| Round 1 | | Atlético Madrid | 1 | 4p Borja | | Half-time: | 1-0 | | Referee: | Bettin 5½ | | Attendance: | 41,706 | | Possession: | 45%-55% | | Total shots: | 16-17 | | MoM: | Rodríguez | | TV: | highlights |
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| | (4-3-3): Sergio Asenjo 7, Mario 7, Ismail 8, Biglia 7½, Rodríguez 8, Garay 6½ (76 Reyes 6½), Salvio 7 (82 Perisic 6), Koke 6½, Borja 6½, Banega 6, Tadic 6½ | | River Plate | 0 |
| | 77 Mouche | | (4-3-3): Ospina 7½, Ferrari 7, Rojo 7½, Buonanotte 7½, López 6, Cabral 6½, Formica 7½, Rosický 6½, López 6½, Amrabat 5½, Mouche 6 | | Espanyol | 0 |
| | Half-time: | 0-0 | | Referee: | Hauge 5 | | Attendance: | 39,435 | | Possession: | 58%-42% | | Total shots: | 13-13 | | MoM: | Ninkovic |
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| | (4-3-3): Kameni 8, Motta 8, Pinto 7, Ninkovic 8½, Hangeland 8, Roncaglia 7½, Callejón 8, Verdú 7, Corominas 6½, Raúl Baena 7 (79 Moisés 6), Olic 7 | | TSG Hoffenheim | 0 |
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| | (4-3-3): Consigli 7, Ebondo 7, Simunic 6½, Luis Gustavo 6, Ruíz 6½, Vorsah 6, Vukcevic 6½, Salihovic 7, Ibisevic 7 (73 Owomoyela 7), Ba 6, Luis García 6 | | Everton | 2 | 6 Braafheid, 35 Yakubu | |
| | (4-3-3): Howard 7, Yobo 7, Braafheid 7, Wallace 6½, Agard 6½, Hibbert 6, Osman 7½, Bilyaletdinov 6½, Yakubu 6½, Anichebe 6, Baxter 5½ | | Sevilla | 1 | 16p Kiessling | | 17 Negredo | | (4-3-3): Carrizo 7, Fernández 7½, Filipe Luis 7, Raul Meireles 8, Alexis 7½, Naldo 6, Kiko 7½, Luscombe 6½ (66 Squillaci 6½), Kiessling 6½, Makoun 7 (75 Silvestre 6), Negredo 6 | | FC Schalke 04 | 0 |
| | Half-time: | 0-1 | | Referee: | Tanner 8 | | Attendance: | 48,975 | | Possession: | 51%-49% | | Total shots: | 12-14 | | MoM: | Congré | | TV: | highlights |
| | 30 De Jong, 52 Kelly | | (4-3-3): Bailly 6, Träsch 7, Salcido 7, Gündogan 7½, Williamson 6½, Kelly 6½, Farfán 8, Costa 7, De Jong 6½, Crouch 6, Sturridge 5½ | | Lorient | 3 | 30 Morel, 54 Congré, 81 Jouffre |
| | (4-3-3): Audard 6, Congré 8½, Morel 6, Balmont 7 (66 Pied 7½), Marchal 7 (64 Jouffre 7), Mignot 6½, Amalfitano 7½, Birsa 8, Hoarau 7, Mvuemba 6, Sagbo 5½ | | Fiorentina | 0 |
| | Half-time: | 0-0 | | Referee: | Sedlacek 5½ | | Attendance: | 37,526 | | Possession: | 51%-49% | | Total shots: | 11-7 | | MoM: | Felipe | | TV: | highlights |
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| | (4-3-3): Forster 7½, De Silvestri 7½, Gobbi 7½, Montolivo 7½, Felipe 8, Comotto 5½, Marchionni 7, Cana 7, Gilardino 7, Altidore 5½, Ljajic 6 | | Napoli | 0 |
