| Round 5 | | Accrington Stanley | 1 | 69 Sterling | | Half-time: | 0-0 | | Referee: | Marcos Antônio 8 | | Attendance: | 18,973 | | Possession: | 39%-61% | | Total shots: | 14-19 | | MoM: | Davis | | TV: | live |
| | 37 Williams | | (4-3-3): Forster 6½, Walker 7, Chambers 7, Smalling 6½, Williams 6½, Ramsey 6½, Sterling 5½, Ambrose 6½, Sturridge 7, Barkley 6, Welbeck 6½ | | Rangers | 1 | 87 Van Damme | | 9 Morrison, 10 Boakye, 32 Bougherra | | (4-3-3): McGregor 7, Hutton 6½, Van Damme 7½, Davis 8, Bougherra 7, Broadfoot 6, Morrison 8, Naismith 6½ (69 Wilson 7½), Lafferty 7½, Boakye 6, Son 7½ | | Belenenses | 3 | 33 Hélder Postiga, 38 Fernández, 82 Fernández | | Half-time: | 2-0 | | Referee: | Vink 6 | | Attendance: | 12,421 | | Possession: | 63%-37% | | Total shots: | 14-4 | | MoM: | Daniel Carrico |
| | 83 Hélder Postiga | | (4-3-3): Jones 7½, Caneira 6½, Miguel Veloso 7½, Adrien Silva 7½, Daniel Carrico 8½, Cervantes 7, Renato Neto 7, Fernández 8, Hélder Postiga 7½, Riveros 6½, João Pedro 7 | | Ajax | 0 |
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| | (4-3-3): Mirante 7, Wielaert 5½, Atouba 6, De Zeeuw 6½, Dainelli 6½, Lindgren 6, Rommedahl 6, Emanuelson 6½, Matavz 6, Floccari 6, Lestienne 6 | | Brøndby | 1 | 15 Roberto Firmino | | Half-time: | 1-1 | | Referee: | Waddel 7 | | Attendance: | 28,824 | | Possession: | 37%-63% | | Total shots: | 6-13 | | MoM: | Krsticic |
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| | (4-3-3): Tørnes 7, Randrup 6½, Belhadj 6, Thygesen 6, Stenderup 6½, Kjær 6½, Labyad 6, Roberto Firmino 7½, Jørgensen 6, Jensen 7, Kristiansen 5½ | | Sampdoria | 1 | 10p Pozzi |
| | (4-3-3): Castellazzi 7, Zauri 6, Costa 7 (69 Rossi 7½), Krsticic 8, Diakité 7, Accardi 7, Padalino 6½, Poli 7, Pozzi 6½, Tissone 6, Testardi 6 | | Chelsea | 1 | 1 Källström | | Half-time: | 1-1 | | Referee: | Gumienny 5 | | Attendance: | 33,598 | | Possession: | 40%-60% | | Total shots: | 9-9 | | MoM: | Shawcross |
| | 6 Källström, 39 Borini, 41 Van Buyten, 46 Lennon, 76 Ibagaza | | (4-3-3): Turnbull 6½, Rafinha 7½, Van Aanholt 6½, Arteta 7, Van Buyten 6½, Touré 6, Lennon 7, Rodríguez 6½, Ibagaza 6½, Källström 6, Borini 6 | | Ayr United | 1 | 11 Townsend |
| | (4-4-2): Guzan 7, Richards 6½, Colback 8, Wilshere 8, Shawcross 8, Westwood 6, Fletcher 7, Anya 6½, Long 7, McCarthy 6½, Townsend 6½ | | Deportivo | 1 | 60 Adúriz | | Half-time: | 0-1 | | Referee: | Dondarini 6 | | Attendance: | 31,002 | | Possession: | 49%-51% | | Total shots: | 9-15 | | MoM: | Diamé |
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| | (4-3-3): Beto 7, Laure 6, Dominguez 7½, Diamé 7½, Colotto 7, Renato Silva 6½, Pablo Álvarez 6½, Tello 7, Adúriz 7½, Riki 6½, Adrián 6½ | | Rubin | 1 | 45 Kasaev |
