| Round 3 | | Everton | 1 | 11 Braafheid | | Half-time: | 1-1 | | Referee: | Larsen 7 | | Attendance: | 34,332 | | Possession: | 56%-44% | | Total shots: | 14-12 | | MoM: | Braafheid |
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| | (4-3-3): Howard 7, Lowton 6½, Braafheid 8, Wallace 6½, Agard 6½, Hibbert 6, Osman 6½, Bilyaletdinov 7½, Anichebe 6½, Yakubu 7, Baxter 5½ | | River Plate | 1 | 15 Buonanotte | | 33 Mouche, 63 Buonanotte | | (4-3-3): Ospina 7, Ferrari 6½, Rojo 6½, Prediguer 7½, López 7½, Cabral 6½, Formica 7, Amrabat 7½, Castillejos 6½, Buonanotte 7, Mouche 5½ | | Fiorentina | 3 | 26 Gilardino, 75p Gilardino, 80 Marchionni | | Half-time: | 1-1 | | Referee: | Sedlacek 7½ | | Attendance: | 35,733 | | Possession: | 49%-51% | | Total shots: | 18-9 | | MoM: | Montolivo |
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| | (4-3-3): Seculin 6, De Silvestri 7½, Gobbi 7, Montolivo 8, Felipe 6½, Camporese 6, Marchionni 7, Cana 5½ (53 Comotto 6½), Gilardino 7½, Altidore 6, Mutu 6 | | Auxerre | 3 | 29 John, 52 Cissokho, 59 Danzé |
| | (4-3-3): Lloris 5½, Danzé 8, Cissokho 7, Capoue 6½, Yanga-Mbiwa 6½, Fanni 7, Briand 8, Menez 7, Libertazzi 6½, John 5½, Rémy 7½ | | Newcastle United | 2 | 12 João Moutinho, 15 Müller | | Half-time: | 2-1 | | Referee: | Cinciripini 6½ | | Attendance: | 52,372 | | Possession: | 51%-49% | | Total shots: | 20-12 | | MoM: | Ruíz | | TV: | highlights |
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| | (4-5-1): Cech 7, Dani Alves 8, Jordi Alba 7, Vidal 7, Hummels 6½, Godín 6, Müller 7½, Hamsík 7, Cavani 6½, João Moutinho 6½, Bale 6½ | | TSG Hoffenheim | 1 | 29 Salihovic | | 49 Salihovic, 72 Vukcevic | | (4-3-3): Consigli 7, Ebondo 7, Simunic 6½, Luis Gustavo 7, Ruíz 8, Vorsah 6½, Vukcevic 6½, Salihovic 6, Ibisevic 6½, Ba 6, Luis García 6 | | Round 4 | | Aston Villa | 2 | 5 Milner, 23 Agbonlahor | | Half-time: | 2-0 | | Referee: | Cardona 5½ | | Attendance: | 40,302 | | Possession: | 53%-47% | | Total shots: | 13-15 | | MoM: | Delph |
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| | (4-3-3): Guzan 8½, Cuéllar 7, Clark 8, Delph 8½, Collins 7, Bouma 6½, Milner 6 (60 Dunne 7), Sidwell 6, Heskey 6½, Cirigliano 6, Agbonlahor 7 | | FC Schalke 04 | 0 |
| | 47 Rausch, 66 Bailly | | (4-3-3): Bailly 7, Träsch 7, Schmitz 6, Gündogan 7, Reinartz 5½, Salcido 6½, Farfán 7 (77 Badibanga 6), Rausch 7, De Jong 6, Hugo Almeida 5½, Sturridge 7 | | Auxerre | 0 |
| | Half-time: | 0-0 | | Referee: | Pyanikh 7½ | | Attendance: | 25,011 | | Possession: | 53%-47% | | Total shots: | 8-13 | | MoM: | Danzé | | TV: | highlights |
