| Round 5 | | 1.FC Köln | 1 | 90 Giroud | | Half-time: | 0-0 | | Referee: | Boggi 6½ | | Attendance: | 46,778 | | Possession: | 45%-55% | | Total shots: | 6-14 | | MoM: | Pasqual |
| | 76 Jean | | (4-3-3): Zieler 7, Höger 6½ (54 Jean 7), Aogo 7, Castro 7 (59 Cabella 7½), Reinartz 7, Corchia 6, Meier 6½, Herrmann 7, Giroud 7, Gameiro 6½, Weihrauch 6½ | | Dnipro | 0 |
| | 7 Konoplyanka, 16 Bruno Alves | | (4-3-3): Hart 7, Lichtsteiner 7½, Pasqual 7½, Rakitic 7½, Veltman 7 (67 Okriashvili 6), Bruno Alves 7, Konoplyanka 6, Matuidi 6½, Dzeko 6, Danny 6½, Uth 6 | | Anderlecht | 1 | 63 Suarez | | Half-time: | 0-0 | | Referee: | Ziober 6½ | | Attendance: | 28,005 | | Possession: | 51%-49% | | Total shots: | 13-13 | | MoM: | Foster |
| | 6 Barry | | (4-3-3): Handanovic 7, Gillet 7, Lukaku 6, Hamsík 7, Barzagli 7½, Kouyaté 6½, Touré 6½, Gnabry 7, Suarez 7, Barry 6½, Watmore 6 | | Melbourne Victory | 0 |
| | 68 Stark | | (4-3-3): Foster 8, Aurier 7½, Baines 7½, Samaris 6½, Stark 6½, Knoche 5½, Aránguiz 6½, Lallana 6½, Immobile 7, Cork 7½, Kruse 6½ | | Catania | 3 | 17 De Paul, 59 Matri, 80og Lulic | | Half-time: | 1-1 | | Referee: | Strampe 8 | | Attendance: | 23,411 | | Possession: | 49%-51% | | Total shots: | 20-9 | | MoM: | Pjanic |
| | 74 David Luiz, 85 Hoedt | | (4-3-3): Viviano 6, Rafael 7 (81 Muñoz 6), Molinaro 6½, Pjanic 8, David Luiz 7, Hoedt 6½, Keko 5½ (80 Burak 6), De Paul 6½, Matri 7, Castro 6½, Vílla 7 | | Lazio | 3 | 3 Berardi, 68 Felipe Anderson, 87p Floccari |
| | (4-3-3): Berisha 6, De Silvestri 7 (50 Lombardi 7), Lulic 7, Biglia 6½, Radu 7, Ciani 6, Candreva 7½, Berardi 7, Floccari 7, Felipe Anderson 6½, Alfaro 6 | | Corinthians | 2 | 7 Özil, 22 Marcelo | | Half-time: | 2-0 | | Referee: | Ziller 6½ | | Attendance: | 40,072 | | Possession: | 59%-41% | | Total shots: | 16-8 | | MoM: | Maxwell | | TV: | live |
| | 76 Vidal, 81 El Haddadi | | (4-3-3): Cech 6½, Pereira 7, Marcelo 6½, Iniesta 6 (48 Maxwell 8½), Ignashevich 7½, Vidal 6½, Özil 8, Di María 7, Higuaín 7½, Ponce 5½, El Haddadi 6½ | | Sassuolo | 1 | 89 Reyes | | 32 Albiol, 34 Bartra | | (4-3-3): Pomini 6, Neto 6½ (65 Hernanes 6½), Durm 7, Motta 6½, Albiol 6½, Bartra 6½, Callejón 7½, Reyes 7, Eto'o 6½, Petagna 6½, Seferovic 7 | | Eintr. Frankfurt | 2 | 10 Badstuber, 24 Kittel | | Half-time: | 2-1 | | Referee: | Vorjas 6 | | Attendance: | 44,782 | | Possession: | 51%-49% | | Total shots: | 17-13 | | MoM: | Silva | | TV: | highlights |
