| Round 5 | | Boca Juniors | 2 | 75 Moralez, 82 Méndez | | Half-time: | 0-0 | | Referee: | McCarvill 5½ | | Attendance: | 33,549 | | Possession: | 47%-53% | | Total shots: | 17-11 | | MoM: | Burdisso |
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| | (4-3-3): Muslera 7, Juárez 7, Routledge 6½, Manuel Fernandes 7½, Burdisso 8, Muñoz 6½, Bruno César 6, Moralez 7, Funes Mori 6 (80 Méndez 6), Barrera 5½, Saviola 5½ | | Udinese | 1 | 88 Zimling |
| | (4-3-3): Romo 7½, Isla 8, Lukovic 7, Lodi 7, Perea 7, Léo 7½, Papadopoulos 6, Zimling 7½, Alex Geijo 6½, Diarra 6½, Jaime 6 | | Boulogne | 0 |
| | Half-time: | 0-2 | | Referee: | Vink 7 | | Attendance: | 14,884 | | Possession: | 51%-49% | | Total shots: | 13-18 | | MoM: | Trindade De Vilhena | | TV: | live |
| | 26 Mikel | | (4-3-3): Frey 6, Srna 7½, Ibañez 7, Thiago 6½, Gamberini 7, Klose 6½, Gökhan 7½, Muniain 7, Álvaro 7 (52 Jadson 6), Mikel 6½, Kalou 6 | | Ajax | 3 | 16 Lens, 45+1 Wijnaldum, 65 Lens |
| | (4-4-2): Cillessen 6, Viergever 7½, De Vrij 7½, Van Der Wiel 7, De Jong 7½, Trindade De Vilhena 7½, Narsingh 7, Emanuelson 7, Wijnaldum 6½, Huntelaar 7, Lens 6 | | CSKA | 2 | 28 Ayew, 88 King | | Half-time: | 1-1 | | Referee: | Beschin 7 | | Attendance: | 13,094 | | Possession: | 39%-61% | | Total shots: | 5-14 | | MoM: | Vukusic |
| | 45 Okay, 46 Fábio Simplício | | (4-3-3): Moyá 7, Sergio Sánchez 6½, Schennikov 6½, Denisov 6½, Ignashevich 6½, Stranzl 6½, Fábio Simplício 7, Dzsudzsák 6½, Borriello 6 (62 King 7½), Okay 6, Ayew 6 | | Hajduk Split | 2 | 19 Vukusic, 61 Ibricic |
| | (4-3-3): Subasic 6, Oremus 7½, Maloca 7½, Vrdoljak 7 (64 Lakic 7½), Sheshukov 6½, Pandza 6½, Rubil 7½, Ibricic 7, Vukusic 7½, Cop 6, Sharbini 6½ | | Fiorentina | 3 | 4 Gilardino, 43 Altidore, 80 Felipe | | Half-time: | 2-2 | | Referee: | Braschi 6½ | | Attendance: | 38,324 | | Possession: | 57%-43% | | Total shots: | 13-12 | | MoM: | Gilardino |
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| | (4-3-3): Mirante 5, De Silvestri 6½, Gobbi 7½, Marchionni 7½, Marchese 5½ (56 Felipe 7½), Cana 6½, Boadu 7, Rômulo 6½, Gilardino 7½, Altidore 6, Ljajic 6½ | | Viktoria Plzen | 4 | 2 Gebre Selassie, 6 Lafata, 54 Kolár, 76 Lafata |
| | (4-4-2): Vaclik 6, Gebre Selassie 7, Kadlec 6½, Suchý 6½, Darida 7, Hübschman 6½, Jirácek 6½, Plasil 7½, Kolár 7½, Lafata 6, Rosický 6½ | | Grasshoppers | 0 |
| | Half-time: | 0-1 | | Referee: | Brito Arceo 7½ | | Attendance: | 17,606 | | Possession: | 45%-55% | | Total shots: | 8-16 | | MoM: | Anita | | TV: | highlights |
