| Round 5 | | Ajax | 2 | 12 Schřne, 87 Schřne | | Half-time: | 1-0 | | Referee: | Jol 8 | | Attendance: | 27,540 | | Possession: | 45%-55% | | Total shots: | 9-16 | | MoM: | Van Der Hart | | TV: | highlights |
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| | (4-3-3): Van Der Hart 8, Martina 6½, Kishna 6, Moisander 6½, Denswil 6 (81 Andersen 6), Van Der Hoorn 7, Duarte 6, Schřne 6½, Milik 6½, Sigţórsson 6½, Bojan 7 | | Racing Genk | 1 | 81 Kara | | 7 Kara, 20 Limbombe | | (4-3-3): Proto 7, Ngcongca 7, Tshimanga 7½, Kara 7½, Koulibaly 6½, Nadson 7, Buffel 7, Limbombe 7, Plet 7½, Simaeys 6, Vossen 6½ | | Arsenal | 1 | 54 Sánchez | | Half-time: | 0-0 | | Referee: | Huzu 7 | | Attendance: | 48,321 | | Possession: | 47%-53% | | Total shots: | 11-9 | | MoM: | Bellerín |
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| | (4-3-3): Ospina 7, Bellerín 8, Nacho Monreal 7, Coquelin 6½ (59 Reine-Adelaďde 6½), Chambers 7½, Debuchy 6, Santi Cazorla 7 (76 Wilshere 5½), Sánchez 7½, Campbell 7, El Nenny 6, Welbeck 6½ | | Villarreal | 0 |
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| | (4-3-3): Diego 6½, Rukavina 7 (60 Damonte 7), Jaume 7, Bruno 7½, Musacchio 7, Chechu 7, Aquino 7, Pérez 7, Uche 6½, Trigueros 7, Jonathan 5½ | | Baník Ostrava | 1 | 86 Promes | | Half-time: | 0-1 | | Referee: | Dean 6½ | | Attendance: | 17,245 | | Possession: | 50%-50% | | Total shots: | 13-9 | | MoM: | Promes | | TV: | highlights |
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| | (4-3-3): Nyland 5½, Fornasier 7, Aké 7½, Oliver 7, Naldo 7, Balanta 7, Promes 8, Martial 7, Córdoba 6½, Sanson 6½, Baldé 5½ | | Botafogo | 2 | 23 Ronaldinho, 82p Vitinho |
| | (4-3-3): Jéfferson 6, Fabinho 8, Laxalt 7 (81 Gabriel 6), Paulinho 7½, Dante 7, Mário Fernandes 6½, Leandrinho 7, Michel Bastos 6 (55 Rodrigo Caio 7), Vitinho 6½, Pasalic 7, Ronaldinho 6 | | Bayern München | 1 | 57 Douglas Costa | | Half-time: | 0-0 | | Referee: | Manning 7 | | Attendance: | 47,456 | | Possession: | 57%-43% | | Total shots: | 19-9 | | MoM: | Götze |
| | 75 Müller | | (4-3-3): Neuer 7, Kimmich 7, Bernat 7, Götze 8, Boateng 7½, McShane 6, Coman 7, Douglas Costa 7, Aitchison 6½ (66 Green 6), Pantovic 5½, Müller 6½ | | Trabzonspor | 0 |
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| | (4-3-3): Onur Recep 7½, Serkan 6½, Olcan 6½, Sapara 7, Celustka 6½, Mustafa 6, Colman 5½, Soner 6½, Janko 6½, Cardozo 6, Halil 6 | | FC Křbenhavn | 1 | 39 Arshavin | | Half-time: | 1-1 | | Referee: | Heynemann 7 | | Attendance: | 39,386 | | Possession: | 57%-43% | | Total shots: | 11-11 | | MoM: | Dolberg |
