao 6, Danny 6½, Hulk 6 | | Real Madrid | 2 | 36og Alex Sandro, 45+1 Modric |
| | (4-3-3): Neuer 6½, Sergio Ramos 7½, Chiellini 7½, Lahm 8, Piqué 7 (76 Pepe 6), Bonucci 6½, Kroos 7, Bale 7, Ibrahimovic 6, Modric 7, Robben 5½ | | Lazio | 1 | 17 Onazi | | Half-time: | 1-1 | | Referee: | Borriello 7 | | Attendance: | 49,440 | | Possession: | 48%-52% | | Total shots: | 9-13 | | MoM: | Schelotto |
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| | (4-3-3): Berisha 6½, Schelotto 8, Radu 7, Ilicic 7½, Maurício 7, Bonera 6½, Onazi 6½, Mertens 6, Defoe 7, Matri 6, Babacar 6½ | | Milan | 2 | 7 Mandzukic, 53 Mandzukic |
| | (4-3-3): Rajkovic 6½, Aurier 7½, Kolasinac 7, Cabaye 7, Javi Martínez 7½, Laporte 7, Volland 7, El Shaarawy 7½, Mandzukic 7, Bacca 5½, Niang 7 | | Newcastle United | 2 | 11 Hummels, 43 Götze | | Half-time: | 2-0 | | Referee: | Brignoccoli 7 | | Attendance: | 52,315 | | Possession: | 52%-48% | | Total shots: | 15-16 | | MoM: | Hummels |
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| | (4-3-3): Courtois 7½, Boateng 6, Alaba 8, Vidal 8, Hummels 8, Tah 7½, Götze 6½, De Bruyne 6½, Higuaín 6½, Silva 7½, Müller 6 | | Lille | 0 |
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| | (4-3-3): Lloris 7½, Valencia 7½, Rodriguez 7, Mavuba 6½, David Luiz 6½, Sidibé 6, Dzemaili 6, Lallana 6½, Negredo 6, Flamini 6, Thauvin 6½ | | Palermo | 2 | 10 Bonaventura, 30 Destro | | Half-time: | 2-0 | | Referee: | Cinciripini 6 | | Attendance: | 38,862 | | Possession: | 45%-55% | | Total shots: | 14-15 | | MoM: | Montolivo | | TV: | live |
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| | (4-3-3): Sommer 7½, Zappacosta 7½, Romagnoli 7, Montolivo 8½, Criscito 7½, Astori 6, Candreva 6½, Bonaventura 6 (47 Drmic 6½), Destro 7, Parolo 6, Vázquez 5½ | | Exeter City | 1 | 71 Keane |
| | (4-3-3): Foster 7½, Coleman 7½, Milner 6½, Barry 7, Terry 7, Keane 6½, Drinkwater 7, Redmond 6½, Vardy 7 (54 Austin 7), Lampard 7, Walcott 7 (52 Johnson 6½) | | Valencia | 1 | 8 Paco Alcácer | | Half-time: | 1-0 | | Referee: | Pyanikh 7 | | Attendance: | 43,551 | | Possession: | 49%-51% | | Total shots: | 7-16 | | MoM: | Arbeloa | | TV: | highlights |
| | 75 Hernández | | (4-3-3): Reina 7, Arbeloa 7½, Vargas 7½, André Gomes 7½, San Jose 7, Aderlan 6½, Lennon 7, Perotti 7½, Paco Alcácer 7, Hernández 6, Santi Mina 6½ | | Nantes | 1 | 83p Gomis |
| | (4-3-3): Ruffier 6½, Colin 7½, Digne 6, Payet 7½, Mendy 5½, Kurzawa 6½, Sissoko 7, Di María 7, Gomis 6, Valbuena 6½, Benzia 5½ | | Round 4 | | Ajax | 2 | 29 Huntelaar, 54 Kishna | | Half-time: | 1-2 | | Referee: | Rodomonti 7 | | Attendance: | 51,580 | | Possession: | 50%-50% | | Total shots: | 10-11 | | MoM: | Matic |
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| | (4-3-3): Cillessen 6½, Veltman 6½, Willems 7½, Klaassen 7½, Bruma 6½, De Vrij 7, Promes 7, Kishna 7, Huntelaar 7, Sneijder 6 (76 Narsingh 6), Milik 6 | | Chelsea | 2 | 15 Mustafi, 28 Kramer |
| | (4-3-3): Sergio Asenjo 7, Rüdiger 7½, Baines 6½, Matic 8, Koulibaly 6½, Mustafi 6½, Callejón 6½, Pedro 7, Llorente 7, Kramer 6½, Bellarabi 5½ | | Ayr United | 1 | 90 Shawcross | | Half-time: | 0-0 | | Referee: | Racek 6½ | | Attendance: | 34,048 | | Possession: | 49%-51% | | Total shots: | 11-13 | | MoM: | Vidal |
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| | (4-3-3): Gordon 7, Clyne 5½, Brunt 7, Fletcher 7½, Dann 6½, Shawcross 6½, Davis 7½, Townsend 6, Fletcher 6, McCarthy 7, Long 7 | | Newcastle United | 0 |
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| | (4-3-3): Courtois 7½, Boateng 6½, Alaba 7, Vidal 8, Hummels 6½, Matip 6½, De Bruyne 6½, Silva 7, Higuaín 7, Götze 6, Müller 6½ | | Exeter City | 2 | 26 Lampard, 75 Milner | | Half-time: | 1-0 | | Referee: | Meese 6½ | | Attendance: | 19,796 | | Possession: | 51%-49% | | Total shots: | 23-8 | | MoM: | Redmond | | TV: | highlights |