| | 26 Libertazzi | | (4-3-3): Lloris 7½, Danzé 8½, Cissokho 8, Capoue 7½, Yanga-Mbiwa 6, Fanni 6½, Briand 7½, Menez 7½, Libertazzi 6½, John 5½, Rémy 6½ | | Everton | 0 |
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| | (4-3-3): Howard 8, Lowton 7, Braafheid 7, Wallace 7, Agard 6½, Hibbert 6, Osman 7, Bilyaletdinov 7, Anichebe 7½, Yakubu 6, Baxter 6 | | Bayer Leverkusen | 1 | 2 Helmes | | Half-time: | 1-0 | | Referee: | Detruche 6 | | Attendance: | 22,467 | | Possession: | 57%-43% | | Total shots: | 15-5 | | MoM: | Piszczek |
| | 55 Elano | | (4-3-3): Wiese 7, Piszczek 8, Kadlec 6½, Castro 8, Schulz 6½ (86 Friedrich 6), Díaz 7, Elano 6½, Arango 7½, Helmes 7½, Rakitic 7, Zárate 6 | | Atlético Madrid | 1 | 85 Rodríguez | | 18 Salvio, 80 Garay | | (4-3-3): Sergio Asenjo 7½, Mario 6, Ismail 7½, Biglia 7, Rodríguez 7, Garay 6½, Salvio 6½, Koke 7, Borja 6, Banega 6, Tadic 5½ | | FC Basel | 5 | 3 Podolski, 15 Cahill, 25 Isco, 39 Soldado, 44 Isco | | Half-time: | 5-0 | | Referee: | Wiley 6½ | | Attendance: | 38,438 | | Possession: | 43%-57% | | Total shots: | 14-17 | | MoM: | Dante | | TV: | live |
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| | (4-4-2): Weidenfeller 6½, Lichtsteiner 7½, Dante 7½, Matuidi 7½, Cahill 6½, Thiago Silva 6, Willian 7½, Podolski 7, Soldado 7½, Isco 7, Mkhitaryan 6½ | | Espanyol | 2 | 69 Verdú, 87 Motta |
| | (4-3-3): Kameni 6½, Motta 6½, Pinto 6½, Raúl Baena 7½, Roncaglia 7, Pareja 6½, Callejón 6½, Verdú 6, Tamudo 7 (72 David García 6), Javi Márquez 6, Olic 7 (56 Sahar 5½) | | Lorient | 3 | 15 Hoarau, 61 Morel, 80 Amalfitano | | Half-time: | 1-0 | | Referee: | Bazzoli 6 | | Attendance: | 15,864 | | Possession: | 57%-43% | | Total shots: | 16-11 | | MoM: | Hoarau | | TV: | highlights |
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| | (4-3-3): Audard 7, Congré 8, Morel 8, Balmont 6½ (66 Pied 7½), Marchal 5½ (64 Jouffre 7½), Mignot 6½, Amalfitano 7, Birsa 7, Hoarau 8½, Mvuemba 7, Sagbo 5½ | | Fiorentina | 0 |
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| | (4-3-3): Avramov 7, De Silvestri 6, Gobbi 7 (59 Bolatti 6½), Montolivo 7½, Felipe 6½, Camporese 6½, Marchionni 6½, Cana 6, Gilardino 6, Altidore 6, Mutu 5½ | | Nantes | 2 | 61 Gomis, 80 Alessandrini | | Half-time: | 0-0 | | Referee: | Hansson 6½ | | Attendance: | 37,333 | | Possession: | 44%-56% | | Total shots: | 16-8 | | MoM: | Hakan |
