Round 3 | Barcelona | 3 | 1 Gomez, 24 Gomez, 60 Gomez | Half-time: | 2-0 | Referee: | Franceschini 7½ | Attendance: | 35,101 | Possession: | 51%-49% | Total shots: | 12-7 | MoM: | Azpilicueta | TV: | highlights |
| 30 Torres, 73 Gomez | (4-3-3): Müller 7½, Bartra 7½, Azpilicueta 8, Tiago 5½ (60 Maxwell 7), Skrtel 7, Mexčs 7, Feghouli 7½, Toivonen 7, Gomez 7½, Torres 5½, Vílla 6½ | Bayer Leverkusen | 0 |
| 83 Castro, 90 Zárate | (4-3-3): Giefer 7, Fritz 7, Schulz 6 (74 Cańete 6½), Cambiasso 6, Díaz 6, Servet 6, Elano 6, Castro 7, Kuranyi 7½, Rubén Pérez 6½, Zárate 6 | Celtic | 0 |
| Half-time: | 0-1 | Referee: | Cesari 6 | Attendance: | 47,445 | Possession: | 40%-60% | Total shots: | 8-24 | MoM: | Alex Sandro |
| 45 Cissé | (4-3-3): Boruc 6½, Oliver 6, Izaguirre 7, Defour 6½, Kolodin 6½, José Ángel 6½, Cahill 6½, Iturbe 6, Keane 6, McGeady 6, Cissé 6 | FC Porto | 2 | 32og Keane, 85 Hulk |
| (4-4-2): Rui Patrício 6½, Miranda 7½, Alex Sandro 8, Danny 8, Alex 7, Leandro Castan 7½, Oscar 7, Fernando 7, Hulk 7, Joăo Moutinho 7½, Falcao 7½ | Feyenoord | 1 | 54 Van La Parra | Half-time: | 0-2 | Referee: | Brignoccoli 6 | Attendance: | 30,310 | Possession: | 45%-55% | Total shots: | 10-15 | MoM: | Vlaar | TV: | highlights |
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| (4-3-3): Verhoeven 6, Hutchinson 7, Pieters 6, De Guzman 7, Vlaar 8, Jaliens 6½, Kuyt 6½ (58 Drenthe 6), Van La Parra 7, Biseswar 7½, Nijholt 6½, Schaken 6 | FC Schalke 04 | 2 | 7 Williamson, 27 De Jong | 38 Williamson, 75 De Jong | (4-3-3): Mielitz 6½, Träsch 7, Rausch 6½, Kroos 7, Westermann 7, Williamson 6, Farfán 7½, Costa 7½, Hugo Almeida 7 (65 Schmitz 7), De Jong 6, Bäcker 5½ | Internacional | 2 | 21 Kléber, 38 Fred | Half-time: | 2-0 | Referee: | Wieser 6½ | Attendance: | 50,313 | Possession: | 46%-54% | Total shots: | 14-9 | MoM: | Parshivlyuk | TV: | live |
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| (4-3-3): Fernando Henrique 6½, Mariano 7, Kléber 7½, Giuliano 7½, Marcelo 6½, Hilton 7, Sandro 6½, Wágner 7½, Fred 6½, Jô 5½, Júlio Baptista 7 | Spartak | 1 | 64 Rondón |
| (4-3-3): Ryzhikov 6½, Parshivlyuk 8, Kombarov 6½, Ozdoev 7½, Makeev 6½ (46 Yanbaev 6½), Zhirkov 6½, Bazhenov 7, Dzagoev 7½, Rondón 7½, Torbinsky 5½, Arshavin 6 | Lorient | 4 | 3og Affranchino, 6 Morel, 27 Morel, 68p Hoarau | Half-time: | 3-1 | Referee: | Dinelli 6½ | Attendance: | 15,781 | Possession: | 49%-51% | Total shots: | 16-6 | MoM: | Ferrari |
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| (4-3-3): Audard 7, Congré 7½, Morel 6½, Balmont 8, Puygrenier 7½, Kanté 5 (63 Pied 6½), Jouffre 7, Diarra 7½, Hoarau 6½, Mvuemba 6½, Birsa 6 | River Plate | 1 | 10 López |
| (4-3-3): Chichizola 6½, Ferrari 8, Rojo 7, Buonanotte 7, López 6½, Orban 6½ (82 Cabral 6), Affranchino 7½, Mouche 7, López 7, Castillejos 6, Villalva 6 | Manchester United | 1 | 1 Berbatov | Half-time: | 1-2 | Referee: | Bolognino 5½ | Attendance: | 51,509 | Possession: | 48%-52% | Total shots: | 7-16 | MoM: | Lahm |
