| Round 5 | | Barcelona | 0 |
| | Half-time: | 0-0 | | Referee: | Van Der Ende 7 | | Attendance: | 72,604 | | Possession: | 58%-42% | | Total shots: | 14-8 | | MoM: | Skrtel | | TV: | live |
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| | (4-3-3): Pinto 7, Bartra 7, Lescott 7½, Xavi 7 (64 Toivonen 7), Skrtel 7½, Mexès 7, Isaac Cuenca 7, Iniesta 6½, Ibrahimovic 7½, Fabregas 7½, Vílla 7 | | Manchester City | 1 | 54 Vertonghen | | 70 Hazard | | (4-3-3): Buffon 7, Song 5½, Vertonghen 7½, Pirlo 7, Piqué 7, Rolando 6½, Herrmann 6½, Özil 7, Vydra 5½, Marchisio 6, Rooney 7 (47 Hazard 6) | | Bayern München | 4 | 15 Klose, 35 Pranjic, 59 Ignjovski, 75 Klose | | Half-time: | 2-0 | | Referee: | Bazzoli 6½ | | Attendance: | 42,310 | | Possession: | 51%-49% | | Total shots: | 18-10 | | MoM: | Klose |
| | 5 Ignjovski | | (4-3-3): Andújar 7½, Essien 6, Pranjic 6½, Pogba 7½, Demichelis 7, Lovren 5½, Diaby 7½, Marin 6, Klose 8, Ignjovski 6, Anelka 7½ | | Internacional | 0 |
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| | (4-3-3): Rafael 7, Mariano 6½, Evaldo 6½, Sandro 6, Hilton 7, Marcelo 5½, Giuliano 7½, Fernando 6, Jô 7, Júlio Baptista 6½, Taison 6½ | | Benfica | 0 |
| | Half-time: | 0-0 | | Referee: | Nielsen 7 | | Attendance: | 44,315 | | Possession: | 51%-49% | | Total shots: | 19-18 | | MoM: | Drogba |
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| | (4-3-3): Eduardo 6, Pereira 7½, Eliseu 6, Carlos Martins 7, Maicon 7, Ricardo Carvalho 6½, Taddei 7, Cleiton Xavier 6½, Drogba 8, Cardozo 6½, Alex 5½ | | Palmeiras | 2 | 55og Carlos Martins, 86 Pierre |
| | (4-3-3): Júlio César 6½, Figueroa 7, Edinho 7, Lucas 7, Danilo 7 (54 Maurício Ramos 7½), Rafael Toloi 6½, Diego Souza 6½, Pierre 7½, Higuaín 7, Robert 6, Ronaldinho 6 | | Celtic | 0 |
| | Half-time: | 0-1 | | Referee: | Uilenberg 7½ | | Attendance: | 45,654 | | Possession: | 57%-43% | | Total shots: | 19-15 | | MoM: | Cherundolo |
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| | (4-3-3): Boruc 6½, Cherundolo 8½, José Ángel 7½, Cahill 7½, Rogne 6½, Kure 6½, Henderson 7, McGeady 7, Cissé 7, Hooper 6½, Keane 7½ | | Dynamo | 1 | 29 Milevskyi | | 57 Milevskyi | | (4-3-3): Carrasso 7, Vida 6½, Nesmachnyi 7½, Tymoschuk 8, Khacheridi 6, Mykhalyk 6½, Bystrov 6½, Blanco 6, Milevskyi 6½, Harmash 6, Zozulya 6 | | Cruz Azul | 1 | 64 Suárez | | Half-time: | 0-1 | | Referee: | Alves Azevedo 8 | | Attendance: | 35,839 | | Possession: | 47%-53% | | Total shots: | 9-12 | | MoM: | Nasri | | TV: | highlights |
| | 50 Jelavic, 77 Jelavic | | (4-3-3): Iraizoz 6, João Pereira 7, Pereira 7½, Fellaini 7½, Jagielka 6½, Samuel 6½, Insigne 6, De Marcos 7, Jelavic 6½, Torrado 6, Suárez 7½ | | Borussia Dortmund | 2 | 12 Nasri, 73 Vucinic |
| | (4-3-3): Neuer 6, Schwaab 6, Schmelzer 7, Kroos 6½, Subotic 7, Höwedes 5½, Jovetic 6½, Nasri 8, Schürrle 7 (83 Draxler 6), Khedira 6½, Vucinic 7 | | Lazio | 1 | 8 Ilicic | | Half-time: | 1-1 | | Referee: | Khussainov 5½ | | Attendance: | 43,766 | | Possession: | 48%-52% | | Total shots: | 19-12 | | MoM: | Bonera |
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| | (4-3-3): Stekelenburg 6½, Bonera 8, Pasqual 6½, Nocerino 6½ (67 Antonelli 7), Radu 7½, Ariaudo 6, Schelotto 6½, Ilicic 6½ (66 Obi 7), Defoe 7, Matri 6½, Di Vaio 6 | | Anderlecht | 1 | 4 Shaqiri |
| | (4-3-3): Malafeev 7, Maggio 6, Pocognoli 7½, Dembélé 6½ (85 Legear 6), Chedjou 7, Chyhrynskyi 6, Taylor 7, Shaqiri 7, Kerzhakov 6½, Lukaku 6, Jonas 6½ | | Liverpool | 1 | 66 Badelj | | Half-time: | 0-0 | | Referee: | Detruche 8 | | Attendance: | 35,104 | | Possession: | 44%-56% | | Total shots: | 6-17 | | MoM: | Zabaleta | | TV: | highlights |