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| | (3-4-3): Mandanda 7, Kaboul 6½, Mangala 7, Sissoko 8, Gonalons 6½ (88 Guilavogui 6), Koscielny 6½, Alessandrini 6 (86 Niang 6), Payet 7½, Gomis 6½, Valbuena 6½, Gouffran 5½ | | Hamburger SV | 0 |
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| | (4-3-3): Hakan 8, Demel 7½, Jansen 6½, Trochowski 7½, Mathijsen 6½ (49 Torun 6½), Cichero 6, Behrami 7, Aogo 7, Pavlyuchenko 6, Rincón 7, Petric 6½ | | Napoli | 0 |
| | Half-time: | 0-1 | | Referee: | Dowd 7 | | Attendance: | 53,417 | | Possession: | 52%-48% | | Total shots: | 13-11 | | MoM: | El Kaoutari |
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| | (4-3-3): De Sanctis 6½, Campagnaro 7, El Kaoutari 7½, Gargano 7, Cannavaro 6, Ranocchia 6, Necip 6½, Cigarini 6½, Gignac 7½, Pazienza 6½, Quagliarella 6½ | | Lyon | 1 | 10 Escudé | | 20 Belfodil, 85 Tiéné | | (4-3-3): Ruffier 7, Gassama 7 (63 Marveaux 7), Taiwo 5½, Grenier 6 (83 Tiéné 6), Escudé 6½, Coulibaly 6½, Atik 6½, Boussoufa 6½, Belfodil 6½, Éderson 6½, Henry 6½ | | Sevilla | 3 | 6 Negredo, 8 Negredo, 89 Negredo | | | 37 Makoun, 38 Kiessling | | (4-3-3): Carrizo 5½, Fernández 6½, Filipe Luis 7, Raul Meireles 7½, Alexis 7½, Naldo 6, Kiko 7, Luscombe 5½ (66 Squillaci 6), Kiessling 7, Makoun 6½ (75 Silvestre 6), Negredo 6½ | | VfB Stuttgart | 3 | 23 Lewandowski, 27 Cacau, 31 Cacau |
| | (4-3-3): Ulreich 5½, Hamit 7, Boka 6 (90 Orbáiz 6), Aquilani 7, Niedermeier 7, Osorio 6, Kuzmanovic 8, Gebhart 6½, Lewandowski 7, Kehl 6½, Cacau 6 | | Spartak | 1 | 40 Arshavin | | Half-time: | 1-1 | | Referee: | Coué 6 | | Attendance: | 36,967 | | Possession: | 43%-57% | | Total shots: | 9-14 | | MoM: | Kombarov |
| | 5 Arshavin, 72 Zhirkov | | (4-3-3): Shunin 6, Anyukov 7, Kombarov 8, Mamaev 7, Berezutsky 6½, Suchý 6½, Bazhenov 6, Arshavin 7½, Pogrebnyak 7½, Zhirkov 6, Yakovlev 6½ | | Juventus | 1 | 30 Afellay |
| | (4-3-3): Adler 7, Sørensen 7, De Ceglie 6, Felipe Melo 7½, Mertesacker 7½, Legrottaglie 6½, Camoranesi 7½, Candreva 7, Berg 6, Afellay 6, Nenê 5½ | | TSG Hoffenheim | 0 |
| | Half-time: | 0-0 | | Referee: | Vorjas 6½ | | Attendance: | 30,140 | | Possession: | 45%-55% | | Total shots: | 15-6 | | MoM: | Luis Gustavo |
| | 37 Ibisevic, 59 Luis García | | (4-3-3): Consigli 7½, Ebondo 6, Simunic 6½, Luis Gustavo 8, Ruíz 7½, Vorsah 6, Vukcevic 6, Salihovic 7, Ibisevic 7 (73 Owomoyela 6), Ba 6, Luis García 6½ | | SV Werder Bremen | 0 |
| | 23 Niemeyer, 56 Oar | | (4-3-3): Gabulov 7½, Uchida 7½, Abdennour 7, Hunt 7½, Pasanen 7, Prödl 6½, Bargfrede 7½, Diego Capel 7, Dost 6½, Niemeyer 6½, Oar 5½ |
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