| Round 3 | | Fiorentina | 1 | 60 Rocchi | | Half-time: | 0-1 | | Referee: | Wächtler 7 | | Attendance: | 47,253 | | Possession: | 47%-53% | | Total shots: | 8-21 | | MoM: | Dainelli |
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| | (4-3-3): Calero 6, Cassani 7, Rullo 6½ (83 Brivio 6), Donadel 7½, Dainelli 7½, Rodríguez 6½, Godeas 6, Van Der Meyde 5½, Rocchi 6½, Pazienza 5½, Cacau 5½ | | Real Betis | 2 | 35 Yeste, 82 Yeste | | 13 Senderos, 14 Yeste, 68 Alex, 70 Armando | | (4-3-3): Armando 6, Chica 6½ (60 Barragán 5½), Del Horno 7, Elano 7, Alex 7, Senderos 6, Raúl García 6½, Yeste 6½, Carew 7½, Petit 6½, Bozhinov 7 | | Independiente | 1 | 79 Cardozo | | Half-time: | 0-0 | | Referee: | Knight 6 | | Attendance: | 41,827 | | Possession: | 47%-53% | | Total shots: | 10-12 | | MoM: | Carlos Alberto | | TV: | live |
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| | (4-3-3): Hélton 6, Rodríguez 7, José Enrique 7, Hargreaves 6½, Paletta 7, Abraham 6, Muñoz 6½ (47 Eduardo Ratinho 7), Cardozo 6, Sanogo 6½, Carlos Martins 6½, Carlos Alberto 7½ | | Athletic Bilbao | 1 | 47 Llorente | | 27 Prieto, 64 Recoba, 85 Dañobeitia | | (4-3-3): Aranzubía 7, Cuéllar 7 (59 Corrales 6½), Amorebieta 7½, Orbáiz 7, Prieto 6½, Ustaritz 6, Rivera 7, Dañobeitia 6, Llorente 7, Gurpegi 6½, Recoba 7 | | Round 4 | | AEK | 2 | 41 Alexopoulos, 55 Drogba | | Half-time: | 1-1 | | Referee: | Almeida Marcal 7 | | Attendance: | 51,300 | | Possession: | 47%-53% | | Total shots: | 14-9 | | MoM: | Tissone | | TV: | highlights |
| | 72 Ujfalusi | | (4-3-3): Abbondanzieri 6, Diarra 8, Bridge 6½, Alexopoulos 6½, Ujfalusi 6 (78 Urretavizcaya 7½), Papastathopoulos 6½, Wright-Phillips 7½, Lakis 5½, Drogba 7½, Gekas 6½, López 6½ | | Roma | 1 | 43 Chevantón |
| | (4-3-3): Castellazzi 7, Panucci 7 (55 Tissone 8), Tonetto 7, Sidwell 6, Bovo 6, Felipe 6, Marchionni 7½, Afellay 6, Paponi 6½, Hysén 7 (70 Motta 6), Chevantón 6½ | | Athletic Bilbao | 1 | 71 Gurpegi | |
| | (4-3-3): Aranzubía 6½, Cuéllar 7, Amorebieta 6½ (69 Corrales 6), Orbáiz 7½, Prieto 6½, Ustaritz 6, Rivera 7, Dañobeitia 7, Llorente 6½, Gurpegi 7½, Recoba 6½ | | Blackburn Rovers | 1 | 38 Osman |
| | (4-3-3): Macho 7½, Yobo 7, Baines 6½, Fábio Simplício 7½, Garay 7 (72 McEveley 6), Todd 6, Frings 7½, Bellamy 7, Anichebe 6, Osman 7 (71 Dickov 6), McCarthy 7 | | Benfica | 0 |
| | Half-time: | 0-1 | | Referee: | Strampe 7½ | | Attendance: | 44,809 | | Possession: | 37%-63% | | Total shots: | 9-15 | | MoM: | Taddei |
