| Round 1 | | Arsenal | 0 |
| | Half-time: | 0-0 | | Referee: | Alvarenga 5½ | | Attendance: | 38,303 | | Possession: | 40%-60% | | Total shots: | 7-19 | | MoM: | Marchisio |
| | 11 Milner, 43 Eboué | | (4-3-3): Boruc 6½, Eboué 6½, Clichy 7, Marcos Senna 7, Samuel 6½, Heinze 7, Kranjcar 6, Milner 5½, Adebayor 7, Pavlyuchenko 6, Mutu 6½ | | Sampdoria | 1 | 83 Totti |
| | (4-4-2): Buffon 7, Zambrotta 7½, Chiellini 7½, Gattuso 7½, Cannavaro 7½, Barzagli 6½, Abate 6, Marchisio 8, Totti 7½, De Rossi 7, Rossi 6½ | | Aston Villa | 2 | 43 Richardson, 58 McFadden | | Half-time: | 1-0 | | Referee: | Husset 6½ | | Attendance: | 42,501 | | Possession: | 55%-45% | | Total shots: | 14-17 | | MoM: | Bale |
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| | (4-3-3): Howard 8, De La Cruz 7, Bale 8½, Ballack 7½, Ridgewell 7, Hughes 6, Pennant 7, Richardson 7, Figueroa 7, Makoun 7½, McFadden 5½ | | Manchester City | 0 |
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| | (4-3-3): Van Der Sar 7, Melli 7, Insúa 7, Heitinga 6, Dunne 7½, Rozehnal 6½, Joaquín 7, Rosický 6½ (77 Jørgensen 6), Crouch 6½, Plasil 6½, Lupoli 5½ | | Auxerre | 3 | 21 Flamini, 59 Diaby, 90+2 Mevlüt | | Half-time: | 1-0 | | Referee: | Bazzoli 5 | | Attendance: | 21,965 | | Possession: | 55%-45% | | Total shots: | 9-7 | | MoM: | Evrà | | TV: | live |
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| | (4-3-3): Mandanda 6½, Sagna 7½, Mathieu 8, Flamini 7½, Delpierre 7, Mignot 6, Gouffran 7, Diaby 7½, Mevlüt 7½, Sissoko 6½, Gameiro 6 | | Liverpool | 1 | 46 Navas | | 50 Robben | | (4-3-3): Víctor Valdés 6½, Mexès 6½, Evrà 8, Lampard 7, Marchena 6½, Chivu 7, Navas 7½, Robben 6, Marilungo 5½, Cambiasso 7, Henry 6½ | | Barcelona | 1 | 21 Berbatov | | Half-time: | 1-3 | | Referee: | Hansson 6½ | | Attendance: | 61,509 | | Possession: | 50%-50% | | Total shots: | 17-15 | | MoM: | Marcelo | | TV: | highlights |
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| | (4-3-3): Gordon 4, Rafinha 7, Cufré 7, Scholes 8, Van Buyten 7, Zaccardo 6, Hleb 7, Malouda 6, Berbatov 6½, Van Bommel 6½, Robinho 6½ | | Lazio | 5 | 11 Messi, 19 Messi, 29 Ibrahimovic, 57 Mascherano, 61 Mascherano |
| | (4-3-3): Reina 5, Maicon 8, Marcelo 8, Mascherano 7½, Sergio Ramos 7½, Pepe 6, Rodríguez 6½, Santi 6½, Ibrahimovic 7½, Benzema 6, Messi 7½ | | Chelsea | 0 |
| | Half-time: | 0-0 | | Referee: | Uilenberg 6 | | Attendance: | 46,844 | | Possession: | 37%-63% | | Total shots: | 12-13 | | MoM: | Boenisch | | TV: | live |