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| (4-3-3): Kuszczak 5½, Emmanuel-Thomas 6½, Assou-Ekotto 6, Carrick 7½, O'Shea 6½, Shelvey 6, Giovani 7, Obertan 7, Berbatov 6½, Diouf 6, Keko 5½ | Arsenal | 4 | 31 Di María, 45og Shelvey, 50 Rooney, 53 Ribéry |
| (3-4-3): De Gea 5, Lahm 7½, Di María 6½, Xavi 6½, Adriano 6, Ivanovic 7, Ribéry 6½, Neymar 7, Suárez 7½, Fabregas 7½, Rooney 6½ | Napoli | 1 | 73 Campagnaro | Half-time: | 0-0 | Referee: | Michel 8 | Attendance: | 50,533 | Possession: | 42%-58% | Total shots: | 14-8 | MoM: | Navas |
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| (4-3-3): De Sanctis 7, Campagnaro 7, Moretti 7, Cigarini 7, Cannavaro 6½, Zaccardo 6½ (74 Maiello 6), Necip 6, Gargano 7, Gignac 7, Keita 6½, Mokotjo 6½ | Sevilla | 0 |
| 13 Silvestre | (4-3-3): Navas 7, Alexis 7½, Fernando Navarro 7, Makoun 6½ (50 O'Donnell 7½), Squillaci 6½, Silvestre 6, Navas 7½, Luscombe 5½, Kiessling 6, Renato 7, Giovinco 6½ | SV Werder Bremen | 3 | 18 Hunt, 62 Hunt, 69 Hunt | Half-time: | 1-1 | Referee: | Gumienny 7 | Attendance: | 35,219 | Possession: | 48%-52% | Total shots: | 6-26 | MoM: | Coleman |
| 2 Diego Capel | (4-3-3): Gabulov 6½, Uchida 7, Abdennour 8, Bargfrede 7, Prödl 6½, Pasanen 7, Oar 6, Hunt 6½, Adebayor 6½, Diego Capel 5½, Wagner 6½ | Exeter City | 1 | 3 Forrest |
| (3-4-3): Foster 6½, Jones 8, Caulker 6½, Barry 6½, Terry 7, Coleman 8, Dyer 6½, Johnson 7½, Lampard 7, Walcott 6½, Forrest 7½ | TSG Hoffenheim | 2 | 11 Ibisevic, 74 Salihovic | Half-time: | 1-1 | Referee: | Meese 8 | Attendance: | 29,993 | Possession: | 44%-56% | Total shots: | 9-11 | MoM: | Luna | TV: | highlights |
| 59 Salihovic | (4-3-3): Fährmann 7, Ebondo 6½, Luna 7½, Maicosuel 7, Ruíz 6½, Simunic 6½, Owomoyela 6½, Salihovic 6½, Ibisevic 6½, Ba 6, Sessčgnon 6 | Lyon | 1 | 26og Maicosuel | 45 Coulibaly | (4-3-3): Bettinelli 7, Gassama 7, Bedimo 6½, Obraniak 7½, Armand 6½, Coulibaly 6, Atik 7½, Boussoufa 7 (67 Sunu 7), Roux 7, Éderson 7, Henry 6 | Round 4 | Arsenal | 4 | 1 Suárez, 5 Rooney, 36 Suárez, 62 Suárez | Half-time: | 3-0 | Referee: | Uilenberg 6½ | Attendance: | 59,863 | Possession: | 49%-51% | Total shots: | 14-9 | MoM: | Müller |
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| (3-4-3): De Gea 7½, Lahm 8, Di María 7, Xavi 7½, Adriano 7½, Ivanovic 6, Ribéry 8, Neymar 6½, Suárez 7½, Fabregas 7, Rooney 7½ | Barcelona | 0 |
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| (4-3-3): Müller 8, Bartra 7½, Azpilicueta 6½, Tiago 6½, Skrtel 7, Mexčs 6, Feghouli 7½, Toivonen 6½, Gomez 7, Torres 5½, Vílla 6½ | Espanyol | 2 | 53 Ninkovic, 90+3og Upson | Half-time: | 0-1 | Referee: | Grabher 7 | Attendance: | 37,117 | Possession: | 54%-46% | Total shots: | 14-6 | MoM: | Pinto |
