Round 3 | Barcelona | 2 | 27 Iniesta, 88 Ibrahimovic | Half-time: | 1-0 | Referee: | Rennie 5½ | Attendance: | 59,135 | Possession: | 61%-39% | Total shots: | 23-6 | MoM: | Maxwell | TV: | highlights |
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| (4-3-3): Pinto 7, Bartra 8, Maxwell 8, Xavi 8, Mexès 6½, Skrtel 7 (72 Toivonen 6), Isaac Cuenca 6 (53 Wijnaldum 7½), Iniesta 7½, Ibrahimovic 8, Fabregas 8, Vílla 6½ | Palmeiras | 0 |
| 2 Robert, 40 Higuaín, 63 Ewerthon, 86 Sandro | (4-3-3): Júlio César 7, Figueroa 6½, Rafael Toloi 6 (73 Sandro 6), Lucas 7, Danilo 6, Edinho 6, Diego Souza 6½, Pierre 5½, Higuaín 7, Robert 5½, Ewerthon 5½ | Bayern München | 1 | 50 Demichelis | Half-time: | 0-1 | Referee: | Collina 5½ | Attendance: | 44,596 | Possession: | 51%-49% | Total shots: | 11-11 | MoM: | Milevskyi |
| 10 Anelka, 68 Essien | (4-3-3): Andújar 6, Essien 6½, Pranjic 6, Pogba 6½, Demichelis 6½, Lovren 6½, Diaby 6, Marin 7, Klose 7, Ignjovski 7, Anelka 6½ | Dynamo | 1 | 16 Milevskyi | 8 Zyryanov, 13 Yarmolenko | (4-3-3): Carrasso 7, Mykhalyk 7, Nesmachnyi 7, Zyryanov 6, Tymoschuk 6½, Vida 5½, Bystrov 6½, Pienaar 7, Milevskyi 7½, Granero 6, Yarmolenko 7 | Benfica | 1 | 39 Drogba | Half-time: | 1-0 | Referee: | Piraux 7½ | Attendance: | 43,375 | Possession: | 49%-51% | Total shots: | 13-13 | MoM: | Maicon | TV: | highlights |
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| (4-3-3): Eduardo 7½, Pereira 7½, Eliseu 6, Carlos Martins 7½, Maicon 8, Ricardo Carvalho 7, Taddei 6½, Cleiton Xavier 7½, Drogba 7½, Cardozo 6, Alex 5½ | Feyenoord | 0 |
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| (4-3-3): Mulder 7½, De Vrij 7 (59 Danquah 6), De Cler 7½, Maduro 7, Vlaar 6½, Pieters 6½, Kuyt 6½, Weijl 6, Van Wolfswinkel 6½, Castaignos 6, Biseswar 6½ | Liverpool | 0 |
| Half-time: | 0-2 | Referee: | Strampe 5½ | Attendance: | 44,142 | Possession: | 44%-56% | Total shots: | 8-17 | MoM: | Kroos |
| 6 Touré | (4-3-3): Pyatov 6, Taylor 7½, Johnson 7½, Touré 7, Alex 6½, Ramsey 6½, Badelj 6½, Nolan 6, Huntelaar 7, Carroll 6, Németh 5½ | Borussia Dortmund | 3 | 4 Nasri, 8 Schmelzer, 65 Nasri |
| (4-3-3): Neuer 6½, Schwaab 6, Schmelzer 7, Kroos 8, Subotic 7, Höwedes 7, Khedira 7, Nasri 7, Jovetic 7½, Bender 7, Vucinic 6½ | Real Madrid | 2 | 14 Messi, 21 Silva | Half-time: | 2-0 | Referee: | Kefalas 6 | Attendance: | 77,674 | Possession: | 59%-41% | Total shots: | 12-7 | MoM: | Sergio Ramos | TV: | live |
| 9 Van Persie, 45+1 Kompany, 69 Santi | (4-3-3): Casillas 6½, Sergio Ramos 8, Badstuber 7½, Xabi Alonso 7, Chiellini 7½, Kompany 6½, Silva 7½, Santi 7, Van Persie 6½, Ronaldo 7½, Messi 7 | Anderlecht | 2 | 48 Pocognoli, 53 Maggio |
| (4-3-3): Proto 6, Maggio 6½, Pocognoli 7, Dembélé 6, Chedjou 6½, Chyhrynskyi 6, Taylor 6½, Shaqiri 6½, Kerzhakov 6, Rolfes 6, Jonas 6½ | Tottenham Hotspur | 1 | 56 Cassano | Half-time: | 0-1 | Referee: | Reijgwart 7½ | Attendance: | 36,146 | Possession: | 47%-53% | Total shots: | 11-11 | MoM: | Cole |