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| | (4-3-3): Cudicini 6, Alexis 7½, Johnson 7 (88 Verón 6), Mikel 7½, Neville 6½, Hunt 6½, N'Zogbia 7, Lennon 6, Pizarro 7, Tiago 6½, Liédson 6 | | FC Schalke 04 | 1 | 87 Meier |
| | (4-3-3): Rost 7, Banouas 6½, Boenisch 8, Rolfes 7½, Schönheim 7½, Lincoln 6, Varela 7½, Kobiashvili 7½, Meier 7 (88 Neuville 6), Pokrivac 7½, Halil 7 | | Hamburger SV | 0 |
| | Half-time: | 0-1 | | Referee: | Rudy 6½ | | Attendance: | 47,989 | | Possession: | 41%-59% | | Total shots: | 14-20 | | MoM: | Hernanes |
| | 41 Yakubu | | (4-3-3): Kirschstein 6, Reveillère 6½, Jansen 6½, Lucas 7, Nelsen 5½, Boulahrouz 6½, Farfán 6½, Trochowski 6½, Yakubu 7, Hunt 6½, Voronin 6 | | Ajax | 2 | 25 Emanuelson, 69 Emanuelson | | 18 Pieters | | (4-3-3): Stekelenburg 6, Marcellis 7, Emanuelson 8, Sneijder 7½, Pieters 6½, Vlaar 7, Hernanes 8, Babel 7 (80 Mendes Da Silva 6), Huntelaar 7, De Jong 6½, George 6 | | Juventus | 2 | 47 Zalayeta, 74 Guðjohnsen | | Half-time: | 0-0 | | Referee: | Vorjas 6 | | Attendance: | 46,362 | | Possession: | 48%-52% | | Total shots: | 15-7 | | MoM: | Córdoba |
| | 50 Zalayeta | | (4-3-3): Dida 7½, Zauri 7½, Córdoba 8, Vieira 7, Kovac 6½, Siviglia 6½, Biglia 6, Volpi 7, Zalayeta 6 (85 Olivera 6), Dalla Bona 6½, Guðjohnsen 6½ | | Milan | 0 |
| | 7 Júlio Baptista | | (4-3-3): Palop 7½, Torres 7½, Augustyn 6½, Banega 7½, Gallas 7, Juan 6, Govou 7½, Júlio Baptista 7, Milito 6½, Pazzini 6, Shevchenko 6 | | Sporting | 3 | 6 Simão, 43 Maniche, 56p Hélder Postiga | | Half-time: | 2-1 | | Referee: | Bolognino 8 | | Attendance: | 45,647 | | Possession: | 58%-42% | | Total shots: | 16-7 | | MoM: | Simão |
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| | (4-3-3): Rui Patrício 7, Miguel 7, Ricardo Rocha 6½, Hugo Viana 7½, Bruno Alves 7, Caneira 6½, Maniche 7½, Simão 8, Hélder Postiga 6½, Nuno Gomes 6, Bruno Gama 6½ | | CSKA | 1 | 26 Khokhlov | | 13 Khokhlov, 18 Jiránek, 53 Mazalov, 86 Fellype Gabriel | | (4-3-3): Nikopolidis 7, Anyukov 6½, Jankulovski 6½, Dudu Cearense 7½, Semberas 7½, Jiránek 5½, Fellype Gabriel 6½, Torbinsky 7, Samodin 6, Khokhlov 6, Mazalov 5½ | | Tottenham Hotspur | 1 | 50og Perea | | Half-time: | 0-0 | | Referee: | Cardona 6½ | | Attendance: | 36,093 | | Possession: | 50%-50% | | Total shots: | 12-11 | | MoM: | Daniel |
| | 41 Defoe, 47 Cole, 87 Cole | | (4-3-3): Robinson 7, Neville 6½, Dawson 6½, Carrick 7, King 7, Taylor 6, Bentley 7, Cole 6½, Defoe 7, Bent 6, Keane 6 | | Lyon | 0 |
| | 3 Keirrison, 70 Eto'o | | (4-3-3): Júlio César 7½, Daniel 8, Abidal 7½, Kaká 7, Vidic 7, Perea 6½, Gourcuff 6, Ribéry 6½, Keirrison 6½, Forlán 6, Eto'o 7 | | Valencia | 0 |