| | 22 Touré, 86 Alex | | (4-3-3): Pyatov 7½, Zabaleta 8, Johnson 7, Touré 7½, Alex 6½, Taylor 6, Badelj 6, Nolan 6½, Huntelaar 6, Ramsey 6½ (53 Sørum 7), Németh 5½ | | São Paulo | 0 |
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| | (4-3-3): Hélton 7½, Wallace 7½, Marcelo 8, Hernanes 6½, David Luiz 7½, Lúcio 6, Ramires 6½, Adriano 7 (78 Rodrigo Caio 6), Willian 6½, Diego 5½, Neymar 6 | | Marseille | 1 | 38 Ribéry | | Half-time: | 1-1 | | Referee: | Borriello 6 | | Attendance: | 59,895 | | Possession: | 55%-45% | | Total shots: | 16-8 | | MoM: | González | | TV: | live |
| | 69 Benzema, 78 Ribéry, 90+1 Ben Arfa | | (4-3-3): Hart 6, Reveillère 6, Sakho 6½, Ben Arfa 7½, Heinze 7, Richarlyson 6½, González 7½, Ribéry 7, Brandão 6½, Rodwell 7, Benzema 7 | | Manchester United | 2 | 13og González, 90+1p Berbatov |
| | (4-3-3): Foster 6½, Richards 7, Evrà 7½, Carrick 6½ (61 Diouf 7), Evans 6, O'Shea 7, Fletcher 7, Obertan 6, Berbatov 6½, Anderson 6, Welbeck 5½ | | Real Madrid | 3 | 7 Ronaldo, 10 Messi, 83p Ronaldo | | Half-time: | 2-0 | | Referee: | Penicka 7½ | | Attendance: | 79,252 | | Possession: | 51%-49% | | Total shots: | 24-10 | | MoM: | Chiellini |
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| | (4-3-3): Casillas 7½, Sergio Ramos 6, Badstuber 7, Xabi Alonso 7½, Chiellini 8, Kompany 7, Silva 6½, Santi 7, Van Persie 6½, Ronaldo 7½, Messi 7 | | Athletic Bilbao | 0 |
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| | (4-3-3): Aranzubía 7½, Iraola 6½, Amorebieta 8, Raúl García 7, Torres 7, Botía 6, Jurado 7, Traoré 6½, Toquero 6½, Mario Suárez 6½, Vela 6½ | | Tottenham Hotspur | 0 |
| | Half-time: | 0-0 | | Referee: | Piller 6½ | | Attendance: | 36,080 | | Possession: | 49%-51% | | Total shots: | 16-11 | | MoM: | De Vrij |
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| | (4-3-3): Víctor Valdés 7½, Walker 6½, Cole 7½, Schweinsteiger 7, Ferdinand 6, Cáceres 5½, Foor 7, Nani 6½, Wickham 7, Modric 7, Cassano 7½ | | Feyenoord | 0 |
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| | (4-3-3): Mulder 7, De Vrij 8, De Cler 7 (67 Leerdam 7½), Maduro 7½, Vlaar 7, Pieters 7, Kuyt 7, Weijl 5½, Van Wolfswinkel 7½, Castaignos 6½, Biseswar 6½ | | Valencia | 1 | 3og Johnson | | Half-time: | 1-0 | | Referee: | Young 7 | | Attendance: | 59,873 | | Possession: | 52%-48% | | Total shots: | 18-7 | | MoM: | Van Der Vaart | | TV: | highlights |
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| | (4-3-3): Reina 8, Lahm 7½, Vargas 6½, Van Der Vaart 8, Mascherano 6½, Puyol 7½, Javi Martínez 7 (79 Perotti 6), Pastore 7½, Hernández 6½ (54 Arbeloa 5½), Llorente 6½, Henríquez 6½ | | West Ham United | 0 |
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| | (4-3-3): Green 7½, Eastmond 5½, Baines 7, Parker 7½, Terry 7, Samba 6½, Walcott 7 (80 Mancienne 6½), Johnson 6, Bent 6, Wilshere 6, Cole 6½ | | Round 3 | | Marseille | 1 | 28 Ribéry | | Half-time: | 1-0 | | Referee: | Bolognino 7½ | | Attendance: | 58,050 | | Possession: | 49%-51% | | Total shots: | 20-14 | | MoM: | Sakho |
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| | (4-3-3): Hart 6½, Reveillère 7½, Sakho 8, Ben Arfa 6½ (50 Bonnart 6½), Heinze 6½, Richarlyson 7, González 7½, Ribéry 6½, Brandão 6½, Rodwell 6½, Benzema 7 | | Manchester City | 1 | 90+1 Özil |
| | (4-3-3): Buffon 6½, Song 6½, Vertonghen 7, Pirlo 7, Piqué 6½, Rolando 7, Herrmann 7½, Özil 6½, Vydra 6, Marchisio 6, Rooney 7 (90+2 Hazard 6) |
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