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| | (4-3-3): Leno 7½, Höwedes 7½, Hector 7½, Bender 8, Mustafi 7, Badstuber 7, Lanig 7, Kittel 7, Kiessling 7, Schwegler 7½, Occean 6 | | Estudiantes (LP) | 1 | 40 Gago | | 89 Obbadi | | (4-3-3): Reina 7½, Fernández 7, Silva 8, Diego 7½, Schunke 6½, Obbadi 6, Salvio 6½, Braña 6½, Zapata 6, Gago 5½, Alexandre Pato 6 | | Espanyol | 3 | 18 Raúl García, 60 Silva, 87 Raúl García | | Half-time: | 1-0 | | Referee: | Van Vliet 7½ | | Attendance: | 40,448 | | Possession: | 60%-40% | | Total shots: | 21-12 | | MoM: | Silva | | TV: | highlights |
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| | (4-3-3): De Gea 7, Piszczek 7, Ruíz 7½, Khedira 8, Koscielny 8, Moreno 6½, Raúl García 7½, Silva 8, Lewandowski 7, Ribéry 7, Agüero 5½ (61 Diego Costa 7) | | Genoa | 1 | 63 Stoian |
| | (4-3-3): Perin 6½, Alvarez 6, Antonelli 6½, Sturaro 8, De Maio 7 (55 Antonini 6), Manfredini 6, Cofie 6½, Stoian 6, Said 5½, Kucka 6½, Konaté 6½ | | FC Basel | 0 |
| | Half-time: | 0-2 | | Referee: | Borriello 5½ | | Attendance: | 38,435 | | Possession: | 58%-42% | | Total shots: | 15-15 | | MoM: | Willian | | TV: | live |
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| | (4-3-3): Lloris 5½, Geria 6½, Jordi Alba 8, Javi Martínez 7, Varane 7, Ricardo Carvalho 7, Xhaka 6½, Schürrle 7½, Doumbia 7, Díaz 5½, Zoua 6 | | Chelsea | 2 | 3 Fabregas, 31 Hazard |
| | (4-3-3): Courtois 6½, Moses 7, Marcos Alonso 7, Willian 8, Cahill 7, Benalouane 5½, Traoré 6, Hazard 7, Falcao 7 (57 Matic 6½), Fabregas 6½, Kenedy 5½ | | Fluminense | 2 | 40 Fred, 86 Nani | | Half-time: | 1-1 | | Referee: | Krondl 7 | | Attendance: | 41,231 | | Possession: | 54%-46% | | Total shots: | 18-11 | | MoM: | Miguel Veloso |
| | 13 Sagna, 30 Campagnaro | | (4-3-3): Muslera 7, Sagna 7½, Nagatomo 7 (87 Gustavo Henrique 6), Arango 8, Vermaelen 7, Campagnaro 6 (87 Orejuela 6), Joaquín 7½, Nani 7½, Fred 7, Miguel Veloso 8, Tévez 5½ | | Racing Club | 1 | 11p Víetto |
| | (4-3-3): Romero 6½, Roncaglia 7, Alaba 6, Verratti 7, Spolli 6½, Lluy 6½, Villar 6½, Piatti 6, Víetto 7 (53 Fariña 6½), Sand 6, Centurión 5½ | | Internacional | 2 | 50 Philippe Coutinho, 77 Lucas Piazón | | Half-time: | 0-2 | | Referee: | Khussainov 7½ | | Attendance: | 48,977 | | Possession: | 50%-50% | | Total shots: | 14-17 | | MoM: | Ronaldo | | TV: | highlights |
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| | (4-3-3): Cristiano 5½, Dani Alves 7, Filipe Luis 6½, Fernandinho 7½, Miranda 7½, Otavio 6, Klaassen 7, Philippe Coutinho 7, Lacazette 6 (71 Lucas Piazón 7½), Lukaku 6, Kaprof 5½ | | Real Madrid | 3 | 18 Ronaldo, 39 Tagliafico, 84 Ronaldo |