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| | (4-3-3): Quim 6, Ben Haim 7, Geovanni 7, Karagounis 6½, André Bahia 6½, Eduardo 6, Marco Ferreira 6½, Muntari 6, Smolarek 6½, Culina 7 (61 Beasley 6½), Miccoli 6½ (64 Nuno Assis 6) | | Corinthians | 2 | 15 Adriano, 60 Vágner Love |
| | (4-3-3): Doni 7, Belletti 6½, Maxwell 7, Josué 7, Luizão 7, Wendel 6, Taddei 8, Adriano 7, Luís Fabiano 7, Fernando 7, Vágner Love 7½ | | Borussia Dortmund | 2 | 65 Di María, 88 Di María | | Half-time: | 0-0 | | Referee: | Reijgwart 5½ | | Attendance: | 50,348 | | Possession: | 43%-57% | | Total shots: | 14-14 | | MoM: | Vucinic | | TV: | highlights |
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| | (4-3-3): Frey 7, Lahm 7, Anita 6½, Seedorf 6½, Piqué 6½, Ricardo Carvalho 6 (65 Kroos 6½), Giovani 7, Di María 7, Gilardino 6½, Touré 6½, Tévez 6½ | | Hajduk Split | 0 |
| | 32 Misimovic | | (4-3-3): Pletikosa 7½, Ivanovic 7, Pranjic 7, Rakitic 7½, Ignashevich 7, Rusol 6, Blatnjak 6½, Hamsyk 7, Kalinic 7, Misimovic 7 (57 Dzsudzsák 6½), Vucinic 8 | | Galatasaray | 0 |
| | Half-time: | 0-1 | | Referee: | Constantin 6½ | | Attendance: | 23,652 | | Possession: | 45%-55% | | Total shots: | 11-8 | | MoM: | Laas | | TV: | highlights |
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| | (4-3-3): Aykut 7, Volkan 7, Emre 7, Sabri 7, Orhan 6, Fehmi Emre 6½, Ayhan 7½, Arda 7, Ümit 7½, Mehmet 6, Kewell 6 | | Independiente | 1 | 41 Sanogo | | 43 Abraham, 72 Rodríguez | | (4-3-3): Hélton 7, Rodríguez 6½, José Enrique 6½ (64 Laas 7½), Hargreaves 7, Paletta 6, Abraham 6½, Muñoz 6½, Cardozo 7, Sanogo 7½, Carlos Martins 7, Carlos Alberto 7 (64 Ramón 6) | | Marseille | 1 | 3 Kehl | | Half-time: | 1-0 | | Referee: | Rudy 5½ | | Attendance: | 46,364 | | Possession: | 52%-48% | | Total shots: | 8-15 | | MoM: | Hart |
| | 30 Diané | | (4-3-3): James 7, Beye 7½, Taiwo 7½, Van Bronckhorst 6½ (75 Deruda 7), Méité 7, Civelli 6, Gabri 7, Kehl 7, Brandão 6½, Diané 6, Niang 7½ | | Atlético Madrid | 0 |
| | 6 Dragutinovic, 9 Azpilicueta | | (1-3-3-3): Hart 7½, Arbeloa 7, Pasqual 6, Barry 7½, Dragutinovic 6½, Fernando Meira 6½, Susaeta 7, Mata 6½, Pedro Oldoni 6, Azpilicueta 5½, Ronaldinho 6½ | | Middlesbrough | 2 | 43 Queudrue, 66 Viduka | | Half-time: | 1-0 | | Referee: | Vítor Pereira 7½ | | Attendance: | 31,575 | | Possession: | 56%-44% | | Total shots: | 17-10 | | MoM: | Boschker |
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| | (4-3-3): Schwarzer 7, McMahon 6, Queudrue 7½, Boateng 7½, Miyamoto 7, Wheater 6 (69 Parnaby 5½), Morrison 7½, Downing 6½, Viduka 7, Rochemback 6½, Rivaldo 7 | | FC Twente | 0 |