| | Half-time: | 0-1 | | Referee: | Circhetta 7½ | | Attendance: | 54,937 | | Possession: | 46%-54% | | Total shots: | 4-24 | | MoM: | Ronaldo | | TV: | highlights |
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| | (4-3-3): Akinfeev 7, Friedrich 7½, Escudé 6½, Muamba 7, Bodmer 6½, Navarro 6½, Rufete 7, Schaars 6½, Bendtner 6, Cissé 6, Menez 5½ | | Manchester United | 2 | 40p Ronaldo, 58 Vílla |
| | (4-4-2): Casillas 7, Antonio López 7, Puyol 8, Terry 7½, Ferdinand 7, Fabregas 7½, Xavi 6½, Ronaldo 8, Gerrard 7, Vílla 8, Torres 7 | | VfB Stuttgart | 2 | 4 Borowski, 67 Marin | | Half-time: | 1-1 | | Referee: | Rupec 5½ | | Attendance: | 47,462 | | Possession: | 50%-50% | | Total shots: | 9-9 | | MoM: | Stranzl | | TV: | highlights |
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| | (4-3-3): Neuer 7, Behrami 7, Stranzl 8, Ernst 7½, Boateng 7, Hummels 6, Borowski 7½, Marin 7, Klose 6 (56 Metzelder 7½), Gomez 6, Podolski 6 | | Espanyol | 1 | 11 Juanfran |
| | (4-3-3): Kameni 6½, Ilsinho 7, Castro 7, Diarra 6½, Fukal 7½, Araujo 6½ (53 Tamudo 6½), Juanfran 6½, Fernández 6, Falcao 6, De La Peña 6½, Luis García 7 | | Round 2 | | Ajax | 2 | 6 Huntelaar, 45+1 Emanuelson | | Half-time: | 2-2 | | Referee: | Craciun 7 | | Attendance: | 45,559 | | Possession: | 52%-48% | | Total shots: | 15-11 | | MoM: | Huntelaar |
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| | (4-3-3): Stekelenburg 6, Marcellis 7, Emanuelson 6½, Sneijder 7½, Pieters 5½, Vlaar 6, Hernanes 7½, Babel 7, Huntelaar 8, De Jong 6 (54 Iaquinta 7), George 5½ | | Aston Villa | 2 | 5 McFadden, 16 Ballack | | 11 Makoun, 18 De La Cruz, 24 Pennant, 34 Ballack, 43 Makoun | | (4-3-3): Howard 6½, De La Cruz 6, Lescott 7, Ballack 6½, Hughes 6, Ridgewell 6½, Pennant 6½ (64 Dagoberto 6½), Bale 6, Figueroa 6½, Makoun 5½, McFadden 7 | | CSKA | 1 | 65 Jankulovski | | Half-time: | 0-1 | | Referee: | Borriello 7 | | Attendance: | 13,017 | | Possession: | 42%-58% | | Total shots: | 11-13 | | MoM: | Stranzl |
| | 21 Anyukov | | (4-3-3): Nikopolidis 6, Anyukov 7, Jankulovski 6½, Dudu Cearense 7, Semberas 7½, Jiránek 6½ (46 Gusev 5½), Fellype Gabriel 6, Torbinsky 6½, Samodin 6, Bystrov 5½, Mazalov 5½ | | VfB Stuttgart | 2 | 36 Klose, 48 Ernst |
| | (4-3-3): Neuer 6½, Behrami 7½, Stranzl 8, Ernst 8, Boateng 7, Hummels 6½, Borowski 8, Marin 6½ (79 Hilbert 6), Klose 7½, Gomez 5½, Podolski 6½ | | Espanyol | 0 |