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| | (4-3-3): Weidenfeller 6½, Sřrensen 7½, Antunes 8, Toutouh 6½, Kjćr 8, Freire 6½, Bolańos 7, Eriksen 7, Dolberg 8, Cornelius 6, Arshavin 7½ | | Hertha BSC Berlin | 1 | 30 Mukhtar |
| | (4-3-3): Adler 6½, Schwaab 7, Kolasinac 6½, Niemeyer 7 (70 Helenius 7½), Brooks 6, Hubník 5½, Olkowski 6½, Mukhtar 6½, Aubameyang 6½, Kalou 5½, Gerard 6 | | Liverpool | 0 |
| | Half-time: | 0-2 | | Referee: | José Pratas 5 | | Attendance: | 32,929 | | Possession: | 60%-40% | | Total shots: | 20-6 | | MoM: | Can |
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| | (4-3-3): Karius 6, Clyne 7½, Milner 7½, Can 8, Lovren 7½, Matip 7, Wilson 6, Mané 7½, Sturridge 6½, Wijnaldum 7, Roberto Firmino 6 | | Pescara | 2 | 29 Montolivo, 36 Belotti |
| | (4-3-3): Consigli 7, Rüdiger 6½, Vertonghen 7½, Soriano 7, Otamendi 6½, Jantschke 6, Inler 6½, Mandzukic 7, Belotti 7, Montolivo 6½, Çelik 5½ | | New York | 1 | 77 Altidore | | Half-time: | 0-1 | | Referee: | Wiley 6½ | | Attendance: | 39,548 | | Possession: | 47%-53% | | Total shots: | 11-22 | | MoM: | Nainggolan |
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| | (4-3-3): Krul 6½, Kühne 7, Johnson 7, Nainggolan 8, Gabriel Paulista 6½, Wanyama 6½, Giovani 6½, Parolo 6½, Altidore 6½, Cook 6½, Benayoun 6½ | | América | 2 | 14 Iago, 86 Dos Santos |
| | (4-3-3): Marchesín 7, Salcedo 7, Cáceres 7, Bermúdez 7 (74 Romero 7), Reyes 6 (86 Coulibaly 6), Maza 6½, Dos Santos 7, Rodríguez 7, Peralta 6½, Atsu 6, Iago 6 | | Newell's Old Boys | 2 | 66 Kokorin, 87 Pastore | | Half-time: | 0-1 | | Referee: | Gumienny 7 | | Attendance: | 31,985 | | Possession: | 51%-49% | | Total shots: | 16-13 | | MoM: | Schmelzer | | TV: | highlights |
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| | (4-3-3): Aitor 7, Ginter 7½, Schmelzer 8, Ramsey 6 (49 López 6½), Martínez 7, Terry 7½, Cabaye 7, Pastore 7, Drogba 7, Rodríguez 7, Kokorin 6 | | Caen | 1 | 25 Féret | | 35 Adéoti | | (4-3-3): Vercoutre 7, Dabo 7, Bessat 7, Féret 7, Da Silva 7½, Genevois 6, Delaplace 6, Imorou 6½, Santini 6, Adéoti 6½, Rodelin 6 | | Parma | 2 | 20 Mauri, 70 Perotti | | Half-time: | 1-0 | | Referee: | Circhetta 8 | | Attendance: | 27,834 | | Possession: | 47%-53% | | Total shots: | 9-9 | | MoM: | De Ruiter | | TV: | live |
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| | (4-3-3): Strakosha 7, Pedro Mendes 7½, Peluso 7, Acquah 6, Paletta 6½, Felipe 6, Rispoli 7½, Perotti 7, Coda 6½, Mauri 6, Palladino 6½ | | Monaco | 0 |
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| | (4-3-3): De Ruiter 8, Appiah 7, Kurzawa 6½, Toulalan 6½ (63 Salli 7½), Medjani 7, Sidibé 7, Mendy 7½, Alessandrini 6½, Touré 6½, Ndinga 6½, Germain 5½ | | Rangers | 1 | 25 Sanabria | | Half-time: | 1-1 | | Referee: | Marriner 5½ | | Attendance: | 29,348 | | Possession: | 62%-38% | | Total shots: | 15-7 | | MoM: | Sanabria |
