| Round 5 | | Atlético Madrid | 1 | 87 Mata | | Half-time: | 0-0 | | Referee: | Hammouti 5½ | | Attendance: | 41,702 | | Possession: | 49%-51% | | Total shots: | 12-11 | | MoM: | Arbeloa |
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| | (1-3-3-3): Hart 6½, Arbeloa 8½, Pasqual 6½ (88 Grounds 6), Barry 7½, Dragutinovic 7½, Fernando Meira 7, Susaeta 6½, Mata 7½, Batuhan 7, Petrov 5½, Ronaldinho 6½ | | Athletic Bilbao | 1 | 47 Llorente | | 37 Jonatan, 45 Cuéllar | | (4-3-3): Aranzubía 7, Cuéllar 7½, Amorebieta 7, Orbáiz 7, Prieto 6½, Ustaritz 6½, Rivera 6½, Gurpegi 6½, Llorente 7, Jonatan 7 (70 Rivas 5½), Recoba 6 | | Bayern München | 2 | 37 Karimi, 50 Zé Roberto | | Half-time: | 1-0 | | Referee: | Hauge 6½ | | Attendance: | 44,831 | | Possession: | 61%-39% | | Total shots: | 15-3 | | MoM: | Salihamidzic | | TV: | highlights |
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| | (4-3-3): Corona 7½, Salihamidzic 8, Warnock 8, Sissoko 7½, Demichelis 7½, Yepes 7, Ottl 6½, Zé Roberto 7, Santa Cruz 7½, Karimi 6½, Guerrero 6½ | | Benfica | 0 |
| | 1 Marco Ferreira, 70 Muntari | | (4-3-3): Quim 7, Ben Haim 7½, Addo 7, Karagounis 6½, André Bahia 6½, Eduardo 6½ (78 Beasley 6), Marco Ferreira 6, Muntari 6, Smolarek 6½, Nuno Assis 6½, Mantorras 5½ | | Blackburn Rovers | 3 | 7 Bellamy, 63 Osman, 66 Baines | | Half-time: | 1-1 | | Referee: | Francisco 5½ | | Attendance: | 31,172 | | Possession: | 48%-52% | | Total shots: | 16-13 | | MoM: | Gilardino |
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| | (4-3-3): Macho 6, Yobo 7½, Baines 7, Cahill 7, Garay 5½ (64 Bolzoni 6), Fábio Simplício 6, Frings 7½, Bellamy 7, Vaughan 7, Osman 6, Davies 6 | | Borussia Dortmund | 3 | 19 Piqué, 79og Cahill, 83 Touré |
| | (4-3-3): Frey 6, Lahm 7, Anita 7, Seedorf 7½, Piqué 6½, Ricardo Carvalho 6½, Giovani 7, Di María 7, Gilardino 7½, Touré 7, Tévez 6 | | Corinthians | 2 | 17og Wright-Phillips, 71 Betão | | Half-time: | 1-0 | | Referee: | Clattenburg 7 | | Attendance: | 51,837 | | Possession: | 53%-47% | | Total shots: | 20-4 | | MoM: | Richarlyson | | TV: | highlights |
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| | (4-3-3): Doni 6½, Belletti 7½, Maxwell 7, Josué 7½, Luizão 7½, Wendel 6½, Taddei 6½, Adriano 6½ (60 Betão 6½), Luís Fabiano 7½, Fernando 6 (56 Richarlyson 7½), Vágner Love 6 | | AEK | 2 | 55 Drogba, 62 Drogba | | 25 Lakis, 28 Wright-Phillips | | (4-3-3): Galinovic 7, Diarra 6, Bridge 6½, Georgeas 6½, Ujfalusi 7, Papastathopoulos 6, Wright-Phillips 7½, Lakis 6½, Drogba 7, Owen 6½ (64 Alexopoulos 5½), López 5½ | | FC Twente | 3 | 17 Weston, 19 Nkufo, 45 Berezutsky | | Half-time: | 3-2 | | Referee: | Pinto Correia 7 | | Attendance: | 13,167 | | Possession: | 44%-56% | | Total shots: | 12-16 | | MoM: | Rat |
