| Round 5 | | Accrington Stan. | 0 |
| | Half-time: | 0-0 | | Referee: | Williams 7 | | Attendance: | 30,886 | | Possession: | 53%-47% | | Total shots: | 12-9 | | MoM: | Klaassen | | TV: | highlights |
| | 69 Musa | | (4-3-3): Hart 7½, Smalling 7, Rose 7½, Barkley 7½, Cahill 6½, Stones 7, Ramsey 7, Sterling 7, Iheanacho 6, Allen 6, Musa 6½ | | Ajax | 0 |
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| | (4-3-3): Cillessen 7½, Veltman 7, Willems 6½, Klaassen 8, Bruma 6, De Vrij 6, Promes 6, Kishna 6½, Huntelaar 6½, Sneijder 6½ (76 Narsingh 5½), Milik 6 | | Anderlecht | 0 |
| | Half-time: | 0-0 | | Referee: | Rottondo 8 | | Attendance: | 27,882 | | Possession: | 39%-61% | | Total shots: | 13-15 | | MoM: | Henderson |
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| | (4-3-3): Mignolet 7, Gillet 6, Deschacht 6½, Wuytens 7, Chedjou 7, Ramis 7 (60 Diandy 6), Marecek 6½, Ilicevic 7, Lukaku 7, Kerzhakov 6, Mollo 5½ | | Liverpool | 0 |
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| | (4-3-3): Pyatov 8, Vrsaljko 6½, Sakho 7, Badelj 6½, Lovren 7, Wimmer 7, Henderson 8, Vitolo 7, Sørum 6½, Can 6, Origi 7 (47 Insúa 6) | | Arsenal | 1 | 38 Boyé | | Half-time: | 1-1 | | Referee: | Duarte 7½ | | Attendance: | 48,582 | | Possession: | 47%-53% | | Total shots: | 13-11 | | MoM: | Wendt | | TV: | highlights |
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| | (4-3-3): Buffon 6½, Bellerín 7, Nacho Monreal 7 (83 Tolisso 6), Koke 7½, Koscielny 7, Mertesacker 6½, Marchisio 6½, Sánchez 7, Debuchy 6½, Coquelin 6½ (63 Wilshere 6½), Boyé 6½ | | Helsingborg | 2 | 33 Eriksen, 62 Sigurðsson | | 10 Sigurðsson | | (4-3-3): De Gea 6½, Azpilicueta 7½, Wendt 8, Wass 7, Rojo 7½, Kjær 6, Ekdal 7, Eriksen 6½, Diego Costa 6½, Sigurðsson 6½, King 6½ | | Barcelona | 0 |
| | Half-time: | 0-1 | | Referee: | Halsey 5 | | Attendance: | 42,158 | | Possession: | 52%-48% | | Total shots: | 18-8 | | MoM: | Busquets |
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| | (4-3-3): Ter Stegen 6½, Sergi Roberto 7½, Maxwell 7, Busquets 8, Bartra 7 (72 Abate 6), Mexès 5½, Feghouli 7, Rakitic 5½, Gomez 7, Torres 5½, Neymar 6 | | Nantes | 1 | 9 Payet |
| | (4-3-3): Ruffier 7, Colin 6½, Digne 7½, Payet 6½, Mendy 7, Kurzawa 6, Sissoko 6½, Di María 7, Gomis 7, Valbuena 6½, Benzia 5½ | | Borussia Dortmund | 1 | 12 Lewandowski | | Half-time: | 1-0 | | Referee: | D'Urso 7½ | | Attendance: | 62,329 | | Possession: | 47%-53% | | Total shots: | 16-15 | | MoM: | Mavuba |
| | 20 Hazard, 35 Giménez | | (4-3-3): Akinfeev 7½, Höwedes 6½ (59 Bernard 6½), Schmelzer 7½, Saúl 6, Giménez 6½, Ginter 6½, Ramires 6, Hazard 7½, Lewandowski 7, Schürrle 6, Fekir 6½ | | Lille | 0 |
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| | (4-3-3): Lloris 7½, Valencia 6½, Rodriguez 8, Mavuba 8, David Luiz 6½, Widmer 6½, Thauvin 7½, Lallana 7½, Negredo 7, Dzemaili 7, Guirassy 6 | | Chelsea | 3 | 3 João Mário, 12 Bellarabi, 39 Pellé | | Half-time: | 3-0 | | Referee: | Wieser 6 | | Attendance: | 55,364 | | Possession: | 52%-48% | | Total shots: | 10-15 | | MoM: | João Mário |
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| | (4-3-3): Sergio Asenjo 7½, Mustafi 6, Baines 7½, Khedira 7, Koulibaly 7, Touré 6½, João Mário 7½, Pedro 5½ (70 Kramer 6), Pellé 7, Asensio 7, Bellarabi 6 | | Ayr United | 0 |
| | 6 McCarthy | | (4-3-3): Gordon 7, Cameron 6½, Brunt 6, Fletcher 7, Dann 6, Shawcross 7, Davis 6½, Townsend 6½, Fletcher 6½, McCarthy 6, Long 6½ | | FC Porto | 3 | 32 Hulk, 49 Philippe Coutinho, 71 Douglas Costa | | Half-time: | 1-1 | | Referee: | Franco 8½ | | Attendance: | 42,863 | | Possession: | 55%-45% | | Total shots: | 17-12 | | MoM: | Falcao |
