Round 1 | Atlético Madrid | 1 | 71 Schaars | Half-time: | 0-2 | Referee: | Gumienny 7 | Attendance: | 38,167 | Possession: | 43%-57% | Total shots: | 19-15 | MoM: | Oscar |
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| (4-3-3): Hamon 4½, Jesús 7, Marcos Alonso 6½, Biglia 7, Rodríguez 7, Marc Muniesa 6½, Salvio 8, Reyes 6, Borja 6, Schaars 6½ (79 Lanzini 6), Bojan 6½ | FC Porto | 4 | 20 Hulk, 37 Danny, 56 Hulk, 81 Hulk |
| (4-4-2): Rui Patrício 5, Miranda 7½, Alex Sandro 7½, Danny 7½, Alex 7½, Leandro Castan 6½, Oscar 8, Philippe Coutinho 7½, Hulk 6½, João Moutinho 6, Falcao 7 | Barcelona | 3 | 45 Torres, 75 Torres, 87 Feghouli | Half-time: | 1-3 | Referee: | Slovic 7 | Attendance: | 50,574 | Possession: | 49%-51% | Total shots: | 12-13 | MoM: | Tiago |
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| (4-3-3): Müller 5, Bartra 6½, Maxwell 7, Tiago 8½, Skrtel 7½, Mexès 7, Feghouli 7, Toivonen 6½, Torres 7, Gomez 5½, Vílla 6½ | River Plate | 5 | 16 Castillejos, 28 Rojo, 37 López, 68 López, 84 Orban | 90 Ferrero | (4-3-3): Chichizola 4½, Ferrari 7 (80 Ferrero 6), Rojo 7, Buonanotte 8, López 6, Orban 7, Affranchino 7½, Mouche 7, López 6½, Castillejos 6½, Villalva 5½ | Celtic | 2 | 22 Iturbe, 55 Iturbe | Half-time: | 1-1 | Referee: | Karlsson 7 | Attendance: | 39,680 | Possession: | 53%-47% | Total shots: | 10-15 | MoM: | Kolodin |
| 90 McGeady | (4-3-3): Boruc 6½, Oliver 7, José Ángel 6½, Defour 7, Kolodin 8, Rogne 6½, Cahill 7, Iturbe 7, Cissé 7, McGeady 5½, Keane 7 | Sevilla | 2 | 18 Makoun, 66p Kiessling | 29 Squillaci, 35 Renato, 60 Silvestre | (4-4-2): Navas 7, Alexis 7, Fernando Navarro 6½, Raul Meireles 8, Squillaci 7, Silvestre 7, Makoun 7, Renato 6, Kiessling 6½, O'Donnell 6, Opare 5½ | Feyenoord | 0 |
| Half-time: | 0-1 | Referee: | Negredo 5½ | Attendance: | 41,821 | Possession: | 48%-52% | Total shots: | 14-19 | MoM: | Rakitic |
| 66 Castaignos | (4-3-3): Alvarado 7, Hutchinson 7, Pieters 6½, De Guzman 7, Vlaar 7, Schenkeveld 7 (74 Babovic 6), Kuyt 6½, Van La Parra 6½, Castaignos 6½, Van Wolfswinkel 6, Schaken 5½ | Lille | 1 | 21 Benatia |
| (4-3-3): Lloris 7½, Benatia 7½, Evrà 7½, Rakitic 7½, David Luiz 6, Jallet 6, Valencia 7, Gaitán 7, Widmer 6½, Dzemaili 6½ (72 Thauvin 6½), Origi 6½ | Internacional | 3 | 18 Fred, 22 Wágner, 52 Kléber | Half-time: | 2-1 | Referee: | Bettin 6½ | Attendance: | 44,726 | Possession: | 61%-39% | Total shots: | 17-10 | MoM: | Marcelo | TV: | live |
| 77 Wágner | (4-3-3): Fernando Henrique 6½, Mariano 8, Kléber 7, Giuliano 7½, Marcelo 8½, Hilton 6½, Sandro 7½, Wágner 6½, Fred 7, Jô 7, Júlio Baptista 6½ | FC Schalke 04 | 1 | 31 Hugo Almeida |
| (4-3-3): Mielitz 6½, Träsch 7, Rausch 7, Kroos 7, Westermann 6, Williamson 6½, Farfán 7½, Costa 7, Hugo Almeida 6½, De Jong 6, Bäcker 5 | Lorient | 0 |
| Half-time: | 0-0 | Referee: | Herivelto 6 | Attendance: | 15,789 | Possession: | 46%-54% | Total shots: | 11-12 | MoM: | Lampard | TV: | highlights |
| 44 Mvuemba, 86 Diarra | (4-3-3): Audard 6½, Congré 6½, Morel 6½, Balmont 7, Puygrenier 6, Kanté 5½, Jouffre 7, Diarra 6, Hoarau 6½, Mvuemba 6, Birsa 6 | Exeter City | 2 | 49 Coleman, 85og Puygrenier |