| | 10 Campagnaro, 65 Moretti, 81 Cannavaro, 83 De Sanctis | | (4-3-3): De Sanctis 7, Campagnaro 7, Moretti 7, Gargano 8, Ranocchia 7, Cannavaro 7, Necip 7½, Cigarini 7, Gignac 6½, Maiello 6, Quagliarella 6½ | | Hamburger SV | 0 |
| | Half-time: | 0-0 | | Referee: | Wieser 6½ | | Attendance: | 44,487 | | Possession: | 46%-54% | | Total shots: | 16-9 | | MoM: | Fritz |
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| | (4-3-3): Hakan 7½, Demel 7½, Jansen 7½, Rincón 7, Mathijsen 7, Rozehnal 7 (61 Mensah 7), Behrami 7, Aogo 6, Pavlyuchenko 6, Ebert 6, Petric 6 | | Bayer Leverkusen | 0 |
| | 27 Kadlec, 53 Zárate | | (4-3-3): Wiese 7, Piszczek 7½, Kadlec 7½, Cambiasso 6½, Schulz 7, Friedrich 7, Elano 7 (61 Fritz 7½), Castro 7½, Kuranyi 6½, Arango 6½, Zárate 5½ | | Juventus | 3 | 11 Mertesacker, 34 Berg, 89 Berg | | Half-time: | 2-0 | | Referee: | William 8½ | | Attendance: | 27,906 | | Possession: | 51%-49% | | Total shots: | 8-16 | | MoM: | Mertesacker |
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| | (4-3-3): Adler 7, Corluka 7, De Ceglie 7½, Felipe Melo 7½, Mertesacker 8, Bassong 7, Camoranesi 7½, Candreva 5½ (47 Palombo 6½), Berg 6½, Sigþórsson 6 (54 Afellay 6), Nenê 6 | | Aston Villa | 1 | 79 Heskey |
| | (4-3-3): Guzan 7½, Cuéllar 7 (77 Shorey 6), Clark 7½, Delph 6½, Collins 7½, Bouma 6½, Milner 7, Sidwell 7, Heskey 6½, Cirigliano 7, Agbonlahor 7 (85 Davies 6) | | Lyon | 0 |
| | Half-time: | 0-1 | | Referee: | Clattenburg 7 | | Attendance: | 40,471 | | Possession: | 46%-54% | | Total shots: | 6-11 | | MoM: | Semshov |
| | 69 Henry | | (4-3-3): Ruffier 7, Gassama 7 (84 Faure 6), Taiwo 6½, Grenier 6½, Escudé 6½, Coulibaly 6, Atik 7, Boussoufa 8, Belfodil 7, Éderson 6½, Henry 5½ | | Spartak | 1 | 28 Arshavin | | 53 Yakovlev | | (4-3-3): Shunin 7, Anyukov 7½, Kombarov 6½ (47 Komisov 6½), Semshov 8, Berezutsky 7, Suchý 6, Bazhenov 7, Arshavin 6½, Prudnikov 7, Mamaev 7½, Yakovlev 5½ | | Newcastle United | 1 | 2 Cavani | | Half-time: | 1-0 | | Referee: | Gvardis 6½ | | Attendance: | 52,322 | | Possession: | 43%-57% | | Total shots: | 10-12 | | MoM: | Lichtsteiner | | TV: | live |
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| | (4-5-1): Cech 7½, Godín 6, Rami 6½, Vidal 7, Hummels 6½, Verratti 6½, Götze 7, Hamsík 6½, Cavani 7½, João Moutinho 6½, Bale 6 | | FC Basel | 0 |