| | 60 Zijler | | (4-3-3): Paauwe 6½, Berezutsky 7½, Braafheid 6, Brama 7, Zomer 7, Wielaert 6½, Landzaat 7, Weston 6, Nkufo 7½, Koevermans 5½ (67 Wilkshire 6), Zijler 6 | | Shakhtar | 2 | 25 Krasic, 33 Krasic |
| | (4-3-3): Lastùvka 6½, Schulz 6, Rat 8½, Tymoschuk 7½, Chyhrynskyi 7, Leonardo 6½, Duljaj 6½, Krasic 7, Caffa 7, Jadson 7½, Vorobyei 7½ | | Fiorentina | 3 | 9 Rocchi, 41 Rocchi, 90 Cacau | | Half-time: | 2-0 | | Referee: | Collina 6½ | | Attendance: | 45,040 | | Possession: | 49%-51% | | Total shots: | 11-13 | | MoM: | Gabri | | TV: | live |
| | 15 Cacau | | (4-3-3): Calero 7, Cassani 7, Rullo 6½, Donadel 7½, Dainelli 8, Rodríguez 6, Godeas 7, Van Der Meyde 6½, Rocchi 7½, Zanetti 6½, Cacau 6 | | Marseille | 0 |
| | 66 Piquionne, 79 Niang | | (4-3-3): Langer 7, Gabri 8½, Van Bronckhorst 7, Kehl 6½, Beye 6½, Méité 6, Oruma 7, Taiwo 6½ (46 Civelli 6), Brandão 6, Piquionne 5½, Niang 6½ | | Hajduk Split | 0 |
| | Half-time: | 0-0 | | Referee: | Penicka 5½ | | Attendance: | 44,620 | | Possession: | 55%-45% | | Total shots: | 18-7 | | MoM: | Kalinic |
| | 6 Hamsyk, 9 Vucinic | | (4-3-3): Pletikosa 7, Rusol 6½, Pranjic 7, Pjanic 7, Ignashevich 8, Skrtel 6, Blatnjak 6, Hamsyk 6½, Kalinic 8, Rakitic 6½, Vucinic 6 | | Middlesbrough | 0 |
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| | (4-3-3): Schwarzer 8, Hoogland 7, Taylor 7, Boateng 6, Miyamoto 6½, Wheater 5½, Morrison 7½, Downing 6½, Graham 6, Rochemback 5½, Rivaldo 6 | | Independiente | 1 | 52 Sanogo | | Half-time: | 0-1 | | Referee: | Webb 6½ | | Attendance: | 48,262 | | Possession: | 55%-45% | | Total shots: | 12-13 | | MoM: | Mudingayi |
| | 33 Sanogo | | (4-3-3): Hélton 7, Rodríguez 6½ (83 Culio 6), José Enrique 7, Hargreaves 7, Paletta 6½, Abraham 7, Muñoz 7, Cardozo 6, Sanogo 7, Carlos Martins 6½, Carlos Alberto 7 | | SV Werder Bremen | 1 | 16 Vranjes | | 26 Van Damme | | (4-3-3): Wiese 7, Demel 6, Van Damme 7 (76 Atouba 6), Vranjes 7, Pasanen 7, Andreasen 6, Mudingayi 7½, Jensen 6, Menseguez 6, Fahrenhorst 7, Valdez 6½ | | Real Madrid | 3 | 2 Riki, 28 Kanouté, 68 Kanouté | | | 11 De Silvestri, 55 Guti | | (4-3-3): Given 7, Mellberg 5½, Roberto Carlos 7½, João Moutinho 7, Milito 6½, Evans 6½, De Silvestri 6½, Guti 5½, Kanouté 7, Riki 5½ (82 Zewlakow 6), Palacio 6 | | Real Betis | 1 | 36 Yeste | | 64 Elano, 67 Lafita | | (4-3-3): Doblas 7, Chica 7½, Garrido 6½, Elano 7½, Alex 6, Marc Torrejón 7, Petit 6½, Yeste 7, Carew 7½, Lafita 6, Bozhinov 6 | | River Plate | 0 |
| | Half-time: | 0-2 | | Referee: | Styles 5 | | Attendance: | 38,831 | | Possession: | 47%-53% | | Total shots: | 8-9 | | MoM: | Zapata | | TV: | highlights |