| 53 Modric | (4-3-3): Víctor Valdés 6, Walker 7, Cole 7½, Schweinsteiger 7, Ferdinand 7½, Cáceres 5½, Foor 6½, Nani 7, Wickham 6, Modric 7, Cassano 7½ | Athletic Bilbao | 2 | 45+1 Traoré, 72 Eduardo |
| (4-3-3): Aranzubía 6½, Iraola 7½, Aurtenetxe 6½, Raúl García 7½, Torres 6, Botía 6, Jurado 6, Traoré 7, Eduardo 7, Mario Suárez 6½, Vela 6½ | Valencia | 3 | 2 Hernández, 11 Puyol, 90+1 Arbeloa | Half-time: | 2-0 | Referee: | Constantin 5½ | Attendance: | 59,881 | Possession: | 55%-45% | Total shots: | 15-12 | MoM: | Pastore |
| 16 Hernández, 16 Vargas | (4-3-3): Reina 7½, Lahm 7½, Vargas 7, Van Der Vaart 7½, Mascherano 7½, Puyol 6½, Javi Martínez 6½ (79 Perotti 6), Pastore 8, Hernández 5½ (54 Arbeloa 7), Llorente 6, Henríquez 6 | Internacional | 1 | 69 Evaldo | 22 Júlio Baptista | (4-3-3): Rafael 7, Mariano 7, Evaldo 7, Sandro 7, Hilton 7, Marcelo 6½, Giuliano 6½, Fernando 6, Jô 6½, Júlio Baptista 6, Taison 7 | Round 4 | Anderlecht | 1 | 85 Shaqiri | Half-time: | 0-1 | Referee: | Young 6½ | Attendance: | 28,031 | Possession: | 43%-57% | Total shots: | 15-11 | MoM: | Taylor |
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| (4-3-3): Proto 6, Maggio 6½, Pocognoli 7, Dembélé 7, Chedjou 6½, Kouyaté 6½, Taylor 7½, Shaqiri 7, Kerzhakov 5½, Lukaku 6, Jonas 6½ (64 Mollo 6) | Barcelona | 2 | 45+2 Iniesta, 68 Di María |
| (4-3-3): Pinto 7, Bartra 6½, Lescott 6½, Xavi 7 (54 Fontás 7½), Skrtel 7½, Mexès 6½, Isaac Cuenca 7, Iniesta 7½, Ibrahimovic 7 (52 Di María 6½), Fabregas 6½, Vílla 6½ | Borussia Dortmund | 1 | 76 Khedira | Half-time: | 0-1 | Referee: | Baldassarri 6½ | Attendance: | 65,543 | Possession: | 46%-54% | Total shots: | 10-11 | MoM: | Schmelzer | TV: | live |
| 25 Vucinic | (4-3-3): Neuer 5½, Schwaab 6½, Schmelzer 8½, Kroos 8, Subotic 6½ (69 Hartherz 7), Höwedes 6, Jovetic 6½, Nasri 7½, Schürrle 7, Khedira 6½, Vucinic 7 | Lazio | 2 | 34 Defoe, 80 Ilicic |
| (4-3-3): Stekelenburg 6, Bonera 8½, Pasqual 7½, Nocerino 7½, Radu 6½, Ariaudo 6½, Schelotto 6½, Ilicic 6½, Defoe 6½, Matri 6½ (76 Obi 6), Di Vaio 6½ | Dynamo | 3 | 14 Milevskyi, 31 Milevskyi, 72 Milevskyi | Half-time: | 2-2 | Referee: | Sarvan 7 | Attendance: | 47,865 | Possession: | 52%-48% | Total shots: | 17-10 | MoM: | Nesmachnyi | TV: | highlights |
| 6 Pienaar, 16 Bystrov | (4-3-3): Carrasso 6½, Mykhalyk 7½, Nesmachnyi 7½, Zyryanov 7, Tymoschuk 6½, Vida 6, Bystrov 7, Pienaar 7, Milevskyi 7, Granero 7, Yarmolenko 7 | Liverpool | 3 | 38 Huntelaar, 43 Ramsey, 46 Huntelaar |
| (4-3-3): Pyatov 6, Taylor 6½, Johnson 7 (69 Aleksic 6), Touré 7½, Alex 6½, Insúa 6½, Badelj 7, Saric 5½, Huntelaar 7½, Ramsey 7 (50 Vrsaljko 7), Németh 5½ | Feyenoord | 0 |
| Half-time: | 0-2 | Referee: | Van Der Ende 7½ | Attendance: | 35,744 | Possession: | 45%-55% | Total shots: | 11-14 | MoM: | Fellaini |
| 60 Van Wolfswinkel | (4-3-3): Mulder 5½, De Vrij 7, De Cler 7 (77 Fer 6), Maduro 7½, Vlaar 7½, Pieters 6½, Kuyt 6½, Weijl 5½, Van Wolfswinkel 6½, Castaignos 6, Biseswar 6½ | Cruz Azul | 2 | 4 De Marcos, 40 Suárez |