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| | (4-3-3): Abbiati 6½, Cavanda 7, Bellusci 7, Anita 7½, Schiemer 6½, Simons 5½, Klaus 6½, Zuber 7, Vossen 7, Janko 6, Ben Khalifa 6½ | | AZ | 1 | 22 Mavuba | | 1 Husev, 34 Nolito | | (4-3-3): Stamatopoulos 6½, Husev 7, Tiendalli 6½, Mavuba 7, Moisander 6½, Moreno 7½, N'Zogbia 6½, Nolito 6½, Jones 6½, Lindgren 6, Esswein 6½ | | Independiente | 2 | 58 Gandín, 73 Tuzzio | | Half-time: | 0-0 | | Referee: | Lytovchak 9 | | Attendance: | 34,540 | | Possession: | 57%-43% | | Total shots: | 16-11 | | MoM: | Özer |
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| | (4-3-3): Orión 7, Tuzzio 7, Vallés 7, Acevedo 7, Galeano 7, Vittor 6, Fredes 6½, Rodríguez 7, Gandín 7, Mancuello 6, Suarez 6 | | Fenerbahçe | 0 |
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| | (4-4-2): Onur Recep 7, Gökhan 6, Cech 6½, Özer 7½, Egemen 6½, Remzi Giray 6, Selçuk 6½, Sezer 6, Sow 7½, Serdar 6, Burak 6½ | | Inter | 0 |
| | Half-time: | 0-2 | | Referee: | Larsen 5½ | | Attendance: | 48,205 | | Possession: | 53%-47% | | Total shots: | 7-14 | | MoM: | Rômulo | | TV: | highlights |
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| | (4-3-3): Belec 6½, Donati 6½, Britos 7, Pandev 7, Biava 6½, Maxim 6, Rômulo 7½, Arnautovic 6½, Milito 7, M'Poku 7 (68 Diamanti 6), Eto'o 6 | | Accrington Stanley | 2 | 14 Welbeck, 20 Sterling | | 27 Sterling | | (4-3-3): Forster 7, Walker 6½, Rose 7½, Smalling 7, Williams 6, Ramsey 7½, Sterling 6½, Allen 7 (81 Chambers 6), Sturridge 6½, Barkley 6, Welbeck 6½ | | Milan | 3 | 28 Joaquín, 41 Kolarov, 55 Kolarov | | Half-time: | 2-0 | | Referee: | Webb 6½ | | Attendance: | 48,772 | | Possession: | 53%-47% | | Total shots: | 17-10 | | MoM: | Tomovic |
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| | (3-4-3): Oblak 7½, Lovren 7½, Ranocchia 6½, Cabaye 6½, Distin 7, Aurier 6½, Joaquín 6, Kolarov 7, Mandzukic 7½, Javi Martínez 6, Diego Costa 6 | | Juventus | 0 |
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| | (4-3-3): Manninger 7, Tomovic 8, De Ceglie 6½, Felipe Melo 7, Palombo 7, Sørensen 6½, Hult 6, Nenê 6½, Sigþórsson 7½, Rossi 6½, Berg 6 | | Palermo | 3 | 27 Insigne, 34 Cassano, 55 Cassano | | Half-time: | 2-0 | | Referee: | Nielsen 7 | | Attendance: | 38,947 | | Possession: | 47%-53% | | Total shots: | 18-7 | | MoM: | Criscito |
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| | (3-4-3): Benaglio 6½, Cassani 6, Motta 6½, Criscito 8, Montolivo 6, Astori 7½, Parolo 7, Cassano 7, Candreva 7, Inler 7½, Insigne 7 | | Hamburger SV | 1 | 65 Ebert |
| | (4-3-3): Karnezis 7, Boenisch 6½, Jansen 6½, Aogo 6½, Mathijsen 6, Rozehnal 6, Ebert 7, Elia 6½, Guerrero 7½, Pavlyuchenko 6, Petric 6 | | VfB Stuttgart | 4 | 18 Gebhart, 23 Gebhart, 39 Gebhart, 62 Schieber | | Half-time: | 3-1 | | Referee: | Brignoccoli 8 | | Attendance: | 32,173 | | Possession: | 54%-46% | | Total shots: | 12-2 | | MoM: | Bruma |