| | Half-time: | 0-1 | | Referee: | Vítor Pereira 5½ | | Attendance: | 46,029 | | Possession: | 46%-54% | | Total shots: | 7-21 | | MoM: | Diarra |
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| | (4-3-3): Kameni 6½, Ilsinho 7½, Castro 7 (81 Eduardo Costa 6), Diarra 8, Fukal 6½, Araujo 6½, Juanfran 6, Fernández 6½, Falcao 6, De La Peña 6, Luis García 6 | | Auxerre | 2 | 13 Diaby, 84 Gameiro | | 5 Mevlüt, 8 Gouffran | | (4-3-3): Mandanda 7, Sagna 6½, Mathieu 7, Flamini 7, Delpierre 7½, Mignot 6, Gouffran 7, Diaby 7, Mevlüt 6½, Sissoko 6, Gameiro 6 | | FC Schalke 04 | 3 | 18 Kobiashvili, 25p Meier, 51 Kobiashvili | | Half-time: | 2-0 | | Referee: | Franceschini 7½ | | Attendance: | 45,441 | | Possession: | 46%-54% | | Total shots: | 12-13 | | MoM: | Rolfes |
| | 14 Varela | | (4-3-3): Rost 6½, Banouas 6½, Boenisch 7½, Rolfes 8, Schönheim 6½, Lincoln 6½, Varela 6½, Kobiashvili 7, Meier 5½ (57 Neuville 7), Pokrivac 6, Halil 7 | | Valencia | 1 | 83 Bendtner | | 64 Muamba | | (4-3-3): Akinfeev 6½, Friedrich 8, Escudé 7½, Muamba 7½, Bodmer 7, Navarro 6, Rufete 7½, Schaars 7, Bendtner 6½, Cissé 6½, Menez 6½ | | Lazio | 2 | 35 Rodríguez, 55p Ibrahimovic | | Half-time: | 1-0 | | Referee: | Knight 7½ | | Attendance: | 56,333 | | Possession: | 45%-55% | | Total shots: | 16-7 | | MoM: | Marcelo |
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| | (4-3-3): Reina 7, Maicon 7, Marcelo 8, Mascherano 7½, Sergio Ramos 6½, Pepe 6½, Rodríguez 8, Santi 7½, Ibrahimovic 6½, Benzema 6, Messi 6½ | | Juventus | 0 |
| | 7 Volpi | | (4-3-3): Dida 8, Zauri 7½, Córdoba 7, Vieira 7½, Kovac 7, Siviglia 6, Biglia 7, Volpi 5½, Zalayeta 6½, Dalla Bona 6½, Guðjohnsen 6 | | Liverpool | 0 |
| | Half-time: | 0-0 | | Referee: | Astrauskas 5½ | | Attendance: | 45,209 | | Possession: | 57%-43% | | Total shots: | 24-10 | | MoM: | Navas |
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| | (4-3-3): Víctor Valdés 8, Mexès 7, Evrà 7, Lampard 7, Lúcio 7, Marchena 6, Navas 8½, Robben 8, Marilungo 6½, Essien 7½, Henry 6½ | | Sporting | 0 |
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| | (4-3-3): Rui Patrício 7½, Miguel 6, Ricardo Rocha 6, Hugo Viana 7, Bruno Alves 7, Caneira 6, Maniche 6, Simão 6½, Hélder Postiga 6, Nuno Gomes 7, Bruno Gama 6 | | Lyon | 4 | 1 Keirrison, 17 Ribéry, 33 Keirrison, 40 Abidal | | Half-time: | 4-0 | | Referee: | Díaz Vega 7 | | Attendance: | 56,231 | | Possession: | 54%-46% | | Total shots: | 15-8 | | MoM: | Daniel |