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| | (4-3-3): Foster 7, Coleman 6½, Milner 6, Barry 7, Terry 7, Keane 5½, Drinkwater 6½, Redmond 7½, Vardy 6 (74 Austin 6), Lampard 7, Walcott 6 | | Arsenal | 0 |
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| | (4-3-3): Buffon 7, Bellerín 7, Nacho Monreal 7 (83 Tolisso 6), Koke 6, Koscielny 6½, Mertesacker 6½, Marchisio 6½, Sánchez 6½, Debuchy 6½, Coquelin 6 (56 Wilshere 5½), Boyé 7 | | FC Basel | 1 | 20 Sanabria | | Half-time: | 1-0 | | Referee: | Piraux 6½ | | Attendance: | 38,460 | | Possession: | 51%-49% | | Total shots: | 4-12 | | MoM: | Rose |
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| | (4-3-3): Weidenfeller 7, Dani Alves 7, Jordi Alba 6, Willian 6, Dante 7½, Juanfran 6½ (68 Berardi 6), Florenzi 6½, Rodríguez 7, Sanabria 7, Mkhitaryan 6½, Keita 5½ | | Accrington Stan. | 1 | 90+2 Sterling |
| | (4-3-3): Hart 7, Smalling 7½, Rose 7½, Barkley 6½, Cahill 6½, Stones 6, Ramsey 6½, Sterling 7, Iheanacho 7, Allen 6½, Musa 6½ | | Helsingborg | 2 | 9 Diego Costa, 72 Eriksen | | Half-time: | 1-1 | | Referee: | Vorjas 5 | | Attendance: | 40,639 | | Possession: | 50%-50% | | Total shots: | 10-16 | | MoM: | Azpilicueta |
| | 61 Kjær | | (4-3-3): De Gea 6, Azpilicueta 8, Wendt 6½, Wass 7, Rojo 6½, Kjær 6, Ekdal 7, Eriksen 6½, Diego Costa 7, Sigurðsson 7, King 6½ | | Barcelona | 1 | 35 Messi |
| | (4-3-3): Ter Stegen 7, Abate 6½, Maxwell 6½, Busquets 7, Bartra 6, Fernández 6, Feghouli 7½, Iniesta 6½, Gomez 7, Neymar 6, Messi 7½ | | Lille | 2 | 9p Negredo, 55 Negredo | | Half-time: | 1-0 | | Referee: | Kefalas 6 | | Attendance: | 17,932 | | Possession: | 43%-57% | | Total shots: | 14-11 | | MoM: | Lallana |
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| | (4-3-3): Lloris 7, Valencia 5½, Rodriguez 7, Mavuba 6½, David Luiz 6, Widmer 6½, Thauvin 7, Lallana 7½, Negredo 6 (81 Flamini 6), Dzemaili 6, Guirassy 6½ | | Anderlecht | 0 |
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| | (4-3-3): Mignolet 7½, Gillet 6½, Deschacht 5½, Dembélé 7½, Chedjou 7, Ramis 5½, Marecek 6, Mollo 7, Lukaku 7½, Kerzhakov 6, Jonas 6½ | | Liverpool | 1 | 31p Sørum | | Half-time: | 1-0 | | Referee: | Colic 7 | | Attendance: | 33,508 | | Possession: | 45%-55% | | Total shots: | 11-14 | | MoM: | Parolo |
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| | (4-3-3): Pyatov 6½, Vrsaljko 6½, Sakho 7, Badelj 7, Lovren 6½, Wimmer 5½, Henderson 7½, Vitolo 6½, Sørum 6, Can 6½ (62 Ings 7½), Origi 6½ | | Palermo | 1 | 82 Parolo |
| | (4-3-3): Sommer 7, Zappacosta 6, Romagnoli 7, Montolivo 7, Criscito 6½, Astori 6, Candreva 7½, Bonaventura 6½, Destro 7½, Parolo 7½, Vázquez 6 | | Milan | 0 |
| | Half-time: | 0-1 | | Referee: | Finnie 6½ | | Attendance: | 56,024 | | Possession: | 49%-51% | | Total shots: | 13-18 | | MoM: | Schmelzer |
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| | (4-3-3): Rajkovic 4½, Aurier 6½ (64 Dória 6½), Kolasinac 6, Cabaye 7, Javi Martínez 7 (55 Linetty 7½), Laporte 6½, Volland 6, El Shaarawy 7½, Mandzukic 6½, Bacca 6, Niang 7 | | Borussia Dortmund | 4 | 31 Hazard, 60 Fekir, 62 Lewandowski, 90+2 Fekir | | 39 Saúl, 70 Giménez | | (4-3-3): Akinfeev 5, Höwedes 7 (59 Bernard 7½), Schmelzer 7½, Saúl 7, Giménez 6½, Ginter 7, Ramires 7, Hazard 6½, Lewandowski 7, Schürrle 5½, Fekir 6½ | | São Paulo | 3 | 29 Lucas Moura, 50 Willian, 85 Robinho | | Half-time: | 1-0 | | Referee: | Pinto Correia 6½ | | Attendance: | 45,937 | | Possession: | 54%-46% | | Total shots: | 18-13 | | MoM: | Marcelo |
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| | (4-3-3): Hélton 6, Maicon 6½, Juan 6½, Casemiro 7, Rodrigo Caio 7, Wendell 7, Kelvin 7½, Lucas Moura 7½, Willian 7, Michel Bastos 7½, Robinho 6 | | FC Porto | 2 | 46 Falcao, 83 Falcao |
| | (4-3-3): Rui Patrício 6½, Wallace 7½, Alex Sandro 6 (83 Ricardo Esgaio 6), Philippe Coutinho 7½, Miranda 6½, Luisão 6½, Marcelo 8, Douglas Costa 6½, Falcao 6½, Danny 6, Hulk 6½ |
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