| (3-4-3): Foster 7, Jones 6½, Caulker 6½, Barry 7, Terry 6½, Coleman 7, Dyer 6½, Johnson 7, Lampard 8, Walcott 6½, Forrest 6½ | Manchester United | 3 | 3 Berbatov, 31 Obertan, 86 Giovani | Half-time: | 2-0 | Referee: | Desmond 6½ | Attendance: | 36,640 | Possession: | 46%-54% | Total shots: | 10-10 | MoM: | Giovani |
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| (4-3-3): Kuszczak 7, Emmanuel-Thomas 6, Assou-Ekotto 6½, Carrick 7½, O'Shea 7, Shelvey 5½, Giovani 8, Obertan 6½, Berbatov 7½, Diouf 5½ (57 Macheda 5½), Keko 6 | Espanyol | 0 |
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| (4-3-3): Yoel 7½, Roncaglia 6½, Pinto 7, Gurpegui 7½, Pareja 7, Hangeland 7, Corominas 7½, Verdú 7½, Juanmi 6½, Ninkovic 6, Olic 7 | Napoli | 1 | 5 Cigarini | Half-time: | 1-0 | Referee: | Bennett 7 | Attendance: | 46,209 | Possession: | 51%-49% | Total shots: | 7-15 | MoM: | Fritz |
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| (4-3-3): De Sanctis 8, Campagnaro 7½, Moretti 7½, Cigarini 6½ (74 Mokotjo 6), Cannavaro 7½, Zaccardo 6, Necip 7½, Gargano 6½, Aronica 5½, Keita 7½, Maiello 5½ | Bayer Leverkusen | 0 |
| 48 Castro | (4-3-3): Giefer 7½, Fritz 8, Schulz 7½, Cambiasso 7, Díaz 6½, Servet 6½, Elano 7, Castro 6½ (67 Iñigo Pérez 7), Kuranyi 6½, Arango 6, Zárate 6 | SV Werder Bremen | 1 | 16 Abdennour | Half-time: | 1-2 | Referee: | Clattenburg 6 | Attendance: | 40,298 | Possession: | 46%-54% | Total shots: | 12-8 | MoM: | Abdennour | TV: | highlights |
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| (4-3-3): Parish 6, Uchida 6½, Abdennour 8, Bargfrede 7, Prödl 7, Pasanen 6½, Diego Capel 6, Hunt 6½, Adebayor 6½ (70 Niemeyer 6), Oar 6, Wagner 6 | Spartak | 3 | 7 Kombarov, 38 Dzagoev, 58 Yakovlev | 13 Arshavin, 54 Dzagoev, 83 Yakovlev, 87 Makeev, 90+1 Bazhenov | (4-3-3): Ryzhikov 6, Parshivlyuk 7, Kombarov 7½, Ozdoev 7½, Makeev 6½, Berezutsky 7½, Bazhenov 7, Dzagoev 7, Rondón 6½ (58 Yakovlev 6½), Zhirkov 5½, Arshavin 7 (74 Serderov 6) | TSG Hoffenheim | 0 |
| Half-time: | 0-2 | Referee: | Sarvan 7 | Attendance: | 30,116 | Possession: | 49%-51% | Total shots: | 6-15 | MoM: | Ribéry | TV: | highlights |
| 22 Ba, 52 Fährmann, 64 Owomoyela | (4-3-3): Fährmann 5½, Ebondo 7½, Simunic 7½, Maicosuel 7 (67 Ogbuke 7½), Ruíz 6½, Amat 6, Owomoyela 6½, Salihovic 6½, Ibisevic 7, Ba 6, Sessègnon 7½ | Arsenal | 3 | 26 Suárez, 36 Suárez, 76 Ribéry |
| (3-4-3): De Gea 6, Lahm 6½, Di María 7, Xavi 7½, Adriano 6, Ivanovic 6½, Ribéry 8, Neymar 7, Suárez 7, Fabregas 6½, Rooney 7½ | West Ham United | 2 | 33 Cole, 71 Bent | Half-time: | 1-1 | Referee: | Rennie 6 | Attendance: | 34,414 | Possession: | 47%-53% | Total shots: | 8-16 | MoM: | Bedimo |
| 89 Johnson | (4-3-3): Green 5½, Eastmond 7½, Gibbs 7½, Gerrard 6, Samba 7, Mancienne 6, Cole 7, Johnson 6½, Bent 7, Carroll 7, Brozovic 6 | Lyon | 4 | 22 Atik, 50 Obraniak, 53 Atik, 88 Roux | 39 Théophile-Catherine, 65 Obraniak | (4-3-3): Bettinelli 5, Gassama 7, Bedimo 7½, Obraniak 7½, Armand 7, Théophile-Catherine 6, Atik 7, Boussoufa 7, Roux 7½, Belfodil 6, Henry 6 | Round 2 | Arsenal | 2 | 19 Ribéry, 39 Ribéry | Half-time: | 2-0 | Referee: | Medina Cantalejo 6½ | Attendance: | 59,886 | Possession: | 57%-43% | Total shots: | 15-7 | MoM: | Lahm |
