| Round 5 | | Aston Villa | 0 |
| | Half-time: | 0-1 | | Referee: | Bradford 9 | | Attendance: | 30,425 | | Possession: | 46%-54% | | Total shots: | 22-15 | | MoM: | Naughton |
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| | (4-3-3): Viviano 7, Naughton 8, Warnock 7½, Aissati 7½, Collins 7½, Bannan 6½, Bamford 6, Nolito 6, Heskey 6½, Reo-Coker 6, Gabriel Jesus 6½ | | Rosenborg | 1 | 15 Schřne |
| | (4-3-3): Begovic 7, Cédric 7½, Van Dijk 6½, Kovacic 7½, Toprak 6½, Gabriel Paulista 6, Skjelbred 7, Schřne 7, Batshuayi 7, Clasie 5½, Aboubakar 7½ | | Auxerre | 2 | 3 Gameiro, 11 Gameiro | | Half-time: | 2-0 | | Referee: | Piller 6½ | | Attendance: | 25,030 | | Possession: | 58%-42% | | Total shots: | 16-17 | | MoM: | Gameiro | | TV: | highlights |
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| | (4-3-3): Aréola 7, Yanga-Mbiwa 8, Cissokho 6, Özyakup 8, Rekik 7, Isimat-Mirin 6½, Capoue 8, John 6, Gameiro 8, Danzé 7½, Libertazzi 5½ | | Rubin | 1 | 57 Murawski |
| | (4-3-3): Rebrov 6½, Kuzmin 7, Kaleshin 7½, Murawski 6½, César Navas 7, Jordi 6, Samedov 7½, Kasaev 6, Jonathas 6, Portnyagin 6, Ari 6 | | Bursaspor | 2 | 56 Bakambu, 70 Tosic | | Half-time: | 0-1 | | Referee: | Braamhaar 7 | | Attendance: | 25,197 | | Possession: | 58%-42% | | Total shots: | 18-8 | | MoM: | Tosic |
| | 7 Tosic | | (4-3-3): Harun 6½, Ozan 6, Emre 6½, Jorquera 7½, Mehmet 7, Spahic 7, Josué 7½, Tosic 7½, Bakambu 7, Behich 6, Necid 6½ | | West Ham United | 1 | 45 Carroll | | 24 Carroll, 87 Gray | | (4-3-3): Wiedwald 6½, Antonio 6½, Cresswell 7, Brozovic 7, Samba 7½, Sané 7 (72 Fink 6½), Gray 6½, Carroll 6½, Zaza 6½, Carroll 6, Sellin 5½ | | CSKA | 0 |
| | Half-time: | 0-1 | | Referee: | Tanner 6½ | | Attendance: | 13,134 | | Possession: | 55%-45% | | Total shots: | 16-7 | | MoM: | Schennikov |
| | 27 Denisov, 60 Ignashevich | | (4-3-3): Moyá 6½, Nababkin 7, Schennikov 7½, Denisov 7, Ignashevich 7, Sergio Sánchez 7, Okay 6½, Dzsudzsák 7, Borriello 7, Pelé 6, Washington 7 | | Independiente | 1 | 21 Mancuello |
| | (4-3-3): Orión 7½, Matheu 7, Vallés 6, Fernández 7, Otamendi 7, Galeano 6, Fredes 6½, Mancuello 7, Osvaldo 6½, Gutierrez 5½, Tévez 7 | | Celtic | 2 | 25 Cissé, 69 Izaguirre | | Half-time: | 1-1 | | Referee: | Derix 5½ | | Attendance: | 32,038 | | Possession: | 56%-44% | | Total shots: | 10-14 | | MoM: | Boruc |
| | 17 Defour | | (4-3-3): Boruc 7½, José Ángel 6½, Izaguirre 7½, Defour 7, Sviatchenko 6½, Rogne 6½, Fulton 7½, Iturbe 7, Cissé 7, Ki 6½, Cissé 6 | | Udinese | 1 | 25 Danilo | | 60 Théréau | | (4-3-3): Szczesny 7, Basta 7, Armero 7½, Iturra 7, Danilo 7, Papadopoulos 6½, Lodi 6, Zimling 6½ (83 Landgren 6), Zapata 7, Diarra 6½, Théréau 6½ | | Fiorentina | 2 | 8 Gilardino, 82 Seferovic | | Half-time: | 1-0 | | Referee: | Rosetti 6 | | Attendance: | 44,209 | | Possession: | 50%-50% | | Total shots: | 14-12 | | MoM: | Gobbi | | TV: | live |
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| | (4-3-3): Mirante 7, Rispoli 7, Gobbi 8½, Rômulo 7½, Felipe 7, Camporese 6, Konko 8, Giaccherini 6 (48 Seferovic 7), Gilardino 7½, Cerci 5½, Jovetic 7 | | Espanyol | 1 | 74 Ninkovic |
