| Round 5 | | Bolton Wanderers | 2 | 10 Diouf, 32 Diouf | | Half-time: | 2-3 | | Referee: | Grabher 6 | | Attendance: | 27,738 | | Possession: | 51%-49% | | Total shots: | 14-11 | | MoM: | Geremi |
| | 22 Murphy, 30 Kyrgiakos | | (4-3-3): Al-Habsi 6, Geremi 8, Gardner 6½, Murphy 7, Diagne-Faye 7, Kyrgiakos 7, Grella 6, Diouf 7, Martins 7, Reid 6½, Vassell 6 | | Rangers | 3 | 3 Naismith, 37 Boyd, 40 Boyd |
| | (4-3-3): Smith 6½, Broadfoot 6, Smith 7, Thomson 7, Bougherra 7, Wilson 6½, Whittaker 7, McCulloch 6½, Boyd 7½, Lafferty 6, Naismith 5½ | | Falkirk | 0 |
| | Half-time: | 0-0 | | Referee: | Cardona 7½ | | Attendance: | 4,713 | | Possession: | 42%-58% | | Total shots: | 6-15 | | MoM: | Melchiot |
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| | (4-3-3): McGregor 7, Caldwell 6½, Scobbie 7, Pelé 7, Melchiot 8, McLean 6, Arfield 6½, Macdonald 6, Finnigan 7, Flynn 6, O'Brien 5½ | | Karlsruher SC | 0 |
| | 39 Iashvili | | (4-3-3): Butt 7½, Staffeldt 6½, Matip 6½, Engelhardt 8, Langkamp 7½, Langkamp 6½, Grosskreutz 7½, Iashvili 7½, Tarvajärvi 7, Aduobe 7, Timm 7½ | | Feyenoord | 0 |
| | Half-time: | 0-0 | | Referee: | McCluskey 8 | | Attendance: | 51,116 | | Possession: | 55%-45% | | Total shots: | 9-14 | | MoM: | Kilbane |
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| | (4-3-3): Mondragón 7, Greene 7½, Salcido 8, Rosinei 7½, Paauwe 6½, Rosi 6½, Dessena 8, Pienaar 7½, Amoah 7, Biseswar 5½, Nihat 7 (51 Vincken 5½) | | Lille | 0 |
| | 3 Larsen, 62 Kilbane | | (4-3-3): Sylva 7, Lichtsteiner 8, Kilbane 8, Cabaye 7, Plestan 7, Mullins 6½, Giuly 7, Cabanas 6, Larsen 6, Moreira 7, Mirallas 6½ | | Leicester City | 0 |
| | Half-time: | 0-1 | | Referee: | Onufer 6 | | Attendance: | 24,260 | | Possession: | 50%-50% | | Total shots: | 13-14 | | MoM: | Morel Rodríguez |
| | 20 Campbell, 60 Fryatt, 90 Weale | | (4-3-3): Weale 6, Hobbs 6, Brown 7, Wellens 6, Morrison 7, Tunchev 6½, Henderson 7½, Dyer 6, Campbell 6½, Routledge 6, Fryatt 5½ | | Boca Juniors | 3 | 11 João Coimbra, 71p Palermo, 74 Palermo |
| | (4-3-3): Sánchez 6, Olarra 6½, Morel Rodríguez 8, Guarín 7½, Díaz 7½, Ischenko 6, Belluschi 7½, João Coimbra 6, Palermo 7, Sergio García 6½ (63 Ryan 7), Buonanotte 6½ | | Newcastle United | 4 | 3 Saha, 16 Luque, 29 Luque, 84 Luque | | Half-time: | 3-0 | | Referee: | Grabher 6½ | | Attendance: | 44,445 | | Possession: | 48%-52% | | Total shots: | 12-12 | | MoM: | Kuyt |
| | 43 Bowyer, 80 Boa Morte, 85 Hübschman | | (4-3-3): Cerný 7½, Stalteri 6, Shorey 6, Dyer 7, Hübschman 6½, Bramble 6½, Bowyer 6½, Luque 7, Saha 6½, Chopra 5 (78 Davies 6), Boa Morte 6½ | | Spartak | 0 |