| | (4-3-3): Zoet 7, Kuzmin 5½, Kaleshin 7½, Murawski 7, César Navas 7, Jordi 5½, Ryazantsev 6, Kasaev 6, Movsisyan 6½, Faty 7, Hasan Salih 6 | | FC Twente | 0 |
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| | (4-3-3): Mihaylov 6½, Stam 7½, Givet 5½, Witsel 7, Douglas 6½, Rajkovic 6, Tioté 6, Beerens 6, Bony 6½, Ojo 6, Wellington 6 | | Palermo | 2 | 15 Candreva, 44 Candreva |
| | (3-4-3): Consigli 6½, Gastaldello 8, Montolivo 8, Criscito 7½, Balzaretti 7½, Cassani 7½, Osvaldo 6½, Cassano 6½, Candreva 7, Inler 6, Motta 6½ | | Hansa Rostock | 2 | 37 Dzeko, 89 Gentner | | Half-time: | 1-2 | | Referee: | Jol 6 | | Attendance: | 28,853 | | Possession: | 49%-51% | | Total shots: | 13-12 | | MoM: | Schäfer |
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| | (4-3-3): Hitz 6, Riether 7½, Schäfer 8, Geromel 8, Rever 7, Leemans 6, Hasebe 7½, Gentner 7, Dzeko 7, Grafite 6½, Salpigidis 6½ | | Bordeaux | 3 | 19 Jussiê, 33 Domizzi, 74 Wendel |
| | (4-3-3): Bédénik 5½, Clerc 7, Domizzi 6½, Sané 7½, M'Bengue 6½, Planus 6½, Bellion 6½, Wendel 6½, Cavenaghi 7, Sertic 6, Jussiê 5½ | | Milan | 3 | 58 Bendtner, 62 Bendtner, 68 Ireland | | Half-time: | 0-1 | | Referee: | Bennett 7 | | Attendance: | 38,047 | | Possession: | 41%-59% | | Total shots: | 11-11 | | MoM: | Badu |
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| | (4-1-2-3): Given 6, Berardi 8, Kolarov 6, Ireland 7½, Distin 7½, Bocchetti 6½, Joaquín 6, Ninis 7, Bendtner 7½, Linetty 6, Adiyiah 5½ | | Newport County | 3 | 40 Rodriguez, 79 Rodriguez, 83 Rodriguez |
| | (4-4-2): McCarthy 6½, Moore 7½, Bertrand 7, Badu 8, Clark 6½, Baker 7, Henderson 7½, Livermore 7, Hooper 8, Cleverley 7, Rodriguez 7 | | Panathinaikos | 3 | 52 M'Bia, 70 Muriel, 79 Carrillo | | Half-time: | 0-0 | | Referee: | Uilenberg 8 | | Attendance: | 29,823 | | Possession: | 46%-54% | | Total shots: | 14-8 | | MoM: | Leto |
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| | (4-3-3): Ujkani 6½, Vyntra 7, Coentrão 6½ (71 Cani 7), Illarramendi 7, Luizão 5½ (71 Leto 7½), Lugano 6, Jozefzoon 7½, Carrillo 7, Vellios 6, M'Bia 7½, Muriel 7 | | Roma | 1 | 55 Kagawa | | 46 Rossi, 62 Barli, 73 Kranjcar, 83 Gago, 90+2 Kranjcar | | (4-3-3): Barli 6½, Cuadrado 6½ (53 Zuculini 6½), Riise 7, Pizarro 7, Coloccini 7 (55 Kranjcar 6), Coates 6, Gago 6½, Kagawa 6½, Velikonja 5½, Noboa 7½, Rossi 7 | | Rosenborg | 1 | 2og Ibrahim | | Half-time: | 1-0 | | Referee: | Reijgwart 6½ | | Attendance: | 21,086 | | Possession: | 47%-53% | | Total shots: | 6-14 | | MoM: | Chrétien | | TV: | highlights |