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| | (4-3-3): Oguzhan 6½, Osorio 7, Boka 8, Lanig 7½, Niedermeier 7, Delpierre 7, Kuzmanovic 6, Gebhart 6½, Schieber 7, Hamit 6, Marica 6 | | Genoa | 1 | 40 Acquafresca |
| | (4-3-3): Edgar Badia 6, Onuoha 7, Riera 7, Bogliacino 7½, Bruma 8½, Kharja 6½, Jankovic 6½, Lazzari 7½, Acquafresca 7, Palladino 6, Palacio 7 | | Villarreal | 0 |
| | Half-time: | 0-1 | | Referee: | Detruche 6½ | | Attendance: | 22,981 | | Possession: | 42%-58% | | Total shots: | 11-15 | | MoM: | Naughton |
| | 51 Hleb | | (4-3-3): Andersen 6½, Eboué 7, Marcellis 6½, Strobl 7, Juan 7, Lopo 6½, Bebé 6, Hleb 7, Derdiyok 7, Campaña 6, Forlán 6½ | | Aston Villa | 1 | 45 Bannan |
| | (4-3-3): Adrián 6½, Naughton 8, Warnock 7, Aissati 7½, Collins 8, Dunne 6½, Sidwell 7, Bannan 7, Delfouneso 5½, Reo-Coker 6½, Agbonlahor 6 | | Round 3 | | Villarreal | 1 | 21og Remzi Giray | | Half-time: | 1-1 | | Referee: | Wieser 6 | | Attendance: | 22,814 | | Possession: | 39%-61% | | Total shots: | 8-20 | | MoM: | Egemen |
| | 3 Campaña, 57 Hleb, 81 Juan | | (4-3-3): Andersen 6, Eboué 7, Marcellis 7½, Strobl 6½, Juan 7, Lopo 6½, Bebé 6½, Hleb 5½, Derdiyok 6, Campaña 6, Forlán 6½ | | Fenerbahçe | 1 | 1 Sow | | 64 Egemen | | (4-4-2): Onur Recep 7, Gökhan 7, Cech 7, Özer 7½, Egemen 7½, Remzi Giray 6½, Selçuk 6½, Sezer 7, Sow 7, Serdar 6½, Burak 7½ | | VfB Stuttgart | 1 | 78 Gebhart | | Half-time: | 0-1 | | Referee: | Rudy 6½ | | Attendance: | 38,584 | | Possession: | 43%-57% | | Total shots: | 9-10 | | MoM: | Aogo |
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| | (4-3-3): Oguzhan 6, Osorio 6, Boka 7, Lanig 7½, Niedermeier 7, Delpierre 6½, Kuzmanovic 7, Gebhart 7½, Schieber 6½, Hamit 6, Marica 5½ | | Hamburger SV | 2 | 14 Guerrero, 66 Guerrero |
| | (4-3-3): Karnezis 6½, Boenisch 7, Jansen 7½, Aogo 8, Mathijsen 8, Rozehnal 7, Ebert 7, Elia 7, Guerrero 7, Pavlyuchenko 5½, Petric 6½ | | Boulogne | 2 | 4p Álvaro, 58 Muniain | | Half-time: | 1-0 | | Referee: | Ancion 7 | | Attendance: | 14,879 | | Possession: | 61%-39% | | Total shots: | 20-7 | | MoM: | Pajot |
| | 47 Thiago, 62 Ibañez, 66 Gamberini | | (4-3-3): Frey 7, Srna 7½, Ibañez 8, Thiago 7½, Gamberini 7, Klose 7½, Gökhan 7½, Muniain 6 (59 Pajot 8), Álvaro 7½, Mikel 7, Kalou 6½ | | Udinese | 1 | 50 Basta |
| | (4-3-3): Romo 6½, Isla 6½, Lukovic 7½, Lodi 6½ (57 Landgren 7), Perea 7, Léo 6, Basta 6½, Zimling 6, Alex Geijo 6, Diarra 5½, Jaime 6 |
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