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| | (4-4-2): Weidenfeller 7, Lichtsteiner 8, Dante 7½, M'Vila 7½, Cahill 7½, Thiago Silva 6½, Willian 6½, Podolski 6, Soldado 7½, Isco 6½, Florenzi 7 | | SV Werder Bremen | 1 | 45+1 Dost | | Half-time: | 1-1 | | Referee: | Vassaras 7½ | | Attendance: | 40,616 | | Possession: | 44%-56% | | Total shots: | 9-18 | | MoM: | Cissokho |
| | 88 Diego Capel | | (4-3-3): Gabulov 7, Uchida 6½, Abdennour 6½, Hunt 6½, Pasanen 7, Prödl 6, Bargfrede 5½, Diego Capel 7, Dost 6½, Niemeyer 6½, Oar 5½ | | Auxerre | 1 | 10 Menez | | 18 Menez | | (4-3-3): Lloris 7, Danzé 7 (75 Isimat-Mirin 6), Cissokho 8, Capoue 7, Yanga-Mbiwa 6½, Ciani 6½, Briand 7½, Menez 7½, Libertazzi 6½, John 5½, Rémy 5½ | | VfB Stuttgart | 0 |
| | Half-time: | 0-1 | | Referee: | Jol 6 | | Attendance: | 45,248 | | Possession: | 44%-56% | | Total shots: | 14-11 | | MoM: | Mangala |
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| | (4-3-3): Ulreich 6, Hamit 7½, Boka 6, Kehl 7, Niedermeier 7, Osorio 7, Kuzmanovic 6½, Gebhart 7, Lewandowski 7 (80 Lanig 6), Aquilani 6, Cacau 5½ | | Nantes | 1 | 44 Payet |
| | (3-4-3): Mandanda 6½, Kaboul 7½, Mangala 8, Gonalons 6½, Toulalan 7 (88 Sissoko 6), Koscielny 6½, Alessandrini 7 (86 Niang 6), Payet 7, Gomis 7, Valbuena 6, Gouffran 6½ | | Round 2 | | Aston Villa | 1 | 1 Heskey | | Half-time: | 1-0 | | Referee: | Bosowski 7 | | Attendance: | 37,929 | | Possession: | 51%-49% | | Total shots: | 14-11 | | MoM: | Salvio |
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| | (4-3-3): Guzan 6½, Cuéllar 8, Clark 6½, Delph 7 (79 Davies 6), Collins 7, Bouma 6, Milner 7, Sidwell 6, Heskey 6½ (72 Reo-Coker 7½), Cirigliano 6½, Agbonlahor 5½ | | Atlético Madrid | 0 |
| | 70 Biglia | | (4-3-3): Sergio Asenjo 7, Mario 6½, Ismail 6, Biglia 6½, Rodríguez 6½, Garay 6½, Salvio 8, Koke 7, Borja 6, Banega 7, Tadic 6 | | Auxerre | 0 |
| | Half-time: | 0-2 | | Referee: | Dean 5 | | Attendance: | 24,986 | | Possession: | 39%-61% | | Total shots: | 13-9 | | MoM: | Verdú |
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| | (4-3-3): Lloris 6, Danzé 7, Cissokho 7½, Capoue 7, Yanga-Mbiwa 6½, Fanni 6, Briand 6½, Menez 7, Libertazzi 6½, John 6, Rémy 6 | | Espanyol | 3 | 8 Olic, 29 Hangeland, 86 Callejón |
| | (4-3-3): Kameni 6½, Motta 8, Pinto 7½, Ninkovic 6½ (54 McKenna 6), Hangeland 7, Roncaglia 6½, Callejón 7, Verdú 8, Corominas 7 (65 Marqués 7), Raúl Baena 6½, Olic 7 | | Bayer Leverkusen | 1 | 73og Farfán | | Half-time: | 0-0 | | Referee: | Franceschini 5½ | | Attendance: | 22,491 | | Possession: | 40%-60% | | Total shots: | 11-13 | | MoM: | Cambiasso |