| | 28 Braafheid, 47 Engelaar, 63 Zomer, 81 Touma, 85 Engelaar | | (4-3-3): Boschker 8, Berezutsky 7, Braafheid 6 (85 Gerritsen 6), Brama 7½, Zomer 6½, Wielaert 6, Landzaat 7, Engelaar 6, Nkufo 7, Denneboom 5½, Touma 5½ | | Real Betis | 0 |
| | | 9 Petit, 75 Bozhinov | | (4-3-3): Armando 6½, Chica 7 (55 Barragán 7½), Del Horno 6½, Elano 7, Alex 7½, Senderos 6, Raúl García 6½, Yeste 7, Carew 6½, Petit 6½, Bozhinov 5½ | | Bayern München | 2 | 61 Zé Roberto, 88 Santa Cruz |
| | (4-3-3): Corona 7, Salihamidzic 7½, Warnock 7½, Sissoko 6½, Demichelis 8, Yepes 7, Ottl 6, Zé Roberto 6½, Santa Cruz 7, Karimi 6, Guerrero 7 | | SV Werder Bremen | 1 | 68 Van Damme | | Half-time: | 0-0 | | Referee: | Marriner 6 | | Attendance: | 42,309 | | Possession: | 55%-45% | | Total shots: | 13-14 | | MoM: | Cassani |
| | 80 Fahrenhorst | | (4-3-3): Wiese 7, Demel 7, Van Damme 7, Vranjes 6½, Pasanen 8, Andreasen 6½, Mudingayi 7, Jensen 7, Menseguez 6½, Fahrenhorst 6, Valdez 6 | | Fiorentina | 0 |
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| | (4-3-3): Calero 7, Cassani 8, Rullo 6 (79 Brivio 6), Donadel 7½, Dainelli 7, Rodríguez 6, Godeas 6½, Van Der Meyde 7, Rocchi 6, Pazienza 6, Cacau 6 | | Shakhtar | 2 | 53 Vorobyei, 72 Krasic | | Half-time: | 0-1 | | Referee: | Beschin 6½ | | Attendance: | 38,385 | | Possession: | 58%-42% | | Total shots: | 20-7 | | MoM: | Rat |
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| | (4-3-3): Lastùvka 7, Lewandowski 6½, Rat 8½, Tymoschuk 8, Chyhrynskyi 6½, Schulz 7½, Duljaj 7, Krasic 7½, Caffa 6½, Jadson 7, Vorobyei 6 | | River Plate | 1 | 41 Montenegro | | 5 Bruce, 68 Ivanschitz, 87 Montenegro | | (4-3-3): Carrizo 7½, Ferrari 6½, Álvarez 7 (53 Ahumada 7½), Zapata 7½, Talamonti 7½, Bruce 6, Patiño 6½, Ivanschitz 7½, Montenegro 6½, Barreto 6, Farías 6 | | Zaragoza | 0 |
| | Half-time: | 0-0 | | Referee: | Tanner 7 | | Attendance: | 34,508 | | Possession: | 47%-53% | | Total shots: | 10-10 | | MoM: | Kanouté |
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| | (4-3-3): Leo Franco 7½, Burdisso 6, Riise 6½, Marcelo Mattos 7½, Brown 7½, Manuel Pablo 7 (83 Dembélé 6), Galletti 7½, Ben Arfa 7, Adrián 5½, Cani 6, Cavani 7 | | Real Madrid | 0 |
| | 31 Guti, 49 Monsoreau | | (4-3-3): Given 7, Mellberg 6½ (79 Balboa 8), Roberto Carlos 7½, João Moutinho 7, Milito 7, Monsoreau 6½, De Silvestri 7, Aimar 7, Kanouté 8, Guti 6½, Palacio 6½ |
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