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| | (4-3-3): Adler 7, Pavlenko 7, D'Alessandro 7½, Diego 7, Evseev 7, Perrotta 6½, Kuyt 8, Bilyaletdinov 6½, Kerzhakov 6½, Edu 7, Sahar 6½ | | Panathinaikos | 2 | 4 Mantzios, 76og Trémoulinas | | Half-time: | 1-2 | | Referee: | Arena 6 | | Attendance: | 47,005 | | Possession: | 46%-54% | | Total shots: | 14-14 | | MoM: | David | | TV: | live |
| | 53 Mantzios | | (4-3-3): Kowalewski 6½, Vintra 6½, Spyropoulos 6 (70 David 7½), Tziolis 7½, Sarriegi 6½, Wawrzyniak 7, Nilsson 7, Christodoulopoulos 7, Mantzios 6, Simão Júnior 7, Salpigidis 7 | | Bordeaux | 2 | 5 Chamakh, 33 Blake |
| | (4-3-3): Sorin 6, Henrique 6, Trémoulinas 7, Clément 6½, Pavón 7, McCartney 7, Ducasse 6, Canobbio 6, Chamakh 7, Blake 6½, Jussiê 6 | | Parma | 0 |
| | Half-time: | 0-0 | | Referee: | Wiley 6 | | Attendance: | 28,987 | | Possession: | 48%-52% | | Total shots: | 17-9 | | MoM: | Pasquale |
| | 66 Bresciano | | (4-3-3): Manninger 7, Paci 5½, Pasquale 8, Mariga 6½, Loria 7, Castellini 7, Morrone 6½, Bresciano 6½, Budan 7, Parravicini 6½, Reginaldo 6 | | West Ham United | 0 |
| | 27 Ferdinand, 56 Etherington | | (4-3-3): Blazek 7, Lopo 6, Capdevila 7½, Mancienne 7, Neill 7, Ferdinand 7 (60 Cork 6½), Davis 7, Riera 7, Lita 6, Etherington 5½, Afonso Alves 6½ | | Sunderland | 1 | 73 Malbranque | | Half-time: | 0-1 | | Referee: | Atkinson 7 | | Attendance: | 29,698 | | Possession: | 51%-49% | | Total shots: | 9-12 | | MoM: | Marcão |
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| | (4-3-3): Fülop 7, Steinsson 7, Ilunga 8, Etuhu 6½, Higginbotham 7, Collins 6½ (54 Mvoto 6½), Larsson 6, Malbranque 6½, Halford 7, Whitehead 6½, Connolly 5½ | | Palmeiras | 1 | 7 Gökhan |
| | (4-3-3): Hakan 7, Torosidis 6 (73 Danilo 6), Marcão 8½, Marquinhos 6½ (73 Robert 7½), Samba 8, Gökhan 6, Pierre 6, Cleiton Xavier 7½, Deivid 7, Obina 6, Johnson 6 | | Udinese | 0 |
| | Half-time: | 0-1 | | Referee: | Marinov 6½ | | Attendance: | 40,364 | | Possession: | 38%-62% | | Total shots: | 13-11 | | MoM: | Aliev |
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| | (4-3-3): De Sanctis 5, O'Shea 7½, Zenoni 5½, Pedretti 7, Sala 7 (53 Loskov 6½), Maresca 6, Aliadière 7, Mauri 6½, Bonazzoli 7, Konstantinou 5½, Ronaldo 7 (55 Cabral 5) | | Dynamo | 3 | 15 Aliev, 85 Balaban, 90+2 Bangoura |
| | (4-3-3): Shovkovskyi 5½, Rodrigo 7½, Nesmachnyi 6½, Aliev 8½, Kovác 7 (81 Yussuf 6), Mensah 6½, Husev 8, Rotan 7, Bangoura 7½, Nicolita 6½, Balaban 7½ | | Villarreal | 3 | 28 Giménez, 53 José Mari, 73 Giménez | | Half-time: | 1-0 | | Referee: | Øvrebø 6½ | | Attendance: | 22,827 | | Possession: | 60%-40% | | Total shots: | 21-7 | | MoM: | Pedro | | TV: | highlights |