| | 18 Forlán, 87 Hutchinson | | (4-3-3): Júlio César 7, Daniel 8, Abidal 8, Kaká 7, Vidic 7½, Perea 5 (48 Hutchinson 6), Gourcuff 7½, Ribéry 7, Keirrison 7 (74 Touré 6), Forlán 5½, Eto'o 8 | | Arsenal | 1 | 61p Adebayor | | 26 Pavlyuchenko | | (4-3-3): Boruc 6½, Eboué 7, Clichy 6½, Marcos Senna 6½, Samuel 7, Heinze 6, Kranjcar 6, Milner 5½, Adebayor 6½, Pavlyuchenko 6½, Mutu 6 | | Manchester City | 1 | 62 Insúa | | Half-time: | 0-0 | | Referee: | Rodomonti 7 | | Attendance: | 49,638 | | Possession: | 46%-54% | | Total shots: | 13-11 | | MoM: | Alexis |
| | 9 Joaquín, 65 Rosický, 73 Dunne, 81 Lupoli, 85 Insúa | | (4-3-3): Van Der Sar 7, Melli 7, Insúa 7½, Heitinga 7, Dunne 6, Rozehnal 7, Joaquín 6, Rosický 7, Crouch 6½, Plasil 6½, Lupoli 5½ | | Chelsea | 0 |
| | 38 Tiago, 40 Pizarro | | (4-3-3): Cudicini 7, Alexis 8, Johnson 6 (79 Verón 7), Mikel 7, Neville 7, Hunt 6½, N'Zogbia 7, Lennon 7, Pizarro 6½, Tiago 6½, Liédson 6 | | Manchester United | 4 | 9 Vílla, 33 Vílla, 54 Ronaldo, 89 Torres | | Half-time: | 2-0 | | Referee: | Onufer 5 | | Attendance: | 68,059 | | Possession: | 54%-46% | | Total shots: | 17-9 | | MoM: | Antonio López |
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| | (4-4-2): Casillas 7, Antonio López 8½, Puyol 7, Terry 6½, Ferdinand 7, Fabregas 6½, Xavi 7½, Ronaldo 7, Gerrard 7½, Vílla 8, Torres 6½ | | Tottenham Hotspur | 1 | 84 Cole | | 48 Keane, 53 Bent, 74 Neville | | (4-3-3): Robinson 6½, Neville 6½, Dawson 6½, Carrick 6½, King 7, Taylor 6½, Bentley 6½, Cole 6½, Defoe 7, Bent 5½, Keane 6 | | Milan | 2 | 19 Milito, 42 Milito | | Half-time: | 2-0 | | Referee: | Grabher 8 | | Attendance: | 51,774 | | Possession: | 43%-57% | | Total shots: | 13-9 | | MoM: | Rafinha |
| | 30 Milito, 54 Juan | | (4-3-3): Palop 7½, Torres 6, Augustyn 7½, Banega 6½, Gallas 7, Juan 6, Govou 7, Júlio Baptista 6, Milito 6½, Pazzini 6, Shevchenko 6 | | Barcelona | 0 |
| | 1 Hleb | | (4-3-3): Gordon 7½, Rafinha 7½, Cufré 7, Raúl 7½, Van Buyten 7½, Zaccardo 6, Scholes 6, Malouda 6½, Berbatov 7½, Hleb 6½, Robinho 7 | | Sampdoria | 3 | 2 Chiellini, 7 Totti, 82 Totti | | Half-time: | 2-0 | | Referee: | Nielsen 7 | | Attendance: | 39,947 | | Possession: | 53%-47% | | Total shots: | 13-9 | | MoM: | Abate |
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| | (4-4-2): Buffon 7, Zambrotta 7, Chiellini 7, Gattuso 7½, Cannavaro 6½, Barzagli 6½, Abate 8, Marchisio 6½, Totti 7, De Rossi 7, Rossi 6½ | | Hamburger SV | 0 |
| | 63 Voronin | | (4-3-3): Kirschstein 7½, Reveillère 7, Jansen 6½, Lucas 7, Nelsen 6, Boulahrouz 6½, Farfán 7, Trochowski 7, Yakubu 6½, Hunt 5½, Voronin 6 |
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