| | (4-3-3): Navas 6½, Sergio Ramos 6½, Tagliafico 7½, Kroos 7, Dos Santos 7, Modric 6, Lucas 7½, Ronaldo 7½, Benzema 6, Casemiro 6½, Jesé 6 | | Leicester City | 2 | 18 Okazaki, 76 Fuchs | | Half-time: | 1-1 | | Referee: | McCluskey 6 | | Attendance: | 32,335 | | Possession: | 44%-56% | | Total shots: | 16-12 | | MoM: | Janmaat |
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| | (4-3-3): Schmeichel 7½, Kelly 6, Fuchs 7½, King 7½, Huth 7, Morgan 6, Drinkwater 7, Mahrez 7, Iheanacho 7, James 6, Okazaki 6 | | Feyenoord | 1 | 22 Huntelaar |
| | (4-3-3): Cillessen 7½, Janmaat 8, Willems 7, Strootman 7½, De Vrij 7, Martins-Indi 7, Sneijder 7 (63 Kongolo 6½), Robben 7½, Huntelaar 7, Van Persie 7 (75 Depay 6), Lens 6½ | | Sunderland | 3 | 7 Dann, 35p Quagliarella, 56 Puncheon | | Half-time: | 2-0 | | Referee: | Waddel 7 | | Attendance: | 32,594 | | Possession: | 43%-57% | | Total shots: | 8-12 | | MoM: | Nacho |
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| | (4-3-3): Mignolet 7½, Van Der Wiel 7½, Rose 7, Sessègnon 7½, Dann 6½, O'Shea 6½, El Mohammadi 6½, Puncheon 6½, Quagliarella 7½, Soldado 5½ (56 Yesil 6½), Wickham 6 | | Elche | 0 |
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| | (4-3-3): Cássio 7½, Nacho 8, Moreno 7, Diego Capel 7 (62 Mané 6½), Britos 7½, Pelegrín 6, Mantecón 6½, Susaeta 7, Martínez 7, Sassá 5½, Vela 6 | | Round 4 | | Genoa | 1 | 32 Stoian | | Half-time: | 1-1 | | Referee: | Young 6½ | | Attendance: | 31,892 | | Possession: | 55%-45% | | Total shots: | 20-5 | | MoM: | Geria |
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| | (4-3-3): Perin 7, Alvarez 6, Antonelli 6½, Sturaro 7½, De Maio 7, Manfredini 6½, Cofie 7, Stoian 8, Said 6, Kucka 6½, Konaté 6½ | | FC Basel | 1 | 12 Doumbia |
| | (4-3-3): Lloris 7, Geria 8, Jordi Alba 7, Javi Martínez 7, Varane 6½, Ricardo Carvalho 7, Xhaka 7, Schürrle 7, Doumbia 6½, Díaz 6½, Zoua 5½ | | Lazio | 1 | 18 Floccari | | Half-time: | 1-2 | | Referee: | Flückiger 9 | | Attendance: | 41,722 | | Possession: | 55%-45% | | Total shots: | 12-8 | | MoM: | Candreva |
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| | (4-3-3): Berisha 6, De Silvestri 7, Lulic 7½, Biglia 7½, Radu 7, Ciani 6, Candreva 8, Berardi 7, Floccari 6½, Felipe Anderson 6, Alfaro 6½ | | Corinthians | 2 | 10 Di María, 33 Higuaín |
| | (4-3-3): Cech 6½, Pereira 6½, Marcelo 6, Iniesta 7 (48 Maxwell 8), Ignashevich 7, Vidal 6, Özil 7, Di María 6½, Higuaín 6½, Ponce 6, El Haddadi 6 |
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