| Round 3 | | Athletic Bilbao | 3 | 4 Aurtenetxe, 13 Eduardo, 20 Traoré | | Half-time: | 3-1 | | Referee: | Foy 5 | | Attendance: | 39,596 | | Possession: | 44%-56% | | Total shots: | 14-16 | | MoM: | Mario Suárez |
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| | (4-3-3): Pigliacelli 5½, Iraola 5½ (80 Toquero 6), Aurtenetxe 6, Mario Suárez 7½, Botía 7, Torres 7, Jurado 6½, Vela 6½, Eduardo 7, Traoré 6½, Osvaldo 6½ | | Borussia Dortmund | 3 | 12 Lewandowski, 51 Schmelzer, 70 Lewandowski | | 23 Hazard | | (4-3-3): Akinfeev 5½, Höwedes 6½, Schmelzer 6½, Bender 7 (66 Podolski 7½), Subotic 6½, Berezutsky 6, Schweinsteiger 5½, Ramires 6, Lewandowski 6½, Hazard 6½, Lavezzi 6 | | Bayern München | 1 | 17 Klose | | Half-time: | 1-0 | | Referee: | Beeby 6½ | | Attendance: | 43,808 | | Possession: | 47%-53% | | Total shots: | 10-8 | | MoM: | Danilo |
| | 73 Anelka | | (4-3-3): Andújar 7½, Essien 7½, Pranjic 7, Sahin 6½, Demichelis 7, Papastathopoulos 6½, Ignjovski 7, Marin 7, Klose 7½, Grafite 6, Anelka 6 | | Palmeiras | 1 | 50 Armero | | 24 Robert, 39 Edinho | | (4-3-3): Júlio César 7, Henrique 7½, Armero 7, Lucas 7, Danilo 7½, Rafael Toloi 6, Pierre 6½, Marquinhos 7, Robert 6, Edinho 7, Ronaldinho 6 | | Dynamo | 1 | 13 Milevskyi | | Half-time: | 1-0 | | Referee: | Nielsen 8 | | Attendance: | 49,622 | | Possession: | 55%-45% | | Total shots: | 13-19 | | MoM: | Vukojevic | | TV: | live |
| | 58 Blanco | | (4-3-3): Carrasso 6, Mykhalyk 7, Nesmachnyi 6, Vukojevic 8, Khacheridi 6½, Vida 6½, Bystrov 7, Pienaar 7, Milevskyi 6½, Blanco 6, Kravets 6 | | FC Basel | 2 | 49 Draxler, 79 Willian |
| | (3-4-3): Weidenfeller 6½, Willian 8, Cahill 7, Matuidi 7, Lichtsteiner 6½, Thiago Silva 6½, Isco 6½, Draxler 7, Kroos 6½, Pirlo 6½, Rodríguez 6½ | | Liverpool | 0 |
| | Half-time: | 0-2 | | Referee: | Piller 7½ | | Attendance: | 38,815 | | Possession: | 39%-61% | | Total shots: | 6-15 | | MoM: | Chiellini | | TV: | highlights |
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| | (4-3-3): Pyatov 6, Vrsaljko 6, Insúa 6½, Nolan 7, Taylor 7, Badelj 6, Aleksic 6, Vitolo 6½, Carroll 6, Sørum 5½, Németh 6½ | | Real Madrid | 2 | 2 Ronaldo, 24 Messi |
| | (4-4-2): Neuer 7, Sergio Ramos 7½, Kompany 7½, Piqué 7½, Chiellini 8, De Rossi 7½, Xabi Alonso 7, Marcelo 8, Messi 7½, Ronaldo 7, Van Persie 6½ | | Manchester City | 1 | 81 Vucinic | | Half-time: | 0-0 | | Referee: | Ziober 6½ | | Attendance: | 36,174 | | Possession: | 49%-51% | | Total shots: | 14-12 | | MoM: | Willians |
| | 27 Rodríguez | | (4-3-3): Arrizabalaga 7, Sagna 6½ (81 Vomácka 6), Vertonghen 8, Sneijder 8, Song 7, Vidic 6, Herrmann 6½, Rodríguez 7, Soldado 7, Källström 6, Vucinic 7 | | Flamengo | 0 |
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| | (4-3-3): Muriel 7, Leo Moura 7, Siqueira 7, Willians 8, Xandão 6½, Welinton 6½, Belluschi 7, Marlos 7½, Lima 7 (76 Juan 6), Wellington Nem 5½, Emerson 6 | | Tottenham Hotspur | 1 | 20 Nani | | Half-time: | 1-3 | | Referee: | Hill 6½ | | Attendance: | 36,190 | | Possession: | 44%-56% | | Total shots: | 10-20 | | MoM: | Cáceres | | TV: | highlights |