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| (3-4-3): De Gea 7½, Lahm 8½, Di María 8, Xavi 6½, Adriano 7, Ivanovic 6½, Ribéry 6½, Neymar 6, Suárez 6, Fabregas 7, Rooney 6½ | Lorient | 0 |
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| (4-3-3): Audard 8, Congré 7, Morel 6½, Balmont 7½, Puygrenier 6, Kanté 6, Jouffre 6½, Diarra 5½, Hoarau 6½, Mvuemba 6½, Birsa 7 | Bayer Leverkusen | 0 |
| Half-time: | 0-0 | Referee: | Reijgwart 6½ | Attendance: | 22,437 | Possession: | 48%-52% | Total shots: | 15-15 | MoM: | Fritz |
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| (4-3-3): Giefer 6, Fritz 8, Schulz 7 (74 Cañete 7½), Cambiasso 7½, Díaz 6½, Servet 6½, Elano 6½, Castro 7½, Kuranyi 6½, Rubén Pérez 6, Zárate 5½ | Internacional | 2 | 62 Wágner, 74 Giuliano |
| (4-3-3): Fernando Henrique 6½, Mariano 7 (55 Vinicius 7), Kléber 7½, Giuliano 7½, Marcelo 6½ (53 Marquinhos Gabriel 8), Hilton 6½, Sandro 6, Wágner 7, Fred 7, Jô 6, Júlio Baptista 6½ | Espanyol | 4 | 11 Pareja, 22 Olic, 25 Olic, 74 Pareja | Half-time: | 3-1 | Referee: | Circhetta 6½ | Attendance: | 36,821 | Possession: | 54%-46% | Total shots: | 13-8 | MoM: | Pareja |
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| (4-3-3): Yoel 7, Roncaglia 6½, Pinto 7½, Gurpegui 7, Pareja 8, Hangeland 6½, Corominas 6½, Verdú 7, Juanmi 6½, Ninkovic 6½, Olic 7½ | Barcelona | 1 | 32p Gomez |
| (4-3-3): Müller 6, Bartra 7½, Azpilicueta 7, Tiago 7, Skrtel 7½, Mexès 6½, Feghouli 7, Toivonen 5½, Gomez 7, Torres 6½, Vílla 6½ | Exeter City | 1 | 20 Dyer | Half-time: | 1-0 | Referee: | Levnikov 6½ | Attendance: | 19,654 | Possession: | 51%-49% | Total shots: | 19-13 | MoM: | Kolodin |
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| (3-4-3): Foster 7, Jones 7, Caulker 7½, Barry 7, Terry 6, Coleman 7½, Dyer 7½, Johnson 7, Lampard 6½, Walcott 6½, Forrest 6 | Celtic | 1 | 85 Cahill | 5 Cahill, 89 Iturbe | (4-3-3): Boruc 6, Oliver 6, Izaguirre 6½, Defour 7, Kolodin 7½, José Ángel 6½, McGeady 6, Iturbe 6½, Cissé 7, Cahill 6½, Keane 6 | FC Porto | 4 | 15 Miranda, 32 Alex Sandro, 40 Alex, 42 Hulk | Half-time: | 4-1 | Referee: | Rosetti 6 | Attendance: | 50,781 | Possession: | 57%-43% | Total shots: | 12-7 | MoM: | Alex Sandro |
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| (4-4-2): Rui Patrício 7½, Miranda 7½, Alex Sandro 8½, Danny 7½, Alex 7, Leandro Castan 7½, Oscar 7½, Philippe Coutinho 6½, Hulk 7, João Moutinho 7, Falcao 7½ | Feyenoord | 1 | 33 Castaignos | 31 Schenkeveld, 65 Castaignos | (4-3-3): Alvarado 6, Hutchinson 7, Pieters 6, De Guzman 7½, Vlaar 6½, Schenkeveld 7 (74 Babovic 6), Kuyt 6, Van La Parra 5½, Castaignos 6, Van Wolfswinkel 5½, Schaken 6 | FC Schalke 04 | 2 | 31 Farfán, 47 Costa | Half-time: | 1-0 | Referee: | Onufer 6 | Attendance: | 36,280 | Possession: | 44%-56% | Total shots: | 15-7 | MoM: | Fährmann |