| | 29 Friedrich, 67 Elano | | (4-3-3): Wiese 6, Piszczek 6½, Kadlec 7, Cambiasso 8, Schulz 6½, Friedrich 6½, Elano 6½, Castro 6½ (62 Kakuta 6½), Kuranyi 7, Rakitic 6½, Zárate 5½ | | FC Schalke 04 | 1 | 51 Schmitz | | 1 Hugo Almeida, 77 Rausch | | (4-3-3): Bailly 8, Träsch 7 (52 Badibanga 7½), Schmitz 7½, Gündogan 6½, Reinartz 7½, Salcido 6½, Farfán 7, Rausch 6½, De Jong 7, Hugo Almeida 5½, Sturridge 6½ | | FC Basel | 3 | 14 Soldado, 24 Soldado, 27p Thiago Silva | | Half-time: | 3-1 | | Referee: | Nielsen 5½ | | Attendance: | 38,318 | | Possession: | 53%-47% | | Total shots: | 22-7 | | MoM: | Soldado |
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| | (4-4-2): Weidenfeller 6½, Lichtsteiner 7½, Dante 8, M'Vila 7½, Cahill 7, Thiago Silva 6, Willian 7½, Podolski 7, Soldado 8, Isco 7, Florenzi 7 | | Everton | 1 | 7 Bilyaletdinov |
| | (4-3-3): Howard 6½, Yobo 7, Braafheid 7½, Wallace 6½, Agard 6, Hibbert 5½, Osman 6½, Bilyaletdinov 6½, Yakubu 6½, Anichebe 5½, Baxter 6½ | | Lorient | 2 | 19 Sagbo, 28 Mvuemba | | Half-time: | 2-0 | | Referee: | Meese 5½ | | Attendance: | 15,716 | | Possession: | 46%-54% | | Total shots: | 13-8 | | MoM: | Congré |
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| | (4-3-3): Audard 6½, Congré 8, Morel 7½, Balmont 7 (66 Pied 7½), Marchal 6 (64 Jouffre 6), Mignot 6, Amalfitano 6, Birsa 6½, Hoarau 7½, Mvuemba 6½, Sagbo 6 | | VfB Stuttgart | 1 | 46 Lewandowski |
| | (4-3-3): Ulreich 7½, Hamit 7, Boka 8, Kehl 7½, Niedermeier 7, Osorio 6½, Kuzmanovic 7½, Gebhart 6½, Lewandowski 7 (80 Lanig 6), Aquilani 7, Cacau 6 | | Nantes | 2 | 31 Payet, 82 Payet | | Half-time: | 1-0 | | Referee: | Brito Arceo 7½ | | Attendance: | 37,289 | | Possession: | 47%-53% | | Total shots: | 21-7 | | MoM: | Gonalons |
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| | (3-4-3): Mandanda 7½, Kaboul 7, Mangala 6½, Gonalons 8, Toulalan 6½ (88 Sissoko 6), Koscielny 6½, Alessandrini 6 (86 Niang 6), Payet 8, Gomis 6½, Valbuena 7, Gouffran 7½ | | Juventus | 0 |
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| | (4-3-3): Adler 8, Corluka 7½, De Ceglie 7, Felipe Melo 7½, Mertesacker 7, Bassong 7 (46 Sørensen 6), Camoranesi 6½, Candreva 6, Berg 7, Sigþórsson 6, Nenê 5½ | | Napoli | 2 | 18 Gignac, 76 Quagliarella | | Half-time: | 1-1 | | Referee: | Hagernäs 7 | | Attendance: | 45,989 | | Possession: | 56%-44% | | Total shots: | 15-11 | | MoM: | Campagnaro |
| | 1 Gignac, 80 De Sanctis | | (4-3-3): De Sanctis 6½, Campagnaro 8, Moretti 8, Gargano 7½, Cannavaro 7½, Ranocchia 6½, Necip 7½, Cigarini 6½, Gignac 6½, Pazienza 7, Quagliarella 6 | | Hamburger SV | 1 | 44 Petric |
