| Round 5 | | Anderlecht | 0 |
| | Half-time: | 0-1 | | Referee: | Sedlacek 6 | | Attendance: | 27,889 | | Possession: | 48%-52% | | Total shots: | 6-13 | | MoM: | Berezutsky | | TV: | live |
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| | (4-3-3): Proto 6, Maggio 7½, Pocognoli 7, Dembélé 7, Chedjou 6½, Chyhrynskyi 6, Gillet 6½, Ilicevic 6½, Kerzhakov 7, Rolfes 6½, Jonas 6½ | | Borussia Dortmund | 2 | 42 Lewandowski, 72 Berezutsky | | 89 Schweinsteiger | | (4-3-3): Neuer 7, Mertesacker 6½, Grosskreutz 6½, Schweinsteiger 7, Berezutsky 7½, Subotic 6½, Ramires 7½, Iniesta 7 (83 Ginter 6), Lewandowski 7, Kroos 6½, Agüero 6 | | Athletic Bilbao | 0 |
| | Half-time: | 0-1 | | Referee: | Young 6 | | Attendance: | 39,677 | | Possession: | 47%-53% | | Total shots: | 12-16 | | MoM: | Van Persie | | TV: | highlights |
| | 90 Mario Suárez | | (4-3-3): Aranzubía 5½, Iraola 6½, Amorebieta 7, Raúl García 7, Botía 7, Aurtenetxe 6½, Jurado 6½, Vela 5½, Eduardo 6½, Mario Suárez 6½, Osvaldo 5½ | | Real Madrid | 3 | 40 Van Persie, 65 Chiellini, 71 Van Persie |
| | (4-4-2): Casillas 6, Sergio Ramos 7, Piqué 6½, Pepe 7, Chiellini 7, Marcelo 7½, Xabi Alonso 7½, Özil 7, Van Persie 8½, Ronaldo 6, Silva 6½ | | Barcelona | 0 |
| | Half-time: | 0-2 | | Referee: | Colic 8 | | Attendance: | 40,731 | | Possession: | 49%-51% | | Total shots: | 10-12 | | MoM: | Isco |
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| | (4-3-3): Pinto 6½, Bartra 6, Maxwell 7, Tiago 7, Skrtel 7, Mexès 6½, Feghouli 6½, Wijnaldum 6, Gomez 7, Torres 6, Isaac Cuenca 6 | | FC Basel | 3 | 6 Podolski, 44 Isco, 54 Pirlo |
| | (3-4-3): Hart 6½, Willian 6½, Dante 6, Matuidi 6, Lichtsteiner 6, Thiago Silva 6½, Isco 7½, Podolski 7, Lavezzi 6, Pirlo 6½, Behrami 6½ | | Cruz Azul | 2 | 26 Jelavic, 57 Jelavic | | Half-time: | 1-0 | | Referee: | Van Der Ende 5½ | | Attendance: | 35,873 | | Possession: | 54%-46% | | Total shots: | 9-12 | | MoM: | Heinze |
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| | (4-3-3): Iraizoz 6, João Pereira 7½, Pereira 6½, Shaqiri 6, Jagielka 6½, Samuel 6, Fellaini 7½, Robben 7½, Jelavic 6½, De Marcos 6½, Giménez 7 | | Marseille | 1 | 87 Richarlyson | | 43 Ben Arfa, 48 Richarlyson, 79 Benzema, 82 Lamela | | (4-3-3): Riou 6½, Reveillère 7, Heinze 7½, Pjanic 6½, Abidal 7, Alex Silva 6, Lamela 6½, Ben Arfa 6½, Brandão 7, Richarlyson 6, Benzema 6 | | Dynamo | 0 |
| | | 88 Mykhalyk | | (4-3-3): Carrasso 7½, Tymoschuk 6½, Nesmachnyi 7, Harmash 7½, Diakhaté 7½, Mykhalyk 6½, Bystrov 6, Pienaar 7 (46 Díaz 6), Kravets 6, Vukojevic 6½, Zozulya 6 | | São Paulo | 1 | 3 Michel Bastos |
| | (4-3-3): Hélton 7, Wallace 6½, Michel Bastos 8½, Hernanes 7½, Lúcio 7½, Rodrigo Caio 6½, Kelvin 6, Lucas 7½, Willian 6, Diego 7½, Robinho 6 | | Lazio | 1 | 28 Matri | | Half-time: | 1-1 | | Referee: | Vítor Pereira 7½ | | Attendance: | 33,442 | | Possession: | 44%-56% | | Total shots: | 16-9 | | MoM: | Ariaudo |
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| | (4-3-3): Stekelenburg 7½, Bonera 7, Pasqual 6½ (68 Verdi 6), Obi 6½ (74 Prestia 6), Ariaudo 7½, Ziegler 7, Schelotto 6½, Ilicic 7, Matri 7, Babacar 5½, Di Vaio 6½ | | Manchester City | 1 | 18 Lucas Piazón |