| | (4-3-3): Álvarez 6½, Roncaglia 7½, Víctor Álvarez 6½, Juanmi 7½, Pareja 7, Pinto 6½, McKenna 6, Toribio 6, Tamudo 6, Javi Márquez 6½, Gerard 7 (49 Ninkovic 6) | | Hamburger SV | 1 | 86 Elia | | Half-time: | 0-0 | | Referee: | Chaib 6½ | | Attendance: | 41,460 | | Possession: | 53%-47% | | Total shots: | 11-13 | | MoM: | Fuchs | | TV: | highlights |
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| | (4-3-3): Hakan 7½, Rincón 7½, Fuchs 8, Aogo 8, Piris 7½, Milosevic 7, Harnik 6½ (86 Rahman 6), Elia 7, Guerrero 7½, Torun 6½, Ghadir 6 | | Napoli | 0 |
| | 4 Aronica, 79 Maiello | | (4-3-3): De Sanctis 8, Maggio 6½, Aronica 7, Keita 7½, Cannavaro 7, Zaccardo 6, Gargano 7½, Cigarini 7, Gignac 6½ (67 Maiello 6), Mokotjo 6½, Quagliarella 6½ | | Inter | 2 | 17 Icardi, 84 Santon | | Half-time: | 1-0 | | Referee: | Řvrebř 6½ | | Attendance: | 48,003 | | Possession: | 57%-43% | | Total shots: | 22-8 | | MoM: | Crisetig |
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| | (4-3-3): Belec 7½, Donati 6½, Santon 7, Crisetig 8, Britos 7½, Muntari 6, Krhin 7, Ljajic 6, Icardi 6½, Eto'o 5½, Arnautovic 6 | | Palmeiras | 0 |
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| | (4-3-3): Gomes 7½, Henrique 7, Alex Telles 7½, Márcio Araújo 6½, Lucas 7½, Rafael Toloi 6, Diego Souza 7½, Marquinhos 6½, Robert 7, Pierre 6, Ewerthon 5½ | | Marseille | 1 | 42 Ben Arfa | | Half-time: | 1-0 | | Referee: | Krondl 5 | | Attendance: | 37,906 | | Possession: | 53%-47% | | Total shots: | 18-12 | | MoM: | Kaboré |
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| | (4-3-3): Riou 6½, Reveillčre 6½, Tabanou 7, Pjanic 7, Kaboré 8, Lamela 5½, González 7, Ben Arfa 7½, Benzema 7, Rodwell 6, Brandăo 5½ | | Grasshoppers | 0 |
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| | (4-3-3): Bürki 8, Weiser 7, Zábavník 7½, Selnćs 8, Simons 6½, Cavanda 6½, Zuber 7, Kiyotake 7½, Janko 6, Svensson 6½, Vossen 6½ | | Roma | 2 | 20 Young, 77 Pazzini | | Half-time: | 1-0 | | Referee: | Hanko 7 | | Attendance: | 57,291 | | Possession: | 55%-45% | | Total shots: | 16-11 | | MoM: | Schneiderlin |
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| | (4-3-3): Adler 6½, Hysaj 6½, Young 7, Kagawa 6 (78 Gago 7½), Fazio 7, Evans 6, Schneiderlin 7½, Çalhanoglu 7½, Pazzini 7½, Tadic 6½, Rossi 7 | | Boulogne | 1 | 69 Emeghara |
| | (4-3-3): Frey 6, Srna 7, Ibáńez 7 (70 Sammir 7), Thiago 7, Gamberini 6½, Kverkvelia 6, Gökhan 6½, Muniain 6, Álvaro 6½, Mikel 7, Emeghara 6 | | TSG Hoffenheim | 0 |
| | Half-time: | 0-0 | | Referee: | Waddel 7½ | | Attendance: | 30,027 | | Possession: | 53%-47% | | Total shots: | 18-9 | | MoM: | Ibisevic |
| | 4 Obasi | | (4-3-3): Fährmann 7, Kaderábek 6, Luna 5½, Sessčgnon 7 (66 Dia 7), Lustig 7, Gulde 6, Obasi 6½, Carlos Eduardo 6, Ibisevic 8, Ba 6½, Mehmedi 6½ | | Shakhtar | 0 |
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| | (4-3-3): Shevchenko 7½, Butko 7½, Ismaily 5, Stepanenko 7½, Rakitskyi 6½ (50 Volovyk 6½), Kucher 7, Fred 7, Arabidze 5½, Ferreyra 7, Malyshev 6½, Dentinho 6½ |
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