| | 17 Rami | | (4-3-3): Leno 5, Cáceres 8½, Crescenzi 7½, Shirokov 7, Rami 6, Álvarez 6½, Foor 7, Nani 7, Matavz 6½, Wickham 6½ (69 Torres 6), Gabbiadini 5½ | | Nantes | 4 | 7 Gonalons, 24 Lacazette, 28 Toulalan, 83 Gomis |
| | (4-3-3): Ruffier 5, Debuchy 8, Mendy 7, Toulalan 7½, Mangala 7½, Koscielny 6, Sissoko 7, Valbuena 7 (68 Umtiti 6), Gomis 7, Gonalons 6½, Lacazette 6½ | | Round 4 | | Benfica | 1 | 63 Drogba | | Half-time: | 0-1 | | Referee: | Sarvan 7 | | Attendance: | 51,411 | | Possession: | 49%-51% | | Total shots: | 14-14 | | MoM: | Rolfes |
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| | (4-3-3): Eduardo 7, Pereira 7½, Eliseu 7½, Javi García 7½, Maicon 7½, Rafa 6, Taddei 7, Cleiton Xavier 7½, Drogba 7, Gourcuff 7, Cardozo 5½ | | Anderlecht | 1 | 31 Dembélé |
| | (4-3-3): Malafeev 7, Maggio 7, Pocognoli 7, Rolfes 8, Chedjou 6½, Chyhrynskyi 6, Marecek 7, Mollo 7, Lukaku 6, Dembélé 6½, Jonas 7 | | Borussia Dortmund | 3 | 25og Álvarez, 34 Lavezzi, 39 Schweinsteiger | | Half-time: | 3-0 | | Referee: | Norman 7½ | | Attendance: | 63,184 | | Possession: | 62%-38% | | Total shots: | 19-4 | | MoM: | Schweinsteiger |
| | 80 Hazard | | (4-3-3): Akinfeev 6½, Höwedes 7, Schmelzer 7, Bender 7, Subotic 7, Berezutsky 6½, Schweinsteiger 7½, Ramires 6½ (66 Guarín 6), Lewandowski 7, Hazard 6½, Lavezzi 5½ (66 Grosskreutz 7) | | Tottenham Hotspur | 0 |
| | 47 Álvarez | | (4-3-3): Leno 7, Cáceres 5½, Crescenzi 6, Shirokov 7½, Rami 6½, Álvarez 6, Foor 5½, Nani 6, Matavz 5½, Wickham 7 (69 Torres 5½), Gabbiadini 6 | | FC Basel | 2 | 43 Matuidi, 47 Rodríguez | | Half-time: | 1-0 | | Referee: | Craciun 5 | | Attendance: | 38,443 | | Possession: | 39%-61% | | Total shots: | 15-22 | | MoM: | Weidenfeller | | TV: | live |
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| | (3-4-3): Weidenfeller 7½, Willian 7, Cahill 6½, Matuidi 7, Lichtsteiner 6½, Thiago Silva 6½, Isco 6½, Draxler 7, Kroos 6½, Pirlo 6½, Rodríguez 6 | | Baník Ostrava | 0 |
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| | (3-4-3): Courtois 7, Di Natale 7, Arda 7, Asamoah 6½, Busquets 7½, Barzagli 7, Yarmolenko 7, Hubocan 6, Touré 7, Giroud 6½, Totti 6½ | | Helsingborg | 1 | 49 Agüero | | Half-time: | 0-0 | | Referee: | López 7 | | Attendance: | 40,725 | | Possession: | 57%-43% | | Total shots: | 23-16 | | MoM: | Abate |
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| | (4-3-3): Marchetti 7½, Abate 8, Agger 7½, Fernández 8, Kjær 7½, Wernbloom 7, Schøne 7½, Elm 7, Balotelli 7, Eriksen 6½, Agüero 7 | | Valencia | 0 |