| 29 Ninkovic | (4-3-3): Yoel 7, Roncaglia 7, Pinto 8, Gurpegui 7, Pareja 7½, Hangeland 6½, Corominas 7, Verdú 7, Juanmi 6½, Ninkovic 7, Olic 7½ | West Ham United | 1 | 25 Johnson | 1 Cole, 11 Gerrard, 26 Bent | (4-3-3): Green 6½, Eastmond 6, Gibbs 6½, Gerrard 7, Mancienne 7, Upson 6, Holmes 6, Johnson 6½ (65 Carroll 7½), Bent 7, Cole 7, Sellin 5½ | Exeter City | 2 | 5 Walcott, 81 Dyer | Half-time: | 1-1 | Referee: | Vassaras 7 | Attendance: | 19,788 | Possession: | 44%-56% | Total shots: | 13-13 | MoM: | Johnson |
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| (3-4-3): Foster 6, Jones 7½, Caulker 6½, Barry 7, Terry 6, Coleman 6, Dyer 6½, Johnson 7½, Lampard 7, Walcott 7½, Forrest 6½ | Internacional | 2 | 42 Fred, 69 Wágner | 74 Júlio Baptista | (4-3-3): Fernando Henrique 6½, Mariano 7 (55 Vinicius 6½), Kléber 7, Giuliano 7½, Marcelo 6½ (53 Marquinhos Gabriel 7), Hilton 6½, Sandro 6½, Wágner 6½, Fred 7, Jô 6, Júlio Baptista 7 | FC Schalke 04 | 4 | 31 Hugo Almeida, 67 Kroos, 75 Rausch, 87 De Jong | |
| (4-3-3): Mielitz 8, Träsch 7, Rausch 8, Kroos 7½, Westermann 8, Williamson 6½, Farfán 8, Costa 6½, Hugo Almeida 5 (65 Schmitz 7), De Jong 6, Bäcker 5½ | Atlético Madrid | 0 |
| 35 Banega, 42 Borja, 45 Biglia, 62 Biglia, 66 Schaars | (4-3-3): Marinelli 7, Jesús 7½, Marcos Alonso 7½, Biglia 6, Rodríguez 8, Marc Muniesa 6½, Banega 6, Schaars 6½, Borja 6, Reyes 5½, Rodrigo 6½ | Lille | 3 | 9 Benatia, 11 Evrŕ, 80 Gaitán | Half-time: | 2-1 | Referee: | Rennie 7 | Attendance: | 18,081 | Possession: | 58%-42% | Total shots: | 16-8 | MoM: | David Luiz |
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| (4-3-3): Lloris 7, Benatia 7½, Evrŕ 7½, Rakitic 7, David Luiz 8, Jallet 5½, Valencia 7, Gaitán 8, Widmer 6½, Dzemaili 5½ (72 Thauvin 6), Origi 5½ | SV Werder Bremen | 1 | 14p Adebayor | 7 Adebayor | (4-3-3): Gabulov 6½, Uchida 6½, Abdennour 7, Bargfrede 7, Prödl 7 (62 Smith 7), Pasanen 7, Oar 5½, Hunt 6½, Adebayor 7, Diego Capel 6, Wagner 6½ | Lyon | 2 | 19 Atik, 88 Boussoufa | Half-time: | 1-2 | Referee: | Sylvestre 6½ | Attendance: | 37,336 | Possession: | 44%-56% | Total shots: | 11-9 | MoM: | Kuyt |
| 8 Roux, 20 Obraniak, 43 Gassama | (4-3-3): Bettinelli 5½, Gassama 6½, Bedimo 6, Obraniak 7, Armand 7, Coulibaly 7, Atik 7, Boussoufa 6½, Roux 6, Belfodil 5½, Henry 7 | Feyenoord | 3 | 5 Van La Parra, 39og Boussoufa, 53 Biseswar | 69 Schaken | (4-3-3): Verhoeven 5½, Hutchinson 6½ (55 Warburton 8½), Pieters 6, De Guzman 7½, Vlaar 7½, Jaliens 7, Kuyt 8, Van La Parra 6½, Biseswar 6½, Babovic 7, Schaken 6 | River Plate | 0 |
| Half-time: | 0-2 | Referee: | Stickroth 6½ | Attendance: | 47,382 | Possession: | 50%-50% | Total shots: | 11-16 | MoM: | Campagnaro |
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| (4-3-3): Chichizola 4½, Ferrari 7½, Rojo 7, Buonanotte 6½, López 6½, Orban 7 (82 Cabral 6), Affranchino 7½, Mouche 6½, López 7½, Castillejos 6, Villalva 6 | Napoli | 4 | 12 Keita, 31 Keita, 70 Gargano, 89 Gargano | 51 Keita | (4-3-3): De Sanctis 5½, Campagnaro 8, Moretti 7½, Cigarini 7, Cannavaro 7, Zaccardo 7 (63 Maiello 6), Necip 6½, Gargano 6½, Gignac 7½, Keita 7, Mokotjo 6 |
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