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| | (4-3-3): Kaminski 7, Stones 7½, Mendy 7½, Thiago 7½, Ceccherini 7½, Murru 6½ (72 Milito 6), Gündogan 7, Bruma 7½, Sanabria 8, Geis 6½, Origi 6½ | | Anzhi | 1 | 24 Zhirkov | | 29 Boussoufa, 52 Jedvaj | | (4-3-3): Buffon 7½, Jedvaj 6½, Zhirkov 7½, Onazi 6, Piqué 6½, Thiago Silva 5½, Ramires 7, Mkhitaryan 6½, Balotelli 7 (73 Mangala 6), Boussoufa 5½, Lavezzi 5½ | | TSV München 1860 | 3 | 14p Sesták, 44 Denis, 87 Sesták | | Half-time: | 2-1 | | Referee: | Rraklli 7 | | Attendance: | 31,553 | | Possession: | 49%-51% | | Total shots: | 13-9 | | MoM: | Bekir |
| | 81 Richards | | (4-3-3): Pletikosa 6½, Schindler 7, Bekir 8, Sheshukov 7, Stranzl 6, Richards 6½, Aigner 5½ (88 Feick 6), Denis 7½, Sesták 7, Hofmann 6, Wood 5½ | | Torino | 2 | 36 Reus, 47 Isco |
| | (4-3-3): Akinfeev 6½, Abate 6, De Sciglio 7½, Reus 7½, Tah 6½, Llorente 7½, Guerreiro 6, Isco 7½, Krajnc 5½, Mauro 7, Olaitan 6 | | Round 3 | | TSV München 1860 | 1 | 24 Bekir | | Half-time: | 1-1 | | Referee: | Beeby 5½ | | Attendance: | 30,390 | | Possession: | 49%-51% | | Total shots: | 14-13 | | MoM: | Moi Gómez |
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| | (4-3-3): Pletikosa 7, Schindler 6½, Bekir 7, Sheshukov 7½, Stranzl 6½, Richards 6, Aigner 7, Denis 7, Sesták 6½, Hofmann 5½, Wood 7 | | Villarreal | 1 | 5 Trigueros |
| | (4-3-3): Diego 6½, Rukavina 7½, Jaume 7, Bruno 7 (55 Moi Gómez 8), Musacchio 7½, Chechu 7, Aquino 7, Pérez 7, Uche 7, Trigueros 7½, Jonathan 5½ | | Rangers | 3 | 58 Bruma, 68 Stones, 79 Bruma | | Half-time: | 0-0 | | Referee: | Kefalas 6 | | Attendance: | 28,029 | | Possession: | 58%-42% | | Total shots: | 18-9 | | MoM: | Tah |
| | 38 Origi, 40 Geis, 62 Bruma | | (4-3-3): Kaminski 7, Stones 7½, Mendy 7½, Thiago 7½, Ceccherini 7½, Murru 7½, Gündogan 7, Bruma 7, Sanabria 5½ (72 Bent 7), Geis 6, Origi 6½ | | Torino | 1 | 73 Krajnc | | 23 Akinfeev | | (4-3-3): Akinfeev 6½, Abate 6, De Sciglio 6½, Reus 7½, Tah 7½, Llorente 6½, Guerreiro 6, Isco 6, Krajnc 5½, Mauro 5½, Olaitan 6 | | Bayern München | 0 |
| | Half-time: | 0-1 | | Referee: | Rosetti 7 | | Attendance: | 44,885 | | Possession: | 48%-52% | | Total shots: | 8-19 | | MoM: | Neuer |
| | 56 Aitchison, 88 Götze | | (4-3-3): Neuer 7½, Kimmich 7, Bernat 6, Götze 7, Boateng 7, McShane 6, Coman 6½, Douglas Costa 7, Aitchison 6½, Green 6½, Müller 7 | | Caen | 1 | 45+2 Imorou |
| | (4-3-3): Vercoutre 7, Dabo 6, Bessat 6½, Féret 7, Da Silva 6½, Genevois 6½, Delaplace 6, Imorou 7, Santini 7, Adéoti 5½, Rodelin 5½ |
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