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| | (4-3-3): Reina 7, Arbeloa 6½ (76 Cruz Mascia 6½), Vargas 7, Van Der Vaart 7, San Jose 6½, Rafinha 6½, Perotti 6½, Pastore 6½, Llorente 6½, Hernández 6, Polter 5½ | | Lazio | 2 | 9 Matri, 14 Mertens | | Half-time: | 2-0 | | Referee: | Circhetta 6½ | | Attendance: | 32,089 | | Possession: | 53%-47% | | Total shots: | 13-9 | | MoM: | Matri | | TV: | highlights |
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| | (4-3-3): Stekelenburg 7½, Bonera 7, Pasqual 7½, Obi 7, Radu 7, Ariaudo 7, Schelotto 6½, Mertens 7, Matri 8, Defoe 6½, Théréau 7 | | Bayern München | 0 |
| | 3 Marin, 30 Grafite | | (4-3-3): Andújar 7½, Essien 6½ (70 Görlitz 6), Pranjic 7, Sahin 7, Demichelis 8, Papastathopoulos 5½, Ignjovski 7, Marin 5½, Klose 7, Grafite 6, Anelka 6 | | Marseille | 0 |
| | Half-time: | 0-1 | | Referee: | Karlsson 5½ | | Attendance: | 50,229 | | Possession: | 44%-56% | | Total shots: | 12-16 | | MoM: | Godín |
| | 3 Menez | | (4-3-3): Riou 6, Reveillère 7½, Kolodziejczak 5½, Kaboré 6, Abidal 7, Alex Silva 6½, Pjanic 6½, Menez 6, Brandão 6½, Lamela 6½, Benzema 7½ | | Newcastle United | 2 | 19 Cavani, 50 Cavani |
| | (3-4-1-2): Cech 6½, Godín 8, Boateng 7, Müller 7, Hummels 7, Vidal 6½, Sánchez 7, Bale 7, Ibrahimovic 8, Cavani 6½, Robben 6 | | Nantes | 1 | 37 Gomis | | Half-time: | 1-0 | | Referee: | Dondarini 6½ | | Attendance: | 37,345 | | Possession: | 58%-42% | | Total shots: | 16-10 | | MoM: | Mangala |
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| | (4-3-3): Ruffier 7½, Debuchy 7½, Mendy 7, Toulalan 7½, Mangala 8, Koscielny 7½, Sissoko 7, Valbuena 6½ (68 Umtiti 7½), Gomis 7, Gonalons 7, Lacazette 7 | | Liverpool | 0 |
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| | (4-3-3): Pyatov 7½, Vrsaljko 6½, Insúa 6, Nolan 7, Taylor 6, Badelj 5½, Aleksic 6, Vitolo 6, Carroll 6½, Sørum 5½, Németh 6 | | Palmeiras | 0 |
| | Half-time: | 0-0 | | Referee: | Beschin 5 | | Attendance: | 28,567 | | Possession: | 40%-60% | | Total shots: | 9-28 | | MoM: | Aurtenetxe |
| | 65 Robert, 83 Edinho | | (4-3-3): Júlio César 7, Henrique 6½, Armero 6½, Lucas 7, Danilo 7½, Rafael Toloi 6, Pierre 6, Marquinhos 7, Robert 5½, Edinho 6, Ronaldinho 6½ | | Athletic Bilbao | 0 |
| | 3 Traoré, 37 Osvaldo | | (4-3-3): Pigliacelli 7½, Iraola 6½ (80 Toquero 6), Aurtenetxe 8, Mario Suárez 7, Botía 7, Torres 7, Jurado 7½, Vela 7, Eduardo 6, Traoré 6½, Osvaldo 6½ | | São Paulo | 0 |
| | Half-time: | 0-0 | | Referee: | Almeida Marcal 5½ | | Attendance: | 49,371 | | Possession: | 51%-49% | | Total shots: | 10-11 | | MoM: | Maicon |
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| | (4-3-3): Hélton 7½, Maicon 8, Michel Bastos 7, Hernanes 7, Rodrigo Caio 6½, Roger Carvalho 6½, Kelvin 6½, Lucas 7, Willian 5½, M'Vila 6½, Robinho 6 | | Cruz Azul | 0 |
| | 8 Torrado | | (4-3-3): Iraizoz 7½, João Pereira 7½, Pereira 7, Hamsík 7½, Jagielka 7, Samuel 6, Fellaini 6½, De Marcos 7, Jelavic 6½, Torrado 6½, Paco Alcácer 6 |
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