| | (4-3-3): Hakan 7, Demel 6½, Aogo 6½, Trochowski 6½, Mathijsen 6½, Rozehnal 6½, Behrami 6, Jansen 6, Pavlyuchenko 6, Rincón 6, Petric 6 | | River Plate | 3 | 8 Rosický, 24 Buonanotte, 30 López | | Half-time: | 3-0 | | Referee: | Circhetta 6½ | | Attendance: | 39,831 | | Possession: | 55%-45% | | Total shots: | 17-12 | | MoM: | Gobbi |
| | 47 Castillejos, 84 Formica, 90 López | | (4-3-3): Ospina 6½, López 7½, Rojo 7½, Buonanotte 7, Cabral 6, Orban 6½, Formica 7, Rosický 5½ (53 Cicinho 7½), López 7, Castillejos 5½, Mouche 5½ | | Fiorentina | 2 | 48 Gobbi, 86 Gobbi |
| | (4-3-3): Forster 6, De Silvestri 7, Gobbi 8, Montolivo 8, Felipe 7, Comotto 7, Marchionni 6½, Cana 6, Gilardino 6½, Altidore 6, Ljajic 6 | | Sevilla | 0 |
| | Half-time: | 0-1 | | Referee: | Karlsson 6 | | Attendance: | 44,908 | | Possession: | 46%-54% | | Total shots: | 13-10 | | MoM: | Godín |
| | 77 Kiessling | | (4-3-3): Carrizo 6, Fernández 7, Filipe Luis 6½, Raul Meireles 7½, Alexis 7, Naldo 6½, Kiko 7½, Luscombe 7 (66 Squillaci 6), Kiessling 7½, Makoun 7 (75 Silvestre 6), Negredo 6½ | | Newcastle United | 2 | 2 Cavani, 49 Bale |
| | (4-5-1): Cech 6, Godín 7½, Rami 6½, Vidal 7, Hummels 6½, Verratti 6, Götze 7, Hamsík 7½, Cavani 7, João Moutinho 7, Bale 7½ | | Spartak | 0 |
| | Half-time: | 0-1 | | Referee: | Rosetti 7 | | Attendance: | 48,506 | | Possession: | 46%-54% | | Total shots: | 11-8 | | MoM: | Berezutsky |
| | 3 Berezutsky, 14 Suchý, 57 Pogrebnyak, 81 Zhirkov | | (4-3-3): Shunin 6, Anyukov 6½, Kombarov 7½, Mamaev 7 (62 Berezutsky 7½), Berezutsky 7½, Suchý 7, Bazhenov 6½, Arshavin 6½, Pogrebnyak 6, Zhirkov 6, Yakovlev 6 | | SV Werder Bremen | 2 | 4p Dost, 48 Dost | | 68 Dost | | (4-3-3): Gabulov 6½, Uchida 6½, Abdennour 6½, Hunt 7½, Pasanen 6½, Prödl 7, Bargfrede 7, Diego Capel 7½, Dost 6½, Niemeyer 7, Oar 6 | | TSG Hoffenheim | 0 |
| | Half-time: | 0-0 | | Referee: | Levnikov 6 | | Attendance: | 30,126 | | Possession: | 44%-56% | | Total shots: | 13-10 | | MoM: | Luis Gustavo |
| | 13 Ebondo | | (4-3-3): Consigli 7, Ebondo 6½, Simunic 7½, Luis Gustavo 7½, Ruíz 7, Vorsah 5½, Vukcevic 7, Salihovic 7, Ibisevic 7 (73 Owomoyela 7), Ba 6½, Luis García 6½ | | Lyon | 1 | 86 Boussoufa |
| | (4-3-3): Ruffier 6½, Gassama 7, Taiwo 6, Grenier 6, Escudé 7½, Coulibaly 5½, Atik 6½ (69 Faure 7), Boussoufa 7½, Belfodil 7 (84 Tiéné 6), Éderson 6½, Henry 6 |
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