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| | (4-3-3): Butina 7, Arzo 7, Arruabarrena 7½, Anderson 7, Contini 7½, Labaka 5½ (76 Khalili 6), Pedro 8, Giménez 7, Xisco Nadal 7, Mikel Alonso 7, José Mari 6½ | | Rosenborg | 0 |
| | 64 Braaten | | (4-3-3): Johnsen 7, Strand 7, Dorsin 6½, Essediri 6, Koppinen 7, Dramé 6½, Skjelbred 6, Braaten 6, Helstad 6½, Johnsen 6, Iversen 6 | | Zenit | 3 | 7 Pogrebnyak, 35 Krizanac, 53 Faizulin | | Half-time: | 2-0 | | Referee: | Craciun 6 | | Attendance: | 21,922 | | Possession: | 55%-45% | | Total shots: | 18-7 | | MoM: | Sirl |
| | 23 Zyryanov, 45+2 Faizulin, 77 Krizanac | | (4-3-3): Malafeev 7, Adriano 7½, Sirl 8, Zyryanov 7½, Puygrenier 6½, Krizanac 7½, Faizulin 7, Denisov 7, Pogrebnyak 7½, Reinaldo 6, Soares 6½ | | FC Porto | 0 |
| | 14 Bosingwa | | (4-3-3): Paulo Ribeiro 7, Bosingwa 7, Seric 6 (75 Ibson 6), Raul Meireles 7, Dellas 7, Cirillo 6, Paulo Assunção 7½, César Peixoto 6, Cardozo 7½, Koné 6, Németh 6 | | Round 3 | | Newcastle United | 3 | 40 Saha, 50og Dorsin, 61 Luque | | Half-time: | 1-0 | | Referee: | Dinelli 6½ | | Attendance: | 49,665 | | Possession: | 56%-44% | | Total shots: | 16-7 | | MoM: | Hübschman |
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| | (4-3-3): Cerný 7, Stalteri 7, Shorey 6½, Dyer 6½, Hübschman 8, Bramble 6, Bowyer 6, Luque 7, Saha 7½, Mido 5½ (82 Eagles 6), Boa Morte 7 | | Rosenborg | 0 |
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| | (4-3-3): Johnsen 7, Strand 6, Dorsin 7, Essediri 6½, Koppinen 6½, Dramé 6, Skjelbred 7, Braaten 6, Helstad 7, Johnsen 6, Iversen 6 | | Udinese | 0 |
| | Half-time: | 0-0 | | Referee: | Fröhlich 6½ | | Attendance: | 32,363 | | Possession: | 39%-61% | | Total shots: | 7-15 | | MoM: | Kuyt |
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| | (4-3-3): De Sanctis 6½, O'Shea 6½, Zenoni 5½, Pedretti 7, Sala 6½, Maresca 6, Aliadière 5½, Mauri 6½, Bonazzoli 7, Konstantinou 6½, Ronaldo 6 | | Spartak | 0 |
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| | (4-3-3): Adler 7, Pavlenko 6½, D'Alessandro 7, Diego 7½, Evseev 7, Perrotta 6½, Kuyt 8, Bilyaletdinov 7, Kerzhakov 7, Edu 6½, Sahar 6½ | | Sunderland | 1 | 29 Steinsson | | Half-time: | 1-0 | | Referee: | Cinciripini 7 | | Attendance: | 33,667 | | Possession: | 60%-40% | | Total shots: | 13-8 | | MoM: | Ilunga |
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| | (4-3-3): Fülop 7½, Steinsson 7, Ilunga 8½, Etuhu 8, Higginbotham 7½, Collins 6½, Larsson 7, Malbranque 7½, Halford 6½, Whitehead 8, Connolly 5½ | | Dynamo | 0 |
| | 3 Nicolita | | (4-3-3): Shovkovskyi 7, Rodrigo 6½, Nesmachnyi 7½, Aliev 6½, Kovác 7, Mensah 6, Husev 7, Rotan 7, Bangoura 6½, Nicolita 6, Balaban 7 (82 Onyewu 6) |
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