| 8 Hugo Almeida | (4-3-3): Mielitz 7½, Träsch 7½, Rausch 7, Kroos 7½, Westermann 6, Williamson 6, Farfán 7½, Costa 6, Hugo Almeida 6 (65 Schmitz 6½), De Jong 6, Bäcker 5½ | TSG Hoffenheim | 0 |
| 57 Amat | (4-3-3): Fährmann 8, Ebondo 6½, Simunic 7, Maicosuel 7 (67 Ogbuke 7½), Ruíz 7, Amat 6, Owomoyela 6½, Salihovic 7, Ibisevic 7½, Ba 6½, Sessègnon 7 | Lille | 4 | 5 Benatia, 35 Rakitic, 45+1 Gaitán, 52 Dzemaili | Half-time: | 3-0 | Referee: | Strampe 6½ | Attendance: | 18,062 | Possession: | 47%-53% | Total shots: | 14-18 | MoM: | Rakitic |
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| (4-3-3): Lloris 7½, Benatia 7, Evrà 7, Rakitic 8, David Luiz 7, Jallet 6, Valencia 7, Gaitán 6½, Widmer 6, Dzemaili 5 (72 Thauvin 6), Origi 6 | Atlético Madrid | 0 |
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| (4-3-3): Hamon 7, Jesús 7½, Marcos Alonso 6½, Biglia 7½, Rodríguez 7, Marc Muniesa 7, Salvio 6½, Reyes 7, Borja 7, Schaars 6½ (79 Lanzini 6), Bojan 6½ | Lyon | 1 | 15 Roux | Half-time: | 1-1 | Referee: | Detruche 7 | Attendance: | 40,464 | Possession: | 61%-39% | Total shots: | 16-4 | MoM: | Gassama |
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| (4-3-3): Bettinelli 7, Gassama 8, Bedimo 6½, Obraniak 7½, Armand 7, Théophile-Catherine 6½, Atik 7, Boussoufa 7½, Roux 7½, Belfodil 6, Henry 6½ | Manchester United | 1 | 6 Obertan |
| (4-3-3): Kuszczak 7, Emmanuel-Thomas 6½, Assou-Ekotto 7, Carrick 7, O'Shea 6, Shelvey 5½, Giovani 6, Obertan 6½, Berbatov 6½, Diouf 6½ (58 Macheda 5½), Keko 5½ | River Plate | 3 | 42 Mouche, 56 Mouche, 83 López | Half-time: | 1-2 | Referee: | Hill 6½ | Attendance: | 40,561 | Possession: | 52%-48% | Total shots: | 17-11 | MoM: | Mouche |
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| (4-3-3): Chichizola 7, Ferrari 5½ (84 Ferrero 6), Rojo 8, Buonanotte 7, López 7½, Orban 7, Affranchino 6½, Mouche 8½, López 7, Castillejos 6½, Villalva 6 | West Ham United | 2 | 17og Affranchino, 37 Johnson |
| (4-3-3): Green 7, Eastmond 6½ (74 Cole 5½), Gibbs 8, Gerrard 7½, Samba 7, Mancienne 6, Holmes 6, Johnson 8, Bent 7, Parker 6, Sellin 5½ | Sevilla | 1 | 62p Kiessling | Half-time: | 0-0 | Referee: | Knight 7 | Attendance: | 44,992 | Possession: | 54%-46% | Total shots: | 15-12 | MoM: | Raul Meireles |
| 26 Alexis | (4-3-3): Navas 7½, Alexis 6½, Fernando Navarro 7½, Raul Meireles 8½, Squillaci 7½, Silvestre 6½, Navas 8, Luscombe 6½, Kiessling 7, Makoun 7½, Kiko 6½ | SV Werder Bremen | 0 |
| 13 Wagner | (4-3-3): Gabulov 7½, Uchida 7, Abdennour 7, Bargfrede 7, Prödl 7 (62 Smith 6½), Pasanen 7, Oar 6, Hunt 7½, Adebayor 6, Diego Capel 6, Wagner 7 | Spartak | 2 | 8 Rondón, 47 Rondón | | 48 Torbinsky | (4-3-3): Ryzhikov 6, Parshivlyuk 8, Kombarov 6½, Ozdoev 7, Makeev 7, Zhirkov 6½, Bazhenov 7½, Dzagoev 7, Rondón 7½, Torbinsky 5½, Arshavin 6½ | Napoli | 2 | 45 Moretti, 50p Gignac |
| (4-3-3): De Sanctis 6½, Campagnaro 7½, Moretti 7½, Cigarini 8, Cannavaro 8, Zaccardo 6½, Necip 7, Gargano 6, Gignac 6½, Keita 6½, Mokotjo 5½ |
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