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| | (4-3-3): Rui Patrício 6½, Wallace 7½, Alex Sandro 7, Philippe Coutinho 7, Miranda 7, Luisão 6½, Marcelo 6½, Douglas Costa 8, Falcao 8, Danny 6½, Hulk 7 | | Milan | 2 | 25 Mandzukic, 72 Mandzukic |
| | (4-3-3): Rajkovic 6½, Aurier 7 (64 Dória 7), Kolasinac 6, Cabaye 6, Javi Martínez 7 (55 Linetty 6), Laporte 5½, Volland 6½, El Shaarawy 6, Mandzukic 6½, Bacca 5½, Niang 6½ | | Lazio | 2 | 3 Mertens, 75 Defoe | |
| | (4-3-3): Berisha 7, Schelotto 6½, Radu 7, Ilicic 7½, Maurício 7, Bonera 6, Onazi 6, Mertens 7½, Defoe 6½, Matri 6, Babacar 5½ | | FC Basel | 0 |
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| | (4-3-3): Weidenfeller 8, Dani Alves 6½, Jordi Alba 7, Willian 6½, Dante 6½, Juanfran 6, Florenzi 7, Matuidi 7, Sanabria 6½, Isco 6½, Keita 6 | | Newcastle United | 1 | 66 Götze | | Half-time: | 0-3 | | Referee: | Strampe 6½ | | Attendance: | 52,232 | | Possession: | 52%-48% | | Total shots: | 18-14 | | MoM: | Sergio Ramos | | TV: | live |
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| | (4-3-3): Courtois 5½, Boateng 6, Alaba 7½, Vidal 7, Hummels 7, Matip 6½, De Bruyne 6, Silva 7½, Higuaín 6½, Götze 7, Müller 7 | | Real Madrid | 4 | 10 Marcelo, 25 Modric, 30 Bale, 74 Sergio Ramos |
| | (4-3-3): Neuer 5½, Sergio Ramos 8, Marcelo 7 (68 De Rossi 6), Lahm 7, Piqué 6½, Mascherano 6, Kroos 6½, Bale 7, Ibrahimovic 7, Modric 6½, Robben 6 | | Palermo | 2 | 30 Destro, 70 Destro | | Half-time: | 1-2 | | Referee: | Vorjas 5½ | | Attendance: | 38,903 | | Possession: | 51%-49% | | Total shots: | 16-10 | | MoM: | Destro | | TV: | live |
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| | (4-3-3): Sommer 6½, Zappacosta 7, Romagnoli 5½, Montolivo 7, Criscito 7½, Astori 6, Candreva 7, Bonaventura 6, Destro 7½, Parolo 6½, Vázquez 6½ | | São Paulo | 2 | 3 Robinho, 22 Michel Bastos |
| | (4-3-3): Hélton 6, Maicon 7, Juan 7½, Casemiro 7½, Rodrigo Caio 6½, Wendell 6, Kelvin 6, Lucas Moura 6½, Willian 6½, Michel Bastos 7, Robinho 6½ | | Valencia | 1 | 86 Paco Alcácer | | Half-time: | 0-0 | | Referee: | Van Der Ende 7½ | | Attendance: | 39,674 | | Possession: | 57%-43% | | Total shots: | 14-10 | | MoM: | Arbeloa | | TV: | highlights |
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| | (4-3-3): Reina 7½, Arbeloa 8, Vargas 6½, André Gomes 6½, San Jose 7½, Aderlan 7, Lennon 7½, Perotti 6½, Paco Alcácer 7½, Hernández 6, Santi Mina 6½ | | Exeter City | 0 |
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| | (4-3-3): Foster 7, Coleman 7, Milner 6½, Barry 6, Terry 7, Keane 6, Drinkwater 6½, Redmond 5½, Vardy 7 (86 Austin 6), Lampard 6½, Walcott 7 (86 Johnson 6) | | Round 3 | | Arsenal | 1 | 7 Coquelin | | Half-time: | 1-0 | | Referee: | Jol 6½ | | Attendance: | 41,221 | | Possession: | 46%-54% | | Total shots: | 14-15 | | MoM: | Buffon |
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| | (4-3-3): Buffon 8½, Bellerín 6½, Nacho Monreal 7, Koke 7½, Koscielny 7, Mertesacker 6½, Marchisio 6½, Sánchez 7, Debuchy 6, Coquelin 6½ (64 Tolisso 7), Boyé 6½ | | São Paulo | 0 |
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| | (4-3-3): Hélton 7½, Maicon 5½, Juan 8, Casemiro 7½, Rodrigo Caio 6½, Wendell 7½, Kelvin 6, Lucas Moura 7½, Willian 6, Michel Bastos 7½, Robinho 6½ |
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