| (4-3-3): Iraizoz 7, João Pereira 6½ (55 Paco Alcácer 7), Pereira 7, Fellaini 8, Jagielka 7, Samuel 6½, Insigne 5½, De Marcos 7½, Jelavic 7, Torrado 7, Suárez 7 | Internacional | 1 | 63 Jô | Half-time: | 0-1 | Referee: | Michel 6 | Attendance: | 44,942 | Possession: | 47%-53% | Total shots: | 10-12 | MoM: | Sakho |
| 45 Jô, 62 Taison | (4-3-3): Rafael 5½, Mariano 6½, Evaldo 7, Sandro 7, Hilton 6½, Marcelo 6½, Giuliano 6½, Fernando 6, Jô 6½, Júlio Baptista 6½ (64 Marquinhos Gabriel 7), Taison 6 | Marseille | 3 | 22 Ribéry, 69 Ribéry, 75 Brandão |
| (4-3-3): Hart 6, Reveillère 7, Sakho 8, Ben Arfa 7 (50 Bonnart 7), Heinze 7½, Richarlyson 7, González 7, Ribéry 7½, Brandão 7, Rodwell 6½, Benzema 7 | Manchester City | 2 | 18 Rooney, 83 Özil | Half-time: | 1-0 | Referee: | Levnikov 7 | Attendance: | 45,746 | Possession: | 53%-47% | Total shots: | 18-16 | MoM: | Piqué |
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| (4-3-3): Buffon 7, Song 6 (77 Inler 6), Vertonghen 6, Pirlo 7½, Piqué 8, Rolando 6, Herrmann 6½, Özil 7½, Vydra 7, Marchisio 6½, Rooney 6½ | Tottenham Hotspur | 0 |
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| (4-3-3): Víctor Valdés 7, Walker 7½, Cole 7½, Schweinsteiger 7½, Ferdinand 7, Cáceres 5½, Foor 6½, Nani 7½, Wickham 6, Modric 7, Cassano 6½ | Manchester United | 0 |
| Half-time: | 0-1 | Referee: | Borgersen 6 | Attendance: | 49,650 | Possession: | 51%-49% | Total shots: | 15-10 | MoM: | Evans |
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| (4-3-3): Foster 6, Richards 7, Evrà 7½, Carrick 6½, Evans 7½, O'Shea 7, Fletcher 7½, Obertan 7½, Berbatov 7, Anderson 6½, Welbeck 6 | Celtic | 3 | 35 McGeady, 63 McGeady, 70 José Ángel | 81 Cissé | (4-3-3): Boruc 6, Cherundolo 7½, José Ángel 7, Cahill 6, Rogne 6½ (77 Mlapa 6½), Kure 6, Henderson 6½, McGeady 7, Cissé 7, Hooper 5½, Keane 6 | São Paulo | 3 | 1 Willian, 9 Ramires, 18 Maicon | Half-time: | 3-0 | Referee: | Gumienny 5½ | Attendance: | 41,904 | Possession: | 53%-47% | Total shots: | 22-12 | MoM: | Maicon |
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| (4-3-3): Hélton 7½, Maicon 7½, Marcelo 6½, Hernanes 7, David Luiz 6½, Lúcio 6, Ramires 6½, Hulk 7, Willian 5½ (57 Lucas 6), Robinho 7½, Neymar 6½ | Benfica | 0 |
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| (4-3-3): Eduardo 7, Pereira 7, Eliseu 6½, Carlos Martins 6½, Maicon 7, Ricardo Carvalho 6, Taddei 7, Cleiton Xavier 6½, Drogba 7, Cardozo 5½, Alex 6 | West Ham United | 1 | 59 Johnson | Half-time: | 0-2 | Referee: | Riley 6 | Attendance: | 34,442 | Possession: | 44%-56% | Total shots: | 15-12 | MoM: | Badstuber |
| 9 Green, 11 Oxlade-Chamberlain, 53 Baines | (4-3-3): Green 6, Jones 7, Baines 6, Gerrard 7½, Terry 7, Samba 6½ (55 Wilshere 6½), Walcott 7, Johnson 6½, Bent 6½, Parker 5½, Oxlade-Chamberlain 6 | Real Madrid | 2 | 39 Messi, 45+1 Messi |
| (4-3-3): Casillas 7, Sergio Ramos 8, Badstuber 8, Xabi Alonso 7, Chiellini 7½, Kompany 6½, Silva 6½, Santi 7, Van Persie 7½, Ronaldo 6½, Messi 7 |
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