| | (4-3-3): Kapino 7, Sagna 6½, Vertonghen 7, Sneijder 7, Vidic 7½, Song 6, Herrmann 6½, Lucas Piazón 7, Soldado 6½, De Jong 7, Ocampos 5½ | | Liverpool | 1 | 54 Touré | | Half-time: | 0-3 | | Referee: | McCluskey 7 | | Attendance: | 43,046 | | Possession: | 46%-54% | | Total shots: | 15-22 | | MoM: | Touré | | TV: | live |
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| | (4-3-3): Vorm 5, Zabaleta 7, Insúa 7, Touré 8, Alex 7, Taylor 6, Badelj 7, Saric 6, Huntelaar 7, Carroll 6, Németh 6 | | Benfica | 4 | 9 Javi García, 16 Cardozo, 40 Gourcuff, 55 Cardozo | | 28 Eliseu | | (4-3-3): Eduardo 5½, Pereira 6½, Eliseu 7½, Gourcuff 7½, Maicon 7, Ricardo Carvalho 6, Taddei 7, Cleiton Xavier 7, Cardozo 7, Javi García 6½, Benteke 6½ | | Lyon | 1 | 36 Henry | | Half-time: | 1-0 | | Referee: | Michel 7 | | Attendance: | 35,467 | | Possession: | 51%-49% | | Total shots: | 11-17 | | MoM: | Obraniak | | TV: | highlights |
| | 14 Éderson, 46 Atik | | (4-3-3): Ruffier 7, Théophile-Catherine 7, Bedimo 7½, Obraniak 8½, Armand 6½, Escudé 6½, Atik 7, Boussoufa 6½, Belfodil 6½, Éderson 6½ (82 Tiéné 6), Henry 6½ | | Nantes | 1 | 81 Valbuena |
| | (3-4-3): Mandanda 7½, Zouma 7½, Mangala 5½, Gonalons 7 (66 Grenier 7), Toulalan 6½, Koscielny 6, Sissoko 7 (71 Alessandrini 6), Payet 8, Gomis 7½, Valbuena 7½, Lacazette 6½ | | Newcastle United | 1 | 64 Cavani | | Half-time: | 0-0 | | Referee: | Onufer 6½ | | Attendance: | 52,369 | | Possession: | 51%-49% | | Total shots: | 14-8 | | MoM: | Hamsík |
| | 65 Hamsík | | (4-5-1): Cech 7½, Dani Alves 8, Jordi Alba 8, Vidal 7½, Hummels 8, Godín 7, Sánchez 7, Hamsík 8, Ibrahimovic 7, Cavani 7, Bale 8 | | Celtic | 0 |
| | 61 Katsouranis | | (4-3-3): Boruc 7½, Kolodin 6, Izaguirre 6½, Defour 7, Katsouranis 6½, Rogne 6½, Brown 5½, McGeady 6½, Cissé 6½, Cissé 5½, Keane 6 | | Tottenham Hotspur | 2 | 53 Nani, 73 Cole | | Half-time: | 0-0 | | Referee: | Munteanu 7½ | | Attendance: | 36,148 | | Possession: | 60%-40% | | Total shots: | 19-6 | | MoM: | Flores |
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| | (4-3-3): Leno 7, Cáceres 8, Cole 8, Kovacic 6 (54 Flores 8½), Rami 7, Willems 7½, Foor 7½, Nani 7½, Wickham 7, Torres 7½, Gabbiadini 7½ | | Palmeiras | 1 | 75 Higuaín | | 50 Robert, 62 Robert | | (4-3-3): Júlio César 7½, Figueroa 5½, Armero 6, Lucas 7, Danilo 7, Edinho 5½, Pierre 6½, Diego Souza 6, Higuaín 8, Robert 5, Ewerthon 5½ | | Valencia | 3 | 33 Rafinha, 54 Llorente, 60 Pastore | | Half-time: | 1-0 | | Referee: | Øvrebø 5½ | | Attendance: | 44,142 | | Possession: | 51%-49% | | Total shots: | 12-8 | | MoM: | Van Der Vaart | | TV: | highlights |
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| | (4-3-3): Zelazny 7½, Arbeloa 7½, San Jose 7, Van Der Vaart 8, Javi Martínez 6½, Javi Manquillo 6, Perotti 7, Pastore 7, Llorente 7, Hernández 5½, Rafinha 7 | | Manchester United | 1 | 52 Berbatov |
| | (4-3-3): Kuszczak 7, Rafael 7 (68 Gibson 6), Assou-Ekotto 6, Carrick 7, Evans 7, O'Shea 6, Giovani 7, Obertan 6½, Berbatov 7½, Diouf 5½, Keko 5½ |
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