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| | (4-3-3): Begovic 7, Høgli 6½ (75 Chibuike 6), Mathieu 7, Shirokov 6½ (82 Dockal 6), Toprak 7½, Lustig 6½, Skjelbred 7, Elyounoussi 7½, Pizarro 7, Chantôme 6, Holm 5½ | | Besiktas | 1 | 85 Batalla | | 29 Sahan | | (4-3-3): Carson 7, Chrétien 8, André Santos 7½, Jones 7, Nounkeu 7, Ibrahim 6, Kavlak 7, Holmén 7, Emenike 6½, Batalla 7, Sahan 6 | | Zenit | 1 | 84 Danny | | Half-time: | 0-1 | | Referee: | Hauge 6 | | Attendance: | 21,943 | | Possession: | 44%-56% | | Total shots: | 9-11 | | MoM: | Víctor Vázquez |
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| | (4-3-3): Gordon 6½, Tomovic 7, Sirl 6, Guilherme 6½, Krizanac 6, Rosina 6, Fayzulin 7½, Danny 7, Kornilenko 6½ (76 Ionov 6), Huszti 5½, Lazovic 6 | | Club Brugge | 1 | 7 Refaelov |
| | (4-3-3): Koval 6½, Meunier 6½ (69 Vezalov 6), Stenman 7, Víctor Vázquez 7½, Donk 6½, Hoefkens 6, Odjidja-Ofoe 6½, Refaelov 6½, Vleminckx 6½, Vargas 7, Akpala 6 | | Round 3 | | Milan | 2 | 12 Ireland, 63 Adiyiah | | Half-time: | 1-2 | | Referee: | Nielsen 6½ | | Attendance: | 44,400 | | Possession: | 39%-61% | | Total shots: | 9-17 | | MoM: | Gastaldello |
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| | (4-1-2-3): Given 5, Berardi 7, Kolarov 6½, Ireland 7, Distin 6½, Bocchetti 6, Joaquín 5½, Ninis 6, Bendtner 6½, Linetty 6, Adiyiah 6 | | Palermo | 4 | 17 Cassano, 27 Candreva, 46 Montolivo, 50 Gastaldello |
| | (3-4-3): Consigli 5, Gastaldello 8, Montolivo 8, Criscito 7½, Balzaretti 7½, Cassani 7, Osvaldo 7½, Cassano 7½, Candreva 7½, Inler 7½, Motta 7 | | Chelsea | 3 | 32 Borini, 54 Rodríguez, 59 Ibagaza | | Half-time: | 1-0 | | Referee: | Arena 7½ | | Attendance: | 33,800 | | Possession: | 57%-43% | | Total shots: | 9-11 | | MoM: | Van Aanholt |
| | 24 Van Buyten, 26 Arteta, 83 Ibagaza | | (4-3-3): Turnbull 6½, Rafinha 6½, Van Aanholt 7½, Arteta 7, Touré 7½, Van Buyten 7, Lennon 7½, Rodríguez 7½, Ibagaza 6½, Källström 7½, Borini 6½ | | Club Brugge | 1 | 57 Refaelov |
| | (4-3-3): Koval 7, Meunier 5½, Stenman 7, Víctor Vázquez 7, Donk 6, Hoefkens 7, Odjidja-Ofoe 7, Refaelov 6½, Vleminckx 6½, Vargas 6, Akpala 5½ | | Round 4 | | Ajax | 1 | 8 Floccari | | Half-time: | 1-1 | | Referee: | Onufer 6½ | | Attendance: | 37,337 | | Possession: | 50%-50% | | Total shots: | 12-9 | | MoM: | De Zeeuw |
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| | (4-3-3): Mirante 6½, Wielaert 6, Atouba 6, De Zeeuw 7½, Dainelli 7½, Lindgren 6, Rommedahl 7, Emanuelson 6½ (83 Suk 6), Matavz 6½, Floccari 6, Lestienne 6½ | | Brøndby | 2 | 17 Roberto Firmino, 90 Jensen | | 53 Kristiansen, 84 Roberto Firmino | | (4-3-3): Tørnes 6½, Randrup 7, Belhadj 7, Thygesen 7, Stenderup 7, Kjær 7, Labyad 6, Roberto Firmino 7½, Jørgensen 6½, Jensen 7, Kristiansen 5½ |
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