| | 4 Ivanschitz, 50 Bruce | | (4-3-3): Carrizo 6, Álvarez 7, Mareque 7, Zapata 8, Talamonti 7 (67 Tula 7), Bruce 6½, Patiño 6½, Ivanschitz 6½ (73 Luciano Henrique 6), Barreto 6½, Montenegro 6, Farías 6½ | | Galatasaray | 2 | 27 Arda, 34 Emre |
| | (4-3-3): Aykut 6, Volkan 6½, Fehmi Emre 7½, Özbek 6½, Emre 7, Orhan 7, Ayhan 7½, Arda 7½, Ümit 7, Serkan 6, Kewell 6 | | Roma | 1 | 36 Lucarelli | | Half-time: | 1-0 | | Referee: | Constantin 5½ | | Attendance: | 33,389 | | Possession: | 55%-45% | | Total shots: | 25-7 | | MoM: | Hysén |
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| | (4-3-3): Castellazzi 6½, Motta 6½, Tonetto 6, Sidwell 6½ (49 Hysén 7½), Bovo 7½, Cribari 5½, Marchionni 7½, Afellay 6½, Lucarelli 6½, Dabo 7, Chevantón 6 | | Zaragoza | 1 | 75 Cavani |
| | (4-3-3): Leo Franco 7, Burdisso 7½, Riise 6½, Marcelo Mattos 6, Brown 6½, Manuel Pablo 6½ (83 Dembélé 6), Galletti 7, Ben Arfa 6, Adrián 6½, Cani 6½, Cavani 7 | | Round 3 | | Real Madrid | 2 | 15 De Silvestri, 26 Roberto Carlos | | Half-time: | 2-0 | | Referee: | D'Urso 7 | | Attendance: | 58,445 | | Possession: | 52%-48% | | Total shots: | 20-16 | | MoM: | Edú |
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| | (4-3-3): Given 7½, Mellberg 7, Roberto Carlos 7½, João Moutinho 6 (54 Edú 8), Evans 8, Milito 6½, De Silvestri 7½, Aimar 6½, Kanouté 7½, Guti 7, Palacio 6½ | | Middlesbrough | 0 |
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| | (4-3-3): Schwarzer 7, Hoogland 7, Taylor 7½, Boateng 7, Miyamoto 6½, Wheater 6½, Morrison 6½, Downing 6, Graham 7, Rochemback 6½, Rivaldo 7 | | Bayern München | 1 | 6p Santa Cruz | | Half-time: | 1-1 | | Referee: | Díaz Vega 6½ | | Attendance: | 56,459 | | Possession: | 57%-43% | | Total shots: | 17-10 | | MoM: | Salihamidzic |
| | 68 Karimi | | (4-3-3): Corona 7, Salihamidzic 8, Warnock 8, Sissoko 7½, Demichelis 7, Yepes 6, Ottl 7, Zé Roberto 7, Santa Cruz 7, Karimi 7, Guerrero 6 | | Galatasaray | 1 | 44 Arda |
| | (4-3-3): Aykut 6½, Volkan 7, Fehmi Emre 7, Özbek 7, Emre 7, Orhan 6, Ayhan 6½, Arda 7½, Ümit 6½, Ferdi 5½, Kewell 5½ | | FC Twente | 1 | 87 Engelaar | | Half-time: | 0-1 | | Referee: | Dondarini 7½ | | Attendance: | 13,118 | | Possession: | 56%-44% | | Total shots: | 24-14 | | MoM: | Engelaar |
| | 30 Engelaar | | (4-3-3): Paauwe 6½, Berezutsky 7½, Braafheid 7½, Brama 8, Zomer 7, Wielaert 6, Landzaat 7½, Engelaar 8, Nkufo 6½, Koevermans 6½, Touma 6½ (61 El Ahmadi 6) | | SV Werder Bremen | 1 | 36 Fahrenhorst | | 51 Andreasen, 83 Vranjes | | (4-3-3): Wiese 7, Demel 7, Van Damme 6 (87 Atouba 6), Vranjes 6, Pasanen 7½, Andreasen 6, Mudingayi 6½, Jensen 7, Menseguez 6, Fahrenhorst 6½, Valdez 6 |
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