| Round 3 | | 1.FC Köln | 0 |
| | Half-time: | 0-0 | | Referee: | Aðalsteinsson 7½ | | Attendance: | 48,264 | | Possession: | 41%-59% | | Total shots: | 11-14 | | MoM: | Matic | | TV: | highlights |
| | 5 Weihrauch, 49 Giroud | | (4-3-3): Zieler 7½, Höger 7 (54 Jean 7), Aogo 6½, Castro 6½ (59 Cabella 7), Reinartz 6½, Corchia 6, Meier 6, Herrmann 8, Giroud 6½, Gameiro 6½, Weihrauch 5½ | | Chelsea | 0 |
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| | (4-3-3): Courtois 8, Moses 8, Marcos Alonso 7½, Matic 8, Cahill 7, Benalouane 7, Traoré 7 (56 Manea 6), Hazard 7, Falcao 7, Fabregas 7, Kenedy 6 | | Anderlecht | 2 | 6 Gnabry, 50 Suarez | | Half-time: | 1-0 | | Referee: | D'Urso 5½ | | Attendance: | 28,012 | | Possession: | 50%-50% | | Total shots: | 11-10 | | MoM: | Hamsík |
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| | (4-3-3): Handanovic 7, Gillet 7½, Lukaku 8, Hamsík 8, Barzagli 7, Rugani 6½, Touré 7, Gnabry 7, Suarez 7, Kouyaté 7, Watmore 5½ | | Lazio | 0 |
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| | (4-3-3): Berisha 7½, De Silvestri 7, Lulic 6½, Biglia 7½, Radu 6½, Ciani 6½, Candreva 7, Berardi 7, Floccari 6, Felipe Anderson 7½, Alfaro 6 | | Corinthians | 3 | 4 Higuaín, 21 El Haddadi, 73 Özil | | Half-time: | 2-0 | | Referee: | Beeby 6 | | Attendance: | 40,011 | | Possession: | 59%-41% | | Total shots: | 16-8 | | MoM: | Marcelo | | TV: | live |
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| | (4-3-3): Cech 7½, Pereira 8, Marcelo 8½, Iniesta 5½ (48 Maxwell 7), Ignashevich 7, Vidal 6, Özil 7½, Di María 7, Higuaín 7½, Ponce 6, El Haddadi 6½ | | Feyenoord | 0 |
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| | (4-3-3): Cillessen 7½, Janmaat 7, Martins-Indi 7, Strootman 6, De Vrij 7, Kongolo 6½, Kuyt 6½, Depay 6½, Van Persie 7, Huntelaar 5½, Darri 5½ | | Eintr. Frankfurt | 1 | 39 Kittel | | Half-time: | 1-0 | | Referee: | Grabher 6½ | | Attendance: | 38,186 | | Possession: | 56%-44% | | Total shots: | 15-9 | | MoM: | Perin | | TV: | highlights |
| | 71 Bender | | (4-3-3): Leno 7½, Höwedes 6, Hector 7½, Bender 7½, Mustafi 7½, Badstuber 7½, Lanig 6½, Kittel 6½, Kiessling 6½, Schwegler 6½, Occean 6½ | | Genoa | 0 |
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| | (4-3-3): Perin 8, Alvarez 6½, Antonelli 6, Sturaro 6, De Maio 6½ (55 Antonini 6½), Manfredini 6½, Cofie 5½, Stoian 7, Said 6, Kucka 5½, Konaté 5½ | | Espanyol | 0 |
| | Half-time: | 0-0 | | Referee: | Wieser 7½ | | Attendance: | 40,423 | | Possession: | 51%-49% | | Total shots: | 10-16 | | MoM: | Koscielny | | TV: | live |
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| | (4-3-3): De Gea 7, Piszczek 7, Ruíz 7, Khedira 7½, Koscielny 8, Moreno 6½, Raúl García 7 (61 Diego Costa 7½), Silva 6½, Lewandowski 6½, Ribéry 7, Agüero 6½ | | Real Madrid | 1 | 55 Ronaldo |
| | (4-3-3): Navas 7½, Sergio Ramos 7, Tagliafico 7, Kroos 7, Dos Santos 7, Modric 6, Lucas 7½, Ronaldo 6½, Benzema 7, Casemiro 7, Jesé 5 | | FC Basel | 1 | 77 Doumbia | | Half-time: | 0-1 | | Referee: | Bettin 7½ | | Attendance: | 38,446 | | Possession: | 52%-48% | | Total shots: | 10-6 | | MoM: | Javi Martínez |
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| | (4-3-3): Lloris 6, Geria 6½, Jordi Alba 7½, Javi Martínez 8, Varane 8, Ricardo Carvalho 6, Xhaka 6½, Schürrle 7, Doumbia 7, Díaz 6½, Zoua 6½ | | Sassuolo | 2 | 28 Reyes, 70 Eto'o | | 33 Petagna | | (4-3-3): Pomini 6, Neto 6½, Durm 7, Duncan 7, Bartra 7 (52 Halilovic 6½), Antei 6, Callejón 7, Reyes 7½, Eto'o 6½, Petagna 6, Seferovic 6½ | | Round 4 | | Chelsea | 1 | 45+3 Marcos Alonso | |
| | (4-3-3): Courtois 7½, Moses 7½, Marcos Alonso 8½, Willian 7, Cahill 6½, Benalouane 6, Traoré 7½, Hazard 8, Falcao 6½ (57 Matic 7), Fabregas 8, Kenedy 6 | | Anderlecht | 0 |
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| | (4-3-3): Handanovic 7½, Gillet 6½, Lukaku 7, Hamsík 7, Barzagli 6½, Kouyaté 6, Touré 6, Gnabry 6, Suarez 6, Barry 5½, Watmore 5½ | | Dnipro | 1 | 65og Drinkwater | | Half-time: | 0-0 | | Referee: | Damgaard 5½ | | Attendance: | 24,363 | | Possession: | 51%-49% | | Total shots: | 13-10 | | MoM: | Rakitic |
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| | (4-3-3): Hart 7½, Lichtsteiner 7½, Pasqual 6, Rakitic 8, Veltman 7, Bruno Alves 6, Konoplyanka 6, Matuidi 7, Dzeko 7½, Danny 6½, Uth 7 | | Leicester City | 0 |
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| | (4-3-3): Schmeichel 7½, Kelly 7, Fuchs 6½, King 7, Huth 6, Morgan 6½, Drinkwater 7, Mahrez 6½, Iheanacho 6, James 6½ (65 Gray 6½), Okazaki 6½ | | Elche | 0 |
| | Half-time: | 0-0 | | Referee: | Strampe 6 | | Attendance: | 38,574 | | Possession: | 42%-58% | | Total shots: | 11-15 | | MoM: | Khedira |
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| | (4-3-3): Cássio 7, Nacho 6½, Moreno 7, Diego Capel 6½, Britos 7, Pelegrín 6½, Mantecón 7, Muniain 6, Martínez 6½, Sassá 6, Vela 7 | | Espanyol | 1 | 83 Silva |
| | (4-3-3): De Gea 6½, Piszczek 6, Ruíz 6½, Khedira 8, Christensen 7, Moreno 6½, Raúl García 7½, Silva 7½, Lewandowski 6½, Ribéry 6½ (84 Diego Costa 6), Agüero 7½ | | Estudiantes (LP) | 1 | 49 Zapata | | Half-time: | 0-0 | | Referee: | José Pratas 7½ | | Attendance: | 38,744 | | Possession: | 61%-39% | | Total shots: | 15-7 | | MoM: | Diego | | TV: | highlights |
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| | (4-3-3): Reina 7½, Fernández 6, Silva 6, Diego 8, Schunke 6, Obbadi 6½, Salvio 6½ (70 Innocenti 7), Braña 7, Zapata 7, Gago 7½, Alexandre Pato 7½ | | Catania | 0 |
| | 26 Hoedt, 46 David Luiz | | (4-3-3): Viviano 7½, Rafael 6½, Molinaro 7, Pjanic 6½, David Luiz 7, Hoedt 6, Keko 6, De Paul 6½, Matri 6½, Castro 7, Vílla 6 | | Feyenoord | 2 | 44 Van Persie, 45+2 Martins-Indi | | Half-time: | 2-0 | | Referee: | Waddel 8 | | Attendance: | 44,300 | | Possession: | 59%-41% | | Total shots: | 16-13 | | MoM: | Kuyt |
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| | (4-3-3): Cillessen 7½, Janmaat 7, Martins-Indi 7, Strootman 7½, De Vrij 8, Kongolo 7½, Kuyt 8, Depay 8, Van Persie 6 (55 Ayoub 7½), Huntelaar 7, Darri 5½ | | Internacional | 1 | 57 Miranda |
| | (4-3-3): Ter Stegen 7½, Dani Alves 6, Filipe Luis 7, Fernandinho 6½, Miranda 7½, Klaassen 6, Fred 7, Philippe Coutinho 6½, Lukaku 6, Lacazette 6, Kaprof 5½ | | Melbourne Victory | 1 | 43 Cork | | Half-time: | 1-1 | | Referee: | Bennett 7½ | | Attendance: | 29,900 | | Possession: | 52%-48% | | Total shots: | 15-15 | | MoM: | El Mohammadi |
| | 12 Lallana, 45+3 Knoche | | (4-3-3): Foster 6½, Aurier 7, Baines 8, Samaris 8, Stark 7, Knoche 6, Aránguiz 7, Lallana 6½ (68 Broerse 6), Immobile 6, Cork 7½, Kruse 6 | | Sunderland | 1 | 26 El Mohammadi |
| | (4-3-3): Mignolet 8, Van Der Wiel 7½, Rose 7½, Sessègnon 7½, Dann 6½, O'Shea 6, El Mohammadi 8, Puncheon 6, Quagliarella 6½, Soldado 5½, Wickham 6 | | Racing Club | 1 | 1og Lanig | | Half-time: | 1-0 | | Referee: | López Nieto 6½ | | Attendance: | 45,108 | | Possession: | 43%-57% | | Total shots: | 16-16 | | MoM: | Hector |
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| | (4-3-3): Mandanda 7½, Roncaglia 6½, Alaba 7, Verratti 7½, Spolli 6½, Lluy 6½, Villar 6½, Piatti 7, Víetto 6½, Oscar 6½, Centurión 6 | | Eintr. Frankfurt | 0 |
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| | (4-3-3): Leno 7½, Höwedes 7½, Hector 8, Bender 7½, Mustafi 7½, Badstuber 7½, Lanig 7, Kittel 7, Kiessling 6, Schwegler 5½, Occean 6 | | Real Madrid | 2 | 55 Ronaldo, 61 Ronaldo | | Half-time: | 0-0 | | Referee: | Sarvan 7 | | Attendance: | 47,338 | | Possession: | 61%-39% | | Total shots: | 14-7 | | MoM: | Kroos |
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| | (4-3-3): Navas 7½, Sergio Ramos 8½, Tagliafico 8½, Kroos 8½, Dos Santos 7½, Modric 7, Lucas 7½, Ronaldo 7½, Benzema 7, Casemiro 7, Jesé 6½ | | Fluminense | 0 |
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| | (4-3-3): Muslera 7, Sagna 6, Vermaelen 7, Behrami 6½, Campagnaro 7, Miguel Veloso 7, Orejuela 7 (54 Douglas 6½), Arango 6½, Fred 6, Gustavo Henrique 5½, Tévez 6½ | | Sassuolo | 2 | 3 Seferovic, 15 Reyes | | Half-time: | 2-0 | | Referee: | Onufer 6 | | Attendance: | 20,317 | | Possession: | 44%-56% | | Total shots: | 15-10 | | MoM: | Aogo |
| | 19 Magnanelli | | (4-3-3): Pomini 7, Neto 6½, Durm 7½, Duncan 7½, Bartra 7, Antei 6½, Callejón 6 (61 Petagna 6½), Reyes 6½, Eto'o 6½, Magnanelli 6½, Seferovic 6 | | 1.FC Köln | 1 | 74 Giroud | | 49 Giroud, 90+1 Castro | | (4-3-3): Zieler 7, Höger 7, Aogo 8, Castro 7, Reinartz 7½, Corchia 6½, Meier 7, Herrmann 6½, Giroud 7½, Gameiro 6½ (75 Jean